{"id":124679,"date":"2018-02-12T06:30:17","date_gmt":"2018-02-11T22:30:17","guid":{"rendered":"\/\/m.iemloyee.com\/?p=124679"},"modified":"2018-02-11T20:35:33","modified_gmt":"2018-02-11T12:35:33","slug":"nat-commun-%e6%a0%91%e6%9e%9d%e7%8a%b6%e6%a0%b8%e5%a3%b3nifecu%e9%87%91%e5%b1%9e%e9%87%91%e5%b1%9e%e6%b0%a7%e5%8c%96%e7%89%a9%e7%94%b5%e6%9e%81%e7%94%a8%e4%ba%8e%e9%ab%98%e6%95%88%e7%94%b5","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=124679","title":{"rendered":"Nat. Commun.: \u6811\u679d\u72b6\u6838\u58f3NiFeCu\u91d1\u5c5e\/\u91d1\u5c5e\u6c27\u5316\u7269\u7535\u6781\u7528\u4e8e\u9ad8\u6548\u7535\u50ac\u5316\u6c34\u6c27\u5316"},"content":{"rendered":"

\u3010<\/strong>\u5f15\u8a00<\/strong>\u3011<\/strong><\/p>\n

\u5206\u89e3\u6c34\u4ee5\u83b7\u53d6\u6c22\u6c14\u662f\u4e00\u79cd\u53ef\u6301\u7eed\u6280\u672f\uff0c\u540c\u65f6\u6c22\u80fd\u4f5c\u4e3a\u4e00\u79cd\u65e0\u78b3\u71c3\u6599\uff0c\u4e3a\u53ef\u518d\u751f\u80fd\u6e90\u7684\u5316\u5b66\u50a8\u5b58\u63d0\u4f9b\u4e86\u4e00\u6761\u5341\u5206\u5177\u6709\u5438\u5f15\u529b\u7684\u9014\u5f84\u3002\u5728\u5b9e\u9645\u5e94\u7528\u4e2d\uff0c\u7535\u89e3\u6c34\u88c5\u7f6e\u7684\u4e24\u4e2a\u7535\u6781\uff1a\u9633\u6781\u548c\u9634\u6781\u5206\u522b\u8d1f\u8f7d\u6c27\u6790\u51fa\u53cd\u5e94\uff08OER\uff09\u548c\u6790\u6c22\u53cd\u5e94\uff08HER\uff09\u50ac\u5316\u5242\u3002\u50ac\u5316\u5242\u7684\u91cd\u8981\u4f5c\u7528\u662f\u964d\u4f4e\u8d85\u7535\u52bf\u4ee5\u9a71\u52a8OER\u548cHER\u4e24\u4e2a\u534a\u53cd\u5e94\u3002\u5728\u8fd9\u4e24\u4e2a\u534a\u53cd\u5e94\u4e2d\uff0cOER\u52a8\u529b\u5b66\u8f83\u4e3a\u7f13\u6162\uff0c\u5c24\u5176\u9700\u8981\u9ad8\u6548\u7684\u50ac\u5316\u5242\u3002\u5728\u8fc7\u53bb\u7684\u51e0\u5341\u5e74\u4e2d\uff0c\u4eba\u4eec\u4e3a\u5408\u6210\u9ad8\u6548\uff0c\u7a33\u5065\u5e76\u5177\u6709\u6210\u672c\u6548\u76ca\u7684OER\u50ac\u5316\u5242\u505a\u51fa\u4e86\u5de8\u5927\u7684\u52aa\u529b\uff0c\u800c\u6536\u6548\u751a\u5fae\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u8fd1\u65e5\uff0cKTH\u7687\u5bb6\u7406\u5de5\u5b66\u9662\u5408\u4f5c\u65af\u5766\u798f\u5927\u5b66SLAC\u56fd\u5bb6\u52a0\u901f\u5668\u5b9e\u9a8c\u5ba4\uff0c\u5927\u8fde\u7406\u5de5\u5927\u5b66\u7b49\u591a\u5bb6\u5355\u4f4d\uff0c\u5927\u8fde\u7406\u5de5\u5927\u5b66\u5b59\u7acb\u6210<\/strong>\u6559\u6388\u4f5c\u4e3a\u901a\u8baf\u4f5c\u8005\u5728Nat. Commun.\u4e0a\u53d1\u8868\u9898\u4e3a\u201cDendritic core-shell nickel-iron-copper metal\/metal oxide electrode for efficient electrocatalytic water oxidation\u201d\u7684\u6587\u7ae0\u3002\u8be5\u7814\u7a76\u4e3a\u52a0\u901f\u6c34\u6c27\u5316\u53cd\u5e94\u7684\u7f13\u6162\u52a8\u529b\u5b66\uff0c\u63d0\u51fa\u4e86\u4e00\u79cd\u5341\u5206\u5177\u6709\u524d\u666f\u7684\u6811\u72b6\u6838\u58f3\u954d\u94c1\u94dc\u91d1\u5c5e\/\u91d1\u5c5e\u6c27\u5316\u7269\u7535\u6781\uff0c\u4ee5\u7535\u6c89\u79ef\u954d\u94c1\u94dc\u5408\u91d1\u4f5c\u4e3a\u524d\u4f53\uff0c\u5236\u5907\u7684\u6838\u58f3\u578b\u954d\u94c1\u94dc\u7535\u6781\u5177\u6709\u591a\u5b54\u6c27\u5316\u7269\u58f3\u5c42\u548c\u91d1\u5c5e\u6838\u5fc3\u3002\u8fd9\u79cd\u4e09\u91d1\u5c5e\u6838\u58f3\u954d\u94c1\u94dc\u7535\u6781\u5728\u78b1\u6027\u4ecb\u8d28\u4e2d\u5bf9\u6c34\u6c27\u5316\u5177\u6709\u663e\u7740\u6d3b\u6027\uff0c\u572810 mA cm-2<\/sup>\u7684\u7535\u6d41\u5bc6\u5ea6\u4e0b\uff0c\u8fc7\u7535\u4f4d\u4ec5\u4e3a180 mV\u3002\u8be5\u7814\u7a76\u6210\u679c\u662f\u76ee\u524d\u6700\u6709\u524d\u9014\u7684OER\u50ac\u5316\u5242\u4e4b\u4e00\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb<\/strong>\u3011<\/p>\n

