{"id":121884,"date":"2018-01-20T06:30:04","date_gmt":"2018-01-19T22:30:04","guid":{"rendered":"\/\/m.iemloyee.com\/?p=121884"},"modified":"2018-01-19T16:21:55","modified_gmt":"2018-01-19T08:21:55","slug":"macromolecules%ef%bc%9a%e7%9b%b4%e6%8e%a5c-h%e5%81%b6%e8%81%94%e6%b3%95%e5%88%b6%e5%a4%87%e9%ab%98%e7%ab%8b%e4%bd%93%e8%a7%84%e6%95%b4%e6%80%a7%e7%9a%84%cf%80%e5%85%b1%e8%bd%ad%e5%ae%98%e8%83%bd","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=121884","title":{"rendered":"Macromolecules\uff1a\u76f4\u63a5C-H\u5076\u8054\u6cd5\u5236\u5907\u9ad8\u7acb\u4f53\u89c4\u6574\u6027\u7684\u03c0\u5171\u8f6d\u5b98\u80fd\u805a\u5408\u7269"},"content":{"rendered":"
\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n \u9ad8\u5ea6\u7acb\u4f53\u89c4\u5219\u7684\u5bfc\u7535\u805a\u5408\u7269\uff0c\u5982\u805a\uff083-\u53d6\u4ee3\u567b\u5429\uff09\uff08rrP3STs\uff09\u662f\u4e00\u7c7b\u91cd\u8981\u7684\u03c0-\u5171\u8f6d\u805a\u5408\u7269\uff0c\u53ef\u7528\u4e8e\u5851\u6599\u7535\u5b50\u5668\u4ef6\u5982\u592a\u9633\u80fd\u7535\u6c60\u548c\u73b0\u573a\u6676\u4f53\u7ba1\u3002\u4f46\u662f\uff0crrP3ST\u7684\u73b0\u6709\u5408\u6210\u6280\u672f\u5168\u90fd\u6d89\u53ca\u8fc7\u6e21\u91d1\u5c5e\u50ac\u5316\u7684\u6742\u82b3\u57fa\u5364\u5316\u7269\u6216\u62df\u5364\u5316\u7269\u4e0e\u6742\u82b3\u57fa\u6709\u673a\u91d1\u5c5e\u8bd5\u5242\u7684\u4ea4\u53c9\u5076\u8054\u3002\u672c\u6587\u4e2d\u4ecb\u7ecd\u4e86\u4e00\u79cd\u5b89\u5168\u3001\u6709\u6548\u7684\u65b9\u6cd5\uff0c\u76f4\u63a5\u4ea4\u53c9\u8026\u5408sp2<\/sup> C-H\u952e\u3002\u66f4\u91cd\u8981\u7684\u662f\uff0c\u8be5\u65b9\u6cd5\u4e0d\u4ec5\u5177\u6709\u8f83\u9ad8\u7684\u533a\u57df\u89c4\u6574\u6027\uff08\u9ad8\u8fbe99\uff05\uff09\uff0c\u800c\u4e14\u53ef\u5e94\u7528\u4e8e\u5177\u6709\u4e0d\u540c\u7ed3\u6784\u548c\u53d6\u4ee3\u57fa\u56e2\u7684\u4e00\u7cfb\u5217\u5e95\u7269\u5316\u5408\u7269\u3002\u8fd9\u63d0\u4f9b\u4e86\u4e00\u4e2a\u901a\u7528\u3001\u76f4\u63a5\u7684\u65b9\u6cd5\u6765\u65b9\u4fbf\u83b7\u5f97\u8bb8\u591a\u529f\u80fd\/\u5bfc\u7535\u805a\u5408\u7269\u3002<\/p>\n \u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n \u03c0\u5171\u8f6d\u805a\u5408\u7269\u4f5c\u4e3a\u91cd\u8981\u7684\u5bfc\u7535\/\u534a\u5bfc\u4f53\u6750\u6599\u5df2\u7ecf\u5f15\u8d77\u4eba\u4eec\u7684\u5e7f\u6cdb\u5174\u8da3\uff0c\u5728\u8fd9\u4e9b\u4e0d\u540c\u7684\uff08\u534a\uff09\u5bfc\u7535\u805a\u5408\u7269\u4e2d\uff0c\u805a\u567b\u5429\uff08PT\uff09\u53ef\u80fd\u662f\u6700\u91cd\u8981\u4e14\u88ab\u5e7f\u6cdb\u7814\u7a76\u7684\u6750\u6599\uff0c\u5e76\u4e14\u5df2\u7ecf\u88ab\u7528\u4e8e\u5404\u79cd\u5e94\u7528\u5982\u573a\u6548\u5e94\u6676\u4f53\u7ba1\uff08FET\uff09\u3001\u805a\u5408\u7269\u53d1\u5149\u4e8c\u6781\u7ba1\uff08PLED\uff09\u3001\u592a\u9633\u80fd\u7535\u6c60\u548c\u5316\u5b66\u4f20\u611f\u5668\u4e2d\u3002\u7531\u4e8e\u533a\u57df\u89c4\u6574\u6027\u4e0d\u540c\uff0c\u5177\u6709\u76f8\u4f3c\u5171\u8f6d\/\u805a\u5408\u957f\u5ea6\u7684\u76f8\u540c\u6750\u6599\u5355\u4f53\u5355\u5143\u5728\u5927\u591a\u6570\u60c5\u51b5\u4e0b\u5177\u6709\u4e0d\u5bf9\u79f0\u7ed3\u6784\uff0c\u8fdb\u800c\u4f1a\u5f71\u54cd\u5176\u6027\u80fd\u3002\u8fd9\u662f\u56e0\u4e3a\u4e0d\u5bf9\u79f0\u5355\u4f53\u7684\u805a\u5408\u5e38\u5e38\u7531\u4e8e\u591a\u4e2a\u6d3b\u6027\u8fde\u63a5\u4f4d\u70b9\u800c\u5bfc\u81f4\u5f62\u6210\u6df7\u5408\u7269\u805a\u5408\u7269\u3002\u5bf9\u4e8e\u805a\u567b\u5429\uff0c\u6700\u5e38\u7528\u76843-\u53d6\u4ee3\u7684\u567b\u5429\u5355\u4f53\uff0c\u901a\u5e38\u5728\u91cd\u590d\u5355\u5143\uff082,2’\uff0c2,5’\u548c5,5’\uff09\u4e4b\u95f4\u5f62\u6210\u542b\u6709\u4e09\u4e2a\u533a\u57df-\u5316\u5b66\u952e\u7684\u805a\u567b\u5429\u7ed3\u6784\u7684\u6df7\u5408\u7269\uff0c\u5373\uff0cHH\uff0cHT\u548cTT\u3002\u5728\u8fc7\u53bb\u7684\u51e0\u5341\u5e74\u4e2d\uff0c\u7814\u7a76\u4eba\u5458\u5236\u5907\u4e86\u9ad8\u5ea6\u533a\u57df\u89c4\u6574\u7684HT\u5076\u8054\u7684\u5177\u6709\u70f7\u57fa\u6216\u70f7\u6c27\u57fa\u7684P3STs\uff0c\u4e00\u822c\u9700\u8981\u901a\u8fc7\u8fc7\u6e21\u91d1\u5c5e\u50ac\u5316\u7684\u6742\u82b3\u57fa\u5364\u5316\u7269\u6216\u62df\u5364\u5316\u7269\u4e0e\u6742\u82b3\u57fa\u6709\u673a\u91d1\u5c5e\u8bd5\u5242\u7684\u4ea4\u53c9\u5076\u8054\u6765\u5f62\u6210\u78b3-\u78b3\u952e\u6216\u53cc\u6742\u82b3\u57fa\u952e\u3002\u867d\u7136\u8fd9\u4e9b\u65b9\u6cd5\u5df2\u7ecf\u53d6\u5f97\u4e86\u5de8\u5927\u7684\u6210\u529f\uff0c\u4f46\u662f\u5b83\u4eec\u90fd\u9700\u8981\u5177\u6709\u542b\u91d1\u5c5e\u6216\u5364\u5316\u7269\u5b98\u80fd\u56e2\u7684\u5355\u4f53\uff0c\u5bfc\u81f4\u6548\u7387\u4f4e\u3001\u4e2d\u95f4\u6750\u6599\u83b7\u53d6\u56f0\u96be\u3002<\/p>\n \u8fd1\u65e5\uff0c\u5357\u5f00\u5927\u5b66<\/strong>\u7684\u9648\u6c38\u80dc<\/strong>\u6559\u6388\u8bfe\u5728Macromolecules<\/strong>\u4e0a\u53d1\u8868\u4e86\u4e00\u7bc7\u9898\u4e3a\u201cA Direct C\u2013H Coupling Method for Preparing \u03c0-Conjugated Functional Polymers with High Regioregularity<\/strong>\u201d\u7684\u6587\u7ae0\u3002\u8be5\u6587\u7ae0\u4ecb\u7ecd\u4e86\u4e00\u79cd\u666e\u904d\u3001\u6e29\u548c\u7684\u65b9\u6cd5\u6765\u76f4\u63a5C-H\u5076\u8054\u5236\u5907\u9ad8\u4ea7\u91cf\u7684\uff08\u9ad8\u8fbe\u5b9a\u91cf\uff09\u5171\u8f6d\u805a\u5408\u7269\u3002\u4f7f\u7528\u4e86\u5404\u79cd\u5355\u4f53\u5e95\u7269\uff0c\u5e76\u901a\u8fc7\u673a\u68b0\u6405\u62cc\u805a\u