{"id":120655,"date":"2018-01-11T06:30:56","date_gmt":"2018-01-10T22:30:56","guid":{"rendered":"\/\/m.iemloyee.com\/?p=120655"},"modified":"2018-01-11T14:14:03","modified_gmt":"2018-01-11T06:14:03","slug":"%e4%b8%ad%e5%8d%97%e6%b0%91%e6%97%8f%e5%a4%a7%e5%ad%a6%e5%bc%a0%e6%b3%bd%e4%bc%9a%e6%95%99%e6%8e%88%e8%af%be%e9%a2%98%e7%bb%84chem-soc-rev-%ef%bc%9a%e5%82%ac%e5%8c%96%e7%a2%b3%e6%b0%b4%e5%8c%96","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=120655","title":{"rendered":"\u4e2d\u5357\u6c11\u5927\u5f20\u6cfd\u4f1aChem. Soc. Rev.\uff1a\u50ac\u5316\u78b3\u6c34\u5316\u5408\u7269\u8f6c\u5316\u4e3a\u6709\u673a\u9178\u548c\u544b\u5583\u5316\u5b66\u54c1"},"content":{"rendered":"<p>\u5728\u5316\u77f3\u8d44\u6e90\u65e5\u76ca\u67af\u7aed\u548c\u73af\u5883\u6c61\u67d3\u4e24\u5927\u4e16\u754c\u96be\u9898\u9762\u524d\uff0c\u5f00\u53d1\u65b0\u578b\u53ef\u6301\u7eed\u7684\u6e05\u6d01\u80fd\u6e90\u663e\u5f97\u5c24\u4e3a\u91cd\u8981\uff1b\u5728\u6b64\u5927\u80cc\u666f\u4e0b\uff0c\u89e3\u51b3\u65b9\u6cd5\u4e4b\u4e00\u5c31\u662f\u53d1\u5c55\u53ef\u518d\u751f\u751f\u7269\u8d28\u8d44\u6e90\u4ee3\u66ff\u4e0d\u53ef\u518d\u751f\u7684\u5316\u77f3\u8d44\u6e90\uff0c\u7528\u4e8e\u751f\u4ea7\u6db2\u4f53\u71c3\u6599\u548c\u5316\u5b66\u54c1\u3002\u8fd1\u5e74\u6765\uff0c\u6b64\u7c7b\u65b9\u6cd5\u5f15\u8d77\u4e86\u56fd\u5185\u5916\u6781\u5927\u7684\u5173\u6ce8\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-120657 aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/01\/1-9.jpg\" alt=\"\" width=\"600\" height=\"483\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/01\/1-9.jpg 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2018\/01\/1-9-300x242.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>\u5f20\u6cfd\u4f1a\u6559\u6388\u5728\u5176\u7814\u7a76\u5de5\u4f5c\u7684\u57fa\u7840\u4e0a\uff0c\u9996\u6b21\u7cfb\u7edf\u603b\u7ed3\u4e86\u50ac\u5316\u6c27\u5316\u6280\u672f\u5728\u50ac\u5316\u751f\u7269\u8d28\u78b3\u6c34\u5316\u5408\u7269\u8f6c\u5316\u4e3a\u5404\u79cd\u91cd\u8981\u7684\u6709\u673a\u9178\uff08\u7532\u9178\u3001\u918b\u9178\u3001\u4e59\u9187\u9178\u3001\u4e19\u4e8c\u9178\u3001\u8349\u9178\u3001\u8461\u8404\u7cd6\u9178\u3001\u8461\u7cd6\u4e8c\u9178\uff09\u53ca\u50ac\u5316\u544b\u5583\u5316\u5408\u7269\u9009\u62e9\u6027\u6c27\u5316\u4e2d\u7684\u5e94\u7528\uff0c\u5e76\u5bf9\u5f53\u524d\u5404\u79cd\u65b9\u6cd5\u8fdb\u884c\u4e86\u6df1\u5165\u8ba8\u8bba\u4e0e\u5206\u6790\u3002\u672c\u6587\u9488\u5bf9\u5f53\u524d\u50ac\u5316\u751f\u7269\u8d28\u6c27\u5316\u4e3a\u6709\u673a\u9178\u548c\u544b\u5583\u7c7b\u5316\u5408\u7269\u7684\u5404\u79cd\u65b9\u6cd5\u8fdb\u884c\u4e86\u8bc4\u8bba\u5e76\u63d0\u4f9b\u4e86\u8be5\u7814\u7a76\u65b9\u5411\u7684\u91cd\u8981\u5efa\u8bae\u3002\u8be5\u7efc\u8ff0\u5bf9\u751f\u7269\u8d28\u50ac\u5316\u6c27\u5316\u5408\u6210\u91cd\u8981\u6709\u673a\u9178\u548c\u544b\u5583\u7c7b\u5316\u5408\u7269\u5177\u6709\u6307\u5bfc\u548c\u5f15\u9886\u4f5c\u7528\u3002\u6587\u7ae0\u4ee5<strong>\u201cCatalytic