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Co\u5219\u503e\u5411\u4e8e\u901a\u8fc7\u52a0\u6c22\u95f4\u63a5\u89e3\u79bbC=O\u952e\u3002\u7406\u8bba\u5206\u6790\u53d1\u73b0\uff0c\u4ea7\u751f\u8fd9\u4e9b\u5dee\u5f02\u7684\u539f\u56e0\u6765\u6e90\u4e8eHCP Co\u7684\u6676\u4f53\u7ed3\u6784\u5bf9\u79f0\u6027\u76f8\u5bf9\u8f83\u4f4e\uff0c\u80fd\u591f\u66b4\u9732\u51fa\u5927\u91cf\u7684\u9ad8\u6d3b\u6027\u6676\u9762\u3002\u57fa\u4e8e\u8fd9\u4e9b\u7ed3\u679c\uff0c\u674e\u5fae\u96ea\u56e2\u961f\u63d0\u51fa\u901a\u8fc7HCP Co\u5f62\u8c8c\u7684\u53ef\u63a7\u5408\u6210\uff0c\u66b4\u9732\u7279\u5b9a\u9ad8\u6d3b\u6027\u7684HCP Co(10-11)\u6676\u9762\u4ee5\u63d0\u9ad8\u6d3b\u6027\u4f4d\u5bc6\u5ea6\uff0c\u800c\u4e0d\u9700\u8981\u901a\u8fc7\u51cf\u5c0f\u50ac\u5316\u5242\u7684\u5c3a\u5bf8\uff0c\u6765\u5b9e\u73b0\u9ad8\u6bd4\u8d28\u91cf\u6d3b\u6027\u3001\u7a33\u5b9a\u7684\u94b4\u57fa\u50ac\u5316\u5242\u7684\u4f18\u5316\u8bbe\u8ba1\u3002\u8fd9\u4e00\u7814\u7a76\u7ed3\u679c\u63ed\u793a\u51fa\u53ef\u4ee5\u5229\u7528\u6750\u6599\u4e0d\u540c\u6676\u76f8\u7ed3\u6784\u6765\u63a7\u5236\u8868\u9762\u7ed3\u6784\u548c\u5f62\u8c8c\uff0c\u901a\u8fc7\u63d0\u9ad8\u672c\u5f81\u6d3b\u6027\u548c\u6d3b\u6027\u4f4d\u5bc6\u5ea6\u6765\u83b7\u5f97\u9ad8\u6548\u3001\u7a33\u5b9a\u50ac\u5316\u6750\u6599\uff0c\u540c\u65f6\u8fd8\u9884\u793a\u4e86\u7b2c\u4e00\u6027\u539f\u7406\u52a8\u529b\u5b66\u7406\u8bba\u8ba1\u7b97\u548c\u6750\u6599\u53ef\u63a7\u5408\u6210\u5c06\u5728\u5176\u4e2d\u53d1\u6325\u7740\u91cd\u8981\u4f5c\u7528\u3002\u8fd9\u4e3a\u5f00\u53d1\u65b0\u4e00\u4ee3\u94b4\u57fa\u8d39\u6258\u5408\u6210\u53cd\u5e94\u50ac\u5316\u5242\u63d0\u4f9b\u4e86\u7406\u8bba\u4e0a\u652f\u6301\u548c\u6307\u5bfc\u3002(<strong><a href=\"http:\/\/pubs.acs.org\/doi\/full\/10.1021\/ja408521w\" target=\"_blank\" rel=\"noopener\">J. Am. Chem. Soc.<\/a><\/strong>, 2013, 135 (44), 16284\u201316287)<\/p>\n<p><strong>2\u3001\u91d1\u5c5e<\/strong><strong>Ru<\/strong><strong>\u6676\u76f8\u8c03\u63a7<\/strong><strong>CO<\/strong><strong>\u6d3b\u5316<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-118093\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/12\/2-56.jpg\" alt=\"\" width=\"650\" height=\"364\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/12\/2-56.jpg 650w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/12\/2-56-300x168.jpg 