{"id":122257,"date":"2018-01-23T14:00:18","date_gmt":"2018-01-23T06:00:18","guid":{"rendered":"\/\/m.iemloyee.com\/?p=122257"},"modified":"2018-01-20T20:18:57","modified_gmt":"2018-01-20T12:18:57","slug":"%e7%a6%8f%e5%a4%a7%e7%8e%8b%e5%bf%83%e6%99%a8adv-funct-mater-%e9%bb%91%e7%a3%b7%e6%b0%ae%e5%8c%96%e7%a2%b3%e5%bc%82%e8%b4%a8%e7%bb%93%e5%85%89%e5%82%ac%e5%8c%96%e5%88%86%e5%ad%90%e6%b0%a7","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=122257","title":{"rendered":"\u798f\u5927\u738b\u5fc3\u6668Adv. Funct. Mater. :\u9ed1\u78f7\/\u6c2e\u5316\u78b3\u5f02\u8d28\u7ed3\u5149\u50ac\u5316\u5206\u5b50\u6c27\u6d3b\u5316"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n

\u5206\u5b50\u6c27\u662f\u7eff\u8272\u3001\u50a8\u91cf\u4e30\u5bcc\u3001\u5ec9\u4ef7\u7684\u6c27\u5316\u5242\u3002\u4e0d\u5e78\u7684\u662f\uff0c\u5927\u90e8\u5206\u6709\u673a\u7269\u7531\u4e8e\u81ea\u65cb\u7981\u963b\u53cd\u5e94\uff0c\u5728\u6e29\u548c\u6761\u4ef6\u4e0b\u4e0d\u80fd\u88ab\u6c27\u5206\u5b50\u6c27\u5316\u3002\u5149\u50ac\u5316\u6d3b\u5316\u5206\u5b50\u6c27\u53ef\u4ee5\u901a\u8fc7\u534a\u5bfc\u4f53\u8868\u9762\u7684\u5149\u751f\u7535\u5b50(e–<\/sup>)\u8fd8\u539f\u6c27\u6c14\u5b9e\u73b0\uff0c\u5e76\u751f\u6210\u9ad8\u6d3b\u6027\u7684\u6d3b\u6027\u6c27\u7269\u79cd(ROS)\uff0c\u5982\u8d85\u6c27\u81ea\u7531\u57fa(\u00b7O2<\/sub><\/span>–<\/sup>)\u3001\u7f9f\u57fa\u81ea\u7531\u57fa(\u00b7OH)\u3001\u5355\u7ebf\u6001\u6c27(1<\/sup>O2<\/sub>)\u548c\u8fc7\u6c27\u5316\u6c22(H2<\/sub>O2<\/sub>)\u3002\u76ee\u524d\uff0c\u7814\u7a76\u4eba\u5458\u5df2\u5bf9\u90e8\u5206\u542b\u6709\u91d1\u5c5e\u7684\u534a\u5bfc\u4f53\u7684\u5206\u5b50\u6c27\u6d3b\u5316\u6027\u80fd\u8fdb\u884c\u4e86\u63a2\u7a76\uff0c\u4f46\u9762\u4e34\u7740\u5927\u89c4\u6a21\u751f\u4ea7\u7684\u7ecf\u6d4e\u6210\u672c\u95ee\u9898\u3002\u56e0\u6b64\uff0c\u5229\u7528\u50a8\u91cf\u4e30\u5bcc\u7684\u975e\u91d1\u5c5e\u5143\u7d20\u6784\u7b51\u5177\u6709\u826f\u597d\u53ef\u89c1\u5149\u5438\u6536\u53ca\u9ad8\u50ac\u5316\u5206\u5b50\u6c27\u6d3b\u5316\u6d3b\u6027\u7684\u5149\u50ac\u5316\u5242\u4ecd\u7136\u662f\u5177\u6709\u6311\u6218\u6027\u7684\u4efb\u52a1\u3002\u975e\u91d1\u5c5e\u7684\u5c42\u72b6\u534a\u5bfc\u4f53\uff0c\u5982\u805a\u5408\u7269\u6c2e\u5316\u78b3(CN)\u548c\u9ed1\u78f7(BP)\uff0c\u5df2\u6210\u4e3a\u6709\u5438\u5f15\u529b\u7684\u7528\u4e8e\u5206\u5b50\u6c27\u6d3b\u5316\u3001\u6c61\u67d3\u7269\u964d\u89e3\u3001\u5206\u89e3\u6c34\u53ef\u89c1\u5149\u50ac\u5316\u5242\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u798f\u5dde\u5927\u5b66\u738b\u5fc3\u6668\u6559\u6388(\u901a\u8baf\u4f5c\u8005)\u7b49<\/strong>\u901a\u8fc7\u8d85\u58f0\u8f85\u52a9\u4e00\u6b65\u6db2\u76f8\u5265\u5c42\u6cd5\u6210\u529f\u5730\u5236\u5907\u4e86\u4e0d\u542b\u91d1\u5c5e\u7684\u9ed1\u78f7(BP)\u548c\u805a\u5408\u7269\u6c2e\u5316\u78b3(CN)\u7ec4\u6210\u7684\u5f02\u8d28\u7ed3\u5149\u50ac\u5316\u5242\uff0c\u5e76\u5728Adv. Funct. Mater.<\/strong>\u4e0a\u53d1\u8868\u4e86\u9898\u4e3a\u201cBlack Phosphorus and Polymeric Carbon Nitride Heterostructure for Photoinduced Molecular Oxygen Activation<\/strong>\u201d\u7684\u7814\u7a76\u8bba\u6587\u3002BP\u4e0eCN\u590d\u5408\u589e\u5f3a\u4e86\u53ef\u89c1\u5149\u5438\u6536\u80fd\u529b\uff0c\u4fc3\u8fdb\u4e86\u5149\u50ac\u5316\u8fc7\u7a0b\u4e2d\u7535\u8377\u5206\u79bb\uff0c\u63d0\u5347\u4e86\u5149\u8bf1\u5bfc\u7684\u5206\u5b50\u6c27\u6d3b\u5316\u80fd\u529b\uff0c\u52a0\u901f\u4e86\u8d85\u6c27\u81ea\u7531\u57fa(\u00b7O2<\/sub>–<\/sup>)\u548c\u8fc7\u6c27\u5316\u6c22\u7684\u4ea7\u751f\u3002\u8be5\u5de5\u4f5c\u5f3a\u8c03\u4e86\u5c06\u80fd\u7ea7\u76f8\u914d\u7684\u534a\u5bfc\u4f53\u590d\u5408\u53ef\u4e3a\u63d0\u5347\u5149\u50ac\u5316\u5242\u4ea7\u751f\u6d3b\u6027\u6c27\u7269\u79cd\u6027\u80fd\u63d0\u4f9b\u4e00\u6761\u7b80\u5355\u3001\u53ef\u884c\u7684\u8def\u7ebf\u3002<\/p>\n