oxidation of carbohydrates into organic acids and furan chemicals\u201d<\/strong>\u4e3a\u9898\u53d1\u8868\u57282018\u5e741\u67083\u65e5\u51fa\u7248\u7684<strong>Chemical Society Reviews<\/strong>\u4e0a\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-120658 aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/01\/2-13.jpg\" alt=\"\" width=\"600\" height=\"316\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/01\/2-13.jpg 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2018\/01\/2-13-300x158.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p style=\"text-align: center;\"><strong>\u56fe1. \u7531\u8461\u8404\u7cd6\u548c\u8461\u8404\u7cd6\u884d\u751f\u7684\u5206\u5b50\u6c27\u5316\u4ea7\u751f\u7684\u5316\u5b66\u54c1<\/strong><\/p>\n<p><strong>\u78b3\u6c34\u5316\u5408\u7269\u8f6c\u5316\u4e3a\u7532\u9178<\/strong><\/p>\n<p>1954\u5e74\uff0c\u6587\u732e\u4e2d\u9996\u5148\u62a5\u9053\u4e86\u5c06\u78b3\u6c34\u5316\u5408\u7269\u6c27\u5316\u4e3a\u7532\u9178\u7684\u7814\u7a76\u3002 \u5176\u4e2d\uff0cSch\u00f6pf\u548cWild\u7528\u5316\u5b66\u8ba1\u91cf\u7684\u9ad8\u7898\u9178\uff08H<sub>5<\/sub>IO<sub>6<\/sub>\uff09\u5c06\u8461\u8404\u7cd6\u6c27\u5316\u6210\u7532\u9178\uff0c\u56fe2\u663e\u793a\u4e861 mol\u8461\u8404\u7cd6\u4e0e3 mol O<sub>2<\/sub>\u7684\u5316\u5b66\u8ba1\u91cf\u53cd\u5e94\uff0c\u7ed3\u679c\u4ea7\u751f\u4e866 mol\u7532\u9178\uff0c\u540c\u65f6\u6ca1\u6709\u4efb\u4f55\u5176\u4ed6\u526f\u4ea7\u7269\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-120659 aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/01\/3-11.jpg\" alt=\"\" width=\"600\" height=\"220\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/01\/3-11.jpg 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2018\/01\/3-11-300x110.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p style=\"text-align: center;\"><strong>\u56fe2. \uff08a\uff09<\/strong>\u8461\u8404\u7cd6\u6c27\u5316\u4e3a\u7532\u9178\u7684\u5316\u5b66\u8ba1\u91cf\u53cd\u5e94; <strong>\uff08b\uff09<\/strong>\u901a\u8fc7H<sub>3+n<\/sub>PV<sub>n<\/sub>Mo<sub>12-n<\/sub>O<u>40<\/u>\uff08HPA\uff09\u50ac\u5316\u5242\u5c06\u78b3\u6c34\u5316\u5408\u7269\u6c27\u5316\u8f6c\u5316\u4e3a\u7532\u9178<\/p>\n<p><strong>\u78b3\u6c34\u5316\u5408\u7269\u8f6c\u5316\u4e3a\u918b\u9178<\/strong><\/p>\n<p>\u751f\u7269\u8d28\u6c27\u5316\u6210\u4e59\u9178\u901a\u5e38\u53d1\u751f\u4e24\u6b65\u53cd\u5e94\uff1a\u9996\u5148\u5c06\u78b3\u6c34\u5316\u5408\u7269\u8f6c\u5316\u4e3a\u4e2d\u95f4\u4f53\uff0c\u7136\u540e\u5c06\u4e2d\u95f4\u4f53\u6c27\u5316\u6210\u4e59\u9178\u3002 