{"id":121478,"date":"2018-01-16T14:00:09","date_gmt":"2018-01-16T06:00:09","guid":{"rendered":"\/\/m.iemloyee.com\/?p=121478"},"modified":"2018-01-15T23:38:09","modified_gmt":"2018-01-15T15:38:09","slug":"nat-commun-%ef%bc%9a%e7%94%a8%e4%ba%8e%e5%a4%9a%e8%89%b2%e5%96%b7%e5%a2%a8%e5%8f%af%e5%a4%8d%e7%94%a8%e7%ba%b8%e4%b8%ad%e7%9a%84%e6%b4%bb%e6%80%a7%e9%87%91%e5%b1%9e%e9%85%8d%e4%bd%93%e9%85%8d","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=121478","title":{"rendered":"Nat. Commun.\uff1a\u7528\u4e8e\u591a\u8272\u55b7\u58a8\u53ef\u590d\u7528\u7eb8\u4e2d\u7684\u6d3b\u6027\u91d1\u5c5e\u914d\u4f53\u914d\u5408\u7269\u7684\u7814\u7a76"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n

\u8fd1\u5e74\u6765\uff0c\u53ef\u590d\u7528\u7eb8\u7531\u4e8e\u5728\u73af\u5883\u4fdd\u62a4\u3001\u8d44\u6e90\u8282\u7ea6\u7b49\u65b9\u9762\u5177\u6709\u7684\u5929\u7136\u4f18\u52bf\u800c\u5907\u53d7\u5173\u6ce8\uff0c\u7136\u800c\u5982\u4f55\u5728\u53ef\u590d\u7528\u7eb8\u4e0a\u5b9e\u73b0\u4fdd\u5b58\u65f6\u95f4\u8db3\u591f\u957f\u7684\u591a\u8272\u55b7\u58a8\u6253\u5370\uff0c\u8fd9\u8fd8\u662f\u4e00\u4e2a\u5c1a\u672a\u7a81\u7834\u7684\u6280\u672f\u96be\u9898\uff0c\u53ef\u590d\u7528\u7eb8\u7684\u5b9e\u9645\u5e94\u7528\u6536\u5230\u9650\u5236\u3002\u672c\u7814\u7a76\u7684\u7b56\u7565\u662f\u5236\u4f5c\u57fa\u4e8e\u7531\u52a8\u6001\u91d1\u5c5e-\u914d\u4f53\u914d\u4f4d\u5f15\u8d77\u7684\u989c\u8272\u6216\u8005\u53d1\u5149\u5f00\u5173\u7684\u53ef\u64e6\u5199\u7eb8\uff0c\u4f7f\u7528\u542b\u6709\u4e0d\u540c\u91d1\u5c5e\u76d0\u7684\u6c34\u6eb6\u6db2\u4f5c\u4e3a\u6cb9\u58a8\uff0c\u6b64\u7c7b\u7eb8\u5373\u53ef\u65b9\u4fbf\u5730\u7528\u4e8e\u591a\u8272\u6c34\u55b7\u5370\uff0c\u5e76\u4e14\u55b7\u6c34\u53ef\u64e6\u5199\u7eb8\u4e0a\u7684\u6253\u5370\u56fe\u50cf\u53ef\u4ee5\u4fdd\u7559\u5f88\u957f\u65f6\u95f4\uff08> 