{"id":121211,"date":"2018-01-14T14:00:52","date_gmt":"2018-01-14T06:00:52","guid":{"rendered":"\/\/m.iemloyee.com\/?p=121211"},"modified":"2018-01-14T07:37:23","modified_gmt":"2018-01-13T23:37:23","slug":"%e5%8d%97%e4%ba%ac%e5%b7%a5%e4%b8%9a%e5%a4%a7%e5%ad%a6nano-energy%ef%bc%9a%e6%97%a0%e5%90%8e%e5%a4%84%e7%90%86%e3%80%81%e6%97%a0%e6%8e%ba%e6%9d%82%e4%ba%8c%e8%8a%b3%e5%9f%ba%e8%8a%b4%e7%b1%bb%e7%ba%b3","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=121211","title":{"rendered":"\u5357\u4eac\u5de5\u4e1a\u5927\u5b66Nano Energy\uff1a\u65e0\u540e\u5904\u7406\u3001\u65e0\u63ba\u6742\u4e8c\u82b3\u57fa\u82b4\u7c7b\u7eb3\u7c73\u5206\u5b50\u4f5c\u4e3a\u67d4\u6027p-i-n\u578b\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u7684\u7a7a\u7a74\u4f20\u8f93\u6750\u6599"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n

\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u56e0\u5176\u9ad8\u80fd\u91cf\u8f6c\u6362\u6548\u7387\u5df2\u5f15\u8d77\u4e86\u9ad8\u5ea6\u5173\u6ce8\uff0c\u8fd9\u79cd\u7535\u6c60\u7684\u4f4e\u6210\u672c\u6eb6\u6db2\u5236\u5907\u6cd5\u548c\u5370\u5237\u6280\u672f\u4f7f\u5176\u5728\u5176\u4ed6\u5149\u4f0f\u5668\u4ef6\u4e2d\u4e5f\u6709\u5e7f\u6cdb\u7684\u6f5c\u5728\u5e94\u7528\u4ef7\u503c\u3002\u8fc7\u53bb\u5341\u5e74\u95f4\uff0c\u7814\u7a76\u4eba\u5458\u81f4\u529b\u4e8e\u6539\u53d8\u7535\u6c60\u7ed3\u6784\u548c\u4f18\u5316\u9499\u949b\u77ff\u8584\u819c\u5f62\u8c8c\uff0c\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u8f6c\u6362\u6548\u7387\u4e5f\u4ece2009\u5e74\u76843.8%\u4e0a\u5347\u81f3\u4eca\u5e74\u768422.1%\u3002\u8fc4\u4eca\u4e3a\u6b62\uff0c\u9ad8\u6548\u7684\u56fa\u6001\u4ecb\u5b54\u548c\u5e73\u9762\u5f02\u8d28\u7ed3\u5df2\u88ab\u7528\u4e8e\u6539\u5584\u5668\u4ef6\u7ed3\u6784\uff0c\u589e\u5f3a\u5668\u4ef6\u6027\u80fd\u3002\u7136\u800c\uff0c\u5229\u7528\u91d1\u5c5e\u6c27\u5316\u7269\uff08\u5982\uff1aTiO2\uff0cSnO2\uff0cCuO\uff09\u7b49\u4f5c\u4e3a\u7535\u5b50\u4f20\u8f93\u5c42\u7684\u4f20\u7edf\u5236\u5907\u65b9\u6cd5\u9700\u8981\u9ad8\u6e29\u5904\u7406\uff0c\u800c\u8fd9\u79cd\u65b9\u6cd5\u4e0d\u4ec5\u5341\u5206\u8017\u80fd\u4e14\u4e0d\u9002\u7528\u4e8e\u67d4\u6027\u5851\u6599\u57fa\u5e95\u3002\u56e0\u6b64\uff0c\u53ef\u4f4e\u6e29\u5236\u5907\u7684\u65e0\u6ede\u540e\u53cd\u5f0f\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\uff08i-PVSC\uff09\u51fa\u73b0\u4e86\u3002\u53cd\u5f0f\u7535\u6