\u3010\u56fe\u6587\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u56fe1 BP\/CN\u5f02\u8d28\u7ed3\u5236\u5907\u793a\u610f\u56fe<\/strong><\/p>\n

\"\"<\/p>\n

\u8d85\u58f0\u8f85\u52a9\u6db2\u76f8\u5265\u5c42\u6cd5\u5236\u5907BP\/CN\u5f02\u8d28\u7ed3\u5149\u50ac\u5316\u5242\u793a\u610f\u56fe\u3002<\/p>\n

\u56fe2 10% BP\/CN\u7eb3\u7c73\u7247\u7684\u5f62\u8c8c\u8868\u5f81<\/strong><\/p>\n

\"\"<\/p>\n

a) 10% BP\/CN\u7eb3\u7c73\u7247\u7684SEM\u56fe\u50cf\uff1b<\/p>\n

b) 10% BP\/CN\u7eb3\u7c73\u7247\u7684TEM\u56fe\u50cf\uff1b<\/p>\n

c) 10% BP\/CN\u7eb3\u7c73\u7247\u7684HRTEM\u56fe\u50cf\uff1b<\/p>\n

d) 10% BP\/CN\u7eb3\u7c73\u7247\u7684AFM\u56fe\u50cf\u4ee5\u53ca\u76f8\u5e94\u7684\u539a\u5ea6\u66f2\u7ebf\u3002<\/p>\n

\u56fe3 BP\/CN\u5f02\u8d28\u7ed3\u7684\u6676\u4f53\u7ed3\u6784\u548c\u5149\u5438\u6536\u8868\u5f81<\/strong><\/p>\n

