{"id":123514,"date":"2018-01-31T14:00:46","date_gmt":"2018-01-31T06:00:46","guid":{"rendered":"\/\/m.iemloyee.com\/?p=123514"},"modified":"2018-01-29T12:04:37","modified_gmt":"2018-01-29T04:04:37","slug":"adv-mater-%ef%bc%9a%e6%b0%ae%e6%8e%ba%e6%9d%82%e7%a2%b3%e7%ac%bc%e5%8c%85%e8%a6%86%e9%92%b4%e9%93%b1%e5%90%88%e9%87%91%e6%a0%b8%e8%b0%83%e8%8a%82%e7%a2%b3%e5%82%ac%e5%8c%96%e6%9e%90%e6%b0%a2%e6%b4%bb","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=123514","title":{"rendered":"Adv. Mater.\uff1a\u6c2e\u63ba\u6742\u78b3\u7b3c\u5305\u8986\u94b4\u94f1\u5408\u91d1\u6838\u8c03\u8282\u78b3\u50ac\u5316\u6790\u6c22\u6d3b\u6027"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/p>\n

\u6c22\u6c14\u4f5c\u4e3a\u4e00\u79cd\u53ef\u518d\u751f\u7684\u9ad8\u80fd\u71c3\u6599\uff0c\u88ab\u8ba4\u4e3a\u662f\u672a\u6765\u71c3\u6599\u7535\u6c60\u6700\u6709\u524d\u9014\u7684\u80fd\u6e90\u8f7d\u4f53\u3002\u4e3a\u4e86\u8fbe\u5230\u8fd9\u4e00\u76ee\u7684\uff0c\u5f00\u53d1\u9ad8\u6548\u3001\u5ec9\u4ef7\u7684\u7535\u50ac\u5316\u5242\u6765\u751f\u4ea7\u5177\u6709\u6210\u672c\u6548\u76ca\u548c\u9ad8\u7eaf\u5ea6\u7684\u6c22\u662f\u81f3\u5173\u91cd\u8981\u7684\u3002\u5c3d\u7ba1\u7814\u7a76\u4eba\u5458\u5728\u66ff\u4ee3\u6750\u6599\u4e0a\u53d6\u5f97\u4e86\u5353\u8d8a\u7684\u8fdb\u5c55\uff0c\u4f46\u662fPt\u4ecd\u7136\u88ab\u8ba4\u4e3a\u662f\u5404\u79cd\u7535\u50ac\u5316\u53cd\u5e94\u7684\u201c\u5723\u676f\u201d\u3002\u5c3d\u7ba1Pt\u7684\u50ac\u5316\u6548\u7387\u9ad8\uff0c\u4f46\u5176\u81ea\u7136\u7a00\u7f3a\u6027\u548c\u6602\u8d35\u7684\u4ef7\u683c\u5374\u5927\u5927\u963b\u788d\u4e86\u5b83\u7684\u5927\u89c4\u6a21\u5546\u4e1a\u5316\uff0c\u5bfb\u627e\u5ec9\u4ef7\u9ad8\u6548\u7684\u975e\u94c2\u7535\u50ac\u5316\u5242\u6210\u4e3a\u65f6\u4e0b\u7684\u7814\u7a76\u70ed\u70b9\u3002<\/p>\n

