{"id":120559,"date":"2018-01-10T14:00:54","date_gmt":"2018-01-10T06:00:54","guid":{"rendered":"\/\/m.iemloyee.com\/?p=120559"},"modified":"2018-01-09T17:52:19","modified_gmt":"2018-01-09T09:52:19","slug":"energy-environ-sci-%e5%85%a8%e5%b0%8f%e5%88%86%e5%ad%90%e5%a4%aa%e9%98%b3%e8%83%bd%e7%94%b5%e6%b1%a0%e7%9a%84%e5%8a%a8%e5%8a%9b%e5%ad%a6%e7%a0%94%e7%a9%b6","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=120559","title":{"rendered":"Energy Environ. Sci.: \u5168\u5c0f\u5206\u5b50\u592a\u9633\u80fd\u7535\u6c60\u7684\u52a8\u529b\u5b66\u7814\u7a76"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n

\u8fd1\u671f\u4ee5\u6765\uff0c\u53ef\u6eb6\u5168\u5c0f\u5206\u5b50\u6709\u673a\u592a\u9633\u80fd\u7535\u6c60\uff08OSC\uff09\u5728\u63d0\u9ad8\u5668\u4ef6\u7a33\u5b9a\u6027\u548c\u5149\u7535\u6548\u7387\u65b9\u9762\u5df2\u7ecf\u53d6\u5f97\u4e86\u663e\u8457\u8fdb\u5c55\u3002\u7136\u800c\uff0c\u76ee\u524d\u5bf9\u8fd9\u7c7b\u6750\u6599\u5149\u81f4\u52a8\u529b\u5b66\u7684\u4e86\u89e3\u975e\u5e38\u6709\u9650\uff0c\u4e3a\u4e86\u80fd\u5145\u5206\u5229\u7528\u5c0f\u5206\u5b50\u5316\u5b66\u672c\u8eab\u7684\u8bbe\u8ba1\u4f18\u52bf\uff0c\u8be6\u7ec6\u4e86\u89e3\u6fc0\u5b50\u89e3\u79bb\u7684\u52a8\u529b\u5b66\u4ee5\u53ca\u7ade\u4e89\u8fc7\u7a0b\u7684\u901f\u7387\u548c\u4ea7\u7387\u662f\u6781\u6709\u5fc5\u8981\u7684\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u00a0<\/strong>\u6700\u8fd1\uff0c\u897f\u73ed\u7259\u9a6c\u5fb7\u91cc\u9ad8\u7ea7\u7814\u7a76\u9662<\/strong>Larry L\u00fcer<\/strong>\u7b49\u4e0e\u5fb7\u56fd\u56fe\u5bbe\u6839\u5927\u5b66\u548c\u9996\u5c14\u56fd\u7acb\u5927\u5b66\u7684\u7814\u7a76\u4eba\u5458<\/strong>\u5229\u7528\u5b9e\u9a8c\u4e0e\u8ba1\u7b97\u76f8\u7ed3\u5408\u7684\u65b9\u6cd5\u7814\u7a76\u4e86\u4e00\u4e2a\u5178\u578b\u7684\u5168\u5c0f\u5206\u5b50\u7684\u3001\u7531p-DTS(FBTTh2<\/sub>)2<\/sub>\u4f5c\u7ed9\u4f53\u3001NIDCS-MO\u4f5c\u53d7\u4f53\u7684\u5171\u6df7\u7269\u7684\u5149\u81f4\u6fc0\u53d1\u52a8\u529b\u5b66\u3002\u8be5\u7814\u7a76\u53d1\u8868\u4e8eEnergy & Environmental Science<\/strong>\uff0c\u9898\u4e3a\u201cDesigning high performance all-small-molecule solar cells with non-fullerene acceptors: comprehensive studies on photoexcitation dynamics and charge separation kinetics<\/strong>\u201d\u3002\u8be5\u7814\u7a76\u7ed3\u679c\u8bc1\u660e\u4e86\u4f53\u7cfb\u4e2d\u53d1\u73b0\u4e86\u9ad8\u7684\u5185\u91cf\u5b50\u4ea7\u7387\u548c\u5f00\u8def\u7535\u538b\uff0c\u9884\u6d4b\u901a\u8fc7\u964d\u4f4e\u7ed9\u4f53\u548c\u53d7\u4f53\u95f4\u7684\u7535\u5b50\u8026\u5408\u53ef\u4ee5\u5b9e\u73b0\u9ad8\u6548\u7a33\u5b9a\u7684\u4f4e\u5149\u5b66\u5e26\u9699\uff1b\u540c\u65f6\u9610\u8ff0\u4e86\u4f5c\u4e3a\u805a\u5408\u7269OSC\u4e2d\u7684\u5173\u952e\u56e0\u7d20\u7684\u79bb\u57df\u6001\u4e0e\u6fc0\u5b50\u6269\u6563\u7684\u4f5c\u7528\uff0c\u91cf\u5316\u4e86\u4e3b\u8981\u635f\u8017\u901a\u9053\u4e0e\u52a0\u5de5\u6761\u4ef6\u7684\u51fd\u6570\u5173\u7cfb\u3002<\/p>\n

