{"id":120586,"date":"2018-01-16T14:00:33","date_gmt":"2018-01-16T06:00:33","guid":{"rendered":"\/\/m.iemloyee.com\/?p=120586"},"modified":"2018-01-16T10:17:39","modified_gmt":"2018-01-16T02:17:39","slug":"%e5%8c%97%e4%ba%ac%e5%8c%96%e5%b7%a5%e5%a4%a7%e5%ad%a6%e7%8e%8b%e5%b3%b0energy-storage-materials%ef%bc%9a%e5%85%bc%e5%85%b7%e7%94%b5%e6%b1%a0-%e7%94%b5%e5%ae%b9%e5%82%a8%e8%83%bd%e7%89%b9%e7%82%b9","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=120586","title":{"rendered":"\u5317\u4eac\u5316\u5de5\u5927\u5b66\u738b\u5cf0Energy Storage Materials\uff1a\u517c\u5177\u7535\u6c60-\u7535\u5bb9\u50a8\u80fd\u7279\u70b9\u7684\u9502\u79bb\u5b50\u7535\u5bb9\u5668\u591a\u5b54\u70ad\u7535\u6781\u6750\u6599"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/b><\/strong><\/p>\n

\u9502\u79bb\u5b50\u7535\u5bb9\u5668\uff08LICs\uff09\u4f5c\u4e3a\u4e00\u79cd\u6df7\u5408\u578b\u50a8\u80fd\u5668\u4ef6\uff0c\u517c\u5177\u4e86\u9502\u79bb\u5b50\u7535\u6c60\u548c\u8d85\u7ea7\u7535\u5bb9\u5668\u7684\u50a8\u80fd\u7279\u70b9\u3002LICs\u7684\u8d1f\u6781\u6750\u6599\u4e3a\u5177\u6709\u9502\u79bb\u5b50\u7535\u6c60\u50a8\u80fd\u7279\u70b9\u7684\u7535\u6781\u6750\u6599\uff0c\u901a\u8fc7\u8868\u9762\u7684\u7535\u8377\u8f6c\u79fb\u8fc7\u7a0b\u548c\u9502\u79bb\u5b50\u7684\u5d4c\u5165\/\u8131\u51fa\u8fc7\u7a0b\u4e3aLICs\u63d0\u4f9b\u8f83\u9ad8\u7684\u80fd\u91cf\u5bc6\u5ea6\u3002\u800cLICs\u7684\u6b63\u6781\u6750\u6599\u4e3a\u5177\u6709\u8d85\u7ea7\u7535\u5bb9\u5668\u50a8\u80fd\u7279\u70b9\u7684\u7535\u6781\u6750\u6599\uff0c\u901a\u8fc7\u53cc\u7535\u5c42\u7535\u5bb9\u6216\u8d5d\u7535\u5bb9\u7684\u50a8\u80fd\u5f62\u5f0f\u4e3aLICs\u63d0\u4f9b\u8f83\u9ad8\u7684\u529f\u7387\u5bc6\u5ea6\u4ee5\u53ca\u8f83\u957f\u7684\u5faa\u73af\u5bff\u547d\u3002\u7136\u800c\uff0c\u76ee\u524d\u62a5\u9053\u7684LICs\u8d1f\u6781\u6750\u6599\uff08\u5982\u77f3\u58a8\u3001\u7845\u3001\u8fc7\u6e21\u91d1\u5c5e\u5316\u5408\u7269\u7b49\uff09\u4ecd\u9762\u4e34\u7740\u53ef\u9006\u5bb9\u91cf\u4f4e\u3001\u500d\