300w\" sizes=\"(max-width: 650px) 100vw, 650px\" \/><\/p>\n<p>\u7b2c\u4e00\u6027\u539f\u7406\u7684\u52a8\u529b\u5b66\u7406\u8bba\u8ba1\u7b97\u9884\u6d4b\u9ad8\u6d3b\u6027FCC Ru\u50ac\u5316\u5242\u3002\u5218\u8fdb\u52cb\u535a\u58eb\u548c\u674e\u5fae\u96ea\u6559\u6388\u9996\u5148\u91c7\u7528\u5bc6\u5ea6\u6cdb\u51fd\u7406\u8bba (DFT) \u8ba1\u7b97\u4e86FCC\u6676\u76f8\u4e0eHCP\u6676\u76f8\u91d1\u5c5eRu\u5728\u70ed\u529b\u5b66\u5e73\u8861\u6761\u4ef6\u4e0bWulff\u5f62\u8c8c\u4ee5\u53ca\u5728\u5404\u66b4\u9732\u8868\u9762\u4e0aCO\u89e3\u79bb\u52bf\u5792\u3002\u4e00\u822c\u8ba4\u4e3a\uff0cCO\u89e3\u79bb\u662f\u8d39\u6258\u5408\u6210\u7684\u5173\u952e\u6b65\u9aa4\uff0c\u800cCO\u89e3\u79bb\u52bf\u5792\u7684\u5927\u5c0f\u53ef\u4ee5\u53cd\u6620\u51fa\u50ac\u5316\u5242\u7684\u8d39\u6258\u5408\u6210\u6d3b\u6027\u3002\u8ba1\u7b97\u7ed3\u679c\u8868\u660eHCP\u6676\u76f8Ru (0001) \u9762\u7684Step-B\u53f0\u9636\u4f4d\u5177\u6709\u6700\u4f4e\u7684CO\u89e3\u79bb\u52bf\u5792\uff0c\u4f46\u5728\u771f\u5b9e\u7eb3\u7c73\u7c92\u5b50\u4f53\u7cfb\u4e2d\uff0c\u8fd9\u79cd\u53f0\u9636\u4f4d\u7f6e\u8f83\u96be\u66b4\u9732\u3002\u800cFCC Ru\u6676\u76f8\u5177\u6709 (100)\u3001(211) \u9762\u4ee5\u53ca (111) \u9762Step-B\u53f0\u9636\u4f4d\u7b49\u4e00\u7cfb\u5217CO\u89e3\u79bb\u80fd\u5792\u8f83\u4f4e\u7684\u8868\u9762\uff0c\u6709\u53ef\u80fd\u5177\u6709\u975e\u5e38\u597d\u7684\u8d39\u6258\u5408\u6210\u50ac\u5316\u6d3b\u6027\u3002\u5728\u8ba1\u7b97\u6307\u5bfc\u4e0b\uff0c\u5b9e\u9a8c\u5408\u6210\u4e86FCC Ru\u50ac\u5316\u5242\u3002\u5982\u7406\u8bba\u9884\u8a00\uff0c\u8be5\u50ac\u5316\u5242\u8f83\u4f20\u7edf\u6027\u80fd\u6700\u597d\u7684HCP Ru\u50ac\u5316\u5242\u7684\u8868\u89c2\u6d3b\u5316\u80fd\u9ad8\uff0c\u4f46\u5176\u6bd4\u8d28\u91cf\u6d3b\u6027\u662f\u76ee\u524d\u62a5\u9053\u7684\u6700\u9ad8\u7684\u6bd4\u8d28\u91cf\u6d3b\u6027\u50ac\u5316\u5242\u7684\u6027\u80fd\u7684\u516d\u500d\u4ee5\u4e0a\u3002\u5229\u7528STEM\u3001XAFS\u3001XRD\u7b49\u624b\u6bb5\u5bf9\u8be5FCC Ru\u50ac\u5316\u5242\u8fdb\u884c\u76f8\u5e94\u7684\u8868\u5f81\u548c\u7ed3\u6784\u6a21\u62df\u91cd\u5efa\uff0c\u53d1\u73b0\u5408\u6210\u7684\u50ac\u5316\u5242\u7684\u786e\u66b4\u9732\u8f83\u591a\u7684Ru(100)\u3001(211)\u3001(311)\u7b49\u6d3b\u6027\u9762\uff0c\u76f8\u5e94\u6d3b\u6027\u4f4d\u5bc6\u5ea6\u662f\u6b64\u524d\u6700\u597dHCP