6\u4e2a\u6708\uff09\uff0c\u76f8\u6bd4\u4e8e\u4e4b\u524d\uff0c\u56fe\u50cf\u663e\u793a\u65b9\u9762\u663e\u793a\u51fa\u4e86\u5f88\u5927\u7684\u8fdb\u6b65\uff0c\u53ef\u4ee5\u8ba4\u4e3a\u8fd9\u79cd\u7c7b\u578b\u7684\u53ef\u64e6\u5199\u7eb8\u53ef\u4ee5\u4f5c\u4e3a\u591a\u8272\u55b7\u58a8\u6253\u5370\u7684\u539f\u578b\u6765\u6ee1\u8db3\u5b9e\u9645\u9700\u8981\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u897f\u5317\u5de5\u4e1a\u5927\u5b66\u9ec4\u7ef4\u9662\u58eb<\/strong>\uff0c\u5357\u4eac\u90ae\u7535\u5927\u5b66\u8d75\u5f3a\u6559\u6388<\/strong>(\u5171\u540c\u901a\u8baf\u4f5c\u8005<\/strong>)\u5728Nat. Commun.<\/strong>\u4e0a\u53d1\u8868\u4e86\u9898\u4e3a\u201cDynamic metal-ligand coordination for multicolour and water-jet rewritable pape<\/strong>r\u201d\u7684\u6587\u7ae0\u3002\u7814\u7a76\u5e76\u63a2\u8ba8\u4e86\u5982\u4f55\u5229\u7528\u52a8\u6001\u91d1\u5c5e\u914d\u4f53\u76f8\u4e92\u4f5c\u7528\u7684\u53ef\u9006\u6027\u6765\u5b9e\u73b0\u53ef\u64e6\u5199\u7eb8\u7684\u5236\u5907\uff0c\u5e76\u7a81\u7834\u4e86\u76ee\u524d\u7684\u9650\u5236\u3002\u7814\u7a76\u4e86\u542b\u6709\u4e09\u8054\u5421\u5576\u914d\u4f53\u7684\u805a\u5408\u7269\u8584\u819c\u5728\u6ee4\u7eb8\u4e0a\u7684\u6d82\u5c42\uff0c\u5176\u4e0a\u53ef\u4ee5\u4f7f\u7528\u4e0d\u540c\u7684\u91d1\u5c5e\u76d0\u6c34\u6eb6\u6db2\uff08MSAS\uff09\u4f5c\u4e3a\u53ef\u4e0e\u914d\u4f53\u914d\u4f4d\u7684\u6cb9\u58a8\u91cd\u590d\u6d82\u8986\u591a\u8272\u56fe\u50cf\uff0c\u7ed3\u679c\u53d1\u73b0\u6253\u5370\u7684\u56fe\u7247\u53ef\u4ee5\u4fdd\u75596\u4e2a\u6708\u4ee5\u4e0a\uff0c\u7528\u56db\u4e01\u57fa\u6c1f\u5316\u94f5\uff08TBAF\uff09\u53ef\u4ee5\u65b9\u4fbf\u5730\u64e6\u9664\u91d1\u5c5e – \u914d\u4f53\u914d\u4f4d\u952e\u3002\u901a\u8fc7\u5c06\u6c34\u54cd\u5e94\u578b\u53d1\u5149\u950c\u7edc\u5408\u7269\u5f15\u5165\u6210\u50cf\u5c42\u4e2d\uff0c\u5236\u9020\u4e86\u53e6\u4e00\u79cd\u53ef\u4ee5\u901a\u8fc7\u4f7f\u7528\u7eaf\u6c34\u4f5c\u4e3a\u58a8\u6c34\u6765\u8bb0\u5f55\u4fe1\u606f\u7684\u53ef\u590d\u5199\u7eb8\u5f20\uff0c\u6c34\u662f\u4e00\u79cd\u7eff\u8272\u8d44\u6e90\uff0c\u56e0\u6b64\u5f00\u53d1\u6c34\u55b7\u5370\u53ef\u64e6\u5199\u7eb8\u5177\u6709\u91cd\u8981\u610f\u4e49\uff0c\u6b64\u5e94\u7528\u5c06\u662f\u5b9e\u73b0\u5177\u6709\u957f\u4fdd\u7559\u65f6\u95f4\u7684\u591a\u8272\u6c34\u55b7\u5370\u7684\u6709\u5e0c\u671b\u7684\u65b9\u6cd5\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n