\u56fe<\/strong>1 NiFeCu<\/strong>\u6bcd\u4f53\u5408\u91d1\u7535\u955c\u56fe<\/strong><\/p>\n

\"\"<\/p>\n

(a,b) \u6ce1\u6cab\u954d\u4e0aNiFeCu\u5408\u91d1\u7684SEM\u56fe(a\u4e2d\u7684\u6bd4\u4f8b\u5c3a\u4e3a10\u03bcm\uff0cb\u4e2d\u4e3a2\u03bcm);<\/p>\n

(c) NiFeCu\u5c16\u7aef\u7684TEM\u56fe(\u6bd4\u4f8b\u5c3a\u4e3a500 nm);<\/p>\n

(d-g) NiFeCu\u5206\u652f\u9876\u7aef\u7684TEM\u56fe\u548c\u76f8\u5e94\u7684\u5143\u7d20\u5206\u5e03(d\u4e2d\u6bd4\u4f8b\u5c3a\u4e3a100 nm)\uff1b<\/p>\n

\u56fe2<\/strong> CS-NiFeCu\u7535\u6781\u7684\u7535\u955c\u56fe<\/strong><\/p>\n

\"\"<\/p>\n

(a,b) \u6ce1\u6cab\u954d\u4e0a\u7684CS-NiFeCu\u7684SEM\u56fe(a\u4e2d\u6bd4\u4f8b\u5c3a\u4e3a10\u03bcm\uff0cb\u4e2d\u4e3a2\u03bcm)\uff1b<\/p>\n

(c) CS-NiFeCu\u58f3\u4f53\u7684TEM\u56fe\u50cf(\u6bd4\u4f8b\u5c3a\u4e3a50 nm);<\/p>\n

(d-h) CS-NiFeCu\u58f3\u4f53\u7684TEM\u56fe\u50cf\u548c\u76f8\u5e94\u7684\u5143\u7d20\u5206\u5e03\u56fe(d\u4e2d\u7684\u6bd4\u4f8b\u5c3a\u4e3a100 nm\uff09<\/p>\n