\u00a0<\/strong>\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n

\u00a0<\/strong>\u56fe<\/strong>1. <\/strong>\u5316\u5b66\u7ed3\u6784\u548c\u524d\u7ebf\u5206\u5b50\u8f68\u9053\u4e0e\u5149\u8c31\u4fe1\u606f<\/strong><\/p>\n

\"\"<\/p>\n

\uff08a\uff09p-DTS(FBTTh2<\/sub>)2<\/sub>\u548cNIDCS-MO\u7684\u5316\u5b66\u7ed3\u6784\u4ee5\u53caDFT\u4f18\u5316\u7ed3\u6784\u7684\u524d\u7ebf\u5206\u5b50\u8f68\u9053\uff1b<\/p>\n

\uff08b\uff09\u6837\u54c1\u7684\u5438\u6536\u5149\u8c31\u4e0ePL\u5149\u8c31\uff1b<\/p>\n

\u9876\u56fe\u548c\u4e2d\u56fe\uff1a\u5728\u6eb6\u6db2\uff08\u6c2f\u4eff;\u865a\u7ebf\u8868\u793a\uff09\u548c\u94f8\u6001\u65cb\u6d82\u8584\u819c\uff08\u5b9e\u7ebf\uff09\u4e2d\u7684\u7eafp-DTS(FBTTh2<\/sub>)2<\/sub>\uff08\u9876\u56fe\uff09\u548cNIDCS-MO\uff08\u4e2d\u56fe\uff09\u5438\u6536\u8c31\uff08\u84dd\u8272\uff09\u548cPL\u5149\u8c31\uff08\u7ea2\u8272\uff09\uff08\u9ed1\u8272\u865a\u7ebf\u4e3a\u8584\u819c\u9000\u706b\u7684PL\u5149\u8c31\uff09\uff1b<\/p>\n

\u5e95\u56fe\uff1a\u9000\u706b\u524d\u540e\u7684\u5171\u6df7\u819c; \u54c1\u7ea2\u8272\u4e3a\u94f8\u6001\u7684\u5438\u6536\u8c31\uff0c\u7eff\u8272\u4e3a\u9000\u706b\u7684\u5438\u6536\u8c31\uff0c\u7ea2\u8272\u4e3aPL\u5149\u8c31\u3002<\/p>\n

\u56fe<\/strong>2. <\/strong>\u5171\u6df7\u8584\u819c\u4e0e\u5355\u4e00\u7ec4\u5206\u8584\u819c\u7684\u5438\u6536\u5149\u8c31<\/strong><\/p>\n

