{"id":118133,"date":"2017-12-22T06:30:46","date_gmt":"2017-12-21T22:30:46","guid":{"rendered":"\/\/m.iemloyee.com\/?p=118133"},"modified":"2017-12-20T20:06:46","modified_gmt":"2017-12-20T12:06:46","slug":"%e8%8b%8f%e5%b7%9e%e5%a4%a7%e5%ad%a6angew-chem-int-ed-%ef%bc%9a%e7%ba%b3%e7%b1%b3%e5%b0%ba%e5%ba%a6%e7%9a%84%e4%b8%89%e9%87%91%e5%b1%9emof%e7%94%a8%e4%ba%8e%e9%ab%98%e6%95%88%e7%9a%84%e6%9e%90","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=118133","title":{"rendered":"\u82cf\u5dde\u5927\u5b66Angew. Chem. Int. Ed.\uff1a\u7eb3\u7c73\u5c3a\u5ea6\u7684\u4e09\u91d1\u5c5eMOF\u7528\u4e8e\u9ad8\u6548\u7684\u6790\u6c27\u7535\u50ac\u5316"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n

\u5982\u4eca\uff0c\u80fd\u6e90\u5371\u673a\u548c\u73af\u5883\u95ee\u9898\u65e5\u76ca\u4e25\u5cfb\uff0c\u8bbe\u8ba1\u9ad8\u6548\u7684\u80fd\u6e90\u8f6c\u6362\u548c\u50a8\u5b58\u7684\u7535\u5316\u5b66\u7cfb\u7edf\uff0c\u5982\u71c3\u6599\u7535\u6c60\u3001\u91d1\u5c5e\u7a7a\u6c14\u7535\u6c60\u548c\u7535\u89e3\u6c34\uff0c\u5c24\u4e3a\u91cd\u8981\u3002\u7136\u800c\uff0c\u7531\u4e8e\u8d28\u5b50\u8026\u5408\u7535\u5b50\u8f6c\u79fb\u8fc7\u7a0b\u6b65\u9aa4\u8f83\u591a\uff0c\u52a8\u529b\u5b66\u53cd\u5e94\u7f13\u6162\uff0c\u5176\u4e2d\u6790\u6c27\u53cd\u5e94\uff08OER, 4OH–<\/sup>\u21922H2<\/sub>O +O2<\/sub> + 4 e–<\/sup>\uff09\u4e25\u91cd\u9650\u5236\u4e86\u7535\u5316\u5b66\u7cfb\u7edf\u7684\u6548\u7387\u3002\u5982\u4eca\uff0c\u6700\u5e38\u89c1\u7684OER\u9634\u6781\u50ac\u5316\u5242\u662f\u8d35\u91d1\u5c5e\u6750\u6599\uff0c \u4f46\u662f\u5e38\u5e38\u9700\u8981\u975e\u5e38\u9ad8\u7684\u8fc7\u7535\u52bf\u4ee5\u6ee1\u8db3\u6240\u9700\u8981\u7684\u7535\u6d41\u5bc6\u5ea6\u3002\u6b64\u5916\uff0c\u8d35\u91d1\u5c5e\u50ac\u5316\u5242\u6210\u672c\u975e\u5e38\u9ad8\uff0c\u9650\u5236\u4e86\u5176\u5927\u89c4\u6a21\u5e94\u7528\u3002\u56e0\u6b64\uff0c\u901a\u8fc7\u8c03\u6574\u6210\u5206\u4e0e\u7ec4\u6210\uff0c\u5982\u91d1\u5c5e\u6c27\u5316\u7269\u3001\u6c22\u6c27\u5316\u7269\u3001\u786b\u65cf\u5316\u5408\u7269\u3001\u6c2e\u5316\u7269\u3001\u78f7\u5316\u7269\u548c\u78b3\u57fa\u6750\u6599\uff0c\u5f00\u53d1\u9ad8\u6548\u4e14\u7a33\u5b9a\u7684OER\u50ac\u5316\u5242\u975e\u5e38\u91cd\u8981\u3002\u800c\u91d1\u5c5e\u6709\u673a\u6846\u67b6 (MOFs)\uff0c \u51ed\u501f\u5176\u5927\u7684\u6bd4\u8868\u9762\u79ef\uff0c\u9ad8\u5b54\u9699\uff0c\u548c\u91d1\u5c5e\u4e2d\u5fc3\u548c\u5b98\u80fd\u56e2\u7684\u591a\u6837\u6027\uff0c\u5728\u5f88\u591a\u9886\u57df\u5438\u5f15\u4e86\u5e7f\u6cdb\u7684\u5173\u6ce8\u3002\u5728\u7535\u50ac\u5316\u4e2d\uff0c\u901a\u8fc7\u7145\u70e7\u5236\u5907\u91d1\u5c5e\u6c27\u5316\u7269\u548c\u591a\u5b54\u7684\u78b3\u6750\u6599\uff0cMOFs\u662f\u6700\u597d\u7684\u524d\u9a71\u4f53\u3002\u800c\u9ad8\u6e29\u70ed\u89e3\u8fc7\u7a0b\u5e38\u5e38\u4f1a\u5bfc\u81f4\u6709\u673a\u914d\u4f53\u7684\u635f\u5931\u548c\u91d1\u5c5e\u7684\u805a\u96c6\uff0c\u8fd9\u5c06\u4f1a\u5b8c\u5168\u7834\u574f\u5176\u7ed3\u6784\uff0c\u964d\u4f4e\u6d3b\u6027\u4f4d\u70b9\u3002\u53e6\u4e00\u65b9\u9762\uff0c MOFs\u5728\u7535\u50ac\u5316\u4e2d\u540c\u65f6\u5177\u6709\u5747\u8d28\u548c\u5f02\u8d28\u50ac\u5316\u5242\u7684\u4f18\u70b9\uff0c\u4ece\u7ed3\u6784\u4e0a\u6765\u8bf4\uff0cMOFs\u53ef\u4ee5\u4e0d\u9700\u8981\u7145\u70e7\u76f4\u63a5\u7528\u4f5cOER\u50ac\u5316\u5242\u3002MOFs\u8868\u9762\u4e0d\u9971\u548c\u7684\u91d1\u5c5e\u539f\u5b50\u548c\u6c22\u6c27\u5316\u7269\u914d\u4f53\uff0c\u4ee5\u53ca\u53cc\u91d1\u5c5e\u8026\u5408\u6548\u5e94\u5927\u5927\u589e\u52a0\u4e86\u7535\u50ac\u5316OER\u6d3b\u6027\uff0c\u7136\u800c\u8bbe\u8ba1\u529f\u80fd\u5316\u7684MOFs\u76f4\u63a5\u7528\u4f5c\u9ad8\u6548\u7684OER\u50ac\u5316\u5242\u4ecd\u7136\u9762\u4e34\u5f88\u591a\u6311\u6218\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u82cf\u5dde\u5927\u5b66\u7684\u90ce\u5efa\u5e73\u6559\u6388\u548c\u9ec4\u5c0f\u9752\u6559\u6388\u56e2\u961f<\/strong>\u5728Angewandte Chemie International Edition<\/strong>\u671f\u520a\u4e0a\u53d1\u8868\u4e86\u9898\u4e3a\u201cNanoscale Trimetallic Metal\u2013Organic Frameworks Enable Efficient Oxygen Evolution Electrocatalysis<\/strong>\u201d\u7684\u6587\u7ae0\uff0c\u6587\u4e2d\u4f5c\u8005\u901a\u8fc7\u6eb6\u5242\u70ed\u6cd5\u5236\u5907\u4e86\u4e00\u7cfb\u5217Fe\/Ni\u57fa\u7684\u4e09\u91d1\u5c5eMOFs \uff08Fe\/Ni\/Co(Mn)-MIL-53\uff09\uff0c \u53ef\u76f4\u63a5\u7528\u4f5c\u9ad8\u6548\u7684\u7535\u50ac\u5316\u5242\u3002Fe\/Ni\/Co(Mn)-MIL-53\u7684OER\u6d3b\u6027\u4e0e\u7ec4\u6210\u76f8\u5173\u3002Fe\/Ni2.4<\/sub>\/Co0.4<\/sub>-MIL-53\u5728236 mV\u7684\u4f4e\u8fc7\u7535\u52bf\u4e0b\u53ef\u4ee5\u8fbe\u523020 mA cm-2<\/sup>\u7684\u7535\u6d41\u5bc6\u5ea6\uff0cTafel\u659c\u7387\u4e5f\u975e\u5e38\u4f4e (52.2 mV dec-1<\/sup>) \u3002\u6b64\u5916\uff0c\u901a\u8fc7\u5c06\u5176\u76f4\u63a5\u589e\u957f\u5728\u6ce1\u6cab\u954d\uff08NF\uff09\u4e0a\u53ef\u4ee5\u663e\u8457\u589e\u5f3a\u8fd9\u4e9bMOFs\u7684OER\u6027\u80fd\u3002\u8be5\u9879\u5de5\u4f5c\u7684\u7b2c\u4e00\u4f5c\u8005<\/strong>\u4e3a\u674e\u98de\u9f99<\/strong>\uff0c\u90ce\u5efa\u5e73\u6559\u6388<\/strong>\u548c\u9ec4\u5c0f\u9752\u6559\u6388<\/strong>\u4e3a\u5171\u540c\u901a\u8baf\u4f5c\u8005\u3002<\/strong><\/p>\n