\u4e0e\u5176\u4ed6\u975e\u91d1\u5c5e\u6750\u6599\u76f8\u6bd4\uff0c\u78b3\u6750\u6599\u5177\u6709\u5bfc\u7535\u6027\u597d\uff0c\u8010\u8150\u8680\u7b49\u4f18\u70b9\u3002\u7136\u800c\uff0c\u4f5c\u4e3a\u4e00\u79cd\u7531\u5355\u5c42\u78b3\u539f\u5b50\u7ec4\u6210\u7684\u4e8c\u7ef4\u6750\u6599\uff0c\u77f3\u58a8\u70ef\u5728\u7535\u50ac\u5316\u6790\u6c22\u53cd\u5e94\u4e2d\u8868\u73b0\u51fa\u60f0\u6027\u3002\u5f02\u8d28\u539f\u5b50 (\u5982N) \u63ba\u6742\u53ef\u4ee5\u901a\u8fc7\u6539\u53d8\u78b3\u9aa8\u67b6\u7684\u7535\u4e2d\u6027\uff0c\u5728\u76f8\u90bb\u78b3\u539f\u5b50\u5468\u56f4\u7684\u7535\u8377\u5206\u5e03\u4e2d\u4ea7\u751f\u4e0d\u5bf9\u79f0\u6027\uff0c\u4ece\u800c\u5229\u4e8e\u53cd\u5e94\u7269\u7684\u5438\u9644\u548c\u4ea7\u7269\u7684\u8131\u9644\u3002\u7136\u800c\u5f88\u591a\u78b3\u57fa\u50ac\u5316\u5242\u7684\u6d3b\u6027\u4e0e\u8d35\u91d1\u5c5e\u76f8\u6bd4\u8fd8\u6709\u5f88\u5927\u7684\u5dee\u8ddd\u3002\u94f1\u94b4\u5408\u91d1\u8868\u9762\u5305\u8986\u7684\u6c2e\u63ba\u6742\u7684\u77f3\u58a8\u70ef\u5c42\u7c7b\u4f3c\u4e8e\u201c\u94e0\u7532\u201d\uff0c\u6709\u5229\u4e8e\u9632\u6b62\u5408\u91d1\u5185\u6838\u88ab\u9178\u8150\u8680\uff0c\u540c\u65f6\u94f1\u94b4\u5408\u91d1\u53ef\u5411\u8868\u9762\u6d3b\u6027\u4f4d\u70b9\u8f6c\u79fb\u7535\u5b50\uff0c\u6539\u53d8\u78b3\u539f\u5b50\u7684\u7535\u5b50\u7ed3\u6784\uff0c\u63d0\u9ad8\u50ac\u5316\u6d3b\u6027\uff0c\u5229\u4e8e\u53cd\u5e94\u7684\u8fdb\u884c\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u4e2d\u56fd\u79d1\u5b66\u6280\u672f\u5927\u5b66\u7684\u9648\u4e7e\u65fa\u6559\u6388<\/strong>\u7b49\u4eba\u5728Advanced Materials<\/strong>\u4e0a\u53d1\u6587\uff0c\u9898\u4e3a\uff1a\u201cTuning the Activity of Carbon for Electrocatalytic Hydrogen Evolution via an Iridium-Cobalt Alloy Core Encapsulated in Nitrogen-Doped Carbon Cages\u201d<\/strong>\u3002\u7814\u7a76\u4eba\u5458\u4ee5Ir\u63ba\u6742\u7684\u91d1\u5c5e\u6709\u673a\u9aa8\u67b6\u6750\u6599\u4e3a\u524d\u9a71\u4f53\u4e00\u6b65\u7145\u70e7\u6765\u5408\u6210\u6c2e\u63ba\u6742\u7684\u77f3\u58a8\u70ef\u5c42\u5305\u9644IrCo\u7eb3\u7c73\u5408\u91d1\u3002\u8be5\u50ac\u5316\u5242\u4ee5\u6781\u4f4e\u7684Ir\u542b\u91cf\uff081.56wt%\uff09\u57280.5M H2<\/sub>SO4<\/sub>\u6eb6\u6db2\u4e2d\u8868\u73b0\u51fa\u4f18\u8d8a\u7684\u7535\u50ac\u5316\u6790\u6c22\u6d3b\u6027\uff0c\u5176\u5854\u83f2\u5c14\u659c\u7387\u4ec5\u4e3a23 mV\/dec\uff0c\u8fbe\u523010mA\/cm2<\/sup>\u7535\u6d41\u5bc6\u5ea6\u65f6\u5176\u8fc7\u7535\u4f4d\u4ec5\u4e3a24mV\uff0c\u663e\u793a\u51fa\u4e0e\u5546\u7528\u768420% Pt\/C\u7535\u50ac\u5316\u5242\u53ef\u6bd4\u7684\u7535\u50ac\u5316\u6790\u6c22\u6027\u80fd\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n

\u56fe1. Ir-\u63ba\u6742Co3<\/sub>[Co(CN)6<\/sub>]2<\/sub>\u524d\u9a71\u4f53\u53caIrCo@NC\u50ac\u5316\u5242\u7684\u5408\u6210\u8def\u7ebf\u793a\u610f\u56fe\u4ee5\u53ca\u8868\u5f81<\/strong><\/p>\n