\"\"<\/p>\n

\uff08a\uff09p-DTS(FBTTh2<\/sub>)2<\/sub>\uff08\u4ee5D\u8868\u793a\uff09\u4e0eNIDCS-MO \uff08\u4ee5A\u8868\u793a\uff091:1\u6bd4\u4f8b\u5171\u6df7\u7684\u8584\u819c\u5438\u6536\u5149\u8c31\uff0c\u54c1\u7ea2\u8272\u4ee3\u8868\u9000\u706b\u524d\uff0c\u7eff\u8272\u4ee3\u8868\u9000\u706b\u540e\uff1b<\/p>\n

\uff08b\uff09\u94f8\u6001D:A\u8584\u819c\u7684\u5438\u6536\u8c31\uff0c\u51cf\u53bb\u7eafA\u819c\u7684\u5149\u8c31\uff0c\u4ee5\u9ed1\u8272\u7684\u865a\u7ebf\u8868\u793a\uff0c\u4e3a\u65b9\u4fbf\u6bd4\u8f83\uff0c\u7eafD\u819c\u4ee5\u84dd\u8272\u5b9e\u7ebf\u8868\u793a\uff1b<\/p>\n

\uff08c\uff09\u9000\u706b\u7684D:A\u819c\u7684\u5438\u6536\u8c31\uff0c\u5176\u4e2d\u51cf\u53bb\u7eafD\u819c\u7684\u5149\u8c31\uff08\u9ed1\u8272\u865a\u7ebf\uff09\uff0c\u7eafA\u819c\u4ee5\u7ea2\u8272\u5b9e\u7ebf\u5bf9\u6bd4\u663e\u793a\u3002<\/p>\n

\u56fe<\/strong>3. <\/strong>\u98de\u79d2<\/strong>TA<\/strong>\u5149\u8c31\u4e0e<\/strong>TA<\/strong>\u52a8\u529b\u5b66<\/strong><\/p>\n

\"\"<\/p>\n

\uff08a\uff09\u5728620nm\u5904\u7eaf\u7ed9\u4f53(D)\u819c\u7684\u98de\u79d2TA\u5149\u8c31\uff1b<\/p>\n

\uff08b\uff09\u5728510nm\u5904\u7eaf\u53d7\u4f53(A)\u819c\u7684\u98de\u79d2TA\u5149\u8c31\uff1b<\/p>\n

\uff08c\uff09\u6570\u503c\u70b9\u4ee3\u8868\u5728\u63a2\u6d4b\u80fd\u91cf\u03c9pr = 1.03 eV\u65f6\uff0c\u7ed9\u51fa\u7684\u6cf5\u80fd\u63a5\u8fd1\u66f2\u7ebf\u65f6\u7684TA\u52a8\u529b\u5b66\uff1b<\/p>\n

\uff08d\uff09\u57281.3 eV\u5904\u63a2\u6d4b\u53d7\u4f53\u8584\u819c\u7684\u7ed3\u679c\u3002<\/p>\n

\u56fe<\/strong>4. <\/strong>\u94f8\u6001\u548c\u9000\u706b\u5171\u6df7\u7269\u7684\u98de\u79d2<\/strong>TA<\/strong>\u5149\u8c31\u4e0e\u52a8\u529b\u5b66<\/strong><\/p>\n

\"\"<\/p>\n

\uff08a\uff09\u548c\uff08b\uff09\u5206\u522b\u4e3a\u94f8\u6001\u7684\u548c\u9000\u706b\u5171\u6df7\u7269\u7684\u98de\u79d2TA\u5149\u8c31\uff1b\u70b9\u4ee3\u8868\u5b9e\u9a8c\u6570\u636e\uff0c\u7ebf\u4ee3\u8868kCT\u4f5c\u4e3a\u552f\u4e00\u7684\u81ea\u7531\u52a8\u529b\u5b66\u53c2\u6570\u60c5\u51b5\u4e0b\u5168\u5c40\u62df\u5408\u7684\u76ee\u6807\u5206\u6790\uff1b<\/p>\n

