{"id":121788,"date":"2018-01-19T06:30:45","date_gmt":"2018-01-18T22:30:45","guid":{"rendered":"\/\/m.iemloyee.com\/?p=121788"},"modified":"2018-08-07T00:26:03","modified_gmt":"2018-08-06T16:26:03","slug":"%e4%b8%ad%e7%a7%91%e9%99%a2%e6%bd%98%e4%b8%96%e7%83%88%e5%9b%a2%e9%98%9f%ef%bc%9a%e6%b0%9f%e5%8c%96%e7%a1%bc%e9%85%b8%e7%9b%90%e4%bd%93%e7%b3%bb%e6%8e%a2%e7%b4%a2%e6%b7%b1%e7%b4%ab%e5%a4%96%e9%9d%9e","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=121788","title":{"rendered":"\u4e2d\u79d1\u9662\u6f58\u4e16\u70c8\u56e2\u961f\uff1a\u6c1f\u5316\u787c\u9178\u76d0\u4f53\u7cfb\u63a2\u7d22\u6df1\u7d2b\u5916\u975e\u7ebf\u6027\u5149\u5b66\u6676\u4f53\u6750\u6599"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/span><\/p>\n

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\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/span><\/p>\n

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\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/span><\/strong><\/p>\n

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(a-b) Li2<\/sub>B6<\/sub>O9<\/sub>F2<\/sub>\u3001LiB6<\/sub>O9<\/sub>F\u3001Li2<\/sub>B3<\/sub>O4<\/sub>F3<\/sub>\u548c\u5546\u4e1a\u5316LBO\u6676\u4f53\u6298\u5c04\u7387\u6bd4\u8f83<\/p>\n

(c) Li2<\/sub>B6<\/sub>O9<\/sub>F2<\/sub>\u7c89\u672b\u7eaf\u76f8\u548c\u7406\u8bba\u503c\u6bd4\u8f83<\/p>\n

(d)Li2<\/sub>B6<\/sub>O9<\/sub>F2<\/sub>\u7684\u900f\u8fc7\u5149\u8c31\uff08\u5728\u7a7a\u6c14\u4e2d\u957f\u65f6\u95f4\u66b4\u9732\u540e\uff09<\/p>\n

(e-f)Li2<\/sub>B6<\/sub>O9<\/sub>F2<\/sub>\u7684\u7c89\u672b\u500d\u9891\u6027\u80fd\u6d4b\u8bd5<\/p>\n

\u56fe2 NH4<\/sub>B4<\/sub>O6<\/sub>F\u6676\u4f53\u7ebf\u6027\u548c\u975e\u7ebf\u6027\u5149\u5b66\u6027\u80fd\u6d4b\u8bd5<\/span><\/strong><\/p>\n

\"\"<\/p>\n

(a) NH4<\/sub>B4<\/sub>O6<\/sub>F\u6df1\u7d2b\u5916\u900f\u8fc7\u5149\u8c31\uff1b(b) \u6298\u5c04\u7387\u8272\u6563\uff1b(c) \u76f8\u4f4d\u5339\u914d\u533a\u95f4\uff1b(d) \u500d\u9891\u6548\u5e94<\/p>\n

\u56fe3AB4<\/sub>O6<\/sub>F\u65cf\u6676\u4f53\u6750\u6599\u7684\u7ed3\u6784\u5bf9\u6bd4<\/span><\/strong><\/p>\n

\"\"<\/p>\n

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\"\"<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/strong><\/span><\/p>\n

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\u6f58\u4e16\u70c8\u7814\u7a76\u5458\u7b80\u4ecb<\/strong>\uff1a<\/p>\n

