{"id":12358,"date":"2016-05-10T08:00:01","date_gmt":"2016-05-10T00:00:01","guid":{"rendered":"\/\/m.iemloyee.com\/?p=12358"},"modified":"2016-05-10T09:12:03","modified_gmt":"2016-05-10T01:12:03","slug":"nature-material%ef%bc%9a%e5%ba%b7%e5%a5%88%e5%b0%94%e5%a4%a7%e5%ad%a6%e9%80%9a%e8%bf%87%e6%b7%bb%e5%8a%a0%e6%b0%a8%e5%9f%ba%e9%85%b8%e8%b0%90%e8%b0%83%e4%bc%98%e5%8c%96%e6%96%b9%e8%a7%a3%e7%9f%b3","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=12358","title":{"rendered":"Nature materials\uff1a\u5eb7\u5948\u5c14\u5927\u5b66\u901a\u8fc7\u6dfb\u52a0\u6c28\u57fa\u9178\u8c10\u8c03\u4f18\u5316\u65b9\u89e3\u77f3\u786c\u5ea6"},"content":{"rendered":"

\u6210\u679c\u7b80\u4ecb\uff1a<\/strong><\/p>\n

\u7ed3\u6784\u578b\u751f\u7269\u77ff\u7269\u4e00\u822c\u4e3a\u6709\u673a\/\u65e0\u673a\u590d\u5408\u6750\u6599\uff0c\u62e5\u6709\u663e\u8457\u7684\u673a\u68b0\u6027\u80fd\u3002\u7136\u800c\uff0c\u5bf9\u4e8e\u5176\u7ed3\u6784-\u6027\u80fd\u4e24\u8005\u95f4\u7684\u5173\u7cfb\uff0c\u5373\u4f7f\u662f\u6700\u7b80\u5355\u7684\u5355\u5143\u2014\u2014\u542b\u5185\u5d4c\u5927\u5206\u5b50\u7684\u77ff\u7269\u5355\u6676\u6750\u6599\uff0c\u79d1\u5b66\u5bb6\u4eec\u4f9d\u7136\u77e5\u4e4b\u751a\u5c11\u3002<\/p>\n

\u8fd1\u671f\uff0c\u5eb7\u5948\u5c14\u5927\u5b66\u4e0e\u82f1\u56fd\u5229\u5179\u5927\u5b66\u7684\u7814\u7a76\u8005\u5728\u5e38\u89c4\u5355\u6676\u65b9\u89e3\u77f3\u4e2d\u5206\u522b\u63ba\u6742\u7518\u6c28\u9178\uff08Gly\uff09\uff080-7mol%\uff09\u4ee5\u53ca\u5929\u51ac\u6c28\u9178\uff08Asp\uff09\uff080-4mol%\uff09\u8fdb\u884c\u6df1\u5165\u7814\u7a76\uff0c\u9610\u8ff0\u4e86\u751f\u7269\u77ff\u65b9\u89e3\u77f3\u62e5\u6709\u72ec\u7279\u5f3a\u5ea6\u7684\u539f\u56e0\u3002\u5b9e\u9a8c\u4e2d\uff0cXRD\u548c\u5206\u5b50\u52a8\u529b\u5b66\u6a21\u62df\u5206\u6790\u4e86\u65b9\u89e3\u77f3\u5185\u90e8\u7684\u6676\u683c\u7578\u53d8\uff0c\u56fa\u6001\u6838\u78c1\u5171\u632f\u8868\u660e\u6c28\u57fa\u9178\u4ee5\u5355\u5206\u5b50\u5f62\u5f0f\u72ec\u7acb\u5b58\u5728\u4e8e\u65b9\u89e3\u77f3\u6676\u4f53\u5185\u3002\u672c\u6b21\u7814\u7a76\u8bc1\u5b9e\u4e86\u65b9\u89e3\u77f3\u786c\u5ea6\u4f1a\u968f\u6c28\u57fa\u9178\u542b\u91cf\u7684\u589e\u52a0\u800c\u589e\u52a0\uff0c\u6700\u7ec8\u8fbe\u5230\u540c\u7c7b\u6750\u6599\u8f83\u9ad8\u786c\u5ea6\u6c34\u5e73\uff08\u5927\u7ea6\u63d0\u9ad8\u4e24\u500d\uff09\u3002\u7814\u7a76\u8005\u4f7f\u7528\u4f4d\u9519\u9489\u624e\u6a21\u578b\u8fdb\u884c\u89e3\u91ca\uff0c\u4ed6\u4eec\u8ba4\u4e3a\u7531\u4e8e\u7834\u574f\u5206\u5b50\u4e2d\u5171\u4ef7\u952e\u9700\u8981\u989d\u5916\u529b\u4ece\u800c\u81f4\u4f7f\u65b9\u89e3\u77f3\u5f3a\u5ea6\u589e\u52a0\u3002<\/p>\n