\uff08c\uff09\u5728\u5b9e\u7ebf\u548c\u865a\u7ebf\u5206\u522b\u4ee3\u8868\u7684\u94f8\u6001\u7684\u548c\u9000\u706b\u5171\u6df7\u7269\u7684\u592a\u9633\u80fd\u5f3a\u5ea6\u4e0b\uff0c\u9ed1\u8272\u548c\u7ea2\u8272\u66f2\u7ebf\u5206\u8868\u4ee3\u8868\u5355\u91cd\u6001\u548c\u7535\u8377\u5206\u79bb\u6001\u7684\u52a8\u529b\u5b66\uff1b<\/p>\n

\u4e0d\u8003\u8651\u53cc\u91cd\u590d\u5408\u7684\u6761\u4ef6\u4e0b\uff0c\u8f7d\u6d41\u5b50\u7684\u8fd1\u4f3c\u503c\u5728\u4e00\u6bb5\u65f6\u95f4\u540e\u8fbe\u5230\u03c6CS<\/sub>\u3002<\/p>\n

\u56fe<\/strong>5. <\/strong>\u7535\u8377\u8f6c\u79fb\u901f\u7387\u3001\u7535\u8377\u91cd\u7ec4\u901f\u7387\u548c\u81ea\u7531\u8f7d\u6d41\u5b50\u4ea7\u7387<\/strong><\/p>\n

\"\"<\/p>\n

\u4f7f\u7528\u6587\u4e2d\u7684\u7b49\u5f0f\u8ba1\u7b97\u7684\u7535\u8377\u8f6c\u79fb\uff08CT\uff09\u901f\u7387\u3001\u7535\u8377\u91cd\u7ec4\uff08CR\uff09\u901f\u7387\u548c\u81ea\u7531\u8f7d\u6d41\u5b50\u4ea7\u7387\u03c6fc<\/sub>\uff1b<\/p>\n

\u53c2\u6570\uff1aEopt<\/sub> = 1.77 eV\uff0c\u03bbv<\/sub>= 0.12 eV\uff0c\u03bce<\/sub>= \u03bch<\/sub>= 10-4<\/sup>cm2<\/sup>V-1<\/sup>s-1<\/sup>\uff0ckq<\/sub>= 1010<\/sup>s-1<\/sup>\uff0cT= 298K\uff0c\u8ba1\u7b97\u7ec6\u8282\u53c2\u89c1ESI \u7684G\u90e8\u5206\u3002<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n

\u8be5\u5de5\u4f5c\u7814\u7a76\u4e86\u53ef\u6eb6\u7684\u5168\u5c0f\u5206\u5b50\u4f53\u5f02\u8d28\u7ed3\u5149\u4f0f\u5171\u6df7\u7684\u539f\u578b\u5b9e\u4f8b\u4e2d\u7684\u5149\u81f4\u6fc0\u53d1\u52a8\u529b\u5b66\uff0c\u7531\u4e8e\u5176\u4e92\u8865\u7684D:A\u5438\u6536\u5149\u8c31\uff0c\u63d0\u4f9b\u4e86\u4e00\u4e2a\u201c\u7406\u60f3\u201d\u4f53\u7cfb\uff0c\u4ece\u800c\u53ef\u4ee5\u72ec\u7acb\u7814\u7a76D-\u6fc0\u53d1\u548cA-\u6fc0\u53d1\u3002\u5728\u534a\u7ecf\u9a8c\u7684Marcus\u7535\u5b50\u4f20\u9012\u7406\u8bba\u4e0b\uff0c\u6b64\u9879\u7814\u7a76\u8bc1\u660e\u4e86\u7ed9\u4f53\u548c\u53d7\u4f53\u90e8\u5206\u95f4\u7684\u5f31\u7535\u5b50\u8026\u5408\u662f\u5728\u5c0f\u5206\u5b50\u4f53\u7cfb\u4e2d\u5b9e\u73b0\u9ad8\u6548\u7535\u8377\u5206\u79bb\u7684\u5173\u952e\u3002\u8fd9\u4e9b\u7ed3\u679c\u4e3a\u53d1\u5c55\u5177\u6709\u8f83\u4f4e\u5149\u5b66\u5e26\u9699\u7684\u5168\u5c0f\u5206\u5b50OSC\u5960\u5b9a\u4e86\u57fa\u7840\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a <\/strong>Designing high performance all-small-molecule solar cells with non-fullerene acceptors: comprehensive studies on photoexcitation dynamics and charge separation kinetics <\/a>(Energy Environ. Sci., 2018, DOI: 10.1039\/C7EE02967E)<\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u8ba1\u7b97\u6750\u6599\u7ec4Annay\u4f9b\u7a3f\uff0c\u6750\u6599\u725b\u6574\u7406\u7f16\u8f91\u3002<\/p>\n