\"\"<\/p>\n

a) BP\/CN\u5f02\u8d28\u7ed3\u7684XRD\u8c31\u56fe\uff1b<\/p>\n

b) BP\/CN\u5f02\u8d28\u7ed3\u6837\u54c1\u7684\u7d2b\u5916\u53ef\u89c1\u6f2b\u53cd\u5c04\u5149\u8c31\u548c\u7167\u7247\u3002<\/p>\n

\u56fe4 BP\/CN\u5f02\u8d28\u7ed3\u7684\u5149\u50ac\u5316\u5206\u5b50\u6c27\u6d3b\u5316\u6027\u80fd(1)<\/strong><\/p>\n

\"\"<\/p>\n

a) BP\u3001CN\u548cBP\/CN\u5149\u50ac\u5316\u964d\u89e3RhB\u6027\u80fd\u6bd4\u8f83(\u03bb > 420 nm)\uff1b<\/p>\n

b) 10% BP\/CN\u5149\u50ac\u5316\u964d\u89e3RhB\u8fc7\u7a0b\u4e2d\u6d3b\u6027\u7269\u79cd\u7684\u5f71\u54cd\uff1b<\/p>\n

c) \u53ef\u89c1\u5149\u4e0b10% BP\/CN\u7684EPR\u5149\u8c31\uff1b<\/p>\n

d) BP\u3001CN\u548c10% BP\/CN\u5149\u50ac\u5316\u00b7O2<\/sub>\u2212<\/sup>\u4ea7\u751f\u66f2\u7ebf\u3002<\/p>\n

\u56fe5 BP\/CN\u5f02\u8d28\u7ed3\u7684\u5149\u50ac\u5316\u5206\u5b50\u6c27\u6d3b\u5316\u6027\u80fd(2)<\/strong><\/p>\n

\"\"<\/p>\n

a) BP\/CN \u7cfb\u5217\u6837\u54c1\u5149\u50ac\u5316H2<\/sub>O2<\/sub>\u4ea7\u751f\u66f2\u7ebf\uff1b<\/p>\n

b) 10% BP\/CN \u5149\u50ac\u5316H2<\/sub>O2<\/sub>\u4ea7\u751f\u7684\u6ce2\u957f\u4f9d\u8d56\u6027\uff1b<\/p>\n

c) 10% BP\/CN \u5149\u50ac\u5316H2<\/sub>O2<\/sub>\u4ea7\u751f\u957f\u6548\u5b9e\u9a8c\uff1b<\/p>\n

d) BP\/CN\u80fd\u5e26\u7ed3\u6784\u793a\u610f\u56fe\u3002<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n

\u7814\u7a76\u4eba\u5458\u901a\u8fc7\u7b80\u5355\u7684\u8d85\u58f0\u8f85\u52a9\u6db2\u76f8\u5265\u79bb\u6cd5\u5236\u5907\u4e86\u975e\u91d1\u5c5e\u7684BP\/CN\u5f02\u8d28\u7ed3\u5149\u50ac\u5316\u5242\u3002\u5f97\u76ca\u4e8eBP\/CN\u590d\u5408\u6750\u6599\u5bbd\u5e7f\u7684\u53ef\u89c1\u5149\u5438\u6536\u8303\u56f4\u3001\u4e30\u5bcc\u7684\u6d3b\u6027\u4f4d\u70b9\u4ee5\u53ca\u6709\u6548\u7684\u7535\u8377\u5206\u79bb\uff0c\u5176\u8868\u73b0\u51fa\u4f18\u5f02\u7684\u5149\u50ac\u5316\u5206\u5b50\u6c27\u6d3b\u5316\u6d3b\u6027\uff0c\u52a0\u901f\u4e86\u8d85\u6c27\u81ea\u7531\u57fa\u548c\u8fc7\u6c27\u5316\u6c22\u7684\u4ea7\u751f\u3002BP\u6bd4\u4f8b10 wt%\u65f6\u6700\u4f18\uff0c\u7167\u5c0415 min\u53ef\u5206\u89e398%\u7684RhB\uff0c10% BP\/CN\u590d\u5408\u6750\u6599\u7684\u901f\u7387\u5e38\u6570\u662f\u539f\u59cbCN\u7684\u51e0\u4e4e\u56db\u500d\u3002\u8be5\u7814\u7a76\u63ed\u793a\u4e86\u6784\u5efa\u5f02\u8d28\u7ed3\u4ee5\u63d0\u5347\u5149\u50ac\u5316\u6d3b\u6027\u7684\u524d\u666f\u5e7f\u9614\uff0c\u5728\u73af\u5883\u6cbb\u7406\u3001\u8d85\u7ea7\u7535\u5bb9\u5668\u548c\u9502\u79bb\u5b50\u7535\u6c60\u7b49\u5176\u4ed6\u9886\u57df\u5e94\u7528\u6f5c\u529b\u5de8\u5927\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a Black Phosphorus and Polymeric Carbon Nitride Heterostructure for Photoinduced Molecular Oxygen Activation<\/a><\/strong>\u00a0(Adv. Funct. Mater., 2018, DOI: 10.1002\/adfm.201705407)<\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u7f16\u8f91\u90e8\u65b0\u80fd\u6e90\u5c0f\u7ec4abc940504\u7f16\u8bd1\u6574\u7406\uff0c\u53c2\u4e0e\u65b0\u80fd\u6e90\u8bdd\u9898\u8ba8\u8bba\u8bf7\u52a0\u5165\u201c\u6750\u6599\u4eba\u65b0\u80fd\u6e90\u6750\u6599\u4ea4\u6d41\u7fa4 422065953\u201d\u3002<\/p>\n