c60\u901a\u5e38\u4f7f\u7528PCBM\u4f5c\u4e3a\u7535\u5b50\u4f20\u8f93\u5c42\uff08ETL\uff09\uff0cPEDOT:PSS\u4f5c\u4e3a\u7a7a\u7a74\u4f20\u8f93\u5c42\uff0c\u9002\u7528\u4e8e\u67d4\u6027\u57fa\u5e95\uff0c\u53ef\u901a\u8fc7\u5370\u5237\u6280\u672f\u91cf\u4ea7\u3002PEDOT:PSS\u7684\u9178\u6027\u548c\u4eb2\u6c34\u6027\u4f1a\u4e0d\u53ef\u907f\u514d\u5730\u8150\u8680ITO\uff0c\u5438\u6536\u73af\u5883\u4e2d\u7684\u6c34\u5206\uff0c\u5f71\u54cd\u5668\u4ef6\u7684\u6027\u80fd\u548c\u7a33\u5b9a\u6027\u3002\u56e0\u6b64\uff0c\u5546\u7528\u7684\u9499\u949b\u77ff\u7535\u6c60\u5341\u5206\u9700\u8981\u65b0\u578b\u6eb6\u6db2\u5904\u7406\u7684\u7a7a\u7a74\u6750\u6599\u3002\u4e0e\u805a\u5408\u7269\u7a7a\u7a74\u6750\u6599\u4e0d\u540c\uff0c\u5c0f\u5206\u5b50\u6613\u4e8e\u63d0\u7eaf\uff0c\u901a\u8fc7\u5206\u5b50\u5de5\u7a0b\u5bf9\u5316\u5b66\u7ed3\u6784\u8fdb\u884c\u6539\u6027\uff0c\u53ef\u4ee5\u63a7\u5236\u5149\u7535\u6027\u80fd\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u6700\u8fd1\uff0c\u5357\u4eac\u5de5\u4e1a\u5927\u5b66\u9ec4\u7ef4\u6559\u6388<\/strong>(<\/strong>\u901a\u8baf\u4f5c\u8005<\/strong>)<\/strong>\u7b49\u4eba\u5728Nano Energy<\/strong> \u4e0a\u53d1\u8868\u9898\u4e3a\u201cDiarylfluorene-based Nano-molecules as Dopant-Free Hole-transporting Materials without Post-treatment Process for Flexible p-i-n Type Perovskite Solar Cells<\/strong>\u201d\u7684\u6587\u7ae0\u3002\u7814\u7a76\u56e2\u961f\u8bbe\u8ba1\u4e86\u4e24\u7ec4\u4e8c\u82b3\u57fa\u82b4\u7c7bHTM\uff0cTPA\u6216\u80059-NPC\u4f5c\u4e3a\u94fe\u81c2\uff0cC8\u6216\u8005C6Cz\u4e3a\u4fa7\u94fe\uff0c\u5206\u522b\u547d\u540d\u4e3aMC8-TPA, MC8-9-NPC\uff0cMC6Cz-TPA\u548cMC6Cz-9-NPC\u3002\u8fd9\u4e9b\u6750\u6599\u5728\u666e\u901a\u6709\u673a\u6eb6\u5242\u4e2d\u6709\u5f88\u597d\u7684\u6eb6\u89e3\u6027\uff0c\u65cb\u6d82\u800c\u6210\u7684\u8584\u819c\u754c\u9762\u5149\u6ed1\uff0c\u758f\u6c34\u6027\u597d\uff0c\u5728ITO\u4e0a\u4e0d\u9700\u540e\u7eed\u70ed\u5904\u7406\u5373\u8868\u73b0\u5b8c\u5168\u7ed3\u6676\u6001\u3002\u5728\u4e8c\u82b3\u57fa\u82b4\u7c7bHTM\u4e0a\u5236\u5907\u7684\u9499\u949b\u77ff\u8584\u819c\u6bd4\u5728PEDOT:PSS\u4e0a\u7684\u6676\u7c92\u66f4\u5927\uff0c\u7ea6\u4e3a300nm\u3002\u5668\u4ef6\u7684\u6700\u9ad8\u6548\u7387\u8fbe\u523013.85%\uff0c\u67d4\u6027\u9499\u949b\u77ff\u7535\u6c60\u6700\u9ad8\u6548\u7387\u4e3a9.09%\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n