\u56fe1 \u591a\u8272\u6c34\u55b7\u5370\u7684\u793a\u610f\u56fe<\/strong><\/p>\n

\"\"<\/p>\n

\u56fe\u6ce8\uff1aL1<\/sub>\uff0cL2<\/sub>\u548cL3<\/sub>\u5373\u4e09\u4e2a\u4e09\u8054\u5421\u5576\u884d\u751f\u7269\u4f5c\u4e3a\u5b9e\u4f8b\uff0c\u56fe\u4e2d\u6709L1<\/sub>\uff0cL2<\/sub>\u548cL3<\/sub>\u7684\u5316\u5b66\u7ed3\u6784\uff0c\u4ee5\u53ca\u7684\u53ef\u64e6\u5199\u7eb8\u7684\u6253\u5370\u548c\u64e6\u9664\u8fc7\u7a0b.<\/p>\n

\u56fe2 \u53ef\u64e6\u5199\u7eb8\u7684\u591a\u8272\u548c\u53ef\u9006\u6027<\/strong><\/p>\n

\"\"<\/p>\n

\uff08a<\/strong>\uff09\u53ef\u64e6\u5199\u7eb8\u5206\u522b\u6dfb\u52a0Fe(NO3<\/sub>)3<\/sub>\uff0cFeCl3<\/sub>\uff0cFeCl2<\/sub>\uff0cNi(NO3<\/sub>)2<\/sub>\uff0cCo(NO3<\/sub>)2<\/sub>\uff0cCuCl2<\/sub>\u548cZn(NO3<\/sub>)2<\/sub>\u540e\u7684\u53cd\u5c04\u7d2b\u5916 – \u53ef\u89c1\u5149\u8c31<\/p>\n

\uff08b<\/strong>\uff09\u52a0\u5165\u4e0d\u540c\u91d1\u5c5e\u76d0\u6240\u5236\u6210\u7684\u53ef\u64e6\u5199\u7eb8\u7684\u7167\u7247<\/p>\n

\uff08c<\/strong>\uff09\u5728\u53ef\u64e6\u5199\u7eb8\u901a\u8fc7FeCl2<\/sub>\u6c34\u6eb6\u6db2\u55b7\u5c04\uff08\u4e66\u5199\uff09\u5faa\u73af\uff0c\u5e76\u4e14\u7528TBAF\u7684CH2<\/sub>Cl2<\/sub>\u6eb6\u6db2\u51b2\u6d17\u53ef\u64e6\u5199\u7eb8\uff08\u64e6\u9664\uff09\u65f6\uff0c\u5728577 nm\u4e0b\u7684\u53cd\u5c04\u7387\u76f8\u5bf9\u4e8e\u53ef\u64e6\u5199\u7eb8\u7684\u5faa\u73af\u6b21\u6570\u56fe<\/p>\n

\u56fe3 \u53ef\u64e6\u5199\u7eb8\u7684\u7ed3\u6784\u548c\u591a\u8272\u5370\u5237<\/strong><\/p>\n

\"\"<\/p>\n

\uff08a<\/strong>\uff09\u57fa\u4e8eL1<\/sub>\u7684\u53ef\u590d\u5199\u7eb8\u5f20\u7684\u56db\u5c42\u7ed3\u6784\u7684\u793a\u610f\u56fe<\/p>\n

\uff08b<\/strong>\uff09\u7531\u4e0d\u540c\u7684\u91d1\u5c5e\u76d0\u6c34\u6eb6\u6db2\u4f5c\u4e3a\u58a8\u6c34\u7ed8\u5236\u7684\u82b1\u7684\u5f69\u8272\u56fe\u50cf\u3002\u6bd4\u4f8b\u5c3a= 1\u5398\u7c73<\/p>\n

\uff08c<\/strong>\uff09\u7528FeCl2<\/sub>\u6c34\u6eb6\u6db2\u586b\u5145\u7684\u5b9a\u5236\u9ed1\u8272\u58a8\u76d2\u6253\u5370\u7684\u6811\u6728\u56fe\u50cf\u3002\u6bd4\u4f8b\u5c3a= 1\u5398\u7c73<\/p>\n

\uff08d<\/strong>\uff09\u4f7f\u7528\u5206\u522b\u586b\u5145\u6709FeCl2<\/sub>\uff0cZn(NO3<\/sub>)2<\/sub>\u548cCo(NO3<\/sub>)2<\/sub>\u7684\u55b7\u58a8\u58a8\u76d2\uff0c\u5c06\u5148\u8fdb\u6750\u6599\u7814\u7a76\u6240\u7684\u5fbd\u7ae0\u5f69\u8272\u5370\u5237\u3002\u6bd4\u4f8b\u5c3a= 1\u5398\u7c73<\/p>\n

\u56fe4 \u53d1\u5149\u7279\u6027\u548c\u5b89\u5168\u5370\u5237<\/strong><\/p>\n

\"\"<\/p>\n

\uff08a<\/strong>\uff09L2<\/sub>\u548cZn\uff08II\uff09\u914d\u5408\u7269\u5728CH2<\/sub>Cl2<\/sub>\uff0810\u03bcM\uff09\u4e2d\u7684\u5ba4\u6e29\u4e0b\u7684\u5149\u81f4\u53d1\u5149\u5149\u8c31<\/p>\n

\uff08b<\/strong>\uff09L2<\/sub>\u548cZn\uff08II\uff09\u914d\u5408\u7269\u5728CH2<\/sub>Cl2<\/sub>\u4e2d\u53d1\u5c04\u989c\u8272\u7684\u7167\u7247<\/p>\n