Ru\u50ac\u5316\u5242\u76841-2\u4e2a\u6570\u91cf\u7ea7\u4ee5\u4e0a\uff0c\u5b8c\u5168\u8bc1\u5b9e\u4e86\u7406\u8bba\u8ba1\u7b97\u7684\u9884\u8a00\u3002\u8fd9\u4e00\u7814\u7a76\u7ed3\u679c\u4e3a\u8bbe\u8ba1\u5408\u6210\u9ad8\u6548\u3001\u7a33\u5b9a\u50ac\u5316\u6750\u6599\u63d0\u4f9b\u4e86\u91cd\u8981\u7406\u8bba\u652f\u6301\uff0c\u66f4\u663e\u793a\u51fa\u7406\u8bba\u8ba1\u7b97\u5728\u9884\u6d4b\u9ad8\u6d3b\u6027\u50ac\u5316\u5242\u4e2d\u7684\u91cd\u8981\u4f5c\u7528\u3002(<strong><a href=\"http:\/\/pubs.acs.org\/doi\/full\/10.1021\/jacs.6b10375\" target=\"_blank\" rel=\"noopener\">J. Am. Chem. Soc.<\/a><\/strong>, 2017, 139, 2267\u20132276)<\/p>\n<p><strong>3\u3001\u91d1\u5c5e<\/strong><strong>Ni<\/strong><strong>\u6676\u76f8\u8c03\u63a7<\/strong><strong>CO<\/strong><strong>\u6d3b\u5316<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-118094\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/12\/3-2.gif\" alt=\"\" width=\"419\" height=\"500\" \/><\/p>\n<p>\u91d1\u5c5e\u954d\u662f\u5e38\u7528\u7684\u4e00\u6c27\u5316\u78b3\uff08CO\uff09\u7532\u70f7\u5316\uff0c\u7532\u70f7\u6c34\u6c7d\u91cd\u6574\u53cd\u5e94\u50ac\u5316\u5242\u3002\u5e38\u6e29\u5e38\u538b\u4e0b\uff0c\u91d1\u5c5e\u954d\u4f53\u76f8\u5177\u6709\u9762\u5fc3\u7acb\u65b9\uff08FCC Ni\uff09\u6676\u683c\u7ed3\u6784\u3002\u5f53\u91d1\u5c5e\u954d\u7eb3\u7c73\u7c92\u5b50\u5c3a\u5bf8\u51cf\u5c0f\u65f6\uff0cFCC Ni\u4f1a\u76f8\u53d8\u4e3a\u5177\u6709\u516d\u89d2\u5bc6\u5806\u6676\u683c\u7ed3\u6784\u7684HCP Ni\u3002\u540c\u65f6\uff0c\u5b9e\u9a8c\u4e0a\u5df2\u7ecf\u80fd\u591f\u901a\u8fc7\u6dfb\u52a0\u7279\u5b9a\u4fdd\u62a4\u5242\u65b9\u6cd5\u6765\u5b9a\u5411\u5408\u6210HCP Ni\u7eb3\u7c73\u7c92\u5b50\u3002\u4e00\u822c\u8ba4\u4e3aCO\u6d3b\u5316\u662f\u7532\u70f7\u5316\u8fc7\u7a0b\u7684\u901f\u63a7\u6b65\u9aa4\uff0c\u63a2\u7d22CO\u89e3\u79bb\u6d3b\u6027\u5bf9\u4e8e\u91d1\u5c5eNi\u6676\u76f8\u548c\u5f62\u8c8c\u7684\u4f9d\u8d56\u5173\u7cfb\uff0c\u5bf9\u4f18\u5316\u8bbe\u8ba1\u9ad8\u6d3b\u6027\u7532\u70f7\u5316Ni\u57fa\u50ac\u5316\u5242\u5177\u6709\u91cd\u8981\u7684\u610f\u4e49\u3002\u6211\u4eec\u5229\u7528\u5bc6\u5ea6\u6cdb\u51fd\u7406\u8bba\u8ba1\u7b97\u65b9\u6cd5\u7cfb\u7edf\u7814\u7a76\u4e86CO\u89e3\u79bb\u5bf9\u91d1\u5c5eNi\u6676\u76f8\u4f9d\u8d56\u5173\u7cfb\uff0c\u4ece\u5fae\u89c2\u4e0a\u7406\u89e3\u4e86FCC\u548cHCP