{"id":118182,"date":"2017-12-24T06:30:11","date_gmt":"2017-12-23T22:30:11","guid":{"rendered":"\/\/m.iemloyee.com\/?p=118182"},"modified":"2017-12-22T13:57:43","modified_gmt":"2017-12-22T05:57:43","slug":"nat-energy-%ef%bc%9a%e9%80%9a%e8%bf%87%e8%b0%83%e8%8a%82%e7%94%b5%e8%a7%a3%e8%b4%a8%e7%bb%84%e5%88%86%e5%a2%9e%e5%bc%ba%e5%a4%aa%e9%98%b3%e8%83%bd%e5%88%86%e8%a7%a3%e6%b0%b4%e4%b8%adbivo4%e5%85%89","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=118182","title":{"rendered":"Nat. Energy \uff1a\u901a\u8fc7\u8c03\u8282\u7535\u89e3\u8d28\u7ec4\u5206\u589e\u5f3a\u592a\u9633\u80fd\u5206\u89e3\u6c34\u4e2dBiVO4\u5149\u9633\u6781\u7684\u957f\u671f\u5149\u7a33\u5b9a\u6027"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n

\u6700\u8fd1\uff0cBiVO4<\/sub>\u7531\u4e8e\u5176\u8bf8\u591a\u4f18\u8d8a\u6027\u80fd\uff0c\u5df2\u6210\u4e3a\u7528\u4e8e\u5149\u7535\u5316\u5b66\u6c60(PEC)\u5206\u89e3\u6c34\u6700\u6709\u524d\u666f\u7684\u6c27\u5316\u7269\u57fa\u5149\u9633\u6781\u4e4b\u4e00\u3002\u968f\u7740BiVO4<\/sub>\u57fa\u5149\u9633\u6781\u6027\u80fd\u7684\u6301\u7eed\u63d0\u5347\uff0c BiVO4<\/sub>\u7684\u5149\u7a33\u5b9a\u6027\u53d7\u5230\u5173\u6ce8\u3002\u76ee\u524d\uff0c\u6709\u4e24\u79cd\u65b9\u6cd5\u53ef\u7f13\u89e3\u5149\u7535\u6781\u7684\u5149\u8150\u8680\u3002\u4e00\u79cd\u65b9\u6cd5\u662f\u5c06\u4fdd\u62a4\u5c42\u9644\u4e8e\u5149\u7535\u6781\u4e0a\uff0c\u53e6\u4e00\u79cd\u662f\u4f7f\u7528\u50ac\u5316\u5242\u5c42\u4ee5\u589e\u52a0\u754c\u9762\u7535\u8377\u8f6c\u79fb\u7684\u901f\u5ea6\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u5a01\u65af\u5eb7\u661f\u5927\u5b66\u9ea6\u8fea\u900a\u5206\u6821Kyoung-Shin Choi\u6559\u6388(\u901a\u8baf\u4f5c\u8005)\u7b49<\/strong>\u62a5\u9053\u4e86\u4f18\u5316\u7535\u89e3\u8d28\u7684\u7ec4\u6210\u53ef\u4ee5\u4f5c\u4e3a\u6291\u5236\u592a\u9633\u80fd\u5206\u89e3\u6c34\u8fc7\u7a0b\u4e2d\u5149\u8150\u8680\u7684\u7b56\u7565\u4e4b\u4e00\uff0c\u5e76\u5728Nat. Energy<\/strong>\u4e0a\u53d1\u8868\u4e86\u9898\u4e3a\u201cEnhancing long-term photostability of BiVO4<\/sub> photoanodes for solar water splitting by tuning electrolyte composition<\/strong>\u201d\u7684\u7814\u7a76\u8bba\u6587\u3002BiVO4<\/sub>\u5149\u9633\u6781\u7684\u9633\u6781\u5149\u8150\u8680\u5373V5+<\/sup>\u4eceBiVO4<\/sub>\u6676\u683c\u4e2d\u9038\u51fa\u3002\u4f5c\u8005\u8bc1\u5b9e\u4f7f\u7528V5+<\/sup>\u9971\u548c\u7684\u7535\u89e3\u8d28\u53ef\u6291\u5236\u5149\u6c27\u5316\u9644\u5e26\u7684BiVO4<\/sub>\u5206\u89e3\uff0c\u53ef\u4ee5\u4f5c\u4e3a\u4e00\u79cd\u6291\u5236BiVO4<\/sub>\u7684\u9633\u6781\u5149\u8150\u8680\u7b80\u5355\u800c\u6709\u6548\u7684\u65b9\u6cd5\u3002\u6eb6\u6db2\u4e2d\u7684V5+<\/sup>\u53ef\u4ee5\u4e0e\u9644\u7740\u4e8eBiVO4<\/sub>\u8868\u9762\u7684FeOOH\/NiOOH\u5236\u6c27\u50ac\u5316\u5242\u5c42\u6574\u5408\uff0c\u8fdb\u4e00\u6b65\u4fc3\u8fdb\u6c34\u6c27\u5316\u52a8\u529b\u5b66\u3002\u6700\u540e\u7cfb\u7edf\u6027\u9610\u8ff0\u4e86\u7535\u89e3\u8d28\u4e2dV5+<\/sup>\u5bf9\u4e8e BiVO4<\/sub>\u7684\u957f\u671f\u5149\u7a33\u5b9a\u6027\u548cFeOOH\/NiOOH\u5236\u6c27\u50ac\u5316\u5242\u5c42\u7684\u6027\u80fd\u7684\u5f71\u54cd\u3002<\/p>\n