\u56fe<\/strong>1.<\/strong>\u65e0\u63ba\u6742\u7a7a\u7a74\u6750\u6599\u7684\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60<\/strong><\/p>\n

\"\"<\/p>\n

\u56fe<\/strong>2.<\/strong>\u65e0\u63ba\u6742\u4e8c\u82b3\u57fa\u82b4\u7c7b\u7a7a\u7a74\u6750\u6599\u7684\u5206\u5b50\u7ed3\u6784\u548c\u7535\u6c60\u7ed3\u6784<\/strong><\/p>\n

\"\"<\/p>\n

a\uff09HTM\u7684\u5316\u5b66\u7ed3\u6784\uff1b<\/p>\n

b\uff09\u5355\u6676\u4e2dMC8-9-npc\u7684\u5206\u5b50\u7ed3\u6784\u548c\u5206\u5b50\u5c3a\u5bf8\uff1b<\/p>\n

c\uff09\u67d4\u6027i-PVSC\u7684\u7ed3\u6784\uff1b<\/p>\n

d\uff09\u6587\u7ae0\u5668\u4ef6\u6d89\u53ca\u7684\u6750\u6599\u7684\u80fd\u5e26\u5206\u5e03\uff1b<\/p>\n

\u56fe<\/strong>3.<\/strong>\u7535\u6c60\u7684\u5149\u5b66\u8868\u5f81<\/strong><\/p>\n

\"\"<\/p>\n

a\uff09\u5728\u4e0d\u540cHTM\u4e0a\u5236\u5907\u7684\u9499\u949b\u77ff\u8584\u819c\u7684\u7d2b\u5916\u53ef\u89c1\u5438\u6536\u5149\u8c31\uff1b<\/p>\n

b\uff09\u57fa\u4e8e\u4e0d\u540cHTM\u7684\u9499\u949b\u77ff\u7684\u7a33\u6001\u8367\u5149\u5149\u8c31\uff1b<\/p>\n

c\uff09\u57fa\u4e8e\u4e0d\u540cHTM\u7684\u9499\u949b\u77ff\u5728\u5cf0\u503c\u53d1\u5c04\u6ce2\u957f\uff08760nm\uff09\u51fa\u62cd\u6444\u7684\u65f6\u95f4\u5206\u8fa8PL\u8870\u51cf\u77ac\u53d8\uff1b<\/p>\n

\u56fe<\/strong>4.<\/strong>\u9499\u949b\u77ff\u8584\u819c\u5f62\u8c8c\u8868\u5f81<\/strong><\/p>\n

\"\"<\/p>\n

a-e)\u65cb\u6d82\u5728ITO\u57fa\u5e95\u4e0a\u7684HTM (a) PEDOT:PSS, (b) MC8-TPA, (c) MC8-9-NPC, (d)MC6Cz-TPA, (e) MC6Cz-9-NPC\u7684AFM\u5f62\u8c8c\uff1b<\/p>\n

f-J)\u4e0d\u540cHTM\u4e0a\u9499\u949b\u77ff\u7684AFM\u5f62\u8c8c\uff1b<\/p>\n

k-o)\u4e0d\u540cHTM\u4e0a\u9499\u949b\u77ff\u7684SEM\u5f62\u8c8c\uff1b<\/p>\n

\u56fe<\/strong>5<\/strong>\u7535\u6c60\u7684\u5149\u7535\u6027\u80fd\u8868\u5f81<\/strong><\/p>\n

