{"id":121958,"date":"2018-01-20T06:30:56","date_gmt":"2018-01-19T22:30:56","guid":{"rendered":"\/\/m.iemloyee.com\/?p=121958"},"modified":"2018-02-12T18:22:31","modified_gmt":"2018-02-12T10:22:31","slug":"%e5%8d%97%e4%ba%ac%e5%a4%a7%e5%ad%a6%e9%97%ab%e4%b8%96%e6%88%90%e8%af%be%e9%a2%98%e7%bb%84%e4%b8%a8acs-catalysis-%e7%9b%b4%e6%8e%a5%e5%88%86%e8%a7%a3%e6%b0%a7%e5%8c%96%e7%89%a9%e5%88%86%e5%ad%90","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=121958","title":{"rendered":"\u5357\u4eac\u5927\u5b66\u95eb\u4e16\u6210\u8bfe\u9898\u7ec4\u4e28ACS Catalysis\uff1a\u76f4\u63a5\u5206\u89e3\u6c27\u5316\u7269\u5206\u5b50\u4f9b\u6c27"},"content":{"rendered":"<p><span style=\"color: #ff0000\"><strong>\u3010\u5f15\u8a00\u3011<\/strong><\/span><\/p>\n<p>\u4fdd\u62a4\u73af\u5883\u662f\u5b9e\u73b0\u4eba\u7c7b\u793e\u4f1a\u53ef\u6301\u7eed\u53d1\u5c55\u7684\u57fa\u672c\u524d\u63d0\uff0c\u6d88\u9664\u6c14\u6001\u6c27\u5316\u7269\u5206\u5b50\u6c61\u67d3\u7269\uff0c\u5982CO<sub>x <\/sub>(CO<sub>2<\/sub>\uff0cCO)\uff0cSO<sub>x <\/sub>(SO<sub>2<\/sub>\uff0cSO<sub>3<\/sub>)\uff0cNO<sub>x <\/sub>(NO\uff0cNO<sub>2<\/sub>) \u7b49\uff0c\u5bf9\u6784\u5efa\u548c\u8c10\u751f\u6001\u73af\u5883\u5177\u6709\u91cd\u8981\u610f\u4e49\u3002\u4f20\u7edf\u7684\u6c27\u5316\u7269\u5206\u5b50\u8f6c\u5316\u6280\u672f\uff0c\u9700\u8981\u4f7f\u7528\u8fd8\u539f\u5242\u548c\u6602\u8d35\u7684\u8d35\u91d1\u5c5e\u50ac\u5316\u5242\uff0c\u56e0\u800c\u6210\u672c\u548c\u80fd\u8017\u8f83\u9ad8\u3002\u5149\u50ac\u5316\u5229\u7528\u592a\u9633\u5149\u6fc0\u53d1\u534a\u5bfc\u4f53\u6750\u6599\u4ea7\u751f\u7535\u5b50-\u7a7a\u7a74\u5bf9\u9a71\u52a8\u6c27\u5316\u8fd8\u539f\u53cd\u5e94\uff0c\u88ab\u8ba4\u4e3a\u662f\u4e00\u79cd\u6f5c\u5728\u7684\u4f4e\u6210\u672c\u3001\u4f4e\u80fd\u8017\u7684\u50ac\u5316\u53cd\u5e94\u6280\u672f\u3002\u7136\u800c\uff0c\u7531\u4e8e\u6c27\u5316\u7269\u5206\u5b50\u901a\u5e38\u662f\u70ed\u529b\u5b66\u7a33\u5b9a\u7684\uff0c\u8fd9\u5bfc\u81f4\u76f4\u63a5\u5206\u89e3\u8fd9\u4e00\u7c7b\u5206\u5b50\u4e3a\u5355\u8d28\u5341\u5206\u56f0\u96be\uff0c\u5982\u4f55\u6291\u5236\u4e2d\u95f4\u4ea7\u7269\u9006\u53cd\u5e94\u8fc7\u7a0b\u662f\u5b9e\u73b0\u6c27\u5316\u7269\u5206\u5b50\u5206\u89e3\u7684\u5173\u952e\u6240\u5728\u3002<\/p>\n<p><span style=\"color: #ff0000\"><strong>\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/span><\/p>\n<p>\u8fd1\u671f\uff0c<strong>\u5357\u4eac\u5927\u5b66\u73b0\u4ee3\u5de5\u7a0b\u4e0e\u5e94\u7528\u79d1\u5b66\u9662\u95eb\u4e16\u6210\u8bfe\u9898\u7ec4<\/strong>\u62a5\u9053\u4e86\u4e00\u79cd\u5229\u7528\u5149\u81f4\u7f3a\u9677\u8f85\u52a9\u76f4\u63a5\u5206\u89e3\u6c27\u5316\u7269\u5206\u5b50\u4ea7\u751f\u6c27\u6c14\u7684\u53cd\u5e94\u9014\u5f84\uff0c\u76f8\u5173\u5de5\u4f5c\u4ee5<strong>Oxygen-Vacancies