{"id":122610,"date":"2018-01-27T06:30:58","date_gmt":"2018-01-26T22:30:58","guid":{"rendered":"\/\/m.iemloyee.com\/?p=122610"},"modified":"2018-01-24T10:43:35","modified_gmt":"2018-01-24T02:43:35","slug":"%e5%94%90%e4%bc%a0%e5%85%b5angew-chem-int-ed-%e7%83%ad%e7%82%b9%e6%96%87%e7%ab%a0-%e7%94%a8%e4%ba%8e%e5%bc%ba%e5%8a%b2%e7%9a%84%e7%a2%b1%e6%80%a7%e9%98%b4%e7%a6%bb%e5%ad%90%e4%ba%a4%e6%8d%a2","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=122610","title":{"rendered":"\u5510\u4f20\u5175Angew. Chem. Int. Ed. \u70ed\u70b9\u6587\u7ae0: \u7528\u4e8e\u5f3a\u52b2\u7684\u78b1\u6027\u9634\u79bb\u5b50\u4ea4\u6362\u819c\u7684\u9633\u79bb\u5b50\u91d1\u5c5e\u6709\u673a\u805a\u7535\u89e3\u8d28"},"content":{"rendered":"
\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n \u805a\u7535\u89e3\u8d28\u5177\u6709\u5e7f\u6cdb\u7684\u5e94\u7528(\u5982\u6d82\u6599\u3001\u751f\u7269\u533b\u5b66\u6750\u6599)\u3002\u5176\u4e2d\uff0c\u9633\u79bb\u5b50\u805a\u7535\u89e3\u8d28\u5df2\u5e7f\u6cdb\u7528\u4f5c\u5c06\u71c3\u6599\u8f6c\u5316\u4e3a\u7535\u80fd\u7684\u78b1\u6027\u71c3\u6599\u7535\u6c60\u7684\u9634\u79bb\u5b50\u4ea4\u6362\u819c(AEMs)\uff0c\u71c3\u6599\u7535\u6c60\u7684\u64cd\u4f5c\u6e29\u5ea6\u4f4e\u4e8e100\u2103\uff0c\u56e0\u6b64\u5176\u4f5c\u4e3a\u7535\u52a8\u6c7d\u8f66\u548c\u4fbf\u643a\u5f0f\u8bbe\u5907\u7684\u80fd\u91cf\u8f6c\u6362\u5668\u4ef6\u5177\u6709\u66f4\u5f3a\u7684\u5438\u5f15\u529b\u3002\u4e00\u822c\u6765\u8bf4\uff0cAEMs\u662f\u542b\u6709\u5171\u4ef7\u8fde\u63a5\u5230\u758f\u6c34\u805a\u5408\u7269\u9aa8\u67b6\u7684\u9633\u79bb\u5b50\u7684\u5171\u805a\u7269\u3002\u6700\u5e38\u7528\u7684\u65b9\u6cd5\u662f\u4f7f\u7528\u542b\u6709\u5b63\u94f5\u9633\u79bb\u5b50(QAC)\u7684\u805a\u5408\u7269\u3002\u7136\u800c\uff0c\u5b63\u94f5\u76d0\u5728\u9ad8\u5ea6\u78b1\u6027\u6761\u4ef6\u5bb9\u6613\u901a\u8fc7\u970d\u592b\u66fc\u964d\u89e3\u6d88\u9664(E2)\u6216\u4eb2\u6838\u53d6\u4ee3(SN<\/sub>2)\u88ab\u964d\u89e3\u3002\u5728\u8fc7\u53bb\u7684\u6570\u5e74\u4e2d\uff0c\u7814\u7a76\u4eba\u5458\u63d0\u51fa\u4e86\u4e00\u4e9b\u7b56\u7565\u4ee5\u63d0\u5347AEM\u9aa8\u67b6\u78b1\u6027\u73af\u5883\u4e0b\u7684\u7a33\u5b9a\u6027\u3002\u7136\u800c\uff0c\u8fd9\u4e9b\u65b9\u6cd5\u6291\u6216\u727a\u7272\u4e86\u79bb\u5b50\u7535\u5bfc\u7387\uff0c\u6291\u6216\u5728\u5b9e\u73b0\u957f\u671f\u7a33\u5b9a\u4ecd\u7136\u9762\u4e34\u6311\u6218\u3002<\/p>\n \u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n \u8fd1\u65e5\uff0c\u7f8e\u56fd\u5357\u5361\u7f57\u6765\u7eb3\u5927\u5b66\u5510\u4f20\u5175\u6559\u6388(\u901a\u8baf\u4f5c\u8005)\u7b49<\/strong>\u5236\u5907\u4e86\u5177\u6709\u5316\u5b66\u60f0\u6027\u4ee5\u53ca\u97e7\u6027\u7684\u9633\u79bb\u5b50\u91d1\u5c5e\u6709\u673a\u805a\u7535\u89e3\u8d28\uff0c\u5c06\u5176\u4f5c\u4e3a\u6301\u4e45\u8010\u7528\u7684\u9634\u79bb\u5b50\u4ea4\u6362\u819c(AEMs)\uff0c\u5e76\u5728Angew. Chem. Int. Ed.