\uff08c<\/strong>\uff09\u4f7f\u7528Zn(CH3<\/sub>COO)2<\/sub>\u6c34\u6eb6\u6db2\u586b\u5145\u7684\u9ed1\u8272\u58a8\u76d2\u6253\u5370\u7684\u65e5\u5149\u548c\u7d2b\u5916\u7ebf\u4e0bQR\u7801\u7684\u56fe\u50cf<\/p>\n

\uff08d<\/strong>\uff09\u4f7f\u7528\u4e09\u8272\u55b7\u58a8\u6253\u5370\u58a8\u76d2\u586b\u5145Zn(CH3<\/sub>COO)2<\/sub>\uff0cZn(NO3<\/sub>)2<\/sub>\u548cZn(CF3<\/sub>SO3<\/sub>)2<\/sub>\u6c34\u6eb6\u6db2\uff0c\u5728\u73af\u5883\u5149\u548c\u7d2b\u5916\u7ebf\u4e0b\u6253\u5370\u51faQR\u7801\u7684\u5f69\u8272\u56fe\u50cf\u3002\u6bd4\u4f8b\u5c3a= 1\u5398\u7c73<\/p>\n

\u56fe5 \u53ef\u64e6\u5199\u7eb8\u7684\u6c34\u55b7\u5c04\u5370\u5237<\/strong><\/p>\n

\"\"<\/p>\n

\uff08a<\/strong>\uff09\u914d\u5408\u7269L3<\/sub>-Zn\u5728\u4e0d\u540c\u6d53\u5ea6\u4e0b\u7684THF-\u6c34\u6df7\u5408\u7269\u4e2d\u7684PL\u5149\u8c31<\/p>\n

\uff08b<\/strong>\uff09\u5728\u53ef\u64e6\u5199\u7eb8\u4e0a\u52a0\u6c34\u4e4b\u524d\u548c\u4e4b\u540e\u7684L3<\/sub>\u2013Zn\u7684\u53d1\u5c04\u5149\u8c31<\/p>\n

\uff08c<\/strong>\uff09\u57fa\u4e8eL3<\/sub>-Zn\u7684\u53ef\u91cd\u5199\u7eb8\u7684\u55b7\u6c34\u5370\u5237\u548c\u64e6\u9664\u8fc7\u7a0b\u7684\u793a\u610f\u56fe<\/p>\n

\uff08d<\/strong>\uff09\u5546\u8d2d\u7684\u55b7\u58a8\u6253\u5370\u673a\u5728\u57fa\u4e8eL3<\/sub>-Zn\u7684\u53ef\u91cd\u5199\u7eb8\u4e0a\uff0c\u91c7\u7528\u6c34\u5145\u6ee1\u58a8\u6c34\u7684\u6c34\u55b7\u58a8\u6253\u5370\u3002\u6bd4\u4f8b\u5c3a= 1\u5398\u7c73<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n

\u901a\u8fc7\u5728\u7eb8\u4e0a\u5f15\u5165L1<\/sub>\uff0cL2<\/sub>\u548cL3<\/sub> -Zn\uff0c\u4f7f\u7528MSAS\u751a\u81f3\u7eaf\u6c34\u4f5c\u4e3a\u89e6\u53d1\uff0c\u5f00\u53d1\u65e0\u58a8\u53ef\u64e6\u5199\u7eb8\u3002\u7531\u91d1\u5c5e\u79bb\u5b50\u548c\u4e09\u8054\u5421\u5576\u914d\u4f53\u4e0e\u5b83\u4eec\u7684\u5149\u7269\u7406\u6027\u8d28\u4e4b\u95f4\u7684\u5173\u7cfb\uff0c\u4ee5\u53ca\u5bf9\u6c34\u89e6\u53d1\u7684\u52a8\u6001\u91d1\u5c5e – \u914d\u4f53\u914d\u4f4d\u952e\u89e3\u79bb\u7684\u673a\u5236\u4e86\u89e3\u66f4\u52a0\u6df1\u5165\uff0c\u5b9e\u73b0\u5728\u4e00\u5f20\u53ef\u64e6\u5199\u7eb8\u4e0a\u8bb0\u5f55\u591a\u8272\u4fe1\u606f\uff0c\u56fe\u50cf\u5bff\u547d\u957f\uff0c\u6c34\u55b7\u5c04\u53ef\u91cd\u5199\u7eb8\u4e5f\u5df2\u5b9e\u73b0\u3002<\/p>\n