Activated CO<sub>2<\/sub> Splitting over Amorphous Oxide Semiconductor Photocatalyst<\/strong>\u4e3a\u9898\u53d1\u8868\u5728\u7f8e\u56fd\u5316\u5b66\u4f1a\u50ac\u5316\u671f\u520a<strong><em>ACS Catalysis<\/em><\/strong>\u6742\u5fd7\u4e0a<strong>(ACS Catal. 2018, 8, 516<\/strong><strong>\u2212<\/strong><strong>525)<\/strong>\u3002\u8be5\u53cd\u5e94\u5229\u7528\u5149\u8150\u8680\u53cd\u5e94\uff0c\u901a\u8fc7\u5149\u751f\u7a7a\u7a74\u4e0e\u6c27\u5316\u7269\u534a\u5bfc\u4f53\u6750\u6599\u4e2d\u7684O\u539f\u5b50\u53cd\u5e94\u4ea7\u751f\u6c27\u7f3a\u9677\uff0c\u4ee5\u6d3b\u5316\u3001\u6355\u83b7\u76ee\u6807\u6c14\u4f53\u5206\u5b50\u4e2d\u7684O\u539f\u5b50\u3002\u56e0\u6c27\u5316\u7269\u5206\u5b50\u4e2d\u7684\u6c27\u539f\u5b50\u88ab\u50ac\u5316\u5242\u6676\u683c\u6c27\u7a7a\u4f4d\u6355\u83b7\u800c\u6709\u6548\u6291\u5236\u4e86\u9006\u53cd\u5e94\u8fc7\u7a0b\uff0c\u5e76\u56e0\u5149\u751f\u7a7a\u7a74\u7684\u6301\u7eed\u6027\u6c27\u5316\u800c\u91ca\u653eO<sub>2<\/sub>\uff1b\u5149\u751f\u7535\u5b50\u5c06\u76ee\u6807\u5206\u5b50CO<sub>x<\/sub>\uff0cSO<sub>x<\/sub>\uff0cNO<sub>x<\/sub>\u4e2d\u7684C\u3001S\u548cN\u7269\u79cd\u8fd8\u539f\u4e3a\u76f8\u5e94\u7684C\u3001S\u548cN<sub>2<\/sub>\u3002<\/p>\n<p><span style=\"color: #ff0000\"><strong>\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/span><\/p>\n<p><span style=\"color: #3366ff\"><strong>\u56fe1 \u5149\u50ac\u5316\u5206\u89e3CO<sub>2<\/sub>\u53cd\u5e94\u673a\u7406\u793a\u610f\u56fe<\/strong><\/span><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-121961 aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/01\/1-19.png\" alt=\"\" width=\"445\" height=\"271\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/01\/1-19.png 445w, \/\/m.iemloyee.com\/wp-content\/uploads\/2018\/01\/1-19-300x183.png 300w\" sizes=\"(max-width: 445px) 100vw, 445px\" \/><\/p>\n<p><span style=\"color: #3366ff\"><strong>\u56fe2 \u6837\u54c1<\/strong><strong>EPR\u53ca\u7d2b\u5916\u53ef\u89c1\u5438\u6536\u5149\u8c31<\/strong><\/span><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-121962 aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/01\/2-16.png\" alt=\"\" width=\"558\" height=\"220\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/01\/2-16.png 558w, \/\/m.iemloyee.com\/wp-content\/uploads\/2018\/01\/2-16-300x118.png 300w\" sizes=\"(max-width: 558px) 100vw, 