\"\"<\/p>\n

a)\u6c2e\u63ba\u6742\u77f3\u58a8\u70ef\u5305\u9644IrCo\u5408\u91d1\u5408\u6210\u793a\u610f\u56fe\uff1b<\/p>\n

b)Ir\u63ba\u6742Co3<\/sub>[Co(CN)6<\/sub>]2<\/sub>\u7684SEM\u56fe\uff1b<\/p>\n

c)IrCo@NC-500 SEM\u56fe\uff1b<\/p>\n

d,g) IrCo@NC-500\u7684HRTEM\u56fe\uff1b<\/p>\n

e)Ir\u63ba\u6742Co3<\/sub>[Co(CN)6<\/sub>]2<\/sub>\u7684TEM\u56fe\uff1b<\/p>\n

f) IrCo@NC-500\u7684TEM\u56fe\uff1b<\/p>\n

h\u2013k) IrCo@NC-500\u7eb3\u7c73\u9897\u7c92\u4e0a\u7684Co, Ir\u548cN\u7684EDS\u66f2\u7ebf\u3002<\/p>\n

\u56fe2. IrCo@NC\u7ed3\u6784\u5206\u6790<\/strong><\/p>\n

\"\"<\/p>\n

a) IrCo@NC-T<\/em>(T <\/em>= 500, 600, 700, 800)XRD\u56fe\uff1b<\/p>\n

b) IrCo@NC-450\u5728\u6c2e\u6c14\u6c14\u6c1b\u4e0b\u4ee510 \u00b0C min\u2212<\/sup>1<\/sup>\u7684\u5347\u6e29\u901f\u7387\u4e0b\u7684TGA-DSC\u7ed3\u679c((b)\u63d2\u56fe: \u5728\u76f8\u53d8\u8fc7\u7a0b\u4e2d\u516d\u65b9IrCo\u548c\u7acb\u65b9IrCo\u76f8\u5e94\u6676\u4f53\u7ed3\u6784\uff1b<\/p>\n

c) Co\u7b94\u548cIrCo@NC-T<\/em>(T <\/em>= 500\uff0c800)\u7684Co K-\u8fb9\u5085\u91cc\u53f6\u53d8\u6362EXAFS\u56fe((c)\u63d2\u56fe: \u4e0a\u8ff0\u6750\u6599\u7684XANES\u56fe)\uff1b<\/p>\n

d) IrCo@NC-500\u7684\u6c2e\u6c14\u5438\u8131\u9644\u66f2\u7ebf\uff1b<\/p>\n

\u56fe3.\u5728N2<\/sub>-\u9971\u548c\u76840.5M H2<\/sub>SO4<\/sub>\u6eb6\u6db2\u4e2d\u7535\u50ac\u5316\u5242HER\u6027\u80fd\u6d4b\u8bd5<\/strong><\/p>\n

\"\"<\/p>\n

a) IrCo@NC-T\u7684LSV\u66f2\u7ebf\uff1b<\/p>\n

b) IrCo@NC-500, Co@NC-600, Ir\/C, Pt\/C\u50ac\u5316\u5242\u5728\u76f8\u540c\u8d1f\u8f7d\u91cf\u4e0b\u7684LSV\u66f2\u7ebf\uff1b<\/p>\n

c) IrCo@NC-500, Ir\/C, Pt\/C\u50ac\u5316\u5242\u5854\u83f2\u5c14\u66f2\u7ebf\uff1b<\/p>\n

d) IrCo@NC\uff0cCo@NC-800\u50ac\u5316\u5242\u963b\u6297\u56fe\uff1b<\/p>\n

e) IrCo@NC-T\u7684\u53cc\u7535\u5c42\u7535\u5bb9\uff1b<\/p>\n

f) IrCo@NC-500\u5728\u9178\u6027\u6eb6\u6db2\u4e2d\u5faa\u73af\u7535\u4f4d\u626b\u63cf\u7684LSV\u66f2\u7ebf((f)\u63d2\u56fe:\u9759\u6001\u7535\u52bf\u4e0b\u65f6\u95f4\u4e0e\u7535\u6d41\u5bc6\u5ea6\u5173\u7cfb\u66f2\u7ebf)\uff1b<\/p>\n

\u56fe4. \u5728N2<\/sub>-\u9971\u548c\u76841 M KOH\u6eb6\u6db2\u4e2d\u50ac\u5316\u5242HER\u6027\u80fd<\/strong><\/p>\n