u7387\u6027\u80fd\u5dee\u6216\u5faa\u73af\u5bff\u547d\u77ed\u7b49\u95ee\u9898\u3002\u5c3d\u7ba1\u901a\u8fc7\u5f15\u5165\u4ecb\u5b54\u901a\u9053\u6216\u8bbe\u8ba1\u590d\u5408\u7ed3\u6784\u53ef\u63d0\u9ad8\u6750\u6599\u7684\u50a8\u9502\u6027\u80fd\uff0c\u4f46\u8fd9\u4e9b\u65b9\u6cd5\u4f1a\u5927\u5927\u63d0\u9ad8\u6750\u6599\u5408\u6210\u96be\u5ea6\u53ca\u6210\u672c\uff0c\u9650\u5236\u5176\u5b9e\u9645\u5e94\u7528\u3002\u53e6\u4e00\u65b9\u9762\uff0c\u4f5c\u4e3aLICs\u6b63\u6781\u6750\u6599\u7684\u6d3b\u6027\u70ad\u867d\u5177\u6709\u5f88\u9ad8\u7684\u6bd4\u8868\u9762\u79ef\uff0c\u4f46\u662f\u5176\u6bd4\u8868\u9762\u79ef\u5927\u90e8\u5206\u6765\u81ea\u4e8e\u5b54\u9053\u534a\u5c01\u95ed\u3001\u65e0\u89c4\u5219\u7684\u5fae\u5b54\u3002\u5728\u5feb\u901f\u7684\u5145\u653e\u7535\u8fc7\u7a0b\u4e2d\uff0c\u5f88\u96be\u5145\u5206\u5229\u7528\u8fd9\u4e9b\u5fae\u5b54\u6bd4\u8868\u9762\u8fdb\u884c\u7535\u8377\u50a8\u5b58\u3002\u5c24\u5176\u662f\u5728\u5177\u6709\u8f83\u5927\u79bb\u5b50\u5c3a\u5bf8\u7684\u6709\u673a\u7535\u89e3\u8d28\u4f53\u7cfb\u4e2d\uff0c\u6d3b\u6027\u70ad\u8868\u73b0\u51fa\u4e86\u8f83\u5dee\u7684\u80fd\u91cf\u548c\u529f\u7387\u8f93\u51fa\u3002\u6b63\u8d1f\u6781\u6750\u6599\u7684\u8bf8\u591a\u95ee\u9898\uff0c\u9650\u5236\u4e86\u9502\u79bb\u5b50\u7535\u5bb9\u5668\u7684\u6027\u80fd\u63d0\u9ad8\u548c\u5b9e\u9645\u5e94\u7528\u3002\u56e0\u6b64\uff0c\u4ecd\u9700\u5bfb\u6c42\u4f4e\u6210\u672c\u3001\u9ad8\u6027\u80fd\u7684\u65b0\u578b\u9502\u79bb\u5b50\u7535\u5bb9\u5668\u7535\u6781\u6750\u6599\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/b><\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u5317\u4eac\u5316\u5de5\u5927\u5b66\u738b\u5cf0\u6559\u6388<\/b><\/strong>\u5e26\u9886\u7684\u56e2\u961f\u63d0\u51fa\u4e00\u79cd\u5236\u5907\u4f4e\u6210\u672c\u3001\u9ad8\u6027\u80fd\u9502\u79bb\u5b50\u7535\u5bb9\u5668\u7535\u6781\u6750\u6599\u7684\u65b0\u7b56\u7565\u3002\u5728\u8be5\u5de5\u4f5c\u4e2d\uff0c\u7814\u7a76\u4eba\u5458\u4ee5\u4f4e\u6210\u672c\u7684