\u6f58\u4e16\u70c8\uff0c\u4e2d\u56fd\u79d1\u5b66\u9662\u65b0\u7586\u7406\u5316\u6280\u672f\u7814\u7a76\u6240\u7814\u7a76\u5458\uff0c\u535a\u58eb\u751f\u5bfc\u5e08\uff0c\u56fd\u5bb6\u6770\u9752\uff0c\u56fd\u5bb6\u201c\u4e07\u4eba\u8ba1\u5212\u201d\u79d1\u6280\u9886\u519b\u4eba\u624d\uff0c\u79d1\u6280\u90e8\u201c\u521b\u65b0\u4eba\u624d\u63a8\u8fdb\u8ba1\u5212\u201d\u4e2d\u9752\u5e74\u79d1\u6280\u9886\u519b\u4eba\u624d\uff0c\u56fd\u5bb6\u767e\u5343\u4e07\u4eba\u624d\u5de5\u7a0b\u4eba\u9009\uff0c\u56fd\u52a1\u9662\u7279\u6b8a\u6d25\u8d34\u4e13\u5bb6\uff0c\u4e2d\u79d1\u9662”\u767e\u4eba\u8ba1\u5212”\u5b66\u8005\u30021996\u5e74\u4e8e\u90d1\u5dde\u5927\u5b66\u83b7\u7406\u5b66\u5b66\u58eb\u5b66\u4f4d\uff0c\u540c\u5e74\u4fdd\u9001\u90d1\u5dde\u5927\u5b66\u7814\u7a76\u751f\u4e8e1999\u5e74\u83b7\u7406\u5b66\u7855\u58eb\u5b66\u4f4d\uff0c2002\u5e747\u6708\u4e8e\u4e2d\u56fd\u79d1\u5b66\u6280\u672f\u5927\u5b66\u83b7\u7406\u5b66\u535a\u58eb\u5b66\u4f4d\uff0c2004\u5e74\u4e2d\u79d1\u9662\u7406\u5316\u6280\u672f\u7814\u7a76\u6240\u535a\u58eb\u540e\u51fa\u7ad9\uff0c\u5230\u7f8e\u56fdNorthwestern University\u505a\u535a\u58eb\u540e\uff0c2007\u5e74\u5230\u4e2d\u79d1\u9662\u65b0\u7586\u7406\u5316\u6280\u672f\u7814\u7a76\u6240\u5de5\u4f5c\uff0c\u5e76\u5165\u9009\u4e2d\u79d1\u9662”\u767e\u4eba\u8ba1\u5212”\uff0c2008\u5e746\u6708\u83b7\u4e2d\u79d1\u9662”\u767e\u4eba\u8ba1\u5212”\uff08\u5f15\u8fdb\u56fd\u5916\u6770\u51fa\u4eba\u624d\uff09\u62e9\u4f18\u652f\u6301\u3002\u73b0\u4efb\u4e2d\u79d1\u9662\u65b0\u7586\u7406\u5316\u6280\u672f\u7814\u7a76\u6240\u526f\u6240\u957f\uff0c\u4e2d\u79d1\u9662\u7279\u6b8a\u73af\u5883\u529f\u80fd\u6750\u6599\u4e0e\u5668\u4ef6\u91cd\u70b9\u5b9e\u9a8c\u5ba4\u4e3b\u4efb\u3002\u4e3b\u8981\u4ece\u4e8b\u65e0\u673a\u5149\u7535\u529f\u80fd\u6676\u4f53\u6750\u6599\u7814\u7a76\u3002\u5df2\u5728J. Am. Chem. Soc., Angew. Chem. Int. Ed.\u7b49\u56fd\u9645\u671f\u520a\u4e0a\u53d1\u8868\u8bba\u6587300\u4f59\u7bc7(\u5176\u4e2d\uff0cSCI\u5f71\u54cd\u56e0\u5b50\u5927\u4e8e4.0\u7684140\u4f59\u7bc7)\uff1b\u6388\u6743\u7f8e\u56fd\u53d1\u660e\u4e13\u52296\u9879\uff0c\u4e2d\u56fd\u53d1\u660e\u4e13\u522965\u9879\u3002\u627f\u62c5\u56fd\u5bb6\u6770\u51fa\u9752\u5e74\u57fa\u91d1\u3001\u56fd\u5bb6973\u3001\u56fd\u5bb6\u91cd\u70b9\u7814\u53d1\u8ba1\u5212\u9879\u76ee\u3001\u56fd\u5bb6\u81ea\u7136\u79d1\u5b66\u57fa\u91d1\u9762\u4e0a\u9879\u76ee\u3001\u4e2d\u56fd\u79d1\u5b66\u9662\u91cd\u70b9\u90e8\u7f72\u9879\u76ee\u3001\u65b0\u7586\u81ea\u6cbb\u533a”\u5341\u4e09\u4e94”\u91cd\u5927\u79d1\u6280\u4e13\u9879\u7b49\u8bfe\u9898\u3002\u66fe\u83b7\u65b0\u7586\u7ef4\u543e\u5c14\u81ea\u6cbb\u533a\u4f18\u79c0\u5f52\u56fd\u7559\u5b66\u4eba\u5458\uff082017\u5e74\uff09\u3001\u81ea\u6cbb\u533a\u5929\u5c71\u82f1\u624d\u5de5\u7a0b\u7b2c\u4e8c\u671f\u7b2c\u4e00\u5c42\u6b21\u57f9\u517b\u4eba\u9009\uff082017\u5e74\uff09\u3001\u7b2c\u4e8c\u6279\u56fd\u5bb6”\u4e07\u4eba\u8ba1\u5212”\u9886\u519b\u4eba\u624d\uff082016\u5e74\uff09\u3001\u4e2d\u56fd\u4fa8\u754c\u8d21\u732e\u5956\uff08\u521b\u65b0\u56e2\u961f\uff09\uff082016\u5e74\uff09\u3001\u6731\u674e\u6708\u534e\u4f18\u79c0\u6559\u5e08\u5956\uff082015\u5e74\uff09\u3001\u65b0\u7586\u7b2c\u5341\u6279\u6709\u7a81\u51fa\u8d21\u732e\u4f18\u79c0\u4e13\u5bb6\uff082015\u5e74\uff09\u3001\u67f3\u5927\u7eb2\u4f18\u79c0\u9752\u5e74\u79d1\u6280\u5956\uff082015\u5e74\uff09\u3001\u65b0\u7586”\u79d1\u5b66\u6280\u672f\u8fdb\u6b65\u5956\u4e00\u7b49\u5956”(2014\u5e74\u7b2c\u4e00\u83b7\u5956\u4eba\uff09\u3001\u56fd\u5bb6\u6770\u51fa\u9752\u5e74\u57fa\u91d1\uff082014\u5e74\uff09\u3001”\u65b0\u7586\u4fa8\u754c\u6770\u51fa\u4eba\u7269”\uff082009\u5e74-2014\u5e74\uff09\u3001\u56fd\u5bb6\u521b\u65b0\u4eba\u624d\u63a8\u8fdb\u8ba1\u5212\u4e2d\u9752\u5e74\u79d1\u6280\u521b\u65b0\u9886\u519b\u4eba\u624d\uff082013\u5e74\uff09\u3001\u4e2d\u56fd\u9752\u5e74\u79d1\u6280\u5956\uff082013\u5e74\uff09\u3001\u5168\u56fd\u5f52\u4fa8\u4fa8\u7737\u5148\u8fdb\u4e2a\u4eba\uff082013\u5e74\uff09\u3001\u4e2d\u79d1\u9662\u9752\u5e74\u79d1\u5b66\u5bb6\u5956\uff082013\u5e74\uff09\u3001\u4e2d\u79d1\u9662\u738b\u5bbd\u8bda\u897f\u90e8\u5b66\u8005\u7a81\u51fa\u8d21\u732e\u5956\uff082013\u5e74\uff09\u3001\u65b0\u7586”\u79d1\u5b66\u6280\u672f\u8fdb\u6b65\u5956\u4e00\u7b49\u5956”(2012\u5e74\u7b2c\u4e00\u83b7\u5956\u4eba\uff09\u3001\u7b2c\u56db\u5c4a\u4e2d\u56fd\u4fa8\u754c\u8d21\u732e\u5956\uff08\u521b\u65b0\u4eba\u624d\uff09\uff082012\u5e74\uff09\u3001\u4e2d\u79d1\u9662”\u767e\u4eba\u8ba1\u5212”\u5b66\u8005\u7ec8\u671f\u8bc4\u4f30”\u4f18\u79c0”\uff082012\u5e74\uff09\u3001\u81ea\u6cbb\u533a\u5929\u5c71\u82f1\u624d\u5de5\u7a0b\u7b2c\u4e00\u671f\u7b2c\u4e00\u5c42\u6b21\u57f9\u517b\u4eba\u9009\uff082012\u5e74\uff09\u3001”\u56fd\u52a1\u9662\u653f\u5e9c\u7279\u6b8a\u6d25\u8d34”\uff082011\u5e74\uff09\u3001\u65b0\u7586”\u7b2c\u4e94\u5c4a\u65b0\u7586\u9752\u5e74\u79d1\u6280\u5956”\uff082011\u5e74\uff09\u3001\u65b0\u7586”\u79d1\u5b66\u6280\u672f\u8fdb\u6b65\u5956\u4e00\u7b49\u5956”(2010\u5e74\u7b2c\u4e00\u83b7\u5956\u4eba\uff09\u3001\u4eba\u529b\u8d44\u6e90\u548c\u793e\u4f1a\u4fdd\u969c\u90e8\u7b497 \u90e8\u59d4”\u65b0\u4e16\u7eaa\u767e\u5343\u4e07\u4eba\u624d\u5de5\u7a0b\u56fd\u5bb6\u7ea7\u4eba\u9009”\uff082009\u5e74\uff09\u7b49\u3002<\/p>\n