\"\"<\/p>\n

a) IrCo@NC-500, Ir\/C, Pt\/C \u50ac\u5316\u5242\u5728\u76f8\u540c\u8d1f\u8f7d\u4e0b\u7684LSV\u66f2\u7ebf\uff1b<\/p>\n

b) IrCo@NC-500, Ir\/C, Pt\/C\u50ac\u5316\u5242\u5854\u83f2\u5c14\u66f2\u7ebf\uff1b<\/p>\n

\u56fe5. IrCo@NC\u8868\u9762\u7ed3\u6784\u5206\u6790<\/strong><\/p>\n

\"\"<\/p>\n

a) IrCo@NC-500\u62c9\u66fc\u56fe ( (a)\u63d2\u56fe: 800\u20142000cm-1<\/sup>\u8303\u56f4\u7684\u62c9\u66fc\u5149\u8c31\u66f2\u7ebf\u62df\u5408\u7ed3\u679c)\uff1b<\/p>\n

b) IrCo@NC-500\u548cIrCo@NC-800\u5404\u79cd\u7f3a\u9677\u7684\u6bd4\u8f83\uff1b<\/p>\n

c) IrCo@NC-500\u7684N 1sXPS\u56fe\u8c31<\/p>\n

d)\u50ac\u5316\u5242\u4e2d\u5404\u7c7b\u578b\u6c2e\u7684\u767e\u5206\u542b\u91cf\uff1b((d)\u63d2\u56fe:\u6c2e\u63ba\u6742\u77f3\u58a8\u70ef\u5c42\u6a21\u578b).<\/p>\n

\u56fe6.\u7406\u8bba\u8ba1\u7b97<\/strong><\/p>\n

\"\"<\/p>\n

a)\u5728\u5e73\u8861\u7535\u4f4d\u4e0b\u4e0d\u540c\u6a21\u578b\u7684\u5438\u9644\u81ea\u7531\u80fd\u56fe\uff1b<\/p>\n

b)\u6c2e\u63ba\u6742\u77f3\u58a8\u70ef\u5305\u9644IrCo\u5408\u91d1\u7684\u5dee\u5206\u7535\u8377\u5bc6\u5ea6\u5206\u5e03\u3002<\/p>\n

\u56fe7.IrCo@NC\u5143\u7d20\u5206\u5e03\u8868\u5f81<\/strong><\/p>\n

\"\"<\/p>\n

a-c)TEM\u56fe\u548c\u76f8\u5e94\u7684\u5143\u7d20\u5206\u5e03\uff1b<\/p>\n

d)\u5305\u542bCo\u548cIr\u5143\u7d20\u7684\u5408\u91d1\u6838\u9897\u7c92\u6a21\u578b\uff1b<\/p>\n

\u3010\u603b\u7ed3\u3011<\/strong><\/p>\n

\u5bcc\u6c2e\u77f3\u58a8\u70ef\u78b3\u7b3c\u5305\u8986IrCo\u7eb3\u7c73\u9897\u7c92IrCo@NC\u5728\u9178\u6027\u7535\u89e3\u8d28\u73af\u5883\u4e2d\u8868\u73b0\u51fa\u4e86\u51fa\u8272\u7684HER\u6d3b\u6027\uff0c\u8be5\u6750\u6599\u7684\u6027\u80fd\u8d85\u8fc7\u4e86\u76ee\u524d\u62a5\u9053\u7684\u5927\u591a\u6570\u50ac\u5316\u5242\uff0c\u5982\u8d35\u91d1\u5c5e\u57fa\u50ac\u5316\u5242\uff0c\u78b3\u57fa\u50ac\u5316\u5242\u7b49\u3002\u5f97\u76ca\u4e8e\u5bcc\u6c2e\u7684\u77f3\u58a8\u70ef\u5c42\u548c\u5305\u8986\u7684IrCo\u5408\u91d1\u4e4b\u95f4\u7684\u5f3a\u76f8\u4e92\u4f5c\u7528\uff0c\u6750\u6599\u7684\u8868\u9762\u7535\u5b50\u7ed3\u6784\u4ee5\u53ca\u7535\u5bfc\u7387\u5f97\u5230\u4e86\u6781\u5927\u5730\u63d0\u5347\u6539\u53d8\uff0c\u8be5\u50ac\u5316\u5242\u8868\u73b0\u51fa\u4e86\u53ef\u4e0e\u5546\u4e1a\u8d35\u91d1\u5c5e\u50ac\u5316\u5242\uff08\u6bd4\u5982Pt\/C\u50ac\u5316\u5242\uff09\u76f8\u5ab2\u7f8e\u7684\u7535\u50ac\u5316\u6027\u80fd\u3002DFT\u8ba1\u7b97\u7ed3\u679c\u8868\u660e\u4eceIrCo\u5408\u91d1\u5185\u6838\u8fc1\u79fb\u5230\u77f3\u58a8\u70ef\u5c42\u7684\u7535\u5b50\u6709\u5229\u4e8e\u7535\u8377\u5728\u6c2e\u539f\u5b50\u8868\u9762\u7684\u5bcc\u96c6\uff0c\u663e\u8457\u964d\u4f4e\u4e86\u0394G<\/em>H*<\/sub>\uff0c\u8fdb\u800c\u63d0\u5347\u4e86\u6027\u80fd\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/strong>Tuning the Activity of Carbon for Electrocatalytic HydrogenEvolution via an Iridium-Cobalt Alloy Core Encapsulated inNitrogen-Doped Carbon Cages<\/a> (Advanced Materials.2018,DOI:10.1002\/adma.201705324)<\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u65b0\u80fd\u6e90\u5b66\u672f\u7ec4Z. Chen\u4f9b\u7a3f\uff0c\u6750\u6599\u725b\u6574\u7406\u7f16\u8f91\u3002<\/p>\n

