{"id":120732,"date":"2018-01-10T14:00:38","date_gmt":"2018-01-10T06:00:38","guid":{"rendered":"\/\/m.iemloyee.com\/?p=120732"},"modified":"2018-01-09T17:56:57","modified_gmt":"2018-01-09T09:56:57","slug":"adv-energy-mater-%ef%bc%9a%e6%a8%a1%e6%8b%9f%e5%85%89%e7%b3%bb%e7%bb%9fii%e8%ae%be%e8%ae%a1%e4%b8%ad%e6%80%a7%e6%b0%b4%e6%b0%a7%e5%8c%96%e5%82%ac%e5%8c%96%e5%89%82-%e4%bb%a5co3o4","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=120732","title":{"rendered":"Adv. Energy Mater.\uff1a\u6a21\u62df\u5149\u7cfb\u7edfII\u8bbe\u8ba1\u4e2d\u6027\u6c34\u6c27\u5316\u50ac\u5316\u5242\u2014\u2014\u4ee5Co3O4\u4e3a\u4f8b"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n

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\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u6765\u81ea\u6e05\u534e\u5927\u5b66\u7684\u738b\u8bad\u6559\u6388\u7b49\u4eba\u5728Advanced Energy Materials\u4e0a\u53d1\u6587\uff0c\u9898\u4e3a\uff1a\u201cMimic the Photosystem II for Water Oxidation in Neutral Solution: A Case of Co3<\/sub>O4<\/sub>\u201d\u3002\u7814\u7a76\u4eba\u5458\u6a21\u62df\u5149\u7cfb\u7edfII\u4e2d\u4ea7\u6c27\u50ac\u5316\u5242\u7684\u7ed3\u6784\u548c\u4ea7\u6c27\u5de5\u4f5c\u673a\u7406\uff0c\u901a\u8fc7\u5f15\u5165\u6cb9\u80fa\u6709\u673a\u5c42\u8986\u76d6\u5728Co3<\/sub>O4<\/sub>\u4e0a\u6a21\u4eff\u5176\u7ed3\u6784\uff0c\u5728\u4f53\u7cfb\u4e2d\u589e\u52a0\u7f13\u51b2\u6eb6\u6db2\u7684\u6d53\u5ea6\u4f5c\u4e3a\u8d28\u5b50\u8f93\u8fd0\u8f7d\u4f53\u4ee5\u6a21\u4eff\u5176\u5de5\u4f5c\u673a\u7406\u3002\u7ed3\u679c\u663e\u793a\uff0c\u8fd9\u4e24\u79cd\u6548\u5e94\u80fd\u591f\u4f7f\u6d3b\u6027\u5927\u5927\u63d0\u9ad8\u3002\u5728\u4e2d\u6027\u73af\u5883\u4e2d\uff0c\u7535\u6d41\u5bc6\u5ea6\u8fbe\u523010 mA cm\u22122<\/sup>\u7684\u8fc7\u7535\u52bf\u4e3a390 mV\u3002\u5f53\u8fc7\u7535\u52bf\u4e3a400 mV\u65f6\uff0c\u5176TOF\u4e3a0.0117\uff0c\u8fd9\u51e0\u4e4e\u4e0e\u5176\u57281 M KOH\u6eb6\u6db2\u4e2d\u7684\u6027\u80fd\u76f8\u540c\u3002\u901a\u8fc7\u5bf9Co3<\/sub>O4<\/sub>\u6790\u6c27\u50ac\u5316\u5242\u7684\u8868\u9762\u5316\u5b66\u8fdb\u4e00\u6b65\u5206\u6790\u8868\u660e\uff0c\u6cb9\u80fa\u7684\u5b58\u5728\u53ef\u4ee5\u63d0\u9ad8\u50ac\u5316\u5242\u7684\u672c\u5f81\u6d3b\u6027\uff0c\u800c\u7f13\u51b2\u6db2\u4f5c\u4e3a\u8d28\u5b50\u8f93\u8fd0\u8f7d\u4f53\u53ef\u4ee5\u5927\u5927\u4fc3\u8fdb\u53cd\u5e94\u7684\u539f\u56e0\u4e0e\u6790\u6c27\u53cd\u5e94\u673a\u5236\u4e2d\u8d28\u5b50\u4ea4\u6362\u7535\u5b50\u8f6c\u79fb\u8fc7\u7a0b\u76f8\u5173\u3002\u8fd9\u4e9b\u7ed3\u679c\u53ef\u80fd\u5f15\u53d1\u5bf9\u4e8e\u6a21\u4eff\u81ea\u7136\u7cfb\u7edf\u7684\u65b0\u89c2\u70b9\u4ee5\u53ca\u7535\u50ac\u5316\u4e2d\u7684\u65b0\u89c1\u89e3\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n

\u56fe1. \u00a0\u5728\u4e2d\u6027\u6eb6\u6db2\u4e2d\u6a21\u62df\u6c34\u6c27\u5316\u7684\u6982\u5ff5<\/strong><\/p>\n

\"\"<\/p>\n

a) PSII\u4e2d\u6c34\u6c27\u5316\u7684\u793a\u610f\u56fe\uff1b<\/p>\n

b) \u5728PSII\u4e0a\u7684Mn4<\/sub>Ca\u56e2\u7c07\u7684\u6676\u4f53\u7ed3\u6784\uff1b<\/p>\n

c) \u672c\u6587\u4e2d\u6a21\u62df\u6c34\u6c27\u5316\u7684PSII\u6982\u5ff5\uff1b<\/p>\n