\u8fd9\u9879\u6210\u679c\u5bf9\u5355\u6676\u751f\u7269\u77ff\u7269\u7684\u673a\u68b0\u6027\u80fd\u7814\u7a76\u6709\u91cd\u8981\u610f\u4e49\uff0c\u53e6\u5916\u4e5f\u4f7f\u5f97\u8c10\u8c03\u6750\u6599\u6027\u80fd\u6216\u6210\u53ef\u80fd\u3002<\/p>\n

\u56fe\u6587\u5bfc\u8bfb\uff1a<\/strong><\/p>\n

\u56fe1\uff1a\u968f\u524d\u9a71\u4f53\u6eb6\u6db2\u4e2d\u6c28\u57fa\u9178\u542b\u91cf\u53ca\u6210\u5206\u4e0d\u540c\uff0c\u6700\u7ec8\u65b9\u89e3\u77f3\u7684\u6676\u4f53\u5f62\u8c8c\u8868\u5f81<\/strong><\/span><\/p>\n

\"nmat4631-f1\"<\/p>\n

a-c\uff1a\u524d\u9a71\u4f53\u6eb6\u6db2\u4e2d\u53ea\u542b\u5929\u51ac\u6c28\u9178(Asp)\uff0c\u6d53\u5ea6\u5206\u522b\u4e3a5\u2009mM (a)\u300120\u2009mM (b)\u300150\u2009mM (c)\uff1b
\nd-f\uff1a\u524d\u9a71\u4f53\u6eb6\u6db2\u4e2d\u53ea\u542b\u7518\u6c28\u9178(Gly)\uff0c\u6d53\u5ea6\u5206\u522b\u4e3a10\u2009mM (d)\u3001100\u2009mM (e)\u3001200\u2009mM (f)\u3002<\/p>\n

\u56fe2\uff1a\u88ab\u963b\u585e\u5728\u65b9\u89e3\u77f3\u6676\u4f53\u5185\u7684Asp\u548cGly\u542b\u91cf\u4e0e\u524d\u9a71\u4f53\u6eb6\u6db2\u4e2d\u5bf9\u5e94\u6d53\u5ea6\u5173\u7cfb<\/strong><\/span><\/p>\n

\u8bf4\u660e<\/strong>\uff1a<\/span>\u4e0b\u6807inc\u8868\u793a\u65b9\u89e3\u77f3\u6676\u4f53\uff0csol\u8868\u793a\u524d\u9a71\u4f53\uff08\u521d\u59cb\uff09\u6eb6\u6db2\uff1bAA\u8868\u793a\u6c28\u57fa\u9178\uff0cAsp\u8868\u793a\u5929\u51ac\u6c28\u9178\uff1bGly\u8868\u793a\u7518\u6c28\u9178\u3002\u5373[AA]inc\u8868\u793a\u6676\u4f53\u4e2d\u6c28\u57fa\u9178\u542b\u91cf\uff0c[AA]sol\u8868\u793a\u521d\u59cb\u6eb6\u6db2\u4e2d\u6c28\u57fa\u9178\u6d53\u5ea6\uff0c\u4e0b\u540c\u3002\u672c\u5b9e\u9a8c\u521d\u59cb\u6eb6\u6db2\u4e2d[Ca2+]sol = 10\u2009mM\u3002\u5185\u5d4c\u56fe\u8868\u793a\u4e0d\u540c\u90e8\u5206\uff1b\u8bef\u5dee\u7ebf\u662f\u7531\u51e0\u6b21\u6d4b\u91cf\u9020\u6210\uff0c\u5bf9\u4e8e\u7518\u6c28\u9178\/\u65b9\u89e3\u77f3\u4f53\u7cfb\uff0c\u7531\u4e8e\u592a\u5c0f\u800c\u672a\u663e\u793a\u8bef\u5dee\u7ebf\u3002<\/p>\n