\u3010\u56fe\u6587\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u56fe1 \u7eb3\u7c73\u591a\u5b54BiVO4<\/sub>\u7535\u6781\u7684\u5f62\u8c8c<\/strong><\/p>\n

\"\"<\/p>\n

a) \u7eb3\u7c73\u591a\u5b54BiVO4<\/sub>\u7535\u6781\u7684\u4fef\u89c6SEM\u56fe\u50cf\uff1b<\/p>\n

b) \u7eb3\u7c73\u591a\u5b54BiVO4<\/sub>\u7535\u6781\u7684\u4fa7\u89c6SEM\u56fe\u50cf\u3002<\/p>\n

\u56fe2 BiVO4<\/sub>\/FeOOH\/NiOOH\u7684\u6027\u80fd\u548c\u7a33\u5b9a\u6027<\/strong><\/p>\n

\"\"<\/p>\n

a) KB\u6eb6\u6db2\u4e2d\uff0cBiVO4<\/sub>(\u9ed1\u8272)\u548cBiVO4<\/sub>\/FeOOH\/NiOOH(\u84dd\u8272)\u7684J-V\u66f2\u7ebf\u56fe(AM 1.5 G\uff0c100 mW\u00b7cm-2<\/sup>\u7167\u5c04\uff1b\u626b\u901f\uff1a10 mV\u00b7s-1<\/sup>) \u7eafBiVO4\u7684\u6697\u7535\u6d41\u4e3a\u9ed1\u8272\u865a\u7ebf\uff1b<\/p>\n

b) KB\u6eb6\u6db2\u4e2dBiVO4<\/sub>\/FeOOH\/NiOOH\u7684J-t\u66f2\u7ebf\u56fe\uff1b<\/p>\n

c) \u5728KB\u6eb6\u6db2\u4e2d\u5bf9BiVO4<\/sub>\u8fdb\u884cJ-t\u6d4b\u8bd560 h\u524d(\u9ed1\u8272)\u540e(\u84dd\u8272)\u7684XRD\u8c31\u56fe\uff1b<\/p>\n

d) \u8fdb\u884cJ-t\u6d4b\u8bd560 h\u524d\u540e\u7684KB\u6eb6\u6db2\u7684ICP\u5206\u6790\u3002<\/p>\n

\u56fe3 \u7535\u89e3\u8d28\u4e2dV5+<\/sup>\u5bf9BiVO4<\/sub>\/FeOOH\/NiOOH\u7684\u6027\u80fd\u548c\u7a33\u5b9a\u6027<\/strong><\/p>\n

\"\"<\/p>\n

a) BiVO4<\/sub>\/FeOOH\/NiOOH\u8584\u819c\u5728KB\u6eb6\u6db2(\u84dd\u8272)\u548cKB + V\u6eb6\u6db2(\u7ea2\u8272)\u4e2d\u7684J-V\u66f2\u7ebf\u56fe(AM 1.5 G\uff0c100 mW\u00b7cm-2<\/sup>\u7167\u5c04\uff1b\u626b\u901f\uff1a10 mV\u00b7s-1<\/sup>) BiVO4<\/sub>\/FeOOH\/NiOOH\u5728KB + V\u6eb6\u6db2\u4e2d\u7684\u6697\u7535\u6d41\u4e3a\u7ea2\u8272\u865a\u7ebf\uff1b<\/p>\n