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\"\"<\/p>\n

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\"\"<\/p>\n

a) IFFT\u5904\u7406\u7684HAADF-STEM\u56fe\uff1b<\/p>\n

b) \u539f\u59cb\u56fe\u50cf.\u9897\u7c92\u8fb9\u7f18\u4e0d\u6e05\u6670\uff0c\u53ef\u80fd\u5b58\u5728\u65e0\u5b9a\u578b\u7684\u7ed3\u6784\uff1b<\/p>\n

c) (b)\u7684FFT\u56fe.<\/p>\n

d,e) (a)STEM\u56fe\u4e2d\u6cbf\u7740\u7eff\u7ebf\u548c\u7ea2\u7ebf\u7684\u5f3a\u5ea6\uff1b<\/p>\n

f,g) \u5176\u4ed6IFFT\u5904\u7406\u7684HAADF-STEM\u56fe\uff1b<\/p>\n

\u56fe4. \u5728KPi<\/sub>\u6eb6\u6db2\u4e2dCo3<\/sub>O4<\/sub>(I)\u6027\u80fd<\/strong><\/p>\n

\"\"<\/p>\n

a) Co3<\/sub>O4<\/sub>(I,0.85) (0.85\u8868\u793a\u50ac\u5316\u5242\u8868\u9762\u7f9f\u57faO\u4e0e\u6c27\u5316\u7269O\u7684\u6bd4\u4f8b)\u548c43R.C. \uff08R.C.\u8868\u793a\u8868\u9762\u6cb9\u80fa\u7684\u76f8\u5bf9\u8986\u76d6\u5ea6\uff09\u7684LSV\u66f2\u7ebf\u4ee5\u53ca\u7a33\u5b9a\u6027\uff1b<\/p>\n

b) \u5177\u6709\u4e0d\u540cC.\u7684\u50ac\u5316\u5242\u7684LSV\u66f2\u7ebf\uff0c \u63d2\u56fe\u4e3a\u5176R.C.\u4e0e\u6d3b\u6027\u7684\u5173\u7cfb\uff1b<\/p>\n

c)\u5728\u76f8\u4f3c\u5236\u5907\u6761\u4ef6\u4e0bCo3<\/sub>O4<\/sub>\u00a0\u50ac\u5316\u5242\u7684\u7a33\u5b9a\u6027\u4e0e\u5176\u8868\u9762\u7f9f\u57faO\u4e0e\u6c27\u5316\u7269O\u6bd4\u4f8b\u7684\u706b\u5c71\u5173\u7cfb\u56fe\uff0c\u6ca1\u6709\u6807\u8bb0\u7684\u70b9\u9897\u7c92\u5e73\u5747\u5c3a\u5bf8\u4e3a3-4nm\uff1b<\/p>\n

d) Co3<\/sub>O4<\/sub>(I,0.85)\u5728\u4e0d\u540c\u4e2d\u6027\u6eb6\u6db2\u4e2d\u7684LSV\u66f2\u7ebf.\u63d2\u56fe\u4e3a\u653e\u5927\u56fe\uff1b<\/p>\n

\u56fe5. Co3<\/sub>O4<\/sub>(I,0.85)\u5728\u4e0d\u540c\u7f13\u51b2\u6eb6\u6db2\u4e2d\u7684\u6027\u80fd<\/strong><\/p>\n

\"\"<\/p>\n

a)\u5728\u4e0d\u540c\u7f13\u51b2\u6eb6\u6db2\uff0c\u4e0d\u540c\u6d53\u5ea6\u4e2d\u00a0E<\/em>10<\/sub>\uff08\u7535\u6d41\u5bc6\u5ea6\u4e3a10mA\/cm2<\/sup>\u65f6\u7684\u7535\u538b\uff09\u4e0e\u7f13\u51b2\u6eb6\u6db2\u6d53\u5ea6\u7684\u5173\u7cfb\uff1b<\/p>\n

b) 1.8V(vs RHE)\u4e0b\u7684\u7535\u6d41\u5bc6\u5ea6\u4e0e\u7f13\u51b2\u6eb6\u6db2\u6d53\u5ea6\u7684\u5173\u7cfb\uff1b<\/p>\n

c)\u5728\u4e0d\u540c\u7f13\u51b2\u6eb6\u6db2\uff0c\u4e0d\u540c\u6d53\u5ea6\u4e2d\u5854\u83f2\u5c14\u659c\u7387\u4e0e\u7f13\u51b2\u6eb6\u6db2\u7684\u6d53\u5ea6\u5173\u7cfb\uff1b<\/p>\n

d)\u7531\u5854\u83f2\u5c14\u659c\u7387\u5916\u63a8\u5f97\u5230\u7684I<\/em>0<\/sub>\u4e0e\u7f13\u51b2\u6eb6\u6db2\u6d53\u5ea6\u7684\u5173\u7cfb\uff1b<\/p>\n

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\u3010\u603b\u7ed3\u3011<\/strong><\/p>\n

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\u6587\u732e\u94fe\u63a5\uff1a<\/strong>Mimic the Photosystem II for Water Oxidation in Neutral Solution: A Case of Co3<\/sub>O4<\/sub> <\/a>(Adv. Energy Mater. 2018., DOI: 10.1002\/aenm.201702313)<\/p>\n

\u56e2\u961f\u4ecb\u7ecd\uff1a<\/strong><\/p>\n

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\u8be5\u9886\u57df\u5de5\u4f5c\u6c47\u603b\uff1a<\/p>\n

Nat. Commun. 2017, 8, 1559<\/p>\n

Am. Chem. Soc. 2017, 139, 8579\u20138585<\/p>\n

Small 2017, 13, 1701487<\/p>\n

Nat. Commun. 2017, 8, 15377<\/p>\n

Adv. Mater.,2017, 29\uff0c 1701354<\/p>\n

Small, 2016, 12, 1006\u20131012<\/p>\n

Chem. Sci.2015, 6, 3572-3576<\/p>\n

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