\u6750\u6599\u725b\u7f51\u4e13\u6ce8\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u53ca\u884c\u4e1a\u8fdb\u5c55\uff0c\u8fd9\u91cc\u6c47\u96c6\u4e86\u5404\u5927\u9ad8\u6821\u7855\u535a\u751f\u3001\u4e00\u7ebf\u79d1\u7814\u4eba\u5458\u4ee5\u53ca\u884c\u4e1a\u4ece\u4e1a\u8005\uff0c\u5982\u679c\u60a8\u5bf9\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u8fdb\u5c55\uff0c\u89e3\u8bfb\u9ad8\u6c34\u5e73\u6587\u7ae0\u6216\u662f\u8bc4\u8ff0\u884c\u4e1a\u6709\u5174\u8da3\uff0c\u70b9\u6211\u52a0\u5165\u7f16\u8f91\u90e8\u5927\u5bb6\u5ead<\/a>\u3002<\/p>\n

\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1tougao@cailiaoren.com<\/a>\u3002<\/p>\n

\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1a<\/strong>RDD-2011-CHERISH<\/strong>\uff0c\u4efb\u4e39\u4e39\uff0c\u6211\u4eec\u4f1a\u9080\u8bf7\u5404\u4f4d\u8001\u5e08\u52a0\u5165\u4e13\u5bb6\u7fa4\u3002<\/strong><\/p>\n

\u6750\u6599\u6d4b\u8bd5\u3001\u6570\u636e\u5206\u6790\uff0c\u4e0a<\/strong>\u6d4b\u8bd5\u8c37<\/strong><\/a>\uff01<\/strong><\/p>\n","protected":false},"excerpt":{"rendered":"

\u3010\u5f15\u8a00\u3011 \u8fd1\u671f\u4ee5\u6765\uff0c\u53ef\u6eb6\u5168\u5c0f\u5206\u5b50\u6709\u673a\u592a\u9633\u80fd\u7535\u6c60\uff08OSC\uff09\u5728\u63d0\u9ad8\u5668\u4ef6\u7a33\u5b9a\u6027\u548c\u5149\u7535\u6548\u7387\u65b9\u9762\u5df2\u7ecf\u53d6\u5f97\u4e86\u663e\u8457\u8fdb\u5c55\u3002\u7136\u800c\uff0c\u76ee\u524d\u5bf9\u8fd9\u7c7b\u6750\u6599\u5149\u81f4\u52a8\u529b\u5b66\u7684\u4e86\u89e3\u975e\u5e38\u6709\u9650\uff0c\u4e3a\u4e86\u80fd\u5145…<\/p>\n","protected":false},"author":5415,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[78,97],"class_list":["post-120559","post","type-post","status-publish","format-standard","hentry","category-jiedu","tag-photovoltaic","tag-computation"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/120559"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/5415"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=120559"}],"version-history":[{"count":3,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/120559\/revisions"}],"predecessor-version":[{"id":120813,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/120559\/revisions\/120813"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=120559"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=120559"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=120559"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}