\u56fe<\/strong>3 NiFeCu<\/strong>\u4e0e<\/strong>CS-NiFeCu<\/strong>\u7535\u6781\u7684<\/strong>HRTEM<\/strong>\uff0c<\/strong>XPS<\/strong>\u548c<\/strong>XAS<\/strong>\u8868\u5f81<\/strong><\/p>\n

\"\"<\/p>\n

(a) NiFeCu\u5408\u91d1HTEM\u56fe(\u6bd4\u4f8b\u5c3a\u4e3a2 nm)<\/p>\n

(b) CS-NiFeCu\u7535\u6781\u7684HTEM\u56fe(\u63d2\u56fe\u4e3a\u6574\u4e2a\u6750\u6599\u7684\u4f4e\u500d\u653e\u5927\u56fe\uff0c\u6bd4\u4f8b\u5c3a\u4e3a2 nm)<\/p>\n

(c-f) NiFeCu\u4ee5\u53caCS-NiFeCu\u7684XPS\u56fe<\/p>\n

\u5176\u4e2dCS-NiFeCu\u7535\u6781\u8868\u9762(c) Ni 2p(d)Fe 2p(e)Cu 2p\u548c(f)O 1s\u7684XPS\u8c31\u56fe<\/p>\n

(g-i) CS-NiFeCu\u7535\u6781\u4e0eNiO\uff0cFe3<\/sub>O4<\/sub>\uff0cFe2<\/sub>O3<\/sub>\u548cCuO\u7684\u5f52\u4e00\u5316\u8f6fXAS\u56fe;<\/p>\n

\u56fe<\/strong>4 OER<\/strong>\u7684\u7535\u5316\u5b66\u8868\u5f81<\/strong><\/p>\n

\"\"<\/p>\n

(a) CS-NiFeCu\uff0cNiFe LDH\uff0cNiFe\uff0cNiCu\u7535\u6781\u548c\u6ce1\u6cab\u954d\u7684\u6781\u5316\u66f2\u7ebf;<\/p>\n

(b) \u4e0d\u540c\u7535\u6781\u8fbe\u5230j = 10 mA cm-2<\/sup>\u6240\u9700\u7684\u8d85\u7535\u52bf\uff1b<\/p>\n

(c) \u4e0d\u540c\u7535\u6781\u5728\u03b7= 250 mV\u65f6\u7684\u7535\u6d41\u5bc6\u5ea6\uff1b<\/p>\n

(d) \u6ce1\u6cab\u954d\uff0cNiCu\uff0cNiFe LDH\uff0cNiFe\u548cCS-NiFeCu\u7535\u6781\u7684Tafel\u56fe\uff1b<\/p>\n

(e) \u4ee5CS-NiFeCu\u4e3a\u50ac\u5316\u5242\uff0c1.0M KOH\u4ecb\u8d28\u4e2d\u5404\u79cd\u7535\u6d41\u5bc6\u5ea6\u4e0bOER\u7684\u8ba1\u65f6\u7535\u4f4d\u6d4b\u91cf\uff1b<\/p>\n

(f) \u5728j=10 mA cm-2<\/sup>\u548cj=20 mA cm-2<\/sup>\u4e0b\u5ef6\u957f\u8ba1\u65f6\u7535\u4f4d\u6d4b\u91cf20h;<\/p>\n

\u56fe<\/strong>5 <\/strong>\u5f71\u54cd\u7535\u6781\u7535\u5316\u5b66\u6d3b\u6027\u9762\u79ef\u7684\u56e0\u7d20<\/strong><\/p>\n

\"\"<\/p>\n

(a) CS-NiFeCu\u548cNiFe LDH\u9633\u6781\u7684\u7535\u5bb9j vs\u626b\u63cf\u901f\u7387;<\/p>\n