<\/strong>\u4e0a\u53d1\u8868\u4e86\u9898\u4e3a\u201cCationic Metallo-Polyelectrolytes for Robust Alkaline Anion-Exchange Membranes<\/strong>\u201d\u7684\u7814\u7a76\u8bba\u6587\u3002\u8be5\u8bba\u6587\u88ab\u9009\u4e3a\u70ed\u70b9\u8bba\u6587\u3002<\/strong>\u5236\u5907\u8fc7\u7a0b\u5148\u4ece\u4e09\u5511\u4f5c\u4e3a\u552f\u4e00\u8fde\u63a5\u57fa\u56e2\u7684\u542b\u4e8c\u8302\u94b4\u9633\u79bb\u5b50\u73af\u8f9b\u70ef\u7684\u5f00\u73af\u6613\u4f4d\u805a\u5408(ROMP)\u5f00\u59cb\uff0c\u4e4b\u540e\u662f\u9aa8\u67b6\u6c22\u5316\uff0c\u8fdb\u800c\u4ea7\u751f\u4e86\u5177\u6709\u7c7b\u805a\u4e59\u70ef\u6846\u67b6\u548c\u78b1\u6027\u7a33\u5b9a\u7684\u4e8c\u8302\u94b4\u9633\u79bb\u5b50\u4f5c\u4e3a\u79bb\u5b50\u4f20\u5bfc\u7684\u65b0\u578bAEMs\u3002\u4e0a\u8ff0AEMs\u8868\u73b0\u51fa\u4f18\u5f02\u7684\u70ed\u3001\u5316\u5b66\u548c\u673a\u68b0\u7a33\u5b9a\u6027\u4ee5\u53ca\u8f83\u9ad8\u7684\u79bb\u5b50\u7535\u5bfc\u7387\u3002<\/p>\n \u3010\u56fe\u6587\u7b80\u4ecb\u3011<\/strong><\/p>\n \u56fe1 \u9634\u79bb\u5b50\u4ea4\u6362\u819c\u6750\u6599\u5236\u5907\u8fc7\u7a0b\u793a\u610f\u56fe<\/strong><\/p>\n a) \u4e8c\u8302\u94b4\u5355\u4f53(2)\u3001\u5171\u805a\u7269(3)\u4ee5\u53ca\u4f5c\u4e3aAEMs\u7684\u6c22\u5316\u805a\u5408\u7269(4)\u7684\u5408\u6210\uff1b<\/p>\n b) \u67d4\u6027\u900f\u660e\u4e8c\u8302\u94b4AEMs\u7684\u56fe\u50cf\uff1b<\/p>\n c) \u542b\u6709\u4e8c\u8302\u94b4\u7684AEMs\u53ef\u80fd\u7684\u5206\u5b50\u94fe\u7ed3\u6784\u548c\u79bb\u5b50\u4f20\u5bfc\u8def\u5f84\u3002<\/p>\n \u56fe2 \u9634\u79bb\u5b50\u4ea4\u6362\u819c\u6750\u6599\u7684\u7ed3\u6784\u8868\u5f81<\/strong><\/p>\n \u4e8c\u8302\u94b4\u5355\u4f53(2)(CDCl3\u6eb6\u5242)(\u4e0a)\u3001\u5171\u805a\u7269(3)(\u4e2d)\u4ee5\u53ca\u6c22\u5316\u805a\u5408\u7269(4)(\u4e8c\u7532\u4e9a\u781c-d6\u6eb6\u5242)(\u4e0b)\u76841<\/sup>H NMR\u8c31\u56fe\u3002<\/p>\n \u56fe3 \u9634\u79bb\u5b50\u4ea4\u6362\u819c\u6750\u6599\u7684\u7a33\u5b9a\u6027\u4ee5\u53ca\u79bb\u5b50\u7535\u5bfc\u7387\u8868\u5f81<\/strong><\/p>\n a) \u4e8c\u8302\u94b4AEMs\u7684TGA\u548cDTG\u66f2\u7ebf\uff1b<\/p>\n b) \u4e8c\u8302\u94b4AEMs\u7684SAXS\u66f2\u7ebf\uff1b<\/p>\n