H<sub>2<\/sub>O<sub>2<\/sub>\u7ecf\u5e38\u7528\u4f5c\u7b2c\u4e8c\u6b65\u7684\u6c27\u5316\u5242\u3002\u6839\u636e\u53cd\u5e94\u6761\u4ef6\uff0c\u4e2d\u95f4\u4f53\u5305\u62ecHMF\uff0c2-\u7ce0\u919b\uff082-FA\uff09\uff0c\u4e73\u9178\u548c\u4e59\u9170\u4e19\u9178\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-120660 aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/01\/4-10.jpg\" alt=\"\" width=\"600\" height=\"455\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/01\/4-10.jpg 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2018\/01\/4-10-300x228.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p style=\"text-align: center;\"><strong>\u56fe3. \u4e24\u6b65\u6cd5\u7528\u4e8e\u7ecf\u7531\u4e0d\u540c\u4e2d\u95f4\u4f53\u751f\u4ea7\u4e59\u9178<\/strong><\/p>\n<p><strong>\u78b3\u6c34\u5316\u5408\u7269\u8f6c\u5316\u4e3a\u8461\u8404\u7cd6\u9178<\/strong><\/p>\n<p>\u4ece\u78b3\u6c34\u5316\u5408\u7269\u5408\u6210\u8461\u8404\u7cd6\u9178\u57fa\u672c\u4e0a\u9700\u8981\u4e24\u4e2a\u8fde\u7eed\u7684\u6b65\u9aa4\uff1a\u5c06\u78b3\u6c34\u5316\u5408\u7269\u50ac\u5316\u6c34\u89e3\u6210\u8461\u8404\u7cd6\uff0c\u968f\u540e\u6c27\u5316\u4ea7\u751f\u7684\u8461\u8404\u7cd6\u9178\u3002 \u56e0\u6b64\uff0c\u7ed3\u5408\u91d1\u5c5e\u548c\u9178\u6027\u4f4d\u70b9\u7684\u53cc\u529f\u80fd\u50ac\u5316\u5242\u5bf9\u4e8e\u5c06\u6c34\u89e3\u548c\u6c27\u5316\u6b65\u9aa4\u6574\u5408\u5230\u7528\u4e8e\u5c06\u78b3\u6c34\u5316\u5408\u7269\u8f6c\u5316\u4e3a\u8461\u8404\u7cd6\u9178\u7684\u4e00\u9505\u53cd\u5e94\u662f\u76ee\u524d\u53d1\u5c55\u7684\u4e00\u4e2a\u8d8b\u52bf\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-120661 aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/01\/5-9.jpg\" alt=\"\" width=\"600\" height=\"340\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/01\/5-9.jpg 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2018\/01\/5-9-300x170.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p style=\"text-align: center;\"><strong>\u56fe4. \u78b3\u6c34\u5316\u5408\u7269\u8f6c\u5316\u6210\u8461\u8404\u7cd6\u9178\u53ca\u5176\u884d\u751f\u7269\u7684\u53cd\u5e94\u8def\u5f84<\/strong><\/p>\n<p><strong>\u544b\u5583\u7c7b\u5316\u5408\u7269\u7684\u50ac\u5316\u6c27\u5316<\/strong><\/p>\n<p>HMF\uff0c\u7ce0\u919b\u548c\u5176\u4ed6\u4ece\u751f\u7269\u8d28\u751f\u4ea7\u7684\u5e73\u53f0\u5316\u5b66\u54c1\u4e5f\u53ef\u4ee5\u88ab\u50ac\u5316\u6c27\u5316\u6210\u591a\u79cd\u5316\u5b66\u54c1\u3002 \u7531C6\u78b3\u6c34\u5316\u5408\u7269\u8131\u6c34\u751f\u6210\u7684HMF\u88ab\u8ba4\u4e3a\u662f\u4ece\u751f\u7269\u8d28\u4e2d\u5f97\u5230\u7684\u6700\u91cd\u8981\u7684\u5e73\u53f0\u5316\u5408\u7269\u4e4b\u4e00\u3002\u5176\u4e2d\uff0cHMF\u9009\u62e9\u6027\u6c27\u5316\u662f\u4e00\u7c7b\u91cd\u8981\u7684\u53cd\u5e94\uff0c\u6587\u7ae0\u5bf9\u5176\u76f8\u5173\u53cd\u5e94\u8fdb\u884c\u4e86\u8bba\u8ff0\uff1a\uff081\uff09<span style=\"color: #000000;\">HMF\u4e2d\u7532\u9170\u57fa\u9009\u62e9\u6027\u6c27\u5316\u4e3aHFCA\u548cFFCA\uff1b\uff082\uff09\u7528O<sub>2<\/sub>\u9009\u62e9\u6027\u6c27\u5316HMF\u81f3DFF\uff1b\uff083\uff09TEMPO\u5bf9HMF\u6c27\u5316\u6210DFF\u7684\u8c03\u8282\uff1b\uff084\uff09\u8d35\u91d1\u5c5e\u50ac\u5316\u5242\u4e2dHMF\u50ac\u5316\u6c27\u5316FDCA\uff1b\uff085\uff09\u4f7f\u7528t-BuOOH\u548cH<sub>2<\/sub>O<sub>2<\/sub>\u4f5c\u4e3a\u6c27\u5316\u5242\u5c06HMF\u50ac\u5316\u6c27\u5316\u6210FDCA\uff1b\uff086\uff09\u7535\u50ac\u5316\u3001\u5149\u50ac\u5316\u6c27\u5316HMF\u7b49\u3002<\/span><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-120662 aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/01\/6-4.jpg\" alt=\"\" width=\"600\" height=\"126\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/01\/6-4.jpg 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2018\/01\/6-4-300x63.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p style=\"text-align: center;\"><strong>\u56fe5. HMF\u548c\u78b3\u6c34\u5316\u5408\u7269\u5408\u6210\u544b\u5583\u7c7b\u5316\u5408\u7269<\/strong><\/p>\n<p>\u603b\u7684\u6765\u8bf4\uff0cHMF\u6c27\u5316\u6210DFF\u4e3b\u8981\u5728\u8fc7\u6e21\u91d1\u5c5e\uff08V\u3001Mn\u6216Ru\uff09\u4f5c\u50ac\u5316\u5242\u7684\u65e0\u78b1\u6709\u673a\u6eb6\u5242\u4e2d\u8fdb\u884c\u3002 \u9492\u50ac\u5316\u5242\u5728DFF\u9009\u62e9\u6027\u548c\u50ac\u5316\u5242\u7a33\u5b9a\u6027\u65b9\u9762\u8868\u73b0\u51fa\u8f83\u4f4e\u7684\u50ac\u5316\u6d3b\u6027\uff0c\u800cO MS-2\uff08KMn<sub>8<\/sub>O<sub>16<\/sub>\u00b7nH<sub>2<\/sub>O\uff09\u50ac\u5316\u5242\u5177\u6709\u8f83\u9ad8\u7684\u5c06HMF\u6c27\u5316\u4e3aDFF\u7684\u6d3b\u6027\u548c\u7a33\u5b9a\u6027\u3002HMF\u6c27\u5316\u6210FDCA\u4e3b\u8981\u5728\u8d1f\u8f7d\u8d35\u91d1\u5c5e\u7684\u50ac\u5316\u5242\uff08Pt\uff0cPd\u548cAu\uff09\u4e14\u78b1\u8fc7\u91cf\u7684\u6c34\u4e2d\u8fdb\u884c\u3002 Au\u50ac\u5316\u5242\u5728HMF\u6709\u6c27\u6c27\u5316\u6210FDCA\u4e2d\u6bd4Pt\u548cPd\u50ac\u5316\u5242\u5177\u6709\u66f4\u9ad8\u7684\u9009\u62e9\u6027\u548c\u7a33\u5b9a\u6027\u3002<\/p>\n<p>\u4f5c\u8005\u5bf9\u90e8\u5206\u5546\u7528\u5316\u5b66\u54c1\u7684\u5e02\u573a\u8fdb\u884c\u5206\u6790\u540e\u53d1\u73b0\uff0c\u5e38\u7528\u7684\u7532\u9178\u3001\u4e59\u9178\u7b49\u7531\u4e8e\u6765\u6e90\u5e7f\u6cdb\uff0c\u6240\u4ee5\u5546\u54c1\u5df2\u5927\u91cf\u751f\u4ea7\uff0c\u5e76\u4e14\u4ef7\u683c\u4f4e\u5ec9\uff1b\u7136\u800c\uff0c\u4e59\u9187\u9178\u30012,5-\u544b\u5583\u4e8c\u7532\u9178 (FDCA)\u7b49\uff0c\u4e00\u65b9\u9762\u7531\u4e8e\u751f\u4ea7\u5de5\u827a\u82db\u523b\u3001\u4e0d\u6210\u719f\uff0c\u53e6\u4e00\u65b9\u9762\u7531\u4e8e\u5176\u53ef\u4ee5\u66ff\u4ee3\u77f3\u6cb9\u884d\u751f\u7269\u751f\u4ea7\u5851\u6599\uff0c\u6a61\u80f6\u7b49\u5316\u5de5\u4ea7\u54c1\uff0c\u5e02\u573a\u9700\u6c42\u91cf\u5de8\u5927\uff0c\u6240\u4ee5\u4ef7\u683c\u6602\u8d35\u3002\u56e0\u6b64\uff0c\u5f20\u6cfd\u4f1a\u6559\u6388\u8bfe\u9898\u7ec4\u5728\u6b64\u524d\u7684\u4e00\u7cfb\u5217\u7814\u7a76\u4e2d\u53d1\u5c55\u4e86\u70ed\u3001\u5149\u50ac\u5316\u4f53\u7cfb\u5bf9\u6728\u8d28\u7d20\u3001\u679c\u7cd6\u3001HMF\u7b49\u8fdb\u884c\u9009\u62e9\u6027\u8f6c\u5316\uff0c\u8be5\u6210\u679c\u53d1\u73b0\u5229\u7528\u8868\u9762\u6742\u5316\u6280\u672f\u53ef\u4ee5\u5b9e\u73b0\u5c06\u542b\u786b\u6c2e\u6742\u91d1\u5c5e\u535f\u5549\u4e0e\u6c2e\u5316\u78b3\u5f62\u6210\u914d\u4f4d\u952e\u8fdb\u884c\u6709\u6548\u8d1f\u8f7d\uff0c\u8fdb\u800c\u80fd\u591f\u5728\u5e38\u6e29\u3001\u5e38\u538b\u4e0b\u5c06\u751f\u7269\u8d28\u884d\u751f\u72695-\u7f9f\u7532\u57fa\u7ce0\u919b\uff08HMF\uff09\u9ad8\u6548\u8f6c\u5316\u4e3a\u5e7f\u6cdb\u5e94\u7528\u4e8e\u5851\u6599\u3001\u6a61\u80f6\u3001\u533b\u836f\u5de5\u4e1a\u7684\u5927\u5b97\u5316\u5b66\u5de5\u4e1a\u4ea7\u54c12\uff0c5-\u544b\u5583\u4e8c\u7532\u9178(FDCA)\uff0c\u5e76\u5229\u7528\u591a\u79cd\u68c0\u6d4b\u624b\u6bb5\u9996\u6b21\u8bc1\u5b9e\u5355\u7ebf\u6001\u6c27\u6d3b\u6027\u7269\u79cd\u5bf9\u9187\u7c7b\u7269\u8d28\u7684\u4eff\u751f\u50ac\u5316\u5177\u6709\u8f83\u597d\u7684\u9009\u62e9\u6027\u3002\u76f8\u5173\u7814\u7a76\u53d1\u8868\u5728\u4e8617\u5e749\u670828\u65e5\u51fa\u7248\u7684\u7684JACS\u4e0a\uff08\u8be6\u89c1<a href=\"http:\/\/pubs.acs.org\/doi\/10.1021\/jacs.7b08861\" target=\"_blank\" rel=\"noopener\">Selective oxidation of 5-hydroxymethylfurfural to 2,5-furandicarboxylic acid using O<sub>2<\/sub> and a photocatalyst of Co-thioporphyrazine bonded to g-C<sub>3<\/sub>N<sub>4<\/sub><\/a>\uff09<\/p>\n<p style=\"text-align: center;\"><strong>\u88681. \u78b3\u6c34\u5316\u5408\u7269\u6c27\u5316\u4ea7\u751f\u7684\u5546\u7528\u5316\u5b66\u54c1\u7684\u5e02\u573a\u9700\u6c42\u91cf\u548c\u5e94\u7528\u3002<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-120663 aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/01\/7-4.jpg\" alt=\"\" width=\"600\" height=\"360\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/01\/7-4.jpg 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2018\/01\/7-4-300x180.