{"id":122545,"date":"2018-01-25T14:00:10","date_gmt":"2018-01-25T06:00:10","guid":{"rendered":"\/\/m.iemloyee.com\/?p=122545"},"modified":"2018-01-24T21:19:58","modified_gmt":"2018-01-24T13:19:58","slug":"%e5%a4%a7%e5%b7%a5%e9%99%86%e5%ae%89%e6%85%a7angew-chem-int-ed-%ef%bc%9a%e7%94%a8%e4%ba%8e%e6%b0%94%e4%bd%93%e5%88%86%e7%a6%bb%e7%9a%84%e6%b8%a9%e6%8e%a7","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=122545","title":{"rendered":"\u5927\u5de5\u9646\u5b89\u6167Angew. Chem. Int. Ed.\uff1a\u7528\u4e8e\u6c14\u4f53\u5206\u79bb\u7684\u6e29\u63a7\u76f8\u8f6c\u53d8\u6cd5\u5408\u6210\u5b54\u5f84\u7cbe\u51c6\u53ef\u63a7\u7684\u4e8c\u7ef4\u7eb3\u7c73\u70ad\u7247"},"content":{"rendered":"

\u3010\u5f15\u8a00<\/strong>\u3011<\/p>\n

\u53d1\u5c55\u53ef\u5c06\u5c3a\u5bf8\u76f8\u8fd1\u6c14\u4f53\u5206\u5b50\u9ad8\u6548\u5206\u79bb\u7684\u591a\u5b54\u5438\u9644\u5242\u662f\u5316\u5de5\u4e1a\u4e2d\u6c14\u4f53\u5206\u79bb\u9886\u57df\u7684\u4e00\u9879\u91cd\u5927\u6311\u6218\u3002\u591a\u5b54\u70ad\u5176\u5316\u5b66\u6027\u8d28\u7a33\u5b9a\u3001\u8010\u6c34\u6c7d\u3001\u5b54\u9699\u53d1\u8fbe\u7b49\u4f18\u70b9\u88ab\u5e7f\u6cdb\u7528\u4e8e\u6c14\u4f53\u5206\u79bb\uff0c\u800c\u5fae\u5b54\u5c3a\u5bf8\u662f\u51b3\u5b9a\u5176\u7b5b\u5206\u6027\u80fd\u7684\u5173\u952e\u56e0\u7d20\u3002\u7136\u800c\uff0c\u7531\u4e8e\u5e38\u89c4\u70ad\u524d\u9a71\u4f53\u7684\u9897\u7c92\u5c3a\u5bf8\u591a\u5728\u5fae\u7c73\u91cf\u7ea7\u4ee5\u4e0a\uff0c\u70ed\u89e3\u8fc7\u7a0b\u4e2d\u5b58\u5728\u4f20\u8d28\u548c\u4f20\u70ed\u4e0d\u5747\u5300\u7684\u95ee\u9898\uff0c\u751f\u6210sp3\u70ad\u542b\u91cf\u9ad8\u7684\u65e0\u5e8f\u6e4d\u6d41\u72b6\u4e71\u5806\u7ed3\u6784\uff0c\u5bfc\u81f4\u5fae\u5b54\u5c3a\u5bf8\u96be\u4ee5\u8c03\u63a7\u3002\u8fd1\u65e5\uff0c\u6709\u5b66\u8005\u62a5\u9053\u4e86\u8d85\u5fae\u5b54\u53ef\u7cbe\u51c6\u8c03\u63a7\u7684\u4e8c\u7ef4\u7eb3\u7c73\u70ad\u7247\u5408\u6210\u65b0\u65b9\u6cd5\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb<\/strong>\u3011<\/p>\n

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\u4f5c\u8005\u5efa\u7acb\u4e86\u6e29\u63a7\u76f8\u8f6c\u53d8\u6cd5\u5408\u6210\u5b54\u5f84\u7cbe\u51c6\u53ef\u63a7\u7684\u4e8c\u7ef4\u7eb3\u7c73\u70ad\u7247\u3002\u8fd9\u79cd\u7eb3\u7c73\u70ad\u7247 sp2<\/sup>\u78b3\u542b\u91cf\u8d85\u8fc780%\uff0c\u5fae\u5b54\u5b54\u5f84\u57280.53 – 0.58 nm\u8303\u56f4\u7cbe\u51c6\u53ef\u8c03\uff0c\u70ad\u7247\u539a\u5ea6\u572830-65 nm\u5185\u7cbe\u51c6\u53ef\u63a7\u3002\u8d85\u8584\u7684\u7ed3\u6784\u4fc3\u8fdb\u4e86\u78b3\u5fae\u6676\u4f53\u7684\u5b9a\u5411\u751f\u957f\uff0c\u5e76\u4e14\u7531\u4e8e\u8584\u5c42\u7ed3\u6784\u7684\u5bfc\u5411\u4f5c\u7528\uff0c\u78b3\u5fae\u6676\u8d8b\u5411\u4e8e\u5e73\u884c\u6392\u5e03\uff0c\u5f62\u6210\u5747\u5300\u8d85\u5fae\u5b54\u3002\u5728\u5ba4\u6e29\u6761\u4ef6\u4e0b\uff0c\u4ece\u5929\u7136\u6c14\u4e2d\u5206\u79bb\u6c14\u4f53\u65f6\uff0c\u7eb3\u7c73\u70ad\u7247\u5bf9CO2<\/sub>\uff0cC2<\/sub>H6<\/sub>\u548cC3<\/sub>H8<\/sub>\u8868\u73b0\u51fa\u9ad8\u5438\u6536\u91cf(5.2, 5.3\u548c5.1mmol g-1<\/sup>)\u548c\u9009\u62e9\u6027(7, 71\u548c386)\u3002\u6b64\u5916\uff0c\u7eb3\u7c73\u70ad\u7247\u7684\u52a8\u6001\u5438\u9644\u91cf\u63a5\u8fd1\u4e8e\u5355\u7ec4\u5206\u7684\u5e73\u8861\u5438\u9644\u91cf\uff0c\u8fdb\u4e00\u6b65\u8868\u660e\u7eb3\u7c73\u70ad\u7247\u5728\u9009\u62e9\u6027\u548c\u5438\u9644\u52a8\u529b\u5b66\u65b9\u9762\u7684\u4f18\u8d8a\u6027\u3002<\/p>\n