b) BiVO4<\/sub>\/FeOOH\/NiOOH\u8584\u819c\u5728KB(\u84dd\u8272)\u548cKB + V(\u7ea2\u8272)\u4e2d\u7684J-t\u66f2\u7ebf\u56fe\uff1b<\/p>\n

c) \u5728KB+ V\u6eb6\u6db2\u4e2d\u5bf9BiVO4<\/sub>\u8fdb\u884cJ-t\u6d4b\u8bd560 h\u524d(\u9ed1\u8272)\u540e(\u7ea2\u8272)\u7684XRD\u8c31\u56fe\uff1b<\/p>\n

d) \u8fdb\u884cJ-t\u6d4b\u8bd560 h\u524d\u540e\u7684KB+ V\u6eb6\u6db2\u7684ICP\u5206\u6790\u3002<\/p>\n

\u56fe4 \u7535\u89e3\u8d28\u4e2dV5+<\/sup>\u5bf9OEC\u5c42\u7684\u5f71\u54cd<\/strong><\/p>\n

\"\"<\/p>\n

a) \u8d1f\u8f7d\u4e8eFTO\u7684FeOOH\/NiOOH\u8584\u819c\u5728KB \u6eb6\u6db2(\u84dd\u8272)\u3001KB + V \u6eb6\u6db2(\u7ea2\u8272)\u548cKB + Fe + Ni\u6eb6\u6db2(\u7c89\u8272)\u7684J-t\u66f2\u7ebf\uff1b<\/p>\n

b) \u8d1f\u8f7d\u4e8eFTO\u7684FeOOH\/NiOOH\u8584\u819c\u572860 h J-t\u6d4b\u8bd5\u524d(\u865a\u7ebf)\u540e(\u5b9e\u7ebf)\u7684LSV\u66f2\u7ebf\uff1b<\/p>\n

c) \u8d1f\u8f7d\u4e8eFTO\u7684FeOOH\/NiOOH\u8584\u819c\u5728KB + V\u6eb6\u6db2\u8fdb\u884c20 h\u6d4b\u8bd5(\u7ea2\u8272)\u540e\u5728KB\u6eb6\u6db2\u8fdb\u884c60 h\u6d4b\u8bd5(\u84dd\u8272)\u3002<\/p>\n

\u56fe5 \u50ac\u5316\u5242\u7684\u957f\u671f\u7a33\u5b9a\u6027\u6d4b\u8bd5<\/strong><\/p>\n

\"\"<\/p>\n

a) BiVO4<\/sub>\/FeOOH\/NiOOH\u8584\u819c\u5728KB + V\u6eb6\u6db2\u4e2d\u7684J-t\u66f2\u7ebf\u56fe\uff1b<\/p>\n

b,c) BiVO4<\/sub>\/FeOOH\/NiOOH\u8584\u819c\u5728\u6d4b\u8bd5300 h\u540e\u7684XRD\u8c31\u56fe\u548cSEM\u56fe\u50cf\uff1b<\/p>\n

d,e) BiVO4<\/sub>\/FeOOH\/NiOOH\u8584\u819c\u5728\u6d4b\u8bd5500 h\u540e\u7684XRD\u8c31\u56fe\u548cSEM\u56fe\u50cf\u3002<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n