Ni\u4e0aCO\u76f4\u63a5\u6d3b\u5316\u548c\u6c22\u52a9\u6d3b\u5316\uff08CO+H \u2192 HCO \u2192 CH+O\u6216\u8005CO+H \u2192 COH \u2192 C+OH\uff09\u8fc7\u7a0b\uff0c\u786e\u7acb\u4e86\u6d3b\u6027\u4e2d\u5fc3\u7ed3\u6784\u548cCO\u6d3b\u5316\u673a\u7406\u3002\u7406\u8bba\u7814\u7a76\u8868\u660e\uff0cFCC\u548cHCP Ni\u5177\u6709\u4e0d\u540c\u7684\u6676\u4f53\u7ed3\u6784\u5bf9\u79f0\u6027\u51b3\u5b9a\u4e86\u5b83\u4eec\u5177\u6709\u4e0d\u540c\u7684\u5f62\u8c8c\u548c\u66b4\u9732\u8868\u9762\u7ed3\u6784\u3002\u5728FCC\u548cHCP Ni\u4e0a\uff0cCO\u5438\u9644\u7ed3\u6784\u4e0d\u654f\u611f\uff0c\u800cCO\u6d3b\u5316\u8fc7\u7a0b\u5177\u6709\u663e\u8457\u7684\u7ed3\u6784\u654f\u611f\u6027\uff0cCO\u6c22\u52a9\u89e3\u79bb\u6bd4\u76f4\u63a5\u89e3\u79bb\u66f4\u5bb9\u6613\u3002\u5728FCC\u548cHCP Ni\u9ad8\u6d3b\u6027\u8868\u9762\u4e0a\uff0cCO\u7ecf\u7531COH\u4e2d\u95f4\u4f53\u7684\u6c22\u52a9\u89e3\u79bb\u8fc7\u7a0b\u66f4\u52a0\u6709\u5229\u3002\u800c\u5728FCC\u548cHCP Ni\u6d3b\u6027\u8f83\u4f4e\u7684\u8868\u9762\u4e0a\uff0cCO\u9700\u7ecf\u7531HCO\u4e2d\u95f4\u4f53\u6c22\u52a9\u89e3\u79bb\u3002\u7406\u8bba\u8ba1\u7b97\u8868\u660eFCC Ni\u6bd4HCP Ni\u5177\u6709\u66f4\u9ad8\u7684CO\u89e3\u79bb\u6d3b\u6027\u548c\u6d3b\u6027\u4f4d\u5bc6\u5ea6\u3002\u800c\u5728\u91d1\u5c5e\u94b4\u4e0a\uff0cHCP Co\u6bd4FCC Co\u5177\u6709\u66f4\u9ad8\u7684CO\u89e3\u79bb\u6d3b\u6027\u3002\u540c\u65f6\u5728HCP Co\u4e0a\uff0cCO\u76f4\u63a5\u6d3b\u5316\u6bd4\u8f83\u6709\u5229\uff0c\u800c\u5728FCC Co\u4e0a\uff0cCO\u9700\u8981\u6c22\u52a9\u6d3b\u5316\u3002\u91d1\u5c5eCo\u548cNi\u5177\u6709\u4e0d\u540c\u7684\u6676\u4f53\u7ed3\u6784\u654f\u611f\u6027\u548cCO\u6d3b\u5316\u673a\u7406\uff0c\u8fd9\u4e3b\u8981\u56e0\u4e3a\u53cd\u5e94\u4e2d\u95f4\u4f53\u7684\u5438\u9644\u5f3a\u5ea6\u4e0d\u540c\u5bfc\u81f4\u3002\u8fd9\u4e3a\u7406\u89e3\u548c\u8bbe\u8ba1\u9ad8\u6d3b\u6027\u91d1\u5c5e\u57fa\u5408\u6210\u6c14\u8f6c\u5316\u50ac\u5316\u5242\u63d0\u4f9b\u66f4\u591a\u7684\u7406\u8bba\u6307\u5bfc\u3002\uff08<strong><a href=\"http:\/\/pubs.acs.org\/doi\/full\/10.1021\/acs.jpcc.6b08742\" target=\"_blank\" rel=\"noopener\">J. Phys. Chem. C<\/a><\/strong>,\u00a02016,\u00a0<em>120<\/em>\u00a0(43), 24895\u201324903\uff09<\/p>\n<p><strong>4\u3001\u53cc\u7269\u76f8\u50ac\u5316\u5242\u8c03\u63a7\u50ac\u5316\u53cd\u5e94\u6d3b\u6027<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-118099\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/12\/4-53.jpg\" alt=\"\" width=\"600\" height=\"377\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/12\/4-53.jpg 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/12\/4-53-300x189.