\"\"<\/p>\n

a\uff09\u6b63\u626b\u65f6\uff0c\u4e0d\u540cHTM\u4e0a\u9499\u949b\u77ff\u7535\u6c60\u7684J-V\u66f2\u7ebf\uff1b<\/p>\n

b\uff09\u6b63\u626b\u65f6\uff0c\u4e0d\u540cHTM\u4e0a\u9499\u949b\u77ff\u7535\u6c60\u6697\u66f2\u7ebf\uff1b<\/p>\n

c\uff09\u6b63\u626b\u65f6\uff0c\u4e0d\u540cHTM\u4e0a\u9499\u949b\u77ff\u7535\u6c60\u7684\u5916\u91cf\u5b50\u6548\u7387\uff08EQE\uff09\u66f2\u7ebf\uff1b<\/p>\n

d\uff09\u67d4\u6027\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u7684J-V\u66f2\u7ebf\uff1b<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n

\u8be5\u7814\u7a76\u5c06\u65b0\u578b\u5c0f\u5206\u5b50HTM\u5f15\u5165p-i-n\u5e73\u9762\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u4e2d\uff0c\u7535\u6c60\u6027\u80fd\u663e\u8457\u63d0\u9ad8\u3002\u800c\u4e14\u8fd9\u4e9b\u4f53\u4e8c\u82b3\u57fa\u82b4\u7c7b\u6750\u6599\u53ef\u4ee5\u5728\u4e0d\u7ecf\u8fc7\u4efb\u4f55\u540e\u5904\u7406\u8fc7\u7a0b\u7684\u60c5\u51b5\u4e0b\u8fdb\u884c\u6eb6\u6db2\u6cd5\u5236\u5907\uff0c\u800c\u4e14\u4e0d\u9700\u63ba\u6742\u5c31\u6709\u5f88\u9ad8\u7684\u4f20\u5bfc\u6027\uff0c\u66f4\u6613\u4ece\u9499\u949b\u77ff\u4e2d\u62bd\u53d6\u7a7a\u7a74\u3002\u6b64\u5916\uff0c\u5728\u6b64\u57fa\u5e95\u4e0a\u7684\u9499\u949b\u77ff\u8584\u819c\u5177\u6709\u6676\u7c92\u5927\u3001\u81f4\u5bc6\u7684\u7279\u70b9\u3002\u8fd9\u4e9b\u4f18\u52bf\u4e5f\u4f7f\u7535\u6c60\u7684\u8f7d\u6d41\u5b50\u635f\u5931\u5c11\uff0c\u6548\u7387\u66f4\u9ad8\u3002\u8bf4\u660e\u4e86\u65b0\u578b\u5c0f\u5206\u5b50\u7a7a\u7a74\u4f20\u8f93\u6750\u6599\u5728\u672a\u6765\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u53d1\u5c55\u4e2d\u7684\u6f5c\u529b\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/strong>Diarylfluorene-based Nano-molecules as Dopant-Free Hole-transporting Materials without Post-treatment Process for Flexible p-i-n Type Perovskite Solar Cells<\/a>\uff08Nano Energy,2017,DIO:10.1016\/j.nanoen.2018.01.005)<\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u7f16\u8f91\u90e8\u6c88\u9ece\u4e3d\u7f16\u8bd1\uff0c\u8d75\u98de\u9f99\u5ba1\u6838\uff0c\u70b9\u6211\u52a0\u5165\u6750\u6599\u4eba\u7f16\u8f91\u90e8\u3002<\/a><\/p>\n

\u6750\u6599\u6d4b\u8bd5\uff0c\u6570\u636e\u5206\u6790\uff0c<\/strong>\u4e0a\u6d4b\u8bd5\u8c37<\/strong><\/a>\uff01<\/strong><\/p>\n","protected":false},"excerpt":{"rendered":"

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