558px\" \/><\/p>\n<p>(a)\u00a0\u6837\u54c1\u4e0d\u540c\u5149\u7167\u65f6\u95f4\u7684\u5ba4\u6e29EPR\u8c31\uff1b<\/p>\n<p>(b)\u00a0\u6837\u54c1\u4e0d\u540c\u5149\u7167\u65f6\u95f4\u7684\u7d2b\u5916\u53ef\u89c1\u5438\u6536\u8c31\u3002<\/p>\n<p><span style=\"color: #3366ff\"><strong>\u56fe3\u00a0<\/strong><strong>CO<sub>2<\/sub>\u5206\u89e3\u7684\u5b9e\u9a8c\u548c\u7406\u8bba\u8bc1\u636e<\/strong><\/span><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-121963 aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/01\/3-12.png\" alt=\"\" width=\"558\" height=\"451\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/01\/3-12.png 558w, \/\/m.iemloyee.com\/wp-content\/uploads\/2018\/01\/3-12-300x242.png 300w\" sizes=\"(max-width: 558px) 100vw, 558px\" \/><\/p>\n<p>(a) \u6837\u54c1\u5206\u522b\u5728CO<sub>2<\/sub>\u73af\u5883\u548c\u771f\u7a7a\u6761\u4ef6\u4e0b\u5149\u716748h\u7684\u5ba4\u6e29EPR\u8c31\uff1b<\/p>\n<p>(b) \u6837\u54c1\u5728C<sup>18<\/sup>O<sub>2<\/sub> \u548c<sup>13<\/sup>CO<sub>2<\/sub>\u5149\u7167\u4e0b\u7684\u4e8c\u6b21\u79bb\u5b50\u8d28\u8c31\uff1b<\/p>\n<p>(c) \u539f\u6837\u53ca\u5176\u5728CO<sub>2<\/sub>\u73af\u5883\u4e0b\u5149\u716748h\u7684NMR\u8c31\uff1b<\/p>\n<p>(d) CO<sub>2<\/sub>\u5438\u9644\u5728\u6837\u54c1\u8868\u9762\u7684\u7535\u8377\u5bc6\u5ea6\u5dee\u5f02\u3002<\/p>\n<p><span style=\"color: #3366ff\"><strong>\u56fe4 \u6837\u54c1\u4ea7\u78b3\u91cf\u3001\u91cf\u5b50\u6548\u7387\u53ca\u53cd\u5e94\u673a\u7406<\/strong><\/span><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-121964 aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/01\/4-15.png\" alt=\"\" width=\"558\" height=\"436\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/01\/4-15.png 558w, \/\/m.iemloyee.com\/wp-content\/uploads\/2018\/01\/4-15-300x234.png 300w\" sizes=\"(max-width: 558px) 100vw, 558px\" \/><\/p>\n<p>(a) \u5149\u81f4\u6c27\u7a7a\u4f4d\u6d53\u5ea6\u4e0e\u78b3\u4ea7\u7387\u5173\u7cfb\uff1b<\/p>\n<p>(b) CO<sub>2<\/sub>\u5206\u89e3\u53cd\u5e94\u91cf\u5b50\u6548\u7387\uff1b<\/p>\n<p>(c) \u5149\u50ac\u5316\u6750\u6599\u7684\u80fd\u7ea7\u4f4d\u7f6e\u4e0eCO<sub>2<\/sub>\u5206\u89e3\u80fd\u91cf\u9700\u6c42\uff1b<\/p>\n<p>(d) \u5206\u5b50\u5206\u89e3\u53cd\u5e94\u7ecf\u5386\u4e86\u4e24\u4e2a\u5149\u53cd\u5e94\u4e0e\u4e24\u4e2a\u6697\u53cd\u5e94\u6b65\u9aa4\u3002<\/p>\n<p><span style=\"color: #ff0000\"><strong>\u3010\u5c0f\u7ed3\u3011<\/strong><\/span><\/p>\n<p>\u672c\u7814\u7a76\u5229\u7528\u5149\u8150\u8680\u53cd\u5e94\u4ea7\u751f\u6c27\u7a7a\u4f4d\u4ee5\u6355\u83b7\u548c\u6d3b\u5316\u6c14\u4f53\u6c27\u5316\u7269\u5206\u5b50\uff0c\u5c06\u5176\u76f4\u63a5\u5206\u89e3\u4ea7\u751f\u6c27\u6c14\u3002\u8fd9\u4e00\u53cd\u5e94\u9014\u5f84\u6240\u9700\u80fd\u91cf\u6d88\u8017\u8f83\u4f4e\uff0c\u5e76\u4e14\u53ef\u4ee5\u5b9e\u73b0\u6301\u7eed\u6027\u5149\u7167\u5206\u89e3\u6c14\u6001\u5206\u5b50\u4ea7O<sub>2<\/sub>\uff0c\u662f\u4e00\u79cd\u7406\u60f3\u7684\u5bc6\u95ed\u7a7a\u95f4\u5185\u79fb\u9664\u6c14\u6001\u6c27\u5316\u7269\u5206\u5b50\u4f9b\u6c27\u7684\u6280\u672f\uff0c\u5728\u592a\u7a7a\u63a2\u7d22\uff08\u6bd4\u5982\u8f7d\u4eba\u5b87\u5b99\u98de\u884c\u5668\uff09\u3001\u6d77\u6d0b\u63a2\u7d22\uff08\u6bd4\u5982\u6c34\u4e0b\u8f7d\u4eba\u52d8\u63a2\uff09\u3001\u6c11\u9632\u5de5\u7a0b\u4ee5\u53ca\u5927\u578b\u516c\u5171\u5bc6\u95ed\u7a7a\u95f4\u5185\u7684\u751f\u6001\u7cfb\u7edf\u6784\u5efa\u65b9\u9762\u5177\u6709\u6f5c\u5728\u7684\u5e94\u7528\u524d\u666f\u3002<\/p>\n<p>\u539f\u6587\u8fde\u63a5\uff1a<a href=\"https:\/\/pubs.acs.org\/doi\/abs\/10.1021\/acscatal.7b02952\">Oxygen-Vacancy-Activated CO<sub>2\u00a0<\/sub>Splitting over Amorphous Oxide Semiconductor Photocatalyst<\/a><\/p>\n<p>\u672c\u6587\u7531\u6750\u6599\u4eba\u7279\u7ea6\u4f5c\u8005\u5434\u79b9\u7ff0\u9080\u8bf7\uff0c\u95eb\u4e16\u6210\u8bfe\u9898\u7ec4\u64b0\u7a3f\uff0c\u7279\u6b64\u611f\u8c22\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u3010\u5f15\u8a00\u3011 \u4fdd\u62a4\u73af\u5883\u662f\u5b9e\u73b0\u4eba\u7c7b\u793e\u4f1a\u53ef\u6301\u7eed\u53d1\u5c55\u7684\u57fa\u672c\u524d\u63d0\uff0c\u6d88\u9664\u6c14\u6001\u6c27\u5316\u7269\u5206\u5b50\u6c61\u67d3\u7269\uff0c\u5982COx (CO2\uff0cCO)\uff0cSOx (SO2\uff0cSO3)\uff0cNOx (NO\uff0cNO2)&#8230;<\/p>\n","protected":false},"author":4695,"featured_media":121961,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[],"class_list":["post-121958","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-jiedu"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/121958"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/4695"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=121958"}],"version-history":[{"count":5,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/121958\/revisions"}],"predecessor-version":[{"id":125880,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/121958\/revisions\/125880"}],"wp:featuredmedia":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/media\/121961"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=121958"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=121958"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=121958"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}