\u751f\u7269\u8d28\u5e9f\u5f03\u7269\u7f8a\u9aa8\u4e3a\u524d\u9a71\u4f53\uff0c\u5728\u65e0\u4efb\u4f55\u5916\u52a0\u6d3b\u5316\u5242\u53ca\u6a21\u677f\u7684\u6761\u4ef6\u4e0b\uff0c\u901a\u8fc7\u7b80\u5355\u7684\u70ed\u5904\u7406\u76f4\u63a5\u5f97\u5230\u5177\u6709\u9ad8\u7f3a\u9677\u5bc6\u5ea6\u7684\u4ecb\u5b54\u70ad\u6750\u6599\uff08HDMPC\uff09\u3002\u7814\u7a76\u53d1\u73b0\uff0c\u7f8a\u9aa8\u4e2d\u7684\u7f9f\u57fa\u78f7\u7070\u77f3\u5728\u70ed\u89e3\u8fc7\u7a0b\u4e2d\u9010\u6b65\u91ca\u653e\u51fa\u6c34\u84b8\u6c14\u548c\u4e8c\u6c27\u5316\u78b3\uff0c\u8fdb\u800c\u5bf9\u80f6\u539f\u57fa\u70ad\u6750\u6599\u8fdb\u884c\u539f\u4f4d\u6d3b\u5316\uff0c\u5f97\u5230\u4e86\u5177\u6709\u6bd4\u8868\u9762\u79ef\u9ad8\u3001\u672c\u5f81\u7f3a\u9677\u53ca\u6742\u539f\u5b50\u8bf1\u5bfc\u7f3a\u9677\u4e30\u5bcc\u7684\u4ecb\u5b54\u70ad\u6750\u6599\u3002\u4e30\u5bcc\u7684\u7f3a\u9677\u548c\u72ec\u7279\u7684\u5b54\u7ed3\u6784\u8d4b\u4e88\u4e86HDMPC\u7535\u5bb9\u548c\u7535\u6c60\u7684\u50a8\u80fd\u7279\u5f81\u3002\u5728\u534a\u7535\u6c60\u6d4b\u8bd5\u4e2d\uff0cHDMPC\u4f5c\u4e3a\u6b63\u6781\u548c\u8d1f\u6781\u6750\u6599\u90fd\u8868\u73b0\u51fa\u4e86\u4f18\u5f02\u7684\u6027\u80fd\u3002\u4ee5HDMPC\u4f5c\u4e3a\u6b63\u8d1f\u6750\u6599\u7684\u9502\u79bb\u5b50\u7535\u5bb9\u5668\u8868\u73b0\u51fa\u4e86\u9ad8\u7684\u80fd\u91cf\u5bc6\u5ea6\uff08106.4 Wh kg-1<\/sup>\uff09\u548c\u529f\u7387\u5bc6\u5ea6\uff0888.8 kW kg-1<\/sup>\uff09\uff0c\u4ee5\u53ca\u4f18\u5f02\u7684\u5faa\u73af\u7a33\u5b9a\u6027\uff08\u5faa\u73af8000\u6b21\u540e\u4ecd\u5177\u670988.3\u00a0%\u7684\u521d\u59cb\u5bb9\u91cf\uff09\u3002\u8be5\u6210\u679c\u4ee5\u9898\u4e3a\u201cPorous carbon electrodes with battery-capacitive storage features for high performance Li-ion capacitors<\/b><\/strong>\u201d\u53d1\u8868\u5728E<\/b><\/strong>nergy<\/b><\/strong>\u00a0S<\/b><\/strong>torage<\/b><\/strong>\u00a0M<\/b><\/strong>aterials<\/b><\/strong>\u4e0a\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/b><\/strong><\/p>\n