c) \u4e8c\u8302\u94b4AEMs\u7684\u7684\u6c22\u6c27\u6839\u4f20\u5bfc\u7387\u968f\u6e29\u5ea6\u7684\u53d8\u5316\uff1b<\/p>\n d) \u4e8c\u8302\u94b4AEMs\u7684\u5ba4\u6e29\u4f20\u5bfc\u7387\u968f\u4ea4\u6362\u819c\u6d78\u5165\u78b1\u6eb6\u6db2\u65f6\u95f4\u7684\u53d8\u5316\u3002<\/p>\n \u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n \u7814\u7a76\u4eba\u5458\u8bbe\u8ba1\u4e86\u542b\u6709\u4e8c\u8302\u94b4\u9633\u79bb\u5b50\u3001\u7c7b\u805a\u4e59\u70ef\u9aa8\u67b6\u548c\u4e0d\u53d1\u751f\u6c34\u89e3\u7684\u8fde\u63a5\u57fa\u56e2\u7684\u805a\u7535\u89e3\u8d28\u4f5c\u4e3a\u65b0\u578b\u9634\u79bb\u5b50\u4ea4\u6362\u819c\u3002\u4e0a\u8ff0\u5171\u805a\u7269\u901a\u8fc7\u5f00\u73af\u6613\u4f4d\u805a\u5408\u7ed3\u5408\u805a\u5408\u7269\u9aa8\u67b6\u6c22\u5316\u5236\u5907\u800c\u6765\u3002\u4e0a\u8ff0\u79bb\u5b50\u4ea4\u6362\u819c\u6301\u4e45\u8010\u7528\uff0c\u5177\u6709\u4f18\u826f\u7684\u97e7\u6027\u548c\u67d4\u6027\uff0c\u9633\u79bb\u5b50\u548c\u805a\u5408\u7269\u5176\u4ed6\u6210\u5206\u51fa\u8272\u7684\u5316\u5b66\u7a33\u5b9a\u6027\u4ee5\u53ca\u826f\u597d\u7684\u79bb\u5b50\u5bfc\u7535\u6027\u3002\u8fd9\u9879\u5de5\u4f5c\u8868\u660e\u4fa7\u94fe\u4e8c\u8302\u94b4\u805a\u5408\u7269\u5728\u71c3\u6599\u7535\u6c60\u9634\u79bb\u5b50\u4ea4\u6362\u819c\u6750\u6599\u7684\u5e94\u7528\u524d\u666f\u826f\u597d\u3002<\/p>\n \u6587\u732e\u94fe\u63a5\uff1a<\/strong>Cationic Metallo-Polyelectrolytes for Robust Alkaline Anion-Exchange Membranes<\/strong> <\/a>(Angew. Chem. Int. Ed., 2018, DOI: 10.1002\/anie.201712387)<\/p>\n \u672c\u6587\u7531\u6750\u6599\u4eba\u7f16\u8f91\u90e8\u65b0\u80fd\u6e90\u5c0f\u7ec4abc940504\u7f16\u8bd1\u6574\u7406\uff0c\u53c2\u4e0e\u65b0\u80fd\u6e90\u8bdd\u9898\u8ba8\u8bba\u8bf7\u52a0\u5165\u201c\u6750\u6599\u4eba\u65b0\u80fd\u6e90\u6750\u6599\u4ea4\u6d41\u7fa4 422065953\u201d\u3002<\/p>\n \u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1aRDD-2011-CHERISH\uff0c\u4efb\u4e39\u4e39\uff0c\u6211\u4eec\u4f1a\u9080\u8bf7\u5404\u4f4d\u8001\u5e08\u52a0\u5165\u4e13\u5bb6\u7fa4\u3002<\/p>\n \u6750\u6599\u725b\u7f51\u4e13\u6ce8\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u53ca\u884c\u4e1a\u8fdb\u5c55\uff0c\u5982\u679c\u60a8\u5bf9\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u8fdb\u5c55\uff0c\u89e3\u8bfb\u9ad8\u6c34\u5e73\u6587\u7ae0\u6216\u662f\u8bc4\u8ff0\u884c\u4e1a\u6709\u5174\u8da3\uff0c\u70b9\u6211\u52a0\u5165\u7f16\u8f91\u90e8<\/a><\/strong>\u3002\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1tougao@cailiaoren.com\u3002<\/p>\n<\/p>\n
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