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>\u5728\u5316\u77f3\u8d44\u6e90\u65e5\u76ca\u67af\u7aed\u7684\u80cc\u666f\u4e0b\uff0c\u53d1\u5c55\u53ef\u518d\u751f\u8d44\u6e90\u83b7\u53d6\u5316\u5b66\u54c1\u548c\u71c3\u6599\u5206\u5b50\u7684\u9700\u6c42\u5c24\u4e3a\u8feb\u5207\u3002\u751f\u7269\u8d28\u8d44\u6e90\u662f\u552f\u4e00\u542b\u78b3\u7684\u7269\u8d28\u6027\u53ef\u518d\u751f\u8d44\u6e90\uff0c\u50ac\u5316\u751f\u7269\u8d28\u8f6c\u5316\u53ef\u4ee5\u83b7\u53d6\u591a\u79cd\u91cd\u8981\u5316\u5b66\u54c1\u3002\u8fd1\u5e74\u6765\uff0c\u5f20\u6cfd\u4f1a\u6559\u6388\u5728\u751f\u7269\u8d28\u50ac\u5316\u8f6c\u5316\u9886\u57df\u53d6\u5f97\u4e86\u8f83\u4e3a\u7a81\u51fa\u6210\u679c\uff0c\u4ee5\u901a\u8baf\u4f5c\u8005\u5728JACS\uff0c ACS Catal.\uff0c Appl. Catal. B-Envrion.\uff0cJ. Catal., Green Chem.\uff0cChemSusChem\uff0cJ. Mater.Chem. A \u7b49\u671f\u520a\u53d1\u8868SCI\u4e00\u533a\u8bba\u6587\u8fd130\u7bc7\u3002\u5f20\u6cfd\u4f1a\u6559\u6388\u7684\u7814\u7a76\u5de5\u4f5c\u53d7\u5230\u4e86\u56fd\u5185\u5916\u540c\u884c\u4e13\u5bb6\u7684\u8ba4\u53ef\uff0c\u76ee\u524d\u6240\u53d1\u8868\u8bba\u6587\u4ed6\u5f15\u6b21\u6570\u8fd12300\u6b21\uff0cH\u6307\u657029\uff0c\u5176\u4e2d1\u7bc7\u901a\u8baf\u4f5c\u8005\u8bba\u6587\u5165\u90092013\u5e74\u5ea6\u4e2d\u56fd\u767e\u7bc7\u6700\u5177\u56fd\u9645\u5f71\u54cd\u5b66\u672f\u8bba\u6587\uff0c8\u7bc7\u901a\u8baf\u4f5c\u8005\u8bba\u6587\u5165\u9009\u7f8e\u56fd\u79d1\u6280\u4fe1\u606f\u6240\u57fa\u672c\u79d1\u5b66\u6307\u6807\u6570\u636e\u5e93\uff08ESI\uff09\u9ad8\u88ab\u5f15\u7528\u8bba\u6587\u3002<\/p>\n<p><strong>\u5168\u6587\u94fe\u63a5\uff1a<a href=\"http:\/\/pubs.rsc.org\/en\/content\/articlelanding\/2018\/cs\/c7cs00213k#!divAbstract\" target=\"_blank\" rel=\"noopener\">Catalytic oxidation of carbohydrates into organic acids and furan chemicals<\/a><\/strong>\u00a0\uff08Chem. Soc. Rev.\uff0c2017\uff0cDOI: 10.1039\/C7CS00213K\uff09<\/p>\n<p>\u300aChemical Society Reviews\u300b\u662f\u82f1\u56fd\u7687\u5bb6\u5316\u5b66\u5b66\u4f1a\u65d7\u4e0b\u7684\u9876\u7ea7\u7efc\u8ff0\u6027\u671f\u520a\uff0c\u6742\u5fd7\u521b\u520a\u4e8e1972\u5e74\uff0c\u5728\u5316\u5b66\u53ca\u76f8\u5173\u9886\u57df\u4e2d\u6709\u7740\u76f8\u5f53\u9ad8\u7684\u5b66\u672f\u5f71\u54cd\u529b\uff0c\u662f\u5316\u5b66\u9886\u57df\u6700\u5177\u6743\u5a01\u7684\u4e09\u5927\u9876\u7ea7\u7efc\u8ff0\u6027\u671f\u520a\u4e4b\u4e00\uff0c2016-2017\u6700\u65b0SCI\u5f71\u54cd\u56e0\u5b50\u4e3a38.618\u3002<\/p>\n<p>\u672c\u6587\u7531\u5f20\u6cfd\u4f1a\u6559\u6388\u8bfe\u9898\u7ec4\u4f9b\u7a3f\uff0c\u6750\u6599\u725b\u6574\u7406\u7f16\u8f91\u3002<\/p>\n<p>\u6750\u6599\u725