\u56fe1.<\/b><\/strong>HDMPC<\/b><\/strong>\u5f62\u8c8c\u7684\u76f8\u5173\u8868\u5f81<\/b><\/strong><\/p>\n

\u00a0\"\"<\/b><\/strong><\/p>\n

HDMPC\u7684(a, b)\u00a0SEM\u548c(c, d) TEM\u5f62\u8c8c\u3002<\/p>\n

\u56fe2.H<\/b><\/strong>DMPC<\/b><\/strong>\u5b54\u7ed3\u6784\u76f8\u5173\u8868\u5f81\u53ca\u5f62\u6210\u673a\u7406\u5206\u6790<\/b><\/strong><\/p>\n

\"\"<\/p>\n

(a) HDMCP\u7684N2<\/sub>\u5438\/\u8131\u9644\u7b49\u6e29\u7ebf\u53caDFT\u5b54\u5f84\u5206\u5e03\u3002\u7f8a\u9aa8\u5728\u6c29\u6c14\u6c14\u6c1b\u4e0b\u7684(b) TGA\u548c(c)\u76f8\u5e94\u7684MS\u66f2\u7ebf\u3002(d)\u7f8a\u9aa8\u5728\u6c29\u6c14\u6c14\u6c1b\u4e2d\u70ed\u89e3\u524d\u540e\u7684FT-IR\u66f2\u7ebf\u3002\u7f8a\u9aa8\u5728\u7a7a\u6c14\u6c14\u6c1b\u4e0b\u7684(e) TGA\u548c(f)\u76f8\u5e94\u7684MS\u66f2\u7ebf\u3002<\/p>\n

\u56fe3.<\/b><\/strong>HDMPC<\/b><\/strong>\u7ed3\u6784\u7684\u76f8\u5173\u8868\u5f81<\/b><\/strong><\/p>\n

\"\"<\/p>\n

(a) XRD\u8c31\u56fe\u3002(b) Raman\u5149\u8c31\u3002\u00a0(c) XPS\u80fd\u8c31\u53ca\u9ad8\u5206\u8fa8\u7684(d) C1s, (e) N1s\u548c(f) O1s\u80fd\u8c31\u3002<\/p>\n

\u56fe4.H<\/b><\/strong>DMPC<\/b><\/strong>\u6b63\u6781\u6750\u6599\u6027\u80fd\u6d4b\u8bd5<\/b><\/strong><\/p>\n

\"\"<\/p>\n

(a)\u4e0d\u540c\u626b\u901f\u4e0b\u7684\u5faa\u73af\u4f0f\u5b89\u6d4b\u8bd5\u3002(b)\u4e0d\u540c\u7535\u6d41\u5bc6\u5ea6\u4e0b\u7684\u6052\u6d41\u5145\u653e\u7535\u6d4b\u8bd5\u3002(c, d)\u5faa\u73af\u6027\u80fd\u6d4b\u8bd5\u3002<\/p>\n

\u56fe5.<\/b><\/strong>\u00a0H<\/b><\/strong>DMPC<\/b><\/strong>\u8d1f\u6781\u6750\u6599\u6027\u80fd\u6d4b\u8bd5<\/b><\/strong><\/p>\n

\"\"<\/p>\n

(a)\u4e0d\u540c\u626b\u901f\u4e0b\u7684\u5faa\u73af\u4f0f\u5b89\u6d4b\u8bd5\u3002(b)\u7535\u5bb9\u548c\u6269\u6563\u63a7\u5236\u8fc7\u7a0b\u5bf9\u5bb9\u91cf\u8d21\u732e\u7684\u8ba1\u7b97\u3002(c, d)\u4e0d\u540c\u7535\u6d41\u5bc6\u5ea6\u4e0b\u7684\u6052\u6d41\u5145\u653e\u7535\u6d4b\u8bd5\u66f2\u7ebf\u548c\u5bb9\u91cf\uff0c(e, f)\u5faa\u73af\u6027\u80fd\u6d4b\u8bd5 (\u6d4b\u8bd5\u524d\u5df2\u9884\u5148\u5bf9HDMPC\u7535\u5316\u5b66\u5d4c\u9502)\u3002<\/p>\n

\u56fe<\/b><\/strong>6<\/b><\/strong>.<\/b><\/strong>\u00a0H<\/b><\/strong>DMPC<\/b><\/strong>|| H<\/b><\/strong>DMPC<\/b><\/strong>\u9502\u79bb\u5b50\u7535\u5bb9\u5668\u6027\u80fd\u6d4b\u8bd5<\/b><\/strong><\/p>\n

\"\"<\/p>\n

(a)\u9502\u79bb\u5b50\u7535\u5bb9\u5668\u653e\u7535\u8fc7\u7a0b\u793a\u610f\u56fe\u3002(b)\u4e0d\u540c\u626b\u901f\u4e0b\u7684\u5faa\u73af\u4f0f\u5b89\u6d4b\u8bd5\u3002 (c)\u4e0d\u540c\u7535\u6d41\u5bc6\u5ea6\u4e0b\u7684\u6052\u6d41\u5145\u653e\u7535\u6d4b\u8bd5\u3002(d)\u9502\u79bb\u5b50\u7535\u5bb9\u5668\u7684Ragone\u66f2\u7ebf\u53ca\u4e0e\u5df2\u62a5\u9053\u7684\u9502\u79bb\u5b50\u7535\u5bb9\u5668\u6027\u80fd\u5bf9\u6bd4\u3002(e)\u9502\u79bb\u5b50\u7535\u5bb9\u5668\u7684\u5faa\u73af\u6027\u80fd\u6d4b\u8bd5\u3002<\/p>\n