\u3010\u56fe\u6587\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u56fe\u4e00\uff1a<\/strong>Fe\/Ni\/Co(Mn)-MIL-53 and <\/strong>Fe\/Ni\/Co(Mn)-MIL-53\/NF<\/strong>\u5408\u6210\u8fc7\u7a0b\u793a\u610f\u56fe<\/strong><\/p>\n

\"\"<\/p>\n

\u56fe\u4e8c\uff1a<\/strong> Fe\/Ni -MIL-53<\/strong>\u7684\u5fae\u89c2\u5f62\u8c8c\u53ca\u7269\u76f8\u8868\u5f81<\/strong><\/p>\n

\"\"<\/p>\n

\uff08a\uff09Fe\/Ni2.4<\/sub>-MIL-53\u7684SEM\u56fe\u50cf\uff1b<\/p>\n

\uff08b\uff09Fe\/Ni2.4<\/sub>-MIL-53\u7684TEM\u56fe\u50cf\uff1b<\/p>\n

\uff08c\uff09\u6a21\u62df\u7684MIL-53, Fe-MIL-53, Fe\/Ni2.4<\/sub>-MIL-53 \u4ee5\u53ca Fe\/Ni2.4<\/sub>\/Co0.4<\/sub>-MIL-53\u7684PXRD\u56fe\u8c31\uff1b<\/p>\n

\uff08d\uff09Fe\/Ni2.4<\/sub>-MIL-53\u7684HAADF-STEM\u56fe\u50cf\u548cSTEM-EDS\u5143\u7d20\u6620\u5c04\u5206\u5e03\u56fe\u50cf\u3002<\/p>\n

\u56fe\u4e09\uff1a<\/strong>Fe\/Nix<\/sub>-MIL-53 (x=1.6, 2.0, 2.4) <\/strong>\u7684\u7535\u5316\u5b66\u6027\u80fd<\/strong><\/p>\n

\"\"<\/p>\n

\uff08a\uff09Fe\/Nix<\/sub>-MIL-53 (x=1.6, 2.0, 2.4)\uff0c\u5546\u7528Ir\/C\u4ee5\u53ca\u7eaf\u73bb\u7483\u78b3\u7535\u6781GC\u7684\u7ebf\u6027\u626b\u63cf\u4f0f\u5b89\u66f2\u7ebf\uff1b<\/p>\n

