{"id":123866,"date":"2018-02-05T14:00:08","date_gmt":"2018-02-05T06:00:08","guid":{"rendered":"\/\/m.iemloyee.com\/?p=123866"},"modified":"2018-02-02T22:27:40","modified_gmt":"2018-02-02T14:27:40","slug":"adv-energy-mater-%e5%8f%af%e8%a7%81%e5%85%89%e4%bd%8e%e5%90%ab%e9%87%8f%e7%89%ba%e7%89%b2%e8%af%95%e5%89%82%e4%b8%8bautio2-g-c3n4-%e5%85%89%e5%82%ac%e5%8c%96%e5%88%b6%e6%b0%a2%e6%80%a7%e8%83%bd","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=123866","title":{"rendered":"Adv. Energy Mater. : \u53ef\u89c1\u5149\u4f4e\u542b\u91cf\u727a\u7272\u8bd5\u5242\u4e0bAu\/TiO2-g-C3N4 \u5149\u50ac\u5316\u5236\u6c22\u6027\u80fd\u589e\u5f3a"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n

\u77f3\u58a8\u76f8\u6c2e\u5316\u78b3(g-C3<\/sub>N4<\/sub>)\u7531\u4e8e\u5176\u5ec9\u4ef7\u3001\u6613\u5f97\u7684\u4f18\u70b9\uff0c\u5e7f\u6cdb\u5e94\u7528\u4e8e\u5149\u50ac\u5316\u9886\u57df\uff0c\u4f46\u7531\u4e8e\u5176\u5149\u751f\u8f7d\u6d41\u5b50\u6613\u4e8e\u590d\u5408\uff0c\u9650\u5236\u4e86\u5176\u5149\u50ac\u5316\u6d3b\u6027\u8fdb\u4e00\u6b65\u63d0\u5347\u3002\u7814\u7a76\u4eba\u5458\u5df2\u63d0\u51fa\u90e8\u5206\u7b56\u7565\u4ee5\u671f\u63d0\u5347\u5176\u5149\u50ac\u5316\u6d3b\u6027\uff0c\u5982\u4e0e\u5176\u4ed6\u534a\u5bfc\u4f53\u5f62\u6210\u8fdb\u884c\u5f02\u8d28\u7ed3\uff0c\u5373\u4ee5g-C3<\/sub>N4<\/sub>\u5bf9\u5176\u8fdb\u884c\u654f\u5316\u83b7\u5f97\u53ef\u89c1\u5149\u5438\u6536\u6216\u63d0\u5347\u8f7d\u6d41\u5b50\u5206\u79bb\u6027\u80fd\u3002\u6b64\u5916\uff0c\u5728g-C3<\/sub>N4<\/sub>\u4e0a\u8d1f\u8f7d\u5404\u79cd\u91d1\u5c5e\u4e5f\u662f\u53ef\u884c\u7b56\u7565\u4e4b\u4e00\uff0c\u53ef\u8bf1\u53d1\u79ef\u6781\u7684\u8096\u7279\u57fa\u52bf\u5792\u6548\u5e94\uff0c\u6709\u6548\u5730\u6355\u83b7\u5149\u751f\u7535\u5b50\uff0c\u4ece\u800c\u63d0\u9ad8\u8f7d\u6d41\u5b50\u5206\u79bb\u3002\u5149\u50ac\u5316\u5236\u6c22\u8fc7\u7a0b\u4e2d\u901a\u5e38\u9700\u8981\u4f7f\u7528\u727a\u7272\u8bd5\u5242\u6355\u83b7\u7a7a\u7a74\uff0c\u4ee5\u63d0\u5347\u8f7d\u6d41\u5b50\u5206\u79bb\u3002\u7136\u800c\uff0c\u7406\u60f3\u72b6\u6001\u4e0b\u5e94\u4e0d\u4f7f\u7528\u6216\u4f7f\u7528\u542b\u91cf\u975e\u5e38\u4f4e\u7684\u727a\u7272\u8bd5\u5242\uff0c\u4ee5\u964d\u4f4e\u6210\u672c\u548c\u8fc7\u7a0b\u4e2d\u7684\u78b3\u6392\u653e\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u6cd5\u56fd\u65af\u7279\u62c9\u65af\u5821\u5927\u5b66Val\u00e9rie Keller\u7814\u7a76\u5458(\u901a\u8baf\u4f5c\u8005)\u7b49<\/strong>\u8bbe\u8ba1\u4f18\u5316\u4e86\u4e09\u7ec4\u5206Au\/TiO2<\/sub>-g-C3<\/sub>N4<\/sub>\u7eb3\u7c73\u590d\u5408\u6750\u6599\u5149\u50ac\u5316\u5242\uff0c\u5e76\u5728Adv. Energy Mater.<\/strong>\u4e0a\u53d1\u8868\u4e86\u9898\u4e3a\u201cAu\/TiO2<\/sub>-g-C3<\/sub>N4<\/sub> Nanocomposites for Enhanced Photocatalytic H2<\/sub> Production from Water under Visible Light Irradiation with Very Low Quantities of Sacrificial Agents<\/strong>\u201d\u7684\u7814\u7a76\u8bba\u6587\u3002\u4e0a\u8ff0\u4e09\u7ec4\u5206\u5149\u50ac\u5316\u5242\u80fd\u591f\u5728\u53ef\u89c1\u5149\u7167\u5c04\u4ee5\u53ca\u4f7f\u7528\u542b\u91cf\u975e\u5e38\u4f4e\u7684\u727a\u7272\u8bd5\u5242\u6761\u4ef6\u4e0b\u6709\u6548\u5730\u4ece\u6c34\u4e2d\u5236\u6c22\u3002\u76f8\u6bd4Au\/TiO2<\/sub>\u548cAu\/g-C3<\/sub>N4<\/sub>\u6750\u6599\uff0c\u4e09\u7ec4\u5206\u6750\u6599\u5149\u50ac\u5316\u6027\u80fd\u589e\u5f3a\u5e94\u5f52\u56e0\u4e8e\u4e09\u7ec4\u5206\u4e4b\u95f4\u9ad8\u6548\u7684\u7ec4\u88c5\u548c\u754c\u9762\u7684\u534f\u540c\u4f5c\u7528\u3002\u5728\u53ef\u89c1\u5149\u7167\u5c04\u4ee5\u53ca\u4f7f\u7528\u542b\u91cf\u975e\u5e38\u4f4e\u7684\u727a\u7272\u8bd5\u5242(\u22641 vol%)\u6761\u4ef6\u4e0b\uff0c\u590d\u5408\u5149\u50ac\u5316\u5242\u7684\u5236\u6c22\u901f\u7387\u53ef\u8fbe\u5230350 \u03bcmol\u00b7h-1<\/sup>\u00b7gcatalyst<\/sub>-1<\/sup>\uff0c\u5176\u6d3b\u6027\u8fdc\u8fdc\u9ad8\u4e8e\u76ee\u524d\u6587\u732e\u62a5\u9053\u7684\u503c\u3002<\/p>\n