\u3010\u7ed3\u8bba\u3011<\/b><\/strong><\/p>\n

\u7814\u7a76\u4eba\u5458\u4ee5\u4f4e\u6210\u672c\u7684\u751f\u7269\u8d28\u5e9f\u5f03\u7269\u7f8a\u9aa8\u4e3a\u524d\u9a71\u4f53\uff0c\u901a\u8fc7\u76f4\u63a5\u70ed\u89e3\u6cd5\u5236\u5907\u5f97\u5230\u4e86\u9ad8\u7f3a\u9677\u7684\u4ecb\u5b54\u70ad\u6750\u6599\u3002\u4e30\u5bcc\u7684\u7f3a\u9677\u53ca\u72ec\u7279\u7684\u5b54\u7ed3\u6784\u4f7f\u5f97\u8be5\u6750\u6599\u517c\u5177\u7535\u6c60-\u7535\u5bb9\u7684\u50a8\u80fd\u7279\u70b9\uff0c\u65e0\u8bba\u4f5c\u4e3a\u6b63\u6781\u548c\u8d1f\u6781\u6750\u6599\u90fd\u8868\u73b0\u51fa\u4e86\u4f18\u5f02\u7684\u6027\u80fd\u3002\u4ee5\u8be5\u6750\u6599\u4f5c\u4e3a\u6b63\u8d1f\u6781\u7684\u9502\u79bb\u5b50\u7535\u5bb9\u5668\u5177\u6709\u9ad8\u7684\u80fd\u91cf\u5bc6\u5ea6\u548c\u529f\u7387\u5bc6\u5ea6\uff0c\u4ee5\u53ca\u4f18\u5f02\u7684\u5faa\u73af\u7a33\u5b9a\u6027\u3002\u8be5\u5de5\u4f5c\u4e0d\u4ec5\u4e3a\u591a\u5b54\u70ad\u6750\u6599\u7684\u5236\u5907\u63d0\u4f9b\u4e86\u4e00\u79cd\u4f4e\u6210\u672c\u3001\u7eff\u8272\u9ad8\u6548\u7684\u65b9\u6cd5\uff0c\u4e5f\u4e3a\u9ad8\u6027\u80fd\u9502\u79bb\u5b50\u7535\u5bb9\u5668\u7684\u7ec4\u88c5\u8bbe\u8ba1\u63d0\u4f9b\u4e86\u65b0\u601d\u8def\u3002<\/p>\n

\u3010\u6587\u732e\u4fe1\u606f\u3011<\/b><\/strong><\/p>\n

\u6587\u732e\u94fe\u63a5\uff1aPorous carbon electrodes with battery-capacitive storage features for high performance Li-ion capacitors<\/u><\/a>\u00a0<\/b><\/strong>(Energy Storage Materials, 2018, DOI\uff1a10.1016\/j.ensm.2017.12.012)<\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u7f16\u8f91\u90e8\u65b0\u80fd\u6e90\u7ec4\u725b\u8d8a\u4f9b\u7a3f\uff0c\u70b9\u6211\u52a0\u5165\u6750\u6599\u4eba\u7f16\u8f91\u90e8<\/u><\/a>\u3002<\/p>\n

\u6750\u6599\u6d4b\u8bd5\uff0c\u6570\u636e\u5206\u6790\uff0c\u4e0a<\/b><\/strong>\u6d4b\u8bd5\u8c37<\/b><\/u><\/strong><\/a>\uff01<\/b><\/strong><\/p>\n","protected":false},"excerpt":{"rendered":"

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