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>\u957f\u671f\u4ee5\u6765\u5408\u6210\u6c14\u9009\u62e9\u6027\u8f6c\u5316\u5230\u542b\u6c27\u5316\u7269\uff0c\u7528\u7684\u90fd\u662f\u4ef7\u683c\u6602\u8d35\u7684\u8d35\u91d1\u5c5e\uff0c\u800c\u78b3\u5316\u94b4\u957f\u671f\u4ee5\u6765\u88ab\u8ba4\u4e3a\u662f\u8d39\u6258\u53cd\u5e94\u7684\u975e\u6d3b\u6027\u76f8\u3002\u5218\u8fdb\u52cb\u535a\u58eb\u548c\u674e\u5fae\u96ea\u6559\u6388\u901a\u8fc7\u7406\u8bba\u8ba1\u7b97\uff0c\u53d1\u73b0\u78b3\u5316\u94b4\u5177\u6709\u5f88\u597d\u91d1\u5c5e\u6027\uff0c\u53ef\u5f88\u597d\u5730\u5438\u9644CO\uff0c\u4f46\u5374\u4e0d\u80fd\u89e3\u79bbCO\uff0c\u91d1\u5c5e\u94b4\u5177\u6709\u5f88\u597d\u5730\u89e3\u79bb\u4e00\u6c27\u5316\u78b3\u7684\u80fd\u529b\u3002\u56e0\u6b64\u7531\u91d1\u5c5e\u94b4\u548c\u78b3\u5316\u94b4\u5f62\u6210\u7684\u754c\u9762\uff0c\u53ef\u4ee5\u6709\u6548\u5730\u5f62\u6210\u542b\u6c27\u5316\u7269\uff0c\u76f8\u5e94\u7684\u8ba1\u7b97\u4e5f\u8bc1\u5b9e\u4e86\u8fd9\u4e00\u70b9\u3002\u8ba1\u7b97\u7ed3\u679c\u5f88\u597d\u5730\u89e3\u91ca\u4e86\u76f8\u5e94\u7684\u5b9e\u9a8c\u7814\u7a76\u7ed3\u679c\u3002\u7814\u7a76\u7ed3\u679c\u8868\u660e\uff0c\u53ef\u4ee5\u5229\u7528\u975e\u8d35\u91d1\u5c5e\u53ca\u5176\u78b3\u5316\u7269\u5f62\u6210\u7684\u7a33\u5b9a\u7684\u754c\u9762\uff0c\u6765\u5b9e\u73b0\u50ac\u5316\u53cd\u5e94\u9009\u62e9\u6027\u7684\u6709\u6548\u8c03\u63a7\uff0c\u66ff\u4ee3\u8d35\u91d1\u5c5e\uff0c\u6587\u7ae0\u53d1\u8868\u5728<strong><a href=\"http:\/\/pubs.acs.org\/doi\/full\/10.1021\/acscatal.5b00791\" target=\"_blank\" rel=\"noopener\">ACS Catal.<\/a><em>, <\/em><\/strong>2015, 5, 3620-3624<strong><em>.