\u7c97\u7565\u4f30\u8ba1\uff0c\u6b64\u53ef\u91cd\u5199\u6253\u5370\u7cfb\u7edf\u6210\u672c\u4f4e\uff0c\u5e76\u901a\u8fc7\u4f7f\u7528\u6807\u51c6\u7684\u7532\u57fa\u567b\u5511\u57fa\u56db\u5511\uff08MTT\uff09\u6d4b\u5b9a\u4e09\u8054\u5421\u5576\u914d\u4f53\u548c\u4e0d\u540c\u7684\u91d1\u5c5e\u914d\u5408\u7269\u7684\u7ec6\u80de\u6bd2\u6027\u6d4b\u91cf\uff0c\u7ed3\u679c\u8868\u660e\uff0c\u5373\u4f7f\u572850\u03bcM\u7684\u9ad8\u6d53\u5ea6\u4e0b\uff0c\u7ec6\u80de\u6d3b\u529b\u4e5f\u88ab\u8bc4\u4f30\u4e3a> 75\uff05\uff0c\u8bf4\u660e\u4f7f\u7528\u7684\u914d\u4f53\u548c\u590d\u5408\u7269\u5728\u4f4e\u6bd2\u6027\u8303\u56f4\u5185\u3002\u6b64\u5916\uff0c\u53ef\u91cd\u5199\u6750\u6599\u80fd\u901a\u8fc7PEG-PPG-PEG \/ PEG\uff08\u4f17\u6240\u5468\u77e5\u7684\u65e0\u5bb3\u6750\u6599\uff09\u4fdd\u62a4\u5c42\u5206\u79bb\uff0c\u53ef\u8fdb\u4e00\u6b65\u63d0\u9ad8\u5b89\u5168\u6027\u3002\u6b64\u8bbe\u8ba1\u539f\u7406\u8fd8\u53ef\u6269\u5c55\u5230\u5404\u79cd\u52a8\u6001\u7684\u8d85\u5206\u5b50\u76f8\u4e92\u4f5c\u7528\uff0c\u4ee5\u751f\u4ea7\u5148\u8fdb\u7684\u53ef\u64e6\u5199\u7eb8\u548c\u7eff\u8272\u5370\u5237\u6280\u672f\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1aDynamic metal-ligand coordination for multicolour and water-jet rewritable paper<\/a><\/strong>\uff08Nat. Commun., 2017,DOI: 10.1038\/s41467-017-02452-w\uff09<\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u7f16\u8f91\u90e8\u65b0\u4eba\u7ec4\u6b27\u4eea\u7f16\u8f91\uff0c\u9648\u70b3\u65ed\u5ba1\u6838\uff0c\u70b9\u6211\u52a0\u5165\u6750\u6599\u4eba\u7f16\u8f91\u90e8<\/a>\u3002<\/p>\n

\u6750\u6599\u6d4b\u8bd5\uff0c\u6570\u636e\u5206\u6790\uff0c\u4e0a\u6d4b\u8bd5\u8c37<\/a>!<\/strong><\/p>\n","protected":false},"excerpt":{"rendered":"

\u3010\u5f15\u8a00\u3011 \u8fd1\u5e74\u6765\uff0c\u53ef\u590d\u7528\u7eb8\u7531\u4e8e\u5728\u73af\u5883\u4fdd\u62a4\u3001\u8d44\u6e90\u8282\u7ea6\u7b49\u65b9\u9762\u5177\u6709\u7684\u5929\u7136\u4f18\u52bf\u800c\u5907\u53d7\u5173\u6ce8\uff0c\u7136\u800c\u5982\u4f55\u5728\u53ef\u590d\u7528\u7eb8\u4e0a\u5b9e\u73b0\u4fdd\u5b58\u65f6\u95f4\u8db3\u591f\u957f\u7684\u591a\u8272\u55b7\u58a8\u6253\u5370\uff0c\u8fd9\u8fd8\u662f\u4e00\u4e2a\u5c1a\u672a\u7a81\u7834\u7684\u6280\u672f…<\/p>\n","protected":false},"author":230,"featured_media":121481,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[2732],"class_list":["post-121478","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-jiedu","tag-2732"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/121478"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/230"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=121478"}],"version-history":[{"count":5,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/121478\/revisions"}],"predecessor-version":[{"id":121810,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/121478\/revisions\/121810"}],"wp:featuredmedia":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/media\/121481"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=121478"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=121478"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=121478"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}