\u6587\u7ae0\u94fe\u63a5\uff1a<\/p>\n

(1) Zhang, B. B.; Shi, G. Q.; Yang, Z. H.; Zhang, F. F.; Pan, S. L., Fluorooxoborates: beryllium-free deep-ultraviolet nonlinear optical materials without layered growth. Angew. Chem. Int. Ed. <\/em>2017, 56<\/em>, 3916\u20133919.<\/a><\/p>\n

(2) Shi, G. Q.; Wang, Y.; Zhang, F. F.; Zhang, B. B.; Yang, Z. H.; Hou, X. L.; Pan, S. L.; Poeppelmeier, K. R., Finding the next deep-ultraviolet nonlinear optical material: NH4<\/sub>B4<\/sub>O6<\/sub>F. J. Am. Chem. Soc. <\/em>2017, 139<\/em>, 10645\u201310648.<\/a><\/p>\n

(3) Wang, X. F.; Wang, Y.; Zhang, B. B.; Zhang, F. F.; Yang, Z. H.; Pan, S. L., CsB4<\/sub>O6<\/sub>F: A congruent-melting deep-ultraviolet nonlinear optical material with superior functional units recombination. Angew. Chem. Int. Ed. <\/em>2017, 56<\/em>, 14119\u201314123.<\/a><\/p>\n

(4) Wang, Y.; Zhang, B. B.; Yang, Z. H.; Pan, S. L.; Cation-tuned synthesis of fluorooxoborates: Approaching the optimal deep-ultraviolet nonlinear optical materials. Angew. Chem. Int. Ed. <\/em>2018, doi: 10.1002\/anie.201712168<\/a><\/p>\n

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