{"id":120061,"date":"2018-01-17T06:30:32","date_gmt":"2018-01-16T22:30:32","guid":{"rendered":"\/\/m.iemloyee.com\/?p=120061"},"modified":"2018-01-16T10:26:46","modified_gmt":"2018-01-16T02:26:46","slug":"%e9%b2%8d%e5%93%b2%e5%8d%97%e6%9c%80%e6%96%b0nature-energy%ef%bc%9a%e5%9d%9a%e9%9f%a7%e5%af%bc%e7%94%b5%e7%9a%84%e9%ab%98%e4%bd%93%e7%a7%af%e5%92%8c%e9%ab%98%e9%9d%a2%e7%a7%af%e5%ae%b9%e9%87%8f","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=120061","title":{"rendered":"\u9c8d\u54f2\u5357\u6700\u65b0Nature Energy\uff1a\u575a\u97e7\u5bfc\u7535\u7684\u9ad8\u4f53\u79ef\u548c\u9ad8\u9762\u79ef\u5bb9\u91cf\u4e8c\u7ef4MOFs\u6750\u6599"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n

\u968f\u7740\u793e\u4f1a\u4e0d\u65ad\u8fdb\u6b65\u53d1\u5c55\uff0c\u5bf9\u5b89\u5168\u53ef\u9760\u3001\u9ad8\u6027\u80fd\u7684\u50a8\u80fd\u5668\u4ef6\u7684\u9700\u6c42\u9010\u6b65\u589e\u52a0\u3002\u7535\u5316\u5b66\u7535\u5bb9\u5668\uff0c\u5373\u8d85\u7ea7\u7535\u5bb9\u5668\u4ee5\u5176\u957f\u4e45\u7684\u5faa\u73af\u5bff\u547d\u3001\u5feb\u901f\u7684\u5145\u653e\u7535\u80fd\u529b\u5728\u50a8\u80fd\u9886\u57df\u5360\u636e\u91cd\u8981\u5730\u4f4d\u3002\u4f46\u662f\uff0c\u80fd\u91cf\u5bc6\u5ea6\u4f4e\u662f\u8d85\u7ea7\u7535\u5bb9\u5668\u7684\u4e00\u5927\u5f0a\u7aef\u3002\u6b64\u5916\uff0c\u5236\u5907\u9ad8\u9762\u79ef\u5bb9\u91cf\u7684\u4e9a\u6beb\u7c73\u7ea7\u522b\u539a\u5ea6\u7684\u7535\u6781\u5728\u5b9e\u9645\u5e94\u7528\u4e2d\u663e\u5f97\u5341\u5206\u91cd\u8981\u3002<\/p>\n