\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1aRDD-2011-CHERISH\uff0c\u4efb\u4e39\u4e39\uff0c\u6211\u4eec\u4f1a\u9080\u8bf7\u5404\u4f4d\u8001\u5e08\u52a0\u5165\u4e13\u5bb6\u7fa4\u3002<\/strong><\/p>\n

\u6750\u6599\u725b\u7f51\u4e13\u6ce8\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u53ca\u884c\u4e1a\u8fdb\u5c55\uff0c\u5982\u679c\u60a8\u5bf9\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u8fdb\u5c55\uff0c\u89e3\u8bfb\u9ad8\u6c34\u5e73\u6587\u7ae0\u6216\u662f\u8bc4\u8ff0\u884c\u4e1a\u6709\u5174\u8da3\uff0c\u70b9\u6211\u52a0\u5165\u7f16\u8f91\u90e8<\/a><\/strong>\u3002\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1tougao@cailiaoren.com\u3002<\/p>\n

\u4eea\u5668\u8bbe\u5907\u3001\u8bd5\u5242\u8017\u6750\u3001\u6750\u6599\u6d4b\u8bd5\u3001\u6570\u636e\u5206\u6790\uff0c\u627e\u6750\u6599\u4eba\u3001\u4e0a\u6d4b\u8bd5\u8c37<\/a><\/strong>\uff01<\/p>\n","protected":false},"excerpt":{"rendered":"

\u3010\u5f15\u8a00\u3011 \u5206\u5b50\u6c27\u662f\u7eff\u8272\u3001\u50a8\u91cf\u4e30\u5bcc\u3001\u5ec9\u4ef7\u7684\u6c27\u5316\u5242\u3002\u4e0d\u5e78\u7684\u662f\uff0c\u5927\u90e8\u5206\u6709\u673a\u7269\u7531\u4e8e\u81ea\u65cb\u7981\u963b\u53cd\u5e94\uff0c\u5728\u6e29\u548c\u6761\u4ef6\u4e0b\u4e0d\u80fd\u88ab\u6c27\u5206\u5b50\u6c27\u5316\u3002\u5149\u50ac\u5316\u6d3b\u5316\u5206\u5b50\u6c27\u53ef\u4ee5\u901a\u8fc7\u534a\u5bfc\u4f53\u8868\u9762\u7684\u5149\u751f\u7535…<\/p>\n","protected":false},"author":4931,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[2761],"class_list":["post-122257","post","type-post","status-publish","format-standard","hentry","category-jiedu","tag-2761"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/122257"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/4931"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=122257"}],"version-history":[{"count":3,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/122257\/revisions"}],"predecessor-version":[{"id":122454,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/122257\/revisions\/122454"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=122257"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=122257"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=122257"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}