\"nmat4631-f2<\/p>\n

a\uff0c\u963b\u585e\u5728CaO3\u6676\u4f53\u5185\u6c28\u57fa\u9178\u542b\u91cf[AA]inc\u4e0e\u6eb6\u6db2\u4e2d\u6c28\u57fa\u9178\u521d\u59cb\u6d53\u5ea6[AA]sol\u7684\u5173\u7cfb\uff1b
\nb\uff0c\u4e24\u79cd\u6c28\u57fa\u9178\u5728\u65b9\u89e3\u77f3\u4e2d\u7684\u5206\u5e03\u7cfb\u6570\u4e0e\u521d\u59cb\u6eb6\u6db2\u4e2d\u6c28\u57fa\u9178\u6d53\u5ea6[AA]sol\u7684\u5173\u7cfb\uff1b
\nc\uff0c\u521d\u59cb\u6eb6\u6db2\u4e2dAsp\u6d53\u5ea6[Asp]sol = 10\u2009mM\u65f6\uff0c\u6676\u4f53\u5185\u963b\u585e\u7684Asp\u542b\u91cf\u4e0e\u6eb6\u6db2\u4e2d[Ca2+]sol\u6d53\u5ea6\u5173\u7cfb\uff1b
\nd\uff0c\u521d\u59cb\u6eb6\u6db2\u4e2d[Asp]sol = 10\u2009mM\u65f6\uff0c\u65b9\u89e3\u77f3\u4e2dAsp\u7684\u5206\u5e03\u7cfb\u6570\u3002<\/p>\n

\u56fe3\uff1a\u65b9\u89e3\u77f3\u9ad8\u5206\u8fa8PXRD\u5206\u6790\u8868\u5f81<\/strong><\/span><\/p>\n

\u6c28\u57fa\u9178\u542b\u91cf\u589e\u52a0\uff0c\u6676\u683c\u7578\u53d8\u7ee7\u7eed\u589e\u52a0\uff0c\u4f46\u4e0d\u5747\u5300\u5e94\u529b\u63a5\u8fd1\u56fa\u5b9a\u503c\u3002\u8fd9\u4e0e\u6a21\u578b\u6a21\u62df\u7ed3\u679c\u4e00\u81f4\u3002<\/strong><\/span><\/p>\n

\"nmat4631-f3<\/p>\n

a,b\uff1a\u7531\u4e8e\u65b9\u89e3\u77f3\u4e2dAsp\u548cGly\u7684\u5b58\u5728\uff0c\u4ece\u800c\u9020\u6210\u5206\u522b\u6cbfc\u8f74(a)\u548ca\u8f74(b)\u53d1\u751f\u6676\u683c\u7578\u53d8\uff1b
\nc,d\uff1a\u7531Asp\u548cGly\u7684\u5b58\u5728\u9020\u6210\u5e94\u529b\u4e0d\u5747\u4ece\u800c\u4ea7\u751fXRD\u5cf0\u5bbd\uff08\u534a\u9ad8\u5bbd\uff09\uff1b<\/p>\n