(b) NiCu\uff0cNiFe\u548cNi\u9633\u6781\u7684\u7535\u5bb9j vs\u626b\u63cf\u901f\u7387–\u5bf9\u4e8ea\u548cb\uff0c\u7ebf\u6027\u659c\u7387\u76f8\u5f53\u4e8e\u53cc\u5c42\u7535\u5bb9Cdl<\/sub>\u7684\u4e24\u500d\uff1b<\/p>\n

(c) CS-NiFeCux<\/sub>\u7535\u6781\u7684\u6781\u5316\u66f2\u7ebf(CS-NiFeCux\u7535\u6781\u7684\u5236\u5907\u65b9\u6cd5\u4e0e\u7535\u6c89\u79ef\u7535\u89e3\u6db2\u4e2d\u6052\u5b9a\u6d53\u5ea6\u7684Ni2+<\/sup>\uff0880 mM\uff09\u548cFe3+<\/sup>\uff0825 mM\uff09\u4ee5\u53ca\u4e0d\u540c\u6d53\u5ea6\u7684Cu2+<\/sup>\uff080-60 mM\uff09\u7684CS-NiFeCu\u76f8\u540c)\uff1b<\/p>\n

(d) CS-NiFeCux<\/sub>\u7684\u9633\u6781\u7535\u5bb9(\u63d2\u56fe\u4e3aj=10 mA cm-2<\/sup>\u6240\u9700\u7684\u8fc7\u7535\u538b)\uff1b\u00a0<\/strong><\/p>\n

\u56fe<\/strong>6 pH<\/strong>\u4f9d\u8d56\u7684<\/strong>OER<\/strong>\u6d3b\u6027<\/strong><\/p>\n

\"\"<\/p>\n

(a,b) CS-NiFeCu\u548cNiFe\u7535\u6781\u4ee510mVs-1<\/sup>\u8bb0\u5f55\u4eceO2<\/sub>\u9971\u548c\u76840.032M KOH\uff08pH 12.5\uff09\u52301M KOH\uff08pH 14\uff09\u7684\u5faa\u73af\u4f0f\u5b89\u6d4b\u91cf;<\/p>\n

(c) iR\u6821\u6b63\u540e1.55 V(vsRHE)\u7684\u7279\u5b9aOER\u6d3b\u6027\uff08\u7535\u6d41\u5bc6\u5ea6\uff09\u4e0epH\u7684\u51fd\u6570\u5173\u7cfb;<\/p>\n

\u56fe<\/strong>7 <\/strong>\u52a8\u529b\u5b66\u5f71\u54cd\u56e0\u7d20<\/strong><\/p>\n

\"\"<\/p>\n

(a)CS-NiFex<\/sub>Cu\u9633\u6781\u7684\u6781\u5316\u66f2\u7ebf;<\/p>\n

(b)\u57281 M KOH\u4ecb\u8d28\u4e2dCS-NiFex<\/sub>Cu\u9633\u6781\u8fbe\u5230j = 10\u548c100 mA cm-2<\/sup>\u6240\u9700\u7684\u8d85\u7535\u52bf\uff1b<\/p>\n

(c) CS-NiFexCu\u9633\u6781\u7684CdI<\/sub>;<\/p>\n

(d)\u57281 M KOH\u4e2d\u7684CS-NiFexCu\u7535\u6781\u7684Tafel\u659c\u7387\uff1b<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n