<\/em><\/strong>\u3002<\/p>\n<p><strong>5\u3001\u6676\u683c\u5931\u914d\u8c03\u63a7\u8d39\u6258\u5408\u6210\u53cd\u5e94\u6d3b\u6027<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-118096\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/12\/5-41.jpg\" alt=\"\" width=\"650\" height=\"364\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/12\/5-41.jpg 650w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/12\/5-41-300x168.jpg 300w\" sizes=\"(max-width: 650px) 100vw, 650px\" \/><\/p>\n<p>\u7164\u3001\u751f\u7269\u8d28\u3001\u9875\u5ca9\u6c14\u6765\u6e90\u7684\u5408\u6210\u6c14\uff0c\u7ecf\u8d39\u6258\u5408\u6210\u5236\u6db2\u4f53\u71c3\u6599\u662f\u7f13\u89e3\u76ee\u524d\u77f3\u6cb9\u8d44\u6e90\u77ed\u7f3a\u3001\u6ee1\u8db3\u80fd\u6e90\u9700\u6c42\u6025\u5267\u589e\u52a0\u7684\u91cd\u8981\u9014\u5f84\u3002\u94b4\u57fa\u50ac\u5316\u5242\u56e0\u5176\u8f83\u9ad8\u7684\u957f\u94fe\u70f7\u70c3\u9009\u62e9\u6027\u548c\u6d3b\u6027\u3001\u7a33\u5b9a\u6027\uff0c\u957f\u671f\u4ee5\u6765\u53d7\u5230\u5173\u6ce8\u3002\u8d39\u6258\u5408\u6210\u53cd\u5e94\u662f\u4e00\u4e2a\u4f4e\u6e29\u6709\u5229\u7684\u5f3a\u653e\u70ed\u53cd\u5e94\uff0c\u5bfb\u627e\u4f4e\u6e29\u3001\u9ad8\u6d3b\u6027\u7684\u94b4\u57fa\u50ac\u5316\u5242\u662f\u76ee\u524d\u7814\u7a76\u7684\u5173\u952e\u3002 \u5317\u4eac\u5927\u5b66\u9a6c\u4e01\u56e2\u961f\u53d1\u5c55\u4e86\u4e00\u6b65\u52a0\u6c22-\u8fd8\u539f\u65b9\u6cd5\uff0c\u5728Co\u50ac\u5316\u5242\u4e2d\u52a0\u5165\u6469\u5c14\u6bd4\u4e3a5%-10%\u7684\u8d35\u91d1\u5c5ePt\uff0c\u6210\u529f\u5730\u5408\u6210\u4e86Pt-Co\u53cc\u91d1\u5c5e\u7eb3\u7c73\u50ac\u5316\u5242\uff0c\u5728413-433K\u6e29\u5ea6\u4e0b\u5b9e\u73b0\u4e86\u9ad8\u6548\u6db2\u76f8\u8d39\u6258\u5408\u6210\uff1aCO\u8f6c\u5316\u7387\u8fbe\u52301 mol COmol Co-1 \u00b7 h-1, C<sub>2-5<\/sub>\u548cC<sub>5+<\/sub>\u9009\u62e9\u6027\u8fbe\u523017%\u548c70%\u3002\u800c\u5728\u5bf9\u7167\u5b9e\u9a8c\u4e2d\uff0c\u5206\u6b65\u8fd8\u539f\u7684Pt-Co\u53cc\u91d1\u5c5e\u50ac\u5316\u5242\u53ca\u7eafCo\u7eb3\u7c73\u50ac\u5316\u5242\u5728\u76f8\u540c\u6e29\u5ea6\u4e0bCO\u8f6c\u5316\u7387\u4ec5\u4e3a0.10 mol COmol Co<sup>-1<\/sup> \u00b7 h<sup>-1<\/sup>\u53ca0.09 mol COmol Co-1 \u00b7 h-1\u3002\u539f\u5b50\u5206\u8fa8\u7403\u5dee\u77eb\u6b63\u626b\u63cf\u900f\u5c04\u7535\u955c\u8868\u660e\uff0c Pt-Co\u53cc\u91d1\u5c5e\u50ac\u5316\u5242\u5b58\u5728\u591a\u79cd\u7ed3\u6784\u5206\u5e03\uff1b\u800c\u63a7\u5236\u5408\u6210\u5b9e\u9a8c\u6392\u9664\u4e86Co\u7eb3\u7c73\u7c92\u5b50\u8d1f\u8f7d\u7684\u5355\u539f\u5b50Pt\u4f5c\u4e3a\u50ac\u5316\u6d3b\u6027\u4e2d\u5fc3\u7684\u53ef\u80fd\u3002 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href=\"http:\/\/pubs.acs.org\/doi\/full\/10.1021\/ja400771a\" target=\"_blank\" rel=\"noopener\"><strong>J. Am. Chem. Soc.