\u56fe\u8868\u663e\u793a\uff0c\u6c28\u57fa\u9178\u542b\u91cf\u589e\u52a0\uff0c\u6676\u683c\u7578\u53d8\u7ee7\u7eed\u589e\u52a0\uff0c\u4f46\u4e0d\u5747\u5300\u5e94\u529b\u63a5\u8fd1\u56fa\u5b9a\u503c\u3002\u4ee5\u4e0a\u884c\u4e3a\u4e0e\u4ed6\u4eec\u5efa\u7acb\u7684\u4e00\u4e2a\u6a21\u578b\u4e00\u81f4\uff0c\u5373\u5f53\u5355\u4e2a\u5206\u5b50\u95f4\u7a7a\u95f4\u51cf\u5c0f(f)\u65f6\uff0cAsp\u548cGly\u5206\u5b50\u6240\u4ea7\u751f\u7684\u5e94\u529b\u573a(\u03b5)\u5f00\u59cb\u53d1\u751f\u91cd\u53e0(g)\u3002<\/p>\n

\u56fe4\uff1a\u6c28\u57fa\u9178\/\u65b9\u89e3\u77f3\u6676\u4f53\u4f53\u7cfb\u7684\u56fa\u6001\u6838\u78c1\u5171\u632f\u8868\u5f81<\/strong><\/span><\/p>\n

\u56fa\u6001\u6838\u78c1\u5171\u632f\u6765\u786e\u5b9a\u6c28\u57fa\u9178\u662f\u5355\u72ec\u5b58\u5728\u8fd8\u662f\u4e0e\u65b9\u89e3\u77f3\u6676\u683c\u76f8\u4e92\u5d4c\u5728\u4e00\u8d77\u3002\u7ed3\u679c\u663e\u793a\u6c28\u57fa\u9178\u5206\u5b50\u72ec\u7acb\u5206\u6563\u4e8e\u65b9\u89e3\u77f3\u6676\u683c\u4e2d\u3002<\/strong> <\/span><\/p>\n

\"nmat4631-f4\"<\/p>\n

\u56fe\u4e3a\u6d53\u5ea6\u4e3a25mM\u65f6\uff0c[1,4-13C2 Asp]\u548c[3-13C Asp]\u5404\u81ea\u5bf9\u5e94\u7684\u8d28\u5b50\u9a71\u52a8\u81ea\u65cb\u6269\u6563\u8f6e\u5ed3\u56fe\u3002\u7ea2\u8272\u8f68\u8ff9\u56fe\u75313-13C\u4fe1\u53f7\u9891\u7387\u548c\u91cd\u53e01\uff0c4-13C\u4fe1\u53f7\u9891\u7387\u7684\u4e8c\u7ef4\u6570\u636e\u5f97\u5230\u30023-13C\u548c1\uff0c4-13C\u793a\u8e2aAsp\u7684\u90bb\u8fd1\u51fa\u73b0\u5cf0\uff08\u7ea2\u8272\u8f68\u8ff9\u7ebf\uff09\uff0c\u5bf9\u5e94\u9891\u7387\u5982\u56fe\u4e2d\u6240\u6807\u7684\u7ea2\u8272\u5782\u76f4\u865a\u7ebf\u3002<\/p>\n

\u56fe5\uff1a\u6c28\u57fa\u9178\/\u65b9\u89e3\u77f3\u4f53\u7cfb\u7684\u529b\u5b66\u6027\u80fd\u6d4b\u8bd5<\/strong><\/span><\/p>\n

\u91c7\u7528\u7eb3\u7c73\u538b\u75d5\u6cd5\u6d4b\u8bd5\u6c28\u57fa\u9178-\u65b9\u89e3\u77f3\u6676\u4f53\u7684\u673a\u68b0\u6027\u80fd\uff08\u786c\u5ea6\uff09\u3002\u968f\u6c28\u57fa\u9178\u542b\u91cf\u589e\u52a0\uff0c\u65b9\u89e3\u77f3\u786c\u5ea6\u6709\u6240\u589e\u52a0\u3002\u5206\u6790\u5f3a\u5ea6\u548c\u6676\u683c\u7578\u53d8\u968f\u7ec4\u5206\u7684\u53d8\u5316\uff0c\u7531\u4e8e\u4f4d\u9519\u963b\u788d\u5207\u529b\u4e0e\u6c28\u57fa\u9178\u9aa8\u67b6\u4e2d\u5171\u4ef7\u952e\u5f3a\u5ea6\u4e00\u81f4\uff0c\u5b66\u8005\u8ba4\u4e3a\u786c\u5ea6\u589e\u52a0\u4e3b\u8981\u662f\u7531\u4e8e\u4f4d\u9519\u5207\u5272\u6c28\u57fa\u9178\u5206\u5b50\u9020\u6210\u3002<\/span><\/strong><\/p>\n