\u3010\u56fe\u7247\u5bfc\u8bfb<\/strong>\u3011<\/p>\n

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\"\"<\/p>\n

\u5c06\u7194\u70b9\u4e3a66\u2103\u7684\u758f\u6c34\u6027\u786c\u8102\u9178\u572880\u2103\u878d\u5316\uff0c\u7136\u540e\u5206\u6563\u5728\u8868\u9762\u6d3b\u6027\u5242F127\u6c34\u6eb6\u6db2\u4e2d\uff0c\u5f62\u6210\u5747\u5300\u7684\u5fae\u4e73\u6db2\u3002\u968f\u540e\u5c06\u8be5\u6eb6\u6db2\u51b7\u5374\u81f328\u2103\uff0c\u786c\u8102\u9178\u7ecf\u5386\u6db2\u76f8\u3001\u56fa\u76f8\u53ca\u5965\u65af\u7279\u74e6\u5c14\u5fb7\u719f\u5316\uff0c\u6700\u7ec8\u5f62\u6210\u786c\u8102\u9178\u7eb3\u7c73\u7247\u6eb6\u80f6\u6db2\u3002\u968f\u540e\u901a\u8fc7\u6c22\u952e\u4f5c\u7528\uff0c\u8bf1\u5bfc\u95f4\u82ef\u4e8c\u915a\/\u7532\u919b\/\u4e19\u80fa\u5728\u786c\u8102\u9178\u8584\u7247\u5468\u56f4\u8fdb\u884c\u754c\u9762\u7ec4\u88c5\u548c\u805a\u5408\uff0c\u6700\u540e\u7ecf\u70ed\u89e3\u5f97\u5230\u4e8c\u7ef4\u7eb3\u7c73\u70ad\u7247\u3002<\/p>\n

\u56fe2 \u6837\u54c1\u7684\u7ed3\u6784\u8868\u5f81\u56fe<\/strong><\/p>\n

\"\"<\/p>\n

(a<\/strong>) FCP-1\u7684SEM\u56fe\uff1b<\/p>\n

(b<\/strong>) \u786c\u8102\u9178\/\u95f4\u82ef\u4e8c\u915a\u8d28\u91cf\u6bd4\u4e0e\u70ad\u7247\u539a\u5ea6\u4e4b\u95f4\u7684\u5173\u7cfb\u56fe\uff1b<\/p>\n

(c,d<\/strong>) FCP-1\u7684TEM\u56fe\uff1b<\/p>\n

(e, f<\/strong>) FCP \u6837\u54c1\u7684N2\u5438\u9644\u7b49\u6e29\u7ebf\u548c\u5b54\u5f84\u5206\u5e03\u56fe\u3002<\/p>\n

\u56fe3 \u9759\u6001\u5438\u9644\u7b49\u6e29\u7ebf\u56fe\u4ee5\u53ca\u52a8\u6001\u7a7f\u900f\u66f2\u7ebf\u56fe\u7b49<\/strong><\/p>\n

\"\"<\/p>\n

(a<\/strong>) 0-0.1bar\u4e0b\u7684\u6c14\u4f53\u5438\u9644\u7b49\u6e29\u7ebf\uff1b<\/p>\n

(b<\/strong>) 0-1bar\u548c298K\u4e0b\u7684\u6c14\u4f53\u5438\u9644\u7b49\u6e29\u7ebf\uff1b<\/p>\n

(c<\/strong>) 298K\u4e0bx\/CH4\u6df7\u5408\u7269\u7684IAST\u9009\u62e9\u6027\uff1b<\/p>\n

(d<\/strong>) \u6c14\u4f53\u5438\u9644\u70ed\uff1b<\/p>\n

(e<\/strong>) 298K\u548c1bar\u4e0bx\/CH4\u7684\u52a8\u6001\u7a7f\u900f\u66f2\u7ebf\uff1b<\/p>\n

(f<\/strong>) C3H8\/CH4\u6df7\u5408\u7269\u768410\u6b21\u5faa\u73af\u5b9e\u9a8c\u56fe\u3002<\/p>\n

\u3010\u5c0f\u7ed3<\/strong>\u3011<\/p>\n

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\u6587\u732e\u94fe\u63a5<\/strong>\uff1aThermoregulated Phase-Transition Synthesis of Two-Dimensional Carbon Nanoplates Rich in sp2 Carbon and Unimodal Ultramicropores for Kinetic Gas Separation<\/a> (Angew. Chem. Int. Ed., 17 January , 2018 , DOI: 10.1002\/anie.201712913\uff09<\/p>\n

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