{"id":122251,"date":"2018-01-24T06:30:12","date_gmt":"2018-01-23T22:30:12","guid":{"rendered":"\/\/m.iemloyee.com\/?p=122251"},"modified":"2018-01-20T20:25:20","modified_gmt":"2018-01-20T12:25:20","slug":"angew-chem-int-ed-%ef%bc%9a%e9%bb%91%e7%a3%b7%e9%92%92%e9%85%b8%e9%93%8bz%e5%9e%8b2d%e5%bc%82%e8%b4%a8%e7%bb%93%e5%8f%af%e8%a7%81%e5%85%89%e5%82%ac%e5%8c%96%e5%88%86%e8%a7%a3%e6%b0%b4","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=122251","title":{"rendered":"Angew. Chem. Int. Ed.\uff1a\u9ed1\u78f7\/\u9492\u9178\u94cbZ\u578b2D\u5f02\u8d28\u7ed3\u53ef\u89c1\u5149\u50ac\u5316\u5206\u89e3\u6c34"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n

\u8d85\u8584\u4e8c\u7ef4(2D)\u7eb3\u7c73\u6750\u6599\u662f\u6750\u6599\u548c\u7eb3\u7c73\u79d1\u5b66\u9886\u57df\u4e00\u9897\u5189\u5189\u5347\u8d77\u7684\u65b0\u661f\uff0c\u5728\u8fc7\u53bb\u7684\u5341\u5e74\uff0c\u5176\u5728\u7535\u5b50\u3001\u50ac\u5316\u3001\u80fd\u91cf\u8f6c\u6362\u7b49\u9886\u57df\u90fd\u53d6\u5f97\u4e86\u6781\u5927\u7684\u7a81\u7834\u3002\u4f5c\u4e3a2D\u5bb6\u65cf\u7684\u65b0\u6210\u5458\u4e4b\u4e00\uff0c\u8d85\u8584\u9ed1\u78f7(BP)\u7531\u4e8e\u5176\u72ec\u7279\u7684\u7269\u7406\u5316\u5b66\u3001\u5149\u5b66\u4ee5\u53ca\u7535\u5b50\u7279\u6027\uff0c\u5728\u80fd\u6e90\u3001\u751f\u7269\u548c\u73af\u5883\u7b49\u76f8\u5173\u9886\u57df\u8fc5\u901f\u751f\u6839\u53d1\u82bd\uff0c\u5f97\u5230\u5e94\u7528\u3002\u9ed1\u78f7\u662f\u4e00\u79cd\u534a\u5bfc\u4f53\uff0c\u5176\u534a\u5bfc\u4f53\u6027\u8d28\u4f7f\u5f97\u9ed1\u78f7\u5728\u5149\u50ac\u5316\u9886\u57df\u4e2d\u7684\u5e94\u7528\u524d\u666f\u826f\u597d\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u65e5\u672c\u5927\u962a\u5927\u5b66Tetsuro Majima\u6559\u6388\u3001Mamoru Fujitsuka\u6559\u6388(\u5171\u540c\u901a\u8baf\u4f5c\u8005)\u7b49<\/strong>\u8bbe\u8ba1\u4e86\u57fa\u4e8e\u9ed1\u78f7(BP)\/\u9492\u9178\u94cb(BiVO4)\u7684\u4e8c\u7ef4(2D)\u5f02\u8d28\u7ed3\u6784\u7684\u65b0\u578b\u4eba\u5de5Z\u578b\u5149\u50ac\u5316\u4f53\u7cfb\uff0c\u5e76\u5728Angew. Chem. Int. Ed.<\/strong>\u4e0a\u53d1\u8868\u4e86\u9898\u4e3a\u201cZ-Scheme Photocatalytic Water Splitting on a 2D Heterostructure of Black Phosphorus\/Bismuth Vanadate Using Visible Light<\/strong>\u201d\u7684\u6587\u7ae0\u3002\u8be5\u8bba\u6587\u88ab\u9009\u4e3a\u91cd\u70b9(VIP)\u8bba\u6587\u3002\u9ad8\u6548\u7684\u7535\u8377\u5206\u79bb\u4f7f\u5f97BP\u8fd8\u539f\u6c34\u548cBiVO4<\/sub>\u6c27\u5316\u6c34\u6210\u4e3a\u53ef\u80fd\u3002\u03bb\u2265420 nm\u65f6BP \/BiVO4<\/sub>\u6700\u4f18\u5236\u6c22\u6790\u6c27\u901f\u7387\u5206\u522b\u4e3a160\u548c102 \u03bcmol\u00b7g-1<\/sup>\u00b7h-1<\/sup>\uff0c\u53ef\u4ee5\u4e0d\u4f7f\u7528\u4efb\u4f55\u727a\u7272\u5242\u6216\u5916\u52a0\u504f\u538b\u3002<\/p>\n