\u8be5\u7814\u7a76\u4ee5\u7535\u6c89\u79efNiFeCu\u5408\u91d1\u4e3a\u524d\u9a71\u4f53\uff0c\u53d1\u73b0\u4e09\u91d1\u5c5e\u57fa\u5408\u91d1\u53ef\u4ee5\u8f6c\u5316\u4e3a\u7528\u4e8eOER\u7684\u6838\u58f3\u72b6\u91d1\u5c5e\/\u91d1\u5c5e\u6c27\u5316\u7269\u50ac\u5316\u5242CS-NiFeCu\u3002CS-NiFeCu\u5bf9\u6c34\u6c27\u5316\u7684\u9ad8\u50ac\u5316\u6027\u80fd\u53ef\u4ee5\u5f52\u56e0\u4e8eNi\uff0cFe\u548cCu\u4e4b\u95f4\u7684\u534f\u540c\u4f5c\u7528\u3002\u5728CS-NiFeCu\u7535\u6781\u4e2d\u7684\u4e09\u79cd\u91d1\u5c5e\u5143\u7d20\u5728\u901a\u8fc7\u63d0\u9ad8\u7535\u6781\u6d3b\u6027\u9762\u79ef\u548c\u5185\u5728\u50ac\u5316\u6d3b\u6027\u4e2d\u8d77\u51b3\u5b9a\u6027\u4f5c\u7528\u3002CS-NiFeCu\u4f5c\u4e3a\u5de5\u4f5c\u7535\u6781\uff0c\u57281 M KOH\u78b1\u6027\u6eb6\u6db2\u4e2d\uff0c\u5728\u8fc7\u7535\u4f4d\u4ec5\u4e3a180 mV\u7684\u60c5\u51b5\u4e0b\u4fbf\u8fbe\u5230\u4e8610 mA cm-2<\/sup>\u7684\u7535\u6d41\u5bc6\u5ea6\uff0c\u8be5\u50ac\u5316\u5242\u662f\u8fc4\u4eca\u4e3a\u6b62\u62a5\u9053\u7684\u6d3b\u6027\u6700\u4f73\u7684OER\u50ac\u5316\u5242\u4e4b\u4e00\u3002\u540c\u65f6\u672c\u6587\u6240\u8ff0\u7684\u7eb3\u7c73\u5408\u6210\u65b9\u6cd5\u4e5f\u53ef\u80fd\u9002\u7528\u4e8e\u5f00\u53d1\u5176\u4ed6\u5408\u91d1\u57fa\u7eb3\u7c73\u6750\u6599\u4f5c\u4e3aOER\u6216\u5176\u4ed6\u7535\u50ac\u5316\u8fc7\u7a0b\u7684\u50ac\u5316\u5242\u3002<\/p>\n

\u00a0<\/strong>\u6587\u732e\u94fe\u63a5<\/strong>\uff1aDendritic core-shell nickel-iron-copper metal\/metal oxide electrode for efficient electrocatalytic water oxidation<\/a> (Nature Communication<\/em>, 2018 ,DOI: 10.1038\/s41467-017-02429-9)<\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u7f16\u8f91\u90e8\u8fde\u5a77\u5a77\u7f16\u8bd1\uff0c\u70b9\u6211\u52a0\u5165\u6750\u6599\u4eba\u7f16\u8f91\u90e8<\/a>\u3002<\/p>\n

\u00a0<\/strong>\u6750\u6599\u6d4b\u8bd5\uff0c\u6570\u636e\u5206\u6790\uff0c<\/strong>\u4e0a\u6d4b\u8bd5\u8c37<\/strong><\/a>\uff01<\/strong><\/p>\n","protected":false},"excerpt":{"rendered":"

\u3010\u5f15\u8a00\u3011 \u5206\u89e3\u6c34\u4ee5\u83b7\u53d6\u6c22\u6c14\u662f\u4e00\u79cd\u53ef\u6301\u7eed\u6280\u672f\uff0c\u540c\u65f6\u6c22\u80fd\u4f5c\u4e3a\u4e00\u79cd\u65e0\u78b3\u71c3\u6599\uff0c\u4e3a\u53ef\u518d\u751f\u80fd\u6e90\u7684\u5316\u5b66\u50a8\u5b58\u63d0\u4f9b\u4e86\u4e00\u6761\u5341\u5206\u5177\u6709\u5438\u5f15\u529b\u7684\u9014\u5f84\u3002\u5728\u5b9e\u9645\u5e94\u7528\u4e2d\uff0c\u7535\u89e3\u6c34\u88c5\u7f6e\u7684\u4e24\u4e2a\u7535\u6781\uff1a…<\/p>\n","protected":false},"author":5849,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215,2],"tags":[2813,2811,2812],"class_list":["post-124679","post","type-post","status-publish","format-standard","hentry","category-jiedu","category-keji","tag-2813","tag-2811","tag-2812"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/124679"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/5849"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=124679"}],"version-history":[{"count":8,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/124679\/revisions"}],"predecessor-version":[{"id":125718,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/124679\/revisions\/125718"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=124679"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=124679"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=124679"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}