<\/strong><\/a>, 2013, 135 (10), 4149\u20134158)<\/p>\n<p>\u9274\u4e8e\u5218\u8fdb\u52cb\u535a\u58eb\u548c\u674e\u5fae\u96ea\u6559\u6388\u5728\u6676\u76f8\u8c03\u63a7\u50ac\u5316\u65b9\u9762\u7684\u5de5\u4f5c\uff0c\u53d7\u9080\u5728<strong><a href=\"http:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/wcms.1267\/full\" target=\"_blank\" rel=\"noopener\">WIREs: Comput. Mol. Sci.<\/a><\/strong>\u548c<strong><a href=\"https:\/\/www.sciencedirect.com\/science\/article\/pii\/S2095809917306069\" target=\"_blank\" rel=\"noopener\">Engineering<\/a><\/strong>\u6742\u5fd7\u4e0a\u53d1\u8868\u7efc\u8ff0\u6587\u7ae0\u3002<\/p>\n<p>\u3010\u56e2\u961f\u4ecb\u7ecd\u3011<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-118097 size-thumbnail\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/12\/6-21-150x150.jpg\" alt=\"\" width=\"150\" height=\"150\" \/><\/p>\n<p>\u4e2d\u56fd\u79d1\u6280\u5927\u5b66\u674e\u5fae\u96ea\u6559\u6388, \u4e3b\u8981\u4ece\u4e8b\u7eb3\u7c73\u50ac\u5316\u53ca\u591a\u76f8\u50ac\u5316\u53cd\u5e94\u7406\u8bba\u7814\u7a76\uff0c\u4ece\u5fae\u89c2\u7684\u7eb3\u7c73\u548c\u539f\u5b50\u5c3a\u5ea6\u4e0a\uff0c\u4ee5\u57fa\u4e8e\u91cf\u5b50\u529b\u5b66\u7684\u5bc6\u5ea6\u6cdb\u6db5\u7406\u8bba\u548c\u5927\u89c4\u6a21\u5e76\u884c\u8ba1\u7b97\u4e3a\u624b\u6bb5\u7814\u7a76\uff1a<br \/>\n (1) 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class=\"aligncenter wp-image-118098 size-thumbnail\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/12\/7-16-150x150.jpg\" alt=\"\" width=\"150\" height=\"150\" \/><\/p>\n<p>\u5218\u8fdb\u52cb\u535a\u58eb\uff0c2015\u5e74\u6bd5\u4e1a\u4e8e\u4e2d\u79d1\u9662\u5927\u8fde\u5316\u5b66\u7269\u7406\u7814\u7a76\u6240\uff0c\u5e08\u4ece\u674e\u5fae\u96ea\u6559\u6388\uff0c\u7406\u8bba\u50ac\u5316\u4e13\u4e1a\u3002\u6bd5\u4e1a\u81f3\u4eca\uff0c\u5728\u8377\u5170\u57c3\u56e0\u970d\u6e29\u7406\u5de5\u5927\u5b66\u8fdb\u884c\u50ac\u5316\u6750\u6599\u7ed3\u6784\u7ed3\u6784\u654f\u611f\u6027\u548c\u50ac\u5316\u53cd\u5e94\u673a\u7406\u7684\u7406\u8bba\u8ba1\u7b97\u7814\u7a76\u3002\u5df2\u5728JACS\uff084\u7bc7\uff09, Angewandte Chemie, Nano Energy, ACS 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