\u3010\u56fe\u6587\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u56fe1 BP\/BiVO4<\/sub>\u5f02\u8d28\u7ed3\u7684\u5f62\u8c8c\u548c\u5143\u7d20\u5206\u6790<\/strong><\/p>\n

\"\"<\/p>\n

a,b) BP\/BiVO4<\/sub>\u5f02\u8d28\u7ed3\u7684HAADF-STEM\u56fe\u50cf\uff1b<\/p>\n

c,d) BP\/BiVO4<\/sub>\u5f02\u8d28\u7ed3\u7684HRTEM\u56fe\u50cf\uff1b<\/p>\n

e) BP\/BiVO4<\/sub>\u5f02\u8d28\u7ed3\u7684\u78f7\u5143\u7d20\u5206\u5e03\uff1b<\/p>\n

f) BP\/BiVO4<\/sub>\u5f02\u8d28\u7ed3\u7684\u94cb\u5143\u7d20\u5206\u5e03\uff1b<\/p>\n

g) BP\/BiVO4<\/sub>\u5f02\u8d28\u7ed3\u7684\u6c27\u5143\u7d20\u5206\u5e03\uff1b<\/p>\n

h) BP\/BiVO4<\/sub>\u5f02\u8d28\u7ed3\u7684\u9492\u5143\u7d20\u5206\u5e03\u3002<\/p>\n

\u56fe2 BP\/BiVO4<\/sub>\u5f02\u8d28\u7ed3\u7684\u5236\u6c22\u673a\u7406<\/strong><\/p>\n

\"\"<\/p>\n

\u53ef\u89c1\u5149\u7167\u5c04\u4e0bBP\/BiVO4<\/sub>\u5f02\u8d28\u7ed3\u5149\u50ac\u5316\u5206\u89e3\u6c34\u7684Z\u578b\u673a\u7406<\/p>\n

\u56fe3 BP\/BiVO4<\/sub>\u5f02\u8d28\u7ed3\u7684\u5149\u50ac\u5316\u5206\u89e3\u6c34\u6027\u80fd<\/strong><\/p>\n

\"\"<\/p>\n

a) BP\/BiVO4<\/sub>\u5f02\u8d28\u7ed3\u5728\u6709\u65e0\u727a\u7272\u8bd5\u5242\u5b58\u5728\u4e0b\u7684\u5149\u50ac\u5316\u5236\u6c22\u6027\u80fd(\u03bb>420 nm)\uff1b<\/p>\n

b) BP\/BiVO4<\/sub>\u5f02\u8d28\u7ed3\u5728\u6709\u65e0\u727a\u7272\u8bd5\u5242\u5b58\u5728\u4e0b\u7684\u5149\u50ac\u5316\u6790\u6c27\u6027\u80fd(\u03bb>420 nm)\uff1b<\/p>\n

c) BP\/BiVO4<\/sub>\u5f02\u8d28\u7ed3\u5728\u65e0\u727a\u7272\u8bd5\u5242\u5b58\u5728\u4e0b\u7684\u5149\u50ac\u5316\u5206\u89e3\u6c34\u6027\u80fd(\u03bb>420 nm)\uff1b<\/p>\n

d) BP\/BiVO4<\/sub>\/Co3<\/sub>O4<\/sub>\u5f02\u8d28\u7ed3\u5728\u6709\u65e0\u727a\u7272\u8bd5\u5242\u5b58\u5728\u4e0b\u7684\u5149\u50ac\u5316\u5206\u89e3\u6c34\u6027\u80fd(\u03bb>420 nm)\uff1b<\/p>\n

e) BP \u6bd4\u4f8b\u5bf9BP\/BiVO4<\/sub>\/Co3<\/span>O4<\/sub>\u5f02\u8d28\u7ed3\u5206\u89e3\u6c34\u6027\u80fd\u7684\u5f71\u54cd\uff1b<\/p>\n

f) BP\/BiVO4<\/sub>\/Co3<\/sub>O4<\/sub>\u5f02\u8d28\u7ed3\u7684\u5faa\u73af\u7a33\u5b9a\u6027\u6d4b\u8bd5\u3002<\/p>\n

\u56fe4 BP\/BiVO4<\/sub>\u5f02\u8d28\u7ed3Z\u578b\u673a\u7406\u9a8c\u8bc1<\/strong><\/p>\n