b\u7f51\u4e13\u6ce8\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u53ca\u884c\u4e1a\u8fdb\u5c55\uff0c\u8fd9\u91cc\u6c47\u96c6\u4e86\u5404\u5927\u9ad8\u6821\u7855\u535a\u751f\u3001\u4e00\u7ebf\u79d1\u7814\u4eba\u5458\u4ee5\u53ca\u884c\u4e1a\u4ece\u4e1a\u8005\uff0c\u5982\u679c\u60a8\u5bf9\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u8fdb\u5c55\uff0c\u89e3\u8bfb\u9ad8\u6c34\u5e73\u6587\u7ae0\u6216\u662f\u8bc4\u8ff0\u884c\u4e1a\u6709\u5174\u8da3\uff0c<a href=\"\/\/m.iemloyee.com\/25127.html\" target=\"_blank\" rel=\"noopener\">\u70b9\u6211\u52a0\u5165\u7f16\u8f91\u90e8\u5927\u5bb6\u5ead<\/a>\u3002<\/p>\n<p>\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1tougao@cailiaoren.com\u3002<\/p>\n<p>\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1aRDD-2011-CHERISH\uff0c\u4efb\u4e39\u4e39\uff0c\u6211\u4eec\u4f1a\u9080\u8bf7\u5404\u4f4d\u8001\u5e08\u52a0\u5165\u4e13\u5bb6\u7fa4\u3002<\/p>\n<p>\u6750\u6599\u6d4b\u8bd5\u3001\u6570\u636e\u5206\u6790\uff0c\u4e0a<a href=\"http:\/\/www.ceshigu.com\/\" target=\"_blank\" rel=\"noopener\">\u6d4b\u8bd5\u8c37<\/a>\uff01<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u5728\u5316\u77f3\u8d44\u6e90\u65e5\u76ca\u67af\u7aed\u548c\u73af\u5883\u6c61\u67d3\u4e24\u5927\u4e16\u754c\u96be\u9898\u9762\u524d\uff0c\u5f00\u53d1\u65b0\u578b\u53ef\u6301\u7eed\u7684\u6e05\u6d01\u80fd\u6e90\u663e\u5f97\u5c24\u4e3a\u91cd\u8981\uff1b\u5728\u6b64\u5927\u80cc\u666f\u4e0b\uff0c\u89e3\u51b3\u65b9\u6cd5\u4e4b\u4e00\u5c31\u662f\u53d1\u5c55\u53ef\u518d\u751f\u751f\u7269\u8d28\u8d44\u6e90\u4ee3\u66ff\u4e0d\u53ef\u518d\u751f\u7684\u5316\u77f3\u8d44\u6e90\uff0c\u7528&#8230;<\/p>\n","protected":false},"author":1369,"featured_media":120657,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[533],"tags":[2704,2703,2702,2701],"class_list":["post-120655","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-zongshu","tag-2704","tag-2703","tag-2702","tag-2701"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/120655"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/1369"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=120655"}],"version-history":[{"count":8,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/120655\/revisions"}],"predecessor-version":[{"id":121093,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/120655\/revisions\/121093"}],"wp:featuredmedia":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/media\/120657"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=120655"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=120655"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=120655"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}