MOFs\uff08metal\u2212organic frameworks\uff0c\u91d1\u5c5e\u6709\u673a\u6846\u67b6\uff09\u662f\u4e00\u79cd\u6709\u7740\u9ad8\u6bd4\u8868\u9762\u79ef\u7684\u591a\u5b54\u6750\u6599\uff0c\u5728\u5206\u5b50\u5c42\u9762\u80fd\u7528\u4e8e\u8bbe\u8ba1\u65e0\u673a\u548c\u6709\u673a\u6846\u67b6\u6750\u6599\uff0c\u5728\u9ad8\u5bb9\u91cf\u8d85\u7ea7\u7535\u5bb9\u5668\u9886\u57df\u4e2d\u6709\u7740\u5e7f\u6cdb\u7684\u5e94\u7528\u524d\u666f\u3002\u7136\u800c\u5927\u90e8\u5206MOFs\u5bfc\u7535\u6027\u592a\u5dee\uff0c\u4e25\u91cd\u5f71\u54cd\u4e86\u50a8\u80fd\u5668\u4ef6\u7684\u6027\u80fd\u3002\u7531\u6b64\u5bfc\u7535MOFs\u5e94\u8fd0\u800c\u751f\uff0c\u5b83\u7531\u914d\u4f4d\u805a\u5408\u7269\uff0c\u5982\u5f3a\u91d1\u5c5e\u914d\u4f4d\u57fa\u8f68\u9053\u6742\u5316\u5f62\u6210\u7684\u534a\u5bfc\u4f53\u548c\u5bfc\u4f53\u7ec4\u6210\u30022D\u548c3D\u7684MOFs\u4e0e1D\u7684\u76f8\u6bd4\uff0c\u62e5\u6709\u66f4\u591a\u7684\u5b54\uff0c\u56e0\u800c\u83b7\u5f97\u66f4\u591a\u7684\u6c27\u5316\u8fd8\u539f\u6d3b\u6027\u4f4d\u70b9\u3002\u4f46\u662f\uff0c\u6846\u67b6\u7684\u672c\u5f81\u80fd\u91cf\u5bc6\u5ea6\u592a\u4f4e\uff0c\u9650\u5236\u4e86\u6c27\u5316\u8fd8\u539f\u6d3b\u6027\u4f4d\u70b9\u7684\u7406\u8bba\u80fd\u91cf\u5bc6\u5ea6\u63d0\u5347\uff0c\u4ece\u800c\u964d\u4f4e\u4e86\u4f53\u79ef\u5bb9\u91cf\u548c\u8d28\u91cf\u5bb9\u91cf\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u6765\u81ea\u65af\u5766\u798f\u5927\u5b66\u7684\u9c8d\u54f2\u5357\u6559\u6388<\/strong>\u8bfe\u9898\u7ec4\u8054\u5408\u65af\u5fb7\u54e5\u5c14\u6469\u5927\u5b66\u548c\u963f\u8d21\u56fd\u5bb6\u5b9e\u9a8c\u5ba4<\/strong>\u5728\u8457\u540dNature\u5b50\u520aNature Energy<\/strong>\u4e0a\u53d1\u8868\u9898\u4e3a\u201d Robust and conductive two-dimensional metal organic frameworks with exceptionally high volumetric and areal capacitance<\/strong>\u201d\u7684\u6587\u7ae0\u3002\u8be5\u6587\u7ae0\u62a5\u9053\u4e86\u4e00\u79cd\u8bbe\u8ba1\u5177\u6709\u6c27\u5316\u8fd8\u539f\u6d3b\u6027\u7684\u5bfc\u7535MOF\u6750\u6599\u7528\u4e8e\u8d85\u7ea7\u7535\u5bb9\u5668\u65b9\u6cd5\uff0c\u8fd9\u79cdMOF\u7684\u5bb9\u91cf\u7531\u8d5d\u7535\u5bb9\u8d21\u732e\uff0c\u800c\u4e0d\u662f\u7535\u53cc\u5c42\u7535\u8377\u3002\u4e3a\u4e86\u589e\u52a0\u6c27\u5316\u8fd8\u539f\u6d3b\u6027\u4e2d\u5fc3\uff0c\u9009\u53d6\u4e86\u8d85\u5c0f\u7684HAB(hexaaminobenzene)\u8fde\u63a5\u4f53\u6784\u7b51\u5bfc\u7535MOF\u3002HAB\u8fde\u63a5\u4f53\u4e0ed8\u548cd9\u76f4\u89d2-\u5e73\u9762\u914d\u4f4d\u51e0\u4f55\u7684\u91d1\u5c5e\u79cd\u7c7b\u4e00\u81f4\uff0c\u56e0\u800c\u4ea7\u751f\u4e86\u4e9a\u7eb3\u7c73\u5b54\u3002\u8fd9\u4e00\u7279\u6027\u4ea7\u751f\u4e86\u9ad8\u4f53\u79ef\u548c\u5927\u9762\u79ef\u7535\u5bb9\uff0c\u80fd\u7528\u4e8e\u4e9a\u6beb\u7c73\u539a\u5ea6\u7684\u7535\u5316\u5b66\u7535\u5bb9\u5668\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n

\u56fe\u4e00\uff1aHAB MOFs\u7684\u5408\u6210\u548c\u7ed3\u6784\u8868\u5f81\u3002<\/strong><\/p>\n

\"\"<\/p>\n

a)Cu-\/Ni-HAB MOFs\u7684\u5408\u6210\u793a\u610f\u56fe\uff1b<\/p>\n

b)Cu-HAB\u7684PXRD\u5b9e\u9a8c\u548c\u6a21\u62df\u66f2\u7ebf\uff1b<\/p>\n

c)Cu-HAB\u8584\u819c\u76842D GIXD\u56fe\u6837\uff1b<\/p>\n

d)Cu-HAB\u7684HR-TEM\u56fe\uff1b<\/p>\n

e)\u56fed\u4e2d\u84dd\u8272\u533a\u57df\u7684HR-TEM\u56fe\uff1b<\/p>\n

f)\u4eceHR-TEM\u8ba1\u7b97\u7684\u5bf9\u79f0\u9644\u52a0\u548c\u5e73\u5747\u6676\u683c\u56fe\u50cf\uff1b<\/p>\n

g)\u5b9e\u9a8c\u548ch)\u6a21\u62df\u7684\u7535\u5b50\u884d\u5c04\u56fe\u6837\uff1b<\/p>\n

i)Cu-HAB\u7684\u7a7a\u95f4\u5206\u5e03\u6a21\u578b\u3002<\/p>\n

\u56fe\u4e8c\uff1a HAB MOFs\u7684\u5236\u5907\u3001\u5438\u6536\u56fe\u8c31\u548c\u5bfc\u7535\u6027\u3002<\/strong><\/p>\n

\"\"<\/p>\n

a)SEM\u56fe\uff1b<\/p>\n

b)\u51b7\u538b\u6210\u578b\u5236\u5907Ni-HAB\uff1b<\/p>\n

c)UV-vis-NIR\u5438\u6536\u5149\u8c31\uff1b<\/p>\n

d)\u6e29\u5ea6-\u7535\u5bfc\u5173\u7cfb\u56fe\u3002<\/p>\n

\u56fe\u4e09\uff1a\u7535\u5316\u5b66\u6027\u80fd\u8868\u5f81\u3002<\/strong><\/p>\n