\"\"<\/p>\n

a,b) BiVO4<\/sub>\u8fd1\u7ea2\u5916\u548c\u53ef\u89c1\u5149\u533a\u57df\u7684\u77ac\u6001\u5438\u6536\u5149\u8c31\uff1b<\/p>\n

c,d) BP\/BiVO4<\/sub>\u8fd1\u7ea2\u5916\u548c\u53ef\u89c1\u5149\u533a\u57df\u7684\u77ac\u6001\u5438\u6536\u5149\u8c31\uff1b<\/p>\n

e) 900 nm\u5904\u5f52\u4e00\u5316\u77ac\u6001\u5438\u6536\u66f2\u7ebf\uff1b<\/p>\n

f) 625 nm\u5904\u5f52\u4e00\u5316\u77ac\u6001\u5438\u6536\u66f2\u7ebf\u3002<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n

\u7814\u7a76\u4eba\u5458\u9996\u6b21\u6784\u7b51\u4e86BP\u548cBiVO4<\/sub>\u76842D\u5f02\u8d28\u7ed3\u6784\uff0c\u5e76\u5c06\u5176\u4f5c\u4e3a\u9ad8\u6548Z\u578b\u5149\u50ac\u5316\u5242\u5206\u89e3\u6c34\u5236\u6c22\u6c14\u548c\u6c27\u6c14\u3002\u5728\u6ca1\u6709\u4efb\u4f55\u727a\u7272\u8bd5\u5242\u548c\u5916\u52a0\u504f\u538b\u7684\u60c5\u51b5\u4e0b\uff0c\u4f7f\u7528BP\/BiVO4<\/sub>\u5f02\u8d28\u7ed3\u6784\uff0c\u53ef\u89c1\u5149\u8f90\u7167\u4e0b\u53ef\u89c2\u5bdf\u5230\u7eaf\u6c34\u5206\u89e3\u4ea7\u751f\u6c22\u6c14\u548c\u6c27\u6c14\u3002\u5176\u80fd\u5e26\u7ed3\u6784\u7684\u4ea4\u9519\u6392\u5217\u6709\u52a9\u4e8e\u7535\u8377\u5206\u79bb\uff0c\u4f7f\u5f97\u6c34\u7684\u8fd8\u539f\u548c\u6c27\u5316\u5206\u522b\u53d1\u751f\u4e8e\u9ed1\u78f7\u548cBiVO4<\/sub>\u3002\u4e0a\u8ff0\u7ed3\u679c\u663e\u793a\u4f7f\u7528Z\u578b\u7ed3\u6784\u8bbe\u8ba1\u5c06BP\u548cBiVO4<\/sub>\u7684\u4f18\u52bf\u76f8\u7ed3\u5408\u5728\u5168\u5206\u89e3\u6c34\u9886\u57df\u524d\u666f\u826f\u597d\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a Z-Scheme Photocatalytic Water Splitting on a 2D Heterostructure of Black Phosphorus\/Bismuth Vanadate Using Visible Light<\/a><\/strong>\u00a0(Angew. Chem. Int. Ed., 2017, DOI: 10.1002\/anie.201711357)<\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u7f16\u8f91\u90e8\u65b0\u80fd\u6e90\u5c0f\u7ec4abc940504\u7f16\u8bd1\u6574\u7406\uff0c\u53c2\u4e0e\u65b0\u80fd\u6e90\u8bdd\u9898\u8ba8\u8bba\u8bf7\u52a0\u5165\u201c\u6750\u6599\u4eba\u65b0\u80fd\u6e90\u6750\u6599\u4ea4\u6d41\u7fa4 422065953\u201d\u3002<\/p>\n

\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1aRDD-2011-CHERISH\uff0c\u4efb\u4e39\u4e39\uff0c\u6211\u4eec\u4f1a\u9080\u8bf7\u5404\u4f4d\u8001\u5e08\u52a0\u5165\u4e13\u5bb6\u7fa4\u3002<\/strong><\/p>\n

\u6750\u6599\u725b\u7f51\u4e13\u6ce8\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u53ca\u884c\u4e1a\u8fdb\u5c55\uff0c\u5982\u679c\u60a8\u5bf9\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u8fdb\u5c55\uff0c\u89e3\u8bfb\u9ad8\u6c34\u5e73\u6587\u7ae0\u6216\u662f\u8bc4\u8ff0\u884c\u4e1a\u6709\u5174\u8da3\uff0c\u70b9\u6211\u52a0\u5165\u7f16\u8f91\u90e8<\/a><\/strong>\u3002\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1tougao@cailiaoren.com\u3002<\/p>\n

\u4eea\u5668\u8bbe\u5907\u3001\u8bd5\u5242\u8017\u6750\u3001\u6750\u6599\u6d4b\u8bd5\u3001\u6570\u636e\u5206\u6790\uff0c\u627e\u6750\u6599\u4eba\u3001\u4e0a\u6d4b\u8bd5\u8c37<\/a><\/strong>\uff01<\/p>\n","protected":false},"excerpt":{"rendered":"

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