\u3010\u56fe\u6587\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u56fe1 \u4e09\u7ec4\u5206\u5149\u50ac\u5316\u5242\u7684\u5f62\u8c8c\u8868\u5f81<\/strong><\/p>\n

\"\"<\/p>\n

a-d) 0.5 wt% Au\/(TiO2<\/sub>-g-C3<\/sub>N4<\/sub>) (95\/5)\u7684TEM\u56fe\u50cf\uff0c\u5176\u4e2d\u56fec\u4e3ag-C3<\/sub>N4<\/sub>\u7684TEM \u56fe\u50cf\uff1b<\/p>\n

e) Au NPs\u5c3a\u5bf8\u5206\u5e03\u76f4\u65b9\u56fe\uff1b<\/p>\n

f) 0.5 wt% Au\/(TiO2<\/sub>-g-C3<\/sub>N4<\/sub>) (95\/5)\u7684HRTEM\u56fe\u50cf\u3002<\/p>\n

\u56fe2 \u4e09\u7ec4\u5206\u5149\u50ac\u5316\u5242\u7684\u8868\u9762\u5143\u7d20\u5206\u6790<\/strong><\/p>\n

\"\"<\/p>\n

a) \u7eafTiO2<\/sub>\u548c0.5 wt% Au\/(TiO2<\/sub>-g-C3<\/sub>N4<\/sub>)\u7684Ti 2p XPS\u5149\u8c31\uff1b<\/p>\n

b) \u7eafg-C3<\/sub>N4<\/sub>\u548c0.5 wt% Au\/(TiO2<\/sub>-g-C3<\/sub>N4<\/sub>) (95\/5)\u7684N 1s XPS\u5149\u8c31\uff1b<\/p>\n

c) \u7eafg-C3<\/sub>N4<\/sub>\u548c0.5 wt% Au\/(TiO2<\/sub>-g-C3<\/sub>N4<\/sub>) (95\/5)\u7684C 1s XPS\u5149\u8c31\uff1b<\/p>\n

d) TiO2<\/sub>-g-C3<\/sub>N4<\/sub>\u590d\u5408\u6750\u6599\u7684\u80fd\u5e26\u7ed3\u6784\u3002<\/p>\n

\u56fe3 \u4e09\u7ec4\u5206\u5149\u50ac\u5316\u5242\u7684\u7535\u5b50\u8fc1\u79fb\u80fd\u529b\u8868\u5f81<\/strong><\/p>\n

\"\"<\/p>\n

a,b,c) \u4e0d\u540c\u50ac\u5316\u5242\u5728360 nm\u3001450 nm\u548c550 nm\u7684TRMC\u4fe1\u53f7\uff1b<\/p>\n

d) 0.5 wt% Au\/TiO2<\/sub>-g-C3<\/sub>N4<\/sub> (95\/5)\u5728360 nm\u3001450 nm\u3001530 nm\u3001550 nm\u548c570 nm\u5904\u7684\u4fe1\u53f7\u6bd4\u8f83\u3002<\/p>\n

\u56fe4 \u4e09\u7ec4\u5206\u5149\u50ac\u5316\u5242\u7684\u5149\u50ac\u5316\u5236\u6c22\u6027\u80fd(1)<\/strong><\/p>\n

\"\"<\/p>\n

a,b) \u592a\u9633\u5149\/\u53ef\u89c1\u5149\u4e0b\uff0c\u50ac\u5316\u5242\u5236\u6c22\u901f\u7387\u968f\u7532\u9187\u52a0\u5165\u91cf\u7684\u53d8\u5316\uff1b<\/p>\n

c) \u592a\u9633\u5149\/\u53ef\u89c1\u5149\u4e0b\uff0c\u50ac\u5316\u5242\u4ee510 mL TEOA (1 vol%)\u4e3a\u727a\u7272\u8bd5\u5242\u7684\u5236\u6c22\u901f\u7387\u3002<\/p>\n

\u56fe5 \u4e09\u7ec4\u5206\u5149\u50ac\u5316\u5242\u7684\u5149\u50ac\u5316\u5236\u6c22\u6027\u80fd(2)<\/strong><\/p>\n

\"\"<\/p>\n

a,b) \u592a\u9633\u5149\/\u53ef\u89c1\u5149\u4e0b\uff0c\u4ee51 vol%\u7532\u9187\u4e3a\u727a\u7272\u8bd5\u5242\u7684\u5236\u6c22\u79ef\u7d2f\u91cf\uff1b<\/p>\n

c,d) \u592a\u9633\u5149\/\u53ef\u89c1\u5149\u4e0b\uff0c\u4ee51 vol% TEOA\u4e3a\u727a\u7272\u8bd5\u5242\u7684\u5236\u6c22\u79ef\u7d2f\u91cf\u3002<\/p>\n

\u56fe6 \u4e09\u7ec4\u5206\u5149\u50ac\u5316\u5242\u7684\u5149\u50ac\u5316\u5236\u6c22\u6027\u80fd(3)<\/strong><\/p>\n

\"\"<\/p>\n

a,b) \u592a\u9633\u5149\/\u53ef\u89c1\u5149\u4e0b\uff0c0.5 wt% Au\/(TiO2<\/sub>-g-C3<\/sub>N4<\/sub>) (95\/5)\u4ee51 vol%\u7532\u9187\u4e3a\u727a\u7272\u8bd5\u5242\u7684\u5faa\u73af\u5b9e\u9a8c\uff1b<\/p>\n

c) \u592a\u9633\u5149\u4e0b\uff0c0.5 wt% Au\/(TiO2<\/sub>-g-C3<\/sub>N4<\/sub>) (95\/5)\u4ee510 mL TEOA\u4e3a\u727a\u7272\u8bd5\u5242\u7684\u5faa\u73af\u5b9e\u9a8c\u3002<\/p>\n

\u56fe7 \u4e09\u7ec4\u5206\u5149\u50ac\u5316\u5242\u7684\u5149\u50ac\u5316\u5236\u6c22\u673a\u7406\u56fe<\/strong><\/p>\n

\"\"<\/p>\n

\u4e09\u7ec4\u5206\u5149\u50ac\u5316\u5242\u7684\u5149\u50ac\u5316\u5236\u6c22\u673a\u7406\u56fe\u3002<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n