\"nmat4631-f6\"<\/p>\n

a\uff1a\u6c28\u57fa\u9178\u542b\u91cf\u4e0e\u5bf9\u5e94\u6676\u4f53\u786c\u5ea6\u5173\u7cfb\u56fe\uff08\u5d4c\u56fe\uff1a\u538b\u75d5\u53d7\u529b\u56fe\uff09\uff1b
\nb\uff0cc\uff1a\u5728\u6c28\u57fa\u9178\u5206\u5b50\u9489\u624e\u70b9\u5904\u4f4d\u9519\u9000\u51fa(b)\uff0c\u4f4d\u9519\u7ebf\u5f20\u529bT\u4e0e\u5206\u5b50\u4ea7\u751f\u7684\u963b\u529b\u4e24\u8005\u53d7\u7406\u5e73\u8861(c)\uff1b\u5207\u529bFc\u53ef\u4f7f\u4f4d\u9519\u7a7f\u8fc7\u5206\u5b50\u3002\u7531\u4e8eFc\u8fdc\u5c0f\u4e8eT\uff0c\u5206\u5b50\u95f4\u6709\u6548\u8ddd\u79bbL\u2019\u5927\u4e8e\u5b9e\u9645\u95f4\u8dddL\uff1b
\nd\uff1a\u901a\u8fc7\u4e0a\u8ff0\u786c\u5ea6\u503c\u548c\u4f30\u7b97\u7684\u5206\u5b50\u95f4\u8ddd\u6765\u8fdb\u884c\u8ba1\u7b97Fc\uff0c\u4e0e\u9884\u6d4b\u7684\u952e\u5f3a\u5ea6\u8fdb\u884c\u5bf9\u6bd4\uff1b
\ne\uff1a\u5f3a\u5ea6\u4e0e\u95f4\u8ddd\uff08L\u22121 = (Cv, AAt)0.5\uff09\u5173\u7cfb\uff0c\u5176\u7ebf\u6027\u884c\u4e3a\u8bc1\u660e\u4e86\u5206\u5b50\u963b\u585e\u589e\u5f3a\u673a\u5236\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1aTuning hardness in calcite by incorporation of amino acids
\n<\/a><\/p>\n","protected":false},"excerpt":{"rendered":"

\u6210\u679c\u7b80\u4ecb\uff1a \u7ed3\u6784\u578b\u751f\u7269\u77ff\u7269\u4e00\u822c\u4e3a\u6709\u673a\/\u65e0\u673a\u590d\u5408\u6750\u6599\uff0c\u62e5\u6709\u663e\u8457\u7684\u673a\u68b0\u6027\u80fd\u3002\u7136\u800c\uff0c\u5bf9\u4e8e\u5176\u7ed3\u6784-\u6027\u80fd\u4e24\u8005\u95f4\u7684\u5173\u7cfb\uff0c\u5373\u4f7f\u662f\u6700\u7b80\u5355\u7684\u5355\u5143\u2014\u2014\u542b\u5185\u5d4c\u5927\u5206\u5b50\u7684\u77ff\u7269\u5355\u6676\u6750\u6599\uff0c\u79d1…<\/p>\n","protected":false},"author":9,"featured_media":12367,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[2],"tags":[43],"class_list":["post-12358","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-keji","tag-composite"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/12358"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/9"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=12358"}],"version-history":[{"count":7,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/12358\/revisions"}],"predecessor-version":[{"id":12428,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/12358\/revisions\/12428"}],"wp:featuredmedia":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/media\/12367"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=12358"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=12358"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=12358"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}