\u6750\u6599\u725b\u7f51\u4e13\u6ce8\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u53ca\u884c\u4e1a\u8fdb\u5c55\uff0c\u8fd9\u91cc\u6c47\u96c6\u4e86\u5404\u5927\u9ad8\u6821\u7855\u535a\u751f\u3001\u4e00\u7ebf\u79d1\u7814\u4eba\u5458\u4ee5\u53ca\u884c\u4e1a\u4ece\u4e1a\u8005\uff0c\u5982\u679c\u60a8\u5bf9\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u8fdb\u5c55\uff0c\u89e3\u8bfb\u9ad8\u6c34\u5e73\u6587\u7ae0\u6216\u662f\u8bc4\u8ff0\u884c\u4e1a\u6709\u5174\u8da3\uff0c\u70b9\u6211\u52a0\u5165\u7f16\u8f91\u90e8<\/a>\u3002<\/p>\n

\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1\uff1atougao@cailiaoren.com\u3002<\/p>\n

\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1aRDD-2011-CHERISH\uff0c\u4efb\u4e39\u4e39\uff0c\u6211\u4eec\u4f1a\u9080\u8bf7\u5404\u4f4d\u8001\u5e08\u52a0\u5165\u4e13\u5bb6\u7fa4\u3002<\/p>\n

\u6750\u6599\u6d4b\u8bd5\uff0c\u6570\u636e\u5206\u6790\uff0c\u4e0a<\/strong>\u6d4b\u8bd5\u8c37<\/strong><\/a>\uff01<\/strong><\/p>\n","protected":false},"excerpt":{"rendered":"

\u3010\u5f15\u8a00\u3011 \u6c22\u6c14\u4f5c\u4e3a\u4e00\u79cd\u53ef\u518d\u751f\u7684\u9ad8\u80fd\u71c3\u6599\uff0c\u88ab\u8ba4\u4e3a\u662f\u672a\u6765\u71c3\u6599\u7535\u6c60\u6700\u6709\u524d\u9014\u7684\u80fd\u6e90\u8f7d\u4f53\u3002\u4e3a\u4e86\u8fbe\u5230\u8fd9\u4e00\u76ee\u7684\uff0c\u5f00\u53d1\u9ad8\u6548\u3001\u5ec9\u4ef7\u7684\u7535\u50ac\u5316\u5242\u6765\u751f\u4ea7\u5177\u6709\u6210\u672c\u6548\u76ca\u548c\u9ad8\u7eaf\u5ea6\u7684\u6c22\u662f\u81f3\u5173\u91cd…<\/p>\n","protected":false},"author":3029,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[2782],"class_list":["post-123514","post","type-post","status-publish","format-standard","hentry","category-jiedu","tag-2782"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/123514"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/3029"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=123514"}],"version-history":[{"count":3,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/123514\/revisions"}],"predecessor-version":[{"id":123666,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/123514\/revisions\/123666"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=123514"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=123514"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=123514"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}