5408\u548c\u5171\u805a\u5408\u65b9\u6cd5\u3002\u66f4\u91cd\u8981\u7684\u662f\uff0c\u8fd9\u79cd\u65b9\u6cd5\u901a\u5e38\u5177\u6709\u9ad8\u533a\u57df\u9009\u62e9\u6027\uff0c\u572860\u2103\u7684\u6e29\u5ea6\u4e0b\u5408\u6210\u540e\u7684\u533a\u57df\u89c4\u6574\u5ea6\u9ad8\u8fbe99\uff05\u3002\u7531\u6b64\uff0c\u567b\u5429\u57fa\u5e95\u4e0a3\u4f4d\u53d6\u4ee3\u57fa\u56e2\u7684\u7535\u5b50\u6548\u5e94\u548c\u7a7a\u95f4\u6548\u5e94\u7684\u534f\u540c\u4f5c\u7528\u4f7f\u5f97\u533a\u57df\u9009\u62e9\u6027\u7684\u673a\u7406\u7814\u7a76\u6210\u4e3a\u53ef\u80fd\u3002<\/p>\n \u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n \u56fe<\/strong>1<\/strong> HT<\/strong>\u7684\u5236\u5907\u65b9\u6cd5<\/strong><\/p>\n \u56fe<\/strong>2<\/strong> \u4e0d\u540c\u65b9\u6cd5\u5408\u6210\u4ea7\u7269\u7684<\/strong>1<\/sup><\/strong>H NMR<\/strong>\u8c31\u6bd4\u8f83<\/strong><\/p>\n \uff08a\uff09\u76f4\u63a5C-H\u5076\u8054\u805a\u5408\u83b7\u5f97\u7684HT\u5076\u8054P3OST\uff082a\uff09\uff1b<\/p>\n \uff08b\uff09\u901a\u8fc7DHAP\u65b9\u6cd5\u83b7\u5f97\u7684HT\u5076\u8054P3OST\uff082a*\uff09\uff1b<\/p>\n \uff08c\uff09\u901a\u8fc7DHAP\u65b9\u6cd5\u83b7\u5f97\u7684HH-TT\u5076\u8054P3OST\uff082a\uff03\uff09\u3002<\/p>\n \u56fe<\/strong>3<\/strong>\u805a\u5408\u7269<\/strong>2a*\/2a #<\/strong>\u7684<\/strong>DHAP<\/strong>\u5408\u6210\u65b9\u6cd5<\/strong><\/p>\n \u56fe<\/strong>4 <\/strong>\u4e0d\u540c\u7269\u8d28\u7684<\/strong>1<\/sup><\/strong>H NMR<\/strong>\u8c31<\/strong><\/p>\n \uff08a\uff09HT-\u5076\u8054\u4ea7\u7269\uff082a\uff09\uff1b<\/p>\n \uff08b\uff09\u901a\u8fc7DHAP\u65b9\u6cd5\u83b7\u5f97\u7684\u53c2\u8003\u805a\u5408\u7269\uff082a*\uff09\uff1b<\/p>\n \uff08c\uff09\u5355\u4f533-\uff08\u8f9b\u57fa\u78fa\u9170\u57fa\uff09\u567b\u5429\u7684\u82b3\u65cf\u533a\u57df\u3002<\/p>\n \u56fe<\/strong>5 <\/strong>\u7d2b\u5916\u53ef\u89c1\u5438\u6536\u5149\u8c31<\/strong><\/p>\n \u56fe<\/strong>6 <\/strong>\u76f4\u63a5<\/strong>C – H<\/strong>\u5076\u8054\u6cd5<\/strong><\/p>\n \u805a\uff08<\/strong>3-<\/strong>\u53d6\u4ee3\u6742\u82b3\u70c3\uff09<\/strong><\/p>\n \u5076\u8054\u82b3\u70c3<\/strong><\/p>\n \u5176\u5b83\u5404\u79cd\u5171\u8f6d\u5171\u805a\u7269<\/strong><\/p>\n \u56fe<\/strong>7<\/strong>\u4e0d\u540c\u65b9\u6cd5\u5f97\u5230\u805a\u5408\u7269\u7684<\/strong>1<\/sup><\/strong>H NMR<\/strong>\u5149\u8c31\u6bd4\u8f83<\/strong><\/p>\n \uff08a\uff09\u76f4\u63a5C-H\u4ea4\u53c9\u5076\u8054\u805a\u5408\u76849a\uff1b<\/p>\n \uff08b\uff09\u901a\u8fc7Stille\u5076\u8054\u65b9\u6cd5\u83b7\u5f97\u76849a *\uff0c\u65b9\u6cd5\u5982\u4e0b\uff1a<\/p>\n \u56fe<\/strong>8 <\/strong>\u76f4\u63a5<\/strong>C-H<\/strong>\u5076\u8054\u5747\u805a\u53cd\u5e94\u7684\u53ef\u80fd\u673a\u7406<\/strong><\/p>\n \u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n \u76f4\u63a5\u7684C-H\u5076\u8054\u6cd5\uff0c\u4e0d\u9700\u8981\u4efb\u4f55\u91d1\u5c5e\u6216\u5364\u5316\u7269\u8bd5\u5242\u5c31\u53ef\u4ee5\u5236\u5907\u5bfc\u7535\u805a\u5408\u7269\u3002\u6b64\u65b9\u6cd5\u4e0d\u4ec5\u5177\u6709\u66f4\u9ad8\u7684\u9009\u62e9\u6027\u548c\u4ea7\u7387\uff0c\u66f4\u91cd\u8981\u7684\u662f\u53ef\u7528\u4e8e\u5747\u805a\u548c\u5171\u805a\uff0c\u5373\u4f7f\u5bf9\u4e8e\u591a\u73af\u7cfb\u7edf\u4e5f\u662f\u5982\u6b64\u3002\u9ad8\u9009\u62e9\u6027\u6765\u81ea\u4e8e\u7b2c\u4e00\u6b65\u7535\u5b50\u6548\u5e94\u548c\u7b2c\u4e8c\u6b65\u7a7a\u95f4\u6548\u5e94\u7684\u534f\u540c\u4f5c\u7528\u3002\u8003\u8651\u5230\u53d6\u4ee3\u805a\u567b\u5429\u548c\u5176\u4ed6\u9ad8\u5bfc\u7535\u805a\u5408\u7269\u5bf9\u5149\u7535\u5b50\u5668\u4ef6\u7684\u91cd\u8981\u6027\uff0c\u8fd9\u79cd\u65b0\u65b9\u6cd5\u53ef\u4ee5\u4f5c\u4e3a\u5404\u79cdHT\u8026\u5408\u5bfc\u7535\u805a\u5408\u7269\u548c\u5176\u4ed6\u529f\u80fd\u805a\u5408\u7269\u7684\u76f4\u63a5\u65b9\u4fbf\u7684\u9014\u5f84\u3002\u6b64\u5916\uff0c\u867d\u7136\u672c\u7814\u7a76\u5927\u90e8\u5206\u96c6\u4e2d\u5728\u805a\u567b\u5429\uff0c\u8be5\u6cd5\u4e5f\u53ef\u4ee5\u5e94\u7528\u4e8e\u5176\u5b83\u82b3\u65cf\u4f53\u7cfb\u805a\u5408\u7269\u3002<\/p>\n \u6587\u732e\u94fe\u63a5<\/strong>\uff1aA Direct C\u2013H Coupling Method for Preparing \u03c0-Conjugated Functional Polymers with High Regioregularity<\/strong><\/a>\uff08Macromolecules\uff0c2017\uff0cDOI: 10.1021\/acs.macromol.7b02390\uff09<\/p>\n \u672c\u6587\u7531\u6750\u6599\u4eba\u7f16\u8f91\u90e8\u9ad8\u5206\u5b50\u5b66\u672f\u7ec4\u6c34\u624b\u4f9b\u7a3f\uff0c\u6750\u6599\u725b\u7f16\u8f91\u6574\u7406\u3002<\/p>\n \u6750\u6599\u725b\u7f51\u4e13\u6ce8\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u53ca\u884c\u4e1a\u8fdb\u5c55\uff0c\u8fd9\u91cc\u6c47\u96c6\u4e86\u5404\u5927\u9ad8\u6821\u7855\u535a\u751f\u3001\u4e00\u7ebf\u79d1\u7814\u4eba\u5458\u4ee5\u53ca\u884c\u4e1a\u4ece\u4e1a\u8005\uff0c\u5982\u679c\u60a8\u5bf9\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u8fdb\u5c55\uff0c\u89e3\u8bfb\u9ad8\u6c34\u5e73\u6587\u7ae0\u6216\u662f\u8bc4\u8ff0\u884c\u4e1a\u6709\u5174\u8da3\uff0c\u70b9\u6211\u52a0\u5165\u6750\u6599\u4eba\u7f16\u8f91\u90e8<\/strong><\/a>\u3002\u53c2\u4e0e\u9ad8\u5206\u5b50\u8bdd\u9898\u8ba8\u8bba\u6216\u4e86\u89e3\u9ad8\u5206\u5b50\u7ec4\u62db\u52df\u8be6\u60c5\uff0c\u8bf7\u52a0\u9ad8\u5206\u5b50\u4ea4\u6d41\u7fa4\uff08298064863\uff09\u3002<\/p>\n
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