\u7814\u7a76\u4eba\u5458\u5bf9TiO2<\/sub>\u3001g-C3<\/sub>N4<\/sub>\u548cAu NPs\u8fdb\u884c\u4f18\u5316\u7ec4\u5408\u5f62\u6210\u4e86Au\/(TiO2<\/sub>-g-C3<\/sub>N4<\/sub>)\u590d\u5408\u6750\u6599\uff0c\u4e0a\u8ff0\u4e09\u7ec4\u5206\u5149\u50ac\u5316\u5242\u80fd\u591f\u5728\u53ef\u89c1\u5149\u7167\u5c04\u4ee5\u53ca\u4f7f\u7528\u542b\u91cf\u975e\u5e38\u4f4e\u7684\u727a\u7272\u8bd5\u5242\u6761\u4ef6\u4e0b\u6709\u6548\u5730\u4ece\u6c34\u4e2d\u5236\u6c22\uff0c\u5145\u5206\u5229\u7528\u4e86\u4e09\u7ec4\u5206\u5404\u81ea\u7279\u6027\u7684\u4f18\u52bf\u3002\u4e09\u7ec4\u5206\u4e4b\u95f4\u9ad8\u6548\u7684\u7ec4\u88c5\u548c\u754c\u9762\u7684\u534f\u540c\u4f5c\u7528\u4f7f\u5f97\u590d\u5408\u6750\u6599\u7684\u53ef\u89c1\u5149\u5438\u6536\u63d0\u5347\uff0c\u5149\u751f\u8f7d\u6d41\u5b50\u590d\u5408\u51e0\u7387\u964d\u4f4e\u3002\u57fa\u4e8e\u4e0a\u8ff0\u534f\u540c\u4f5c\u7528\uff0c\u5df2\u5b9e\u73b0\u53ef\u89c1\u5149\u7167\u5c04\u4e0b\u9ad8\u6548\u6c34\u4e2d\u5149\u50ac\u5316\u5236\u6c22\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1aAu\/TiO2<\/sub>-g-C3<\/sub>N4<\/sub> Nanocomposites for Enhanced Photocatalytic H2<\/sub> Production from Water under Visible Light Irradiation with Very Low Quantities of Sacrificial Agents<\/a><\/strong> (Adv. Energy Mater., 2018, DOI: 10.1002\/aenm.201702142)<\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u7f16\u8f91\u90e8\u65b0\u80fd\u6e90\u5c0f\u7ec4abc940504\u7f16\u8bd1\u6574\u7406\uff0c\u53c2\u4e0e\u65b0\u80fd\u6e90\u8bdd\u9898\u8ba8\u8bba\u8bf7\u52a0\u5165\u201c\u6750\u6599\u4eba\u65b0\u80fd\u6e90\u6750\u6599\u4ea4\u6d41\u7fa4 422065953\u201d\u3002<\/p>\n

\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1aRDD-2011-CHERISH\uff0c\u4efb\u4e39\u4e39\uff0c\u6211\u4eec\u4f1a\u9080\u8bf7\u5404\u4f4d\u8001\u5e08\u52a0\u5165\u4e13\u5bb6\u7fa4\u3002<\/strong><\/p>\n

\u6750\u6599\u725b\u7f51\u4e13\u6ce8\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u53ca\u884c\u4e1a\u8fdb\u5c55\uff0c\u5982\u679c\u60a8\u5bf9\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u8fdb\u5c55\uff0c\u89e3\u8bfb\u9ad8\u6c34\u5e73\u6587\u7ae0\u6216\u662f\u8bc4\u8ff0\u884c\u4e1a\u6709\u5174\u8da3\uff0c\u70b9\u6211\u52a0\u5165\u7f16\u8f91\u90e8<\/a><\/strong>\u3002\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1tougao@cailiaoren.com\u3002<\/p>\n

\u4eea\u5668\u8bbe\u5907\u3001\u8bd5\u5242\u8017\u6750\u3001\u6750\u6599\u6d4b\u8bd5\u3001\u6570\u636e\u5206\u6790\uff0c\u627e\u6750\u6599\u4eba\u3001\u4e0a\u6d4b\u8bd5\u8c37<\/a><\/strong>\uff01<\/p>\n","protected":false},"excerpt":{"rendered":"

\u3010\u5f15\u8a00\u3011 \u77f3\u58a8\u76f8\u6c2e\u5316\u78b3(g-C3N4)\u7531\u4e8e\u5176\u5ec9\u4ef7\u3001\u6613\u5f97\u7684\u4f18\u70b9\uff0c\u5e7f\u6cdb\u5e94\u7528\u4e8e\u5149\u50ac\u5316\u9886\u57df\uff0c\u4f46\u7531\u4e8e\u5176\u5149\u751f\u8f7d\u6d41\u5b50\u6613\u4e8e\u590d\u5408\uff0c\u9650\u5236\u4e86\u5176\u5149\u50ac\u5316\u6d3b\u6027\u8fdb\u4e00\u6b65\u63d0\u5347\u3002\u7814\u7a76\u4eba\u5458\u5df2\u63d0\u51fa\u90e8\u5206…<\/p>\n","protected":false},"author":4931,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[2804],"class_list":["post-123866","post","type-post","status-publish","format-standard","hentry","category-jiedu","tag-2804"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/123866"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/4931"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=123866"}],"version-history":[{"count":7,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/123866\/revisions"}],"predecessor-version":[{"id":124635,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/123866\/revisions\/124635"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=123866"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=123866"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=123866"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}