\uff08b\uff09Fe\/Nix<\/sub>-MIL-53 (x=1.6, 2.0, 2.4)\uff0c\u4ee5\u53ca\u5546\u7528Ir\/C\u7684Tafel\u659c\u7387\u6bd4\u8f83\u3002<\/p>\n

\u56fe\u56db\uff1a<\/strong>Fe\/Ni\/Co(Mn)-MIL-53<\/strong>\u7684\u5fae\u89c2\u5f62\u8c8c\u8868\u5f81\u53ca\u7535\u5316\u5b66\u6027\u80fd<\/strong><\/p>\n

\"\"<\/p>\n

\u00a0<\/strong>\uff08a\uff09Fe\/Ni2.4<\/sub>\/Co0.4<\/sub>-MIL-53\u7684SEM\u56fe\u50cf\uff1b<\/p>\n

\uff08b\uff09Fe\/Ni2.4<\/sub>\/Co0.4<\/sub>-MIL-53\u4ee5\u53ca\uff08c\uff09Fe\/Ni2.4<\/sub>\/Mn0.4<\/sub>-MIL-53\u7684HAADF-STEM\u56fe\u50cf\u548cSTEM-EDS\u5143\u7d20\u6620\u5c04\u5206\u5e03\u56fe\u50cf\uff1b<\/p>\n

\uff08d\uff09Fe\/Ni2.4<\/sub>-MIL-53\u548cFe\/Ni2.4<\/sub>\/Mx<\/sub>-MIL-53\uff08M=Co, Mn; x=0.2, 0.4\uff09\u7684OER\u6781\u5316\u66f2\u7ebf\uff1b<\/p>\n

\uff08e\uff09\u4e0d\u540c\u50ac\u5316\u5242\u5206\u522b\u572810 mA cm-2<\/sup>\u548c1.5 V vs \u53ef\u9006\u6c22\u7535\u6781\uff08RHE\uff09\u4e0b\u76f8\u5bf9\u5e94\u7684\u8fc7\u7535\u52bf\u548c\u7535\u6d41\u5bc6\u5ea6\uff1b<\/p>\n

\uff08f\uff09\u4e0d\u540c\u50ac\u5316\u5242\u7684Tafel\u659c\u7387\uff1b<\/p>\n

\uff08g\uff09Fe\/Ni2.4<\/sub>\/Co0.4<\/sub>-MIL-53\u57281000\u5708\u5faa\u73af\u524d\u540e\u7684\u6781\u5316\u66f2\u7ebf\u3002<\/p>\n

\u56fe\u4e94\uff1a\u751f\u957f\u5728<\/strong>NF<\/strong>\u4e0a\u4e0d\u540c\u50ac\u5316\u5242\u7684<\/strong>OER<\/strong>\u7535\u5316\u5b66\u6027\u80fd<\/strong>
\n <\/strong><\/p>\n

\"\"<\/strong><\/p>\n

\uff08a\uff09NF, NF\u505a\u652f\u6491\u7684Fe\/Ni-MIL-53\u3001Fe\/Ni\/Mn0.2<\/sub>-MIL-53\u3001Fe\/Ni\/Mn0.4<\/sub>-MIL-53\u3001Fe\/Ni\/Co0.2<\/sub>-MIL-53\u4ee5\u53caFe\/Ni\/Co0.4<\/sub>-MIL-53\u7684OER\u6781\u5316\u66f2\u7ebf\uff1b<\/p>\n

\uff08b\uff09\u76f8\u5bf9\u5e94\u7684Tafel\u659c\u7387\uff1b<\/p>\n

\uff08c\uff09 Fe\/Ni\/Co0.4<\/sub>-MIL-53\/NF\u5728300 mV vs. RHE\u4e0b\u6301\u7eed\u5f88\u957f\u65f6\u95f4\u6d4b\u5f97\u7684\u7535\u6d41\u5bc6\u5ea6\u3002<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n