\"\"<\/p>\n

a)\/b)CV\u56fe\uff1b<\/p>\n

c)EIS\u56fe\uff1b<\/p>\n

d)\u626b\u901f\u4e0e\u91cd\u91cf\u7535\u5bb9\u3001\u4f53\u79ef\u7535\u5bb9\u7684\u5173\u7cfb\uff1b<\/p>\n

e)Ni-HAB\u7535\u6781\u4e0d\u540c\u8f7d\u91cf\u4e0b\u7684\u9762\u79ef\u500d\u7387\u6027\u80fd\uff1b<\/p>\n

f)10A g-1\u7535\u6d41\u5bc6\u5ea6\u5145\u653e\u7535\u7684\u7535\u5bb9\u4fdd\u6301\u91cf\u3002<\/p>\n

\u56fe\u56db\uff1aNi-HAB\u4f53\u79ef\u548c\u9762\u79ef\u5bb9\u91cf\u4e0e\u5176\u4ed6\u6750\u6599\u7684\u6bd4\u8f83\u3002<\/strong><\/p>\n

\"\"<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n

\u5236\u5907\u4e86\u4e00\u79cd\u57fa\u4e8eHAB\u914d\u4f4d\u57fa\u7684\u9ad8\u5bfc\u7535\u4e8c\u7ef4MOFs\uff0c\u8be5\u6750\u6599\u5177\u6709\u826f\u597d\u5316\u5b66\u7a33\u5b9a\u6027\u3002\u9009\u53d6\u7684\u5c0fHAB\u914d\u4f4d\u57fa\u4e0d\u4ec5\u5229\u4e8e\u5408\u6210\u9ad8\u5bc6\u5ea6\u7684\u6846\u67b6\uff0c\u5e76\u4e14\u5f97\u5230\u4e86\u8d85\u9ad8\u4f53\u79ef\u7535\u5bb9\u6027\u80fd\uff08760F cm-3<\/sup>\uff09\u7684\u540c\u65f6\uff0c\u4e5f\u83b7\u5f97\u4e86\u7a33\u5b9a\u7684\u6c27\u5316\u8fd8\u539f\u884c\u4e3a\u548c400F g-1<\/sup>\u7684\u8d28\u91cf\u7535\u5bb9\u3002\u7531\u4e8eHAB MOF\u9897\u7c92\u5c3a\u5bf8\u8f83\u5c0f\uff0c\u5c3d\u7ba1\u7535\u6781\u7684\u539a\u5ea6\u589e\u52a0\u81f3360\u03bcm\uff0c \u9762\u79ef\u7535\u5bb9\u7684\u503c\u4e5f\u8fbe\u523020F cm-2<\/sup>\u3002\u5e76\u4e14\uff0c12000\u6b21\u5faa\u73af\u540e\u7535\u5bb9\u4fdd\u6301\u91cf\u4ecd\u670990%\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/strong>Robust and conductive two-dimensional metal organic frameworks with exceptionally high volumetric and areal capacitance<\/a>(Nature Energy: 10.1038\/s41560-017-0044-5)<\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u65b0\u80fd\u6e90\u7ec4Jespen\u4f9b\u7a3f\uff0c\u6750\u6599\u725b\u6574\u7406\u7f16\u8f91\u3002<\/p>\n

\u6750\u6599\u725b\u7f51\u4e13\u6ce8\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u53ca\u884c\u4e1a\u8fdb\u5c55\uff0c\u8fd9\u91cc\u6c47\u96c6\u4e86\u5404\u5927\u9ad8\u6821\u7855\u535a\u751f\u3001\u4e00\u7ebf\u79d1\u7814\u4eba\u5458\u4ee5\u53ca\u884c\u4e1a\u4ece\u4e1a\u8005\uff0c\u5982\u679c\u60a8\u5bf9\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u8fdb\u5c55\uff0c\u89e3\u8bfb\u9ad8\u6c34\u5e73\u6587\u7ae0\u6216\u662f\u8bc4\u8ff0\u884c\u4e1a\u6709\u5174\u8da3\uff0c\u70b9\u6211\u52a0\u5165\u7f16\u8f91\u90e8\u5927\u5bb6\u5ead<\/a><\/a>\u3002<\/p>\n

\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1tougao@cailiaoren.com\u3002<\/p>\n

\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1aRDD-2011-CHERISH\uff0c\u4efb\u4e39\u4e39<\/strong>\uff0c\u6211\u4eec\u4f1a\u9080\u8bf7\u5404\u4f4d\u8001\u5e08\u52a0\u5165\u4e13\u5bb6\u7fa4\u3002<\/p>\n

\u6750\u6599\u6d4b\u8bd5\u3001\u6570\u636e\u5206\u6790\uff0c\u4e0a\u6d4b\u8bd5\u8c37<\/a>\uff01<\/p>\n","protected":false},"excerpt":{"rendered":"

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