\u7814\u7a76\u4eba\u5458\u8bc1\u5b9e\u4e86\u4f7f\u7528V5+<\/sup>\u9971\u548c\u7535\u89e3\u6db2\u80fd\u591f\u6291\u5236BiVO4<\/sub>\u7684\u9633\u6781\u5149\u8150\u8680\u3002V5+<\/sup>\u7535\u89e3\u8d28\u6291\u5236\u4e86\u5149\u6c27\u5316\u9644\u5e26\u7684BiVO4<\/sub>\u5206\u89e3\uff0c\u963b\u788d\u4e86BiVO4<\/sub>\u7684\u9633\u6781\u5149\u8150\u8680\u3002\u4e0a\u8ff0\u901a\u8fc7\u4f18\u5316\u7535\u89e3\u8d28\u6210\u5206\u7684\u6291\u5236\u5149\u8150\u8680\u7b56\u7565\u4e5f\u53ef\u7528\u4e8e\u5176\u4ed6\u5b58\u5728\u5149\u8150\u8680\u73b0\u8c61\u7684\u5149\u7535\u6781\u3002\u6b64\u5916\uff0c\u7814\u7a76\u4eba\u5458\u8fd8\u53d1\u73b0\u542bV5+<\/sup>\u7535\u89e3\u8d28\u53ef\u4ee5\u5728FeOOH\/NiOOH\u8584\u819c\u8868\u9762\u539f\u4f4d\u751f\u6210\u542b\u9492\u754c\u9762\u5c42\uff0c\u53ef\u4ee5\u4fc3\u8fdb\u6c34\u6c27\u5316\u52a8\u529b\u5b66\u3002\u8be5\u7814\u7a76\u8868\u660e\u91c7\u7528\u5408\u9002\u7684\u7535\u89e3\u8d28\uff0c\u53ef\u4ee5\u6291\u5236\u5149\u7535\u6781\u548c\u50ac\u5316\u5242\u7684\u6d3b\u6027\u6210\u5206\u7684\u635f\u5931\uff0c\u662f\u63d0\u5347\u5177\u6709\u6d3b\u6027\u9ad8\u4f46\u7a33\u5b9a\u6027\u7a0d\u5dee\u7684\u5149\u7535\u6781\u548c\u50ac\u5316\u5242\u957f\u671f\u7a33\u5b9a\u6027\u7684\u4e00\u79cd\u6709\u6548\u7684\u65b9\u6cd5\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a Enhancing long-term photostability of BiVO4<\/sub> photoanodes for solar water splitting by tuning electrolyte composition<\/a><\/strong>\u00a0 (Nat. Energy, 2017, DOI: 10.1038\/s41560-017-0057-0)<\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u7f16\u8f91\u90e8\u65b0\u80fd\u6e90\u5c0f\u7ec4abc940504\u7f16\u8bd1\u6574\u7406\uff0c\u53c2\u4e0e\u65b0\u80fd\u6e90\u8bdd\u9898\u8ba8\u8bba\u8bf7\u52a0\u5165\u201c\u6750\u6599\u4eba\u65b0\u80fd\u6e90\u6750\u6599\u4ea4\u6d41\u7fa4 422065953\u201d\u3002<\/p>\n

\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1aRDD-2011-CHERISH\uff0c\u4efb\u4e39\u4e39\uff0c\u6211\u4eec\u4f1a\u9080\u8bf7\u5404\u4f4d\u8001\u5e08\u52a0\u5165\u4e13\u5bb6\u7fa4\u3002<\/strong><\/p>\n

\u6750\u6599\u725b\u7f51\u4e13\u6ce8\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u53ca\u884c\u4e1a\u8fdb\u5c55\uff0c\u5982\u679c\u60a8\u5bf9\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u8fdb\u5c55\uff0c\u89e3\u8bfb\u9ad8\u6c34\u5e73\u6587\u7ae0\u6216\u662f\u8bc4\u8ff0\u884c\u4e1a\u6709\u5174\u8da3\uff0c\u70b9\u6211\u52a0\u5165\u7f16\u8f91\u90e8<\/a><\/strong>\u3002\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1tougao@cailiaoren.com\u3002<\/p>\n

\u4eea\u5668\u8bbe\u5907\u3001\u8bd5\u5242\u8017\u6750\u3001\u6750\u6599\u6d4b\u8bd5\u3001\u6570\u636e\u5206\u6790\uff0c\u627e\u6750\u6599\u4eba<\/a><\/strong>\u3001\u4e0a\u6d4b\u8bd5\u8c37<\/a><\/strong>\uff01<\/p>\n","protected":false},"excerpt":{"rendered":"

\u3010\u5f15\u8a00\u3011 \u6700\u8fd1\uff0cBiVO4\u7531\u4e8e\u5176\u8bf8\u591a\u4f18\u8d8a\u6027\u80fd\uff0c\u5df2\u6210\u4e3a\u7528\u4e8e\u5149\u7535\u5316\u5b66\u6c60(PEC)\u5206\u89e3\u6c34\u6700\u6709\u524d\u666f\u7684\u6c27\u5316\u7269\u57fa\u5149\u9633\u6781\u4e4b\u4e00\u3002\u968f\u7740BiVO4\u57fa\u5149\u9633\u6781\u6027\u80fd\u7684\u6301\u7eed\u63d0\u5347\uff0c BiVO…<\/p>\n","protected":false},"author":4931,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[],"class_list":["post-118182","post","type-post","status-publish","format-standard","hentry","category-jiedu"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/118182"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/4931"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=118182"}],"version-history":[{"count":4,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/118182\/revisions"}],"predecessor-version":[{"id":118403,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/118182\/revisions\/118403"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=118182"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=118182"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=118182"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}