\u672c\u6587\u4f5c\u8005\u5229\u7528\u6c34\u70ed\u6cd5\u6210\u529f\u5236\u5907\u4e86\u4e00\u7cfb\u5217Fe\/Ni\u6469\u5c14\u6bd4\u53ef\u8c03\u7684Fe\/Ni\u57faMOFs\uff0c\u53ef\u4ee5\u76f4\u63a5\u7528\u4f5c\u5177\u6709\u9ad8\u6d3b\u6027\u548c\u7a33\u5b9a\u6027\u7684OER\u50ac\u5316\u5242\u3002\u6027\u80fd\u6700\u4f18\u7684Fe\/Ni2.4<\/sub>\/Co0.4<\/sub>-MIL-53\u5728236 mV\u7684\u4f4e\u8fc7\u7535\u52bf\u4e0b\u53ef\u4ee5\u8fbe\u523020 mA cm-2<\/sup>\u7684\u7535\u6d41\u5bc6\u5ea6\uff0c Tafel\u659c\u7387\u4e5f\u975e\u5e38\u4f4e (52.2 mV dec-1<\/sup>) \u3002\u8be5MOFs\u9ad8\u6548\u7684OER\u6027\u80fd\u4e3b\u8981\u662f\u7531\u4e8e\u5176\u4f18\u5f02\u7684\u7ed3\u6784\u548c\u591a\u5b54\u6027\uff0c\u4ee5\u53ca\u6df7\u5408\u91d1\u5c5e\u7684\u534f\u540c\u6548\u5e94\u3002\u901a\u8fc7\u81ea\u6a21\u677f\u65b9\u6cd5\u5c06\u4e09\u91d1\u5c5e\u7684MOFs\u6784\u5efa\u5728NF\u4e0a\u66f4\u8fdb\u4e00\u6b65\u589e\u5f3a\u4e86\u5176OER\u6d3b\u6027\u548c\u7a33\u5b9a\u6027\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/strong>Nanoscale Trimetallic Metal\u2013Organic Frameworks Enable Efficient Oxygen Evolution Electrocatalysis<\/a> (Angew. Chem. Int. Ed. 2017, DOI: 10.1002\/anie.201711376)<\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u7f16\u8f91\u90e8\u661d\u840d<\/strong>\u7f16\u8bd1\uff0c\u70b9\u6211\u52a0\u5165\u6750\u6599\u4eba\u7f16\u8f91\u90e8<\/a>\u3002<\/p>\n

\u6750\u6599\u6d4b\u8bd5\uff0c\u6570\u636e\u5206\u6790\uff0c\u4e0a\u6d4b\u8bd5\u8c37\uff01<\/a><\/p>\n","protected":false},"excerpt":{"rendered":"

\u3010\u5f15\u8a00\u3011 \u5982\u4eca\uff0c\u80fd\u6e90\u5371\u673a\u548c\u73af\u5883\u95ee\u9898\u65e5\u76ca\u4e25\u5cfb\uff0c\u8bbe\u8ba1\u9ad8\u6548\u7684\u80fd\u6e90\u8f6c\u6362\u548c\u50a8\u5b58\u7684\u7535\u5316\u5b66\u7cfb\u7edf\uff0c\u5982\u71c3\u6599\u7535\u6c60\u3001\u91d1\u5c5e\u7a7a\u6c14\u7535\u6c60\u548c\u7535\u89e3\u6c34\uff0c\u5c24\u4e3a\u91cd\u8981\u3002\u7136\u800c\uff0c\u7531\u4e8e\u8d28\u5b50\u8026\u5408\u7535\u5b50\u8f6c\u79fb\u8fc7\u7a0b\u6b65\u9aa4…<\/p>\n","protected":false},"author":3094,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[116,245],"class_list":["post-118133","post","type-post","status-publish","format-standard","hentry","category-jiedu","tag-catalyst","tag-mof"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/118133"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/3094"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=118133"}],"version-history":[{"count":4,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/118133\/revisions"}],"predecessor-version":[{"id":118160,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/118133\/revisions\/118160"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=118133"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=118133"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=118133"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}