{"id":117899,"date":"2018-01-19T06:30:09","date_gmt":"2018-01-18T22:30:09","guid":{"rendered":"\/\/m.iemloyee.com\/?p=117899"},"modified":"2018-01-18T21:16:55","modified_gmt":"2018-01-18T13:16:55","slug":"__trashed-6","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=117899","title":{"rendered":"\u4e2d\u79d1\u9662\u7269\u7406\u6240\u79b9\u4e60\u8c26&#038;\u80e1\u52c7\u80dcJoule\uff1a \u94a0\u79bb\u5b50\u7535\u6c60\u6b63\u6781\u53ef\u9006\u6c27\u53d8\u4ef7\u673a\u7406"},"content":{"rendered":"<p><span style=\"color: #33cccc;\"><strong>\u3010\u5f15\u8a00\u3011<\/strong><\/span><\/p>\n<p>\u5d4c\u5165\u578b\u8fc7\u6e21\u91d1\u5c5e\u5c42\u72b6\u6c27\u5316\u7269\uff08AMO<sub>2<\/sub>, A=Li<sup>+<\/sup>\u6216 Na<sup>+<\/sup>, M=\u8fc7\u6e21\u91d1\u5c5e\uff09\u662f\u91cd\u8981\u7684\u9502\u79bb\u5b50\/\u94a0\u79bb\u5b50\u7535\u6c60\u6b63\u6781\u6750\u6599\u3002\u5728\u4f20\u7edf\u89c2\u5ff5\u4e2d\uff0c\u8fc7\u6e21\u91d1\u5c5e\u7684\u6c27\u5316\u8fd8\u539f\u53cd\u5e94\u63d0\u4f9b\u4e86\u79bb\u5b50\u8131\u5d4c\u5165\u6750\u6599\u8fc7\u7a0b\u4e2d\u7684\u7535\u8377\u8865\u507f\uff0c\u56e0\u6b64\u6b63\u6781\u6750\u6599\u7684\u5bb9\u91cf\u53d7\u9650\u4e8e\u5c42\u72b6\u6c27\u5316\u7269\u6750\u6599\u4e2d\u8fc7\u6e21\u91d1\u5c5e\u7684\u6c27\u5316\u8fd8\u539f\u80fd\u529b\u3002\u7136\u800c\u8fd9\u4e00\u4f20\u7edf\u89c2\u5ff5\u968f\u7740\u9502\u79bb\u5b50\u7535\u6c60\u5bcc\u9502\u5c42\u72b6\u6c27\u5316\u7269\u6b63\u6781\u6750\u6599\uff08O3\u7ed3\u6784Li[Li<sub>x<\/sub>M1-x]O<sub>2<\/sub>\uff09\u7684\u53d1\u73b0\u800c\u53d7\u5230\u6311\u6218\u3002\u5bcc\u9502\u6750\u6599\u5177\u6709\u8d85\u9ad8\u53ef\u9006\u6bd4\u5bb9\u91cf\uff08300mAh\/g\uff09\uff0c\u4f46\u662f\u8be5\u5bb9\u91cf\u6765\u6e90\u5df2\u7ecf\u4e0d\u80fd\u4ec5\u7528\u8fc7\u6e21\u91d1\u5c5e\u6c27\u5316\u8fd8\u539f\u6765\u89e3\u91ca\u3002\u5927\u91cf\u7814\u7a76\u5de5\u4f5c\u8868\u660e\uff0c\u5bcc\u9502\u5c42\u72b6\u6750\u6599\u4e2d\u7684\u6676\u683c\u6c27\u53c2\u4e0e\u4e86\u5f97\u5931\u7535\u5b50\u8fc7\u7a0b\uff0c\u4ece\u800c\u63d0\u4f9b\u989d\u5916\u5bb9\u91cf\u3002\u5b9e\u9645\u4e0a\uff0c\u4e0d\u4ec5\u4ec5\u662f\u5bcc\u9502\u6750\u6599\uff0c<strong>\u8bb8\u591a\u5c42\u72b6\u6c27\u5316\u7269\u6750\u6599\u90fd\u53ef\u4ee5\u5b9e\u73b0\u6c27\u53c2\u4e0e\u7535\u8377\u8865\u507f\u63d0\u4f9b\u989d\u5916\u5bb9\u91cf\u7684\u7535\u5316\u5b66\u8fc7\u7a0b\u3002\u4f46\u662f\u6676\u683c\u6c27\u5982\u4f55\u53c2\u4e0e\u7535\u8377\u8865\u507f\u3001\u5982\u4f55\u5b9e\u73b0\u53ef\u9006\u7684\u6c27\u53d8\u4ef7\u4e00\u76f4\u662f\u754c\u5185\u4e89\u8bba\u7684\u70ed\u70b9<\/strong>\uff0c<span style=\"color: #000080;\"><strong>\u800c\u9610\u660e\u6676\u4f53\u7ed3\u6784\u4e0e\u6c27\u79bb\u5b50\u53d8\u4ef7\u8fc7\u7a0b\u7684\u5173\u7cfb\u66f4\u662f\u89e3\u91ca\u5176\u53cd\u5e94\u673a\u5236\u7684\u5173\u952e<\/strong>\u3002<\/span><\/p>\n<p><span style=\"color: #33cccc;\"><strong>\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/span><\/p>\n<p><span style=\"color: #000000;\">\u8fd1\u65e5\uff0c<\/span><strong><span style=\"color: #000000;\">\u4e2d\u56fd\u79d1\u5b66\u9662<\/span>\u7269\u7406\u7814\u7a76\u6240\u79b9\u4e60\u8c26\u526f\u7814\u7a76\u5458<\/strong>\u548c<strong>\u80e1\u52c7\u80dc\u7814\u7a76\u5458<\/strong>\u7b49\u5728Cell Press\u65d7\u4e0b\u7684\u80fd\u6e90\u9886\u57df\u65b0\u65d7\u8230\u671f\u520a\u00a0<strong>Joule<\/strong>\u4e0a\u53d1\u8868\u6700\u65b0\u7814\u7a76\u6210\u679c\u201c<strong>Structure-Induced Reversible Anionic Redox Activity in Na Layered Oxide Cathode<\/strong>\u201d\u3002\u7814\u7a76\u8005\u4e0e\u7f8e\u56fd\u6a61\u6811\u5cad\u56fd\u5bb6\u5b9e\u9a8c\u5ba4\u3001\u5e03\u9c81\u514b\u6d77\u6587\u56fd\u5bb6\u5b9e\u9a8c\u5ba4\u3001\u52b3\u4f26\u65af\u4f2f\u514b\u5229\u56fd\u5bb6\u5b9e\u9a8c\u5ba4\u3001\u65af\u5766\u798f\u76f4\u7ebf\u52a0\u901f\u5668\u4e2d\u5fc3\u7b49\u5355\u4f4d\u7814\u7a76\u5de5\u4f5c\u8005\u5408\u4f5c\uff0c\u901a\u8fc7\u4e2d\u5b50\u6563\u5c04\u3001\u540c\u6b65\u8f90\u5c04\u6280\u672f\u7b49\u5148\u8fdb\u8868\u5f81\u624b\u6bb5\u7ec6\u81f4\u7814\u7a76\u4e86\u4ec5\u7531\u6c27\u79bb\u5b50\u53c2\u4e0e\u6c27\u5316\u8fd8\u539f\u53cd\u5e94\u4e14\u9ad8\u5ea6\u53ef\u9006\u7684P3-Na<sub>0.6<\/sub>[Li<sub>0.2<\/sub>Mn<sub>0.8<\/sub>]O<sub>2<\/sub>\u94a0\u79bb\u5b50\u7535\u6c60\u6b63\u6781\u6750\u6599\u7684\u50a8\u94a0\u673a\u7406\uff0c\u9610\u660e\u4e86\u8be5\u6750\u6599\u5b9e\u73b0\u53ef\u9006\u6c27\u53d8\u4ef7\u7684\u7ed3\u6784\u539f\u56e0\u3002<\/p>\n<p><span style=\"color: #33cccc;\"><strong>\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/span><\/p>\n<p><span style=\"color: #33cccc;\"><strong>\u56fe1 P3-Na<sub>0.6<\/sub>[Li<sub>0.2<\/sub>Mn<sub>0.8<\/sub>]O<sub>2<\/sub>\u7535\u5316\u5b66\u6027\u80fd<\/strong><\/span><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-117906\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/12\/1-63.jpg\" alt=\"\" width=\"658\" height=\"246\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/12\/1-63.jpg 658w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/12\/1-63-300x112.jpg 300w\" sizes=\"(max-width: 658px) 100vw, 658px\" \/><\/p>\n<p>(a) 0.1 C\u548c2.0 C\u500d\u7387\u4e0b\u7684\u5178\u578b\u5145\u653e\u7535\u66f2\u7ebf\uff1b<br \/>\n (b) 0.1 C\u548c2.0 C\u500d\u7387\u4e0b\u7684\u5faa\u73af\u6027\u80fd\u3002<\/p>\n<p><span style=\"color: #33cccc;\"><strong>\u56fe2 P3-Na<sub>0.6<\/sub>[Li<sub>0.2<\/sub>Mn<sub>0.8<\/sub>]O<sub>2<\/sub>\u521d\u59cb\u6001\u548c\u5145\u7535\u6001nPDF\u53caxPDF\u5bf9\u6bd4\u5206\u6790<\/strong><\/span><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-117907\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/12\/2-54.jpg\" alt=\"\" width=\"658\" height=\"316\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/12\/2-54.jpg 658w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/12\/2-54-300x144.jpg 300w\" sizes=\"(max-width: 658px) 100vw, 658px\" \/><\/p>\n<p>\u7814\u7a76\u56e2\u961f\u501f\u52a9\u4e2d\u5b50\u5bf9\u5206\u5e03\u51fd\u6570\u5b9e\u9a8c\u6280\u672f\uff08neutron pair distribution function, nPDF\uff09\u5e76\u7ed3\u5408X\u5c04\u7ebf\u4e0e\u4e2d\u5b50\u884d\u5c04\u6280\u672f\uff0c\u7814\u7a76\u4e86\u8be5P3\u6b63\u6781\u6c27\u5316\u7269\u6750\u6599\u4e2d\u6c27\u53c2\u4e0e\u7535\u5316\u5b66\u53cd\u5e94\u524d\u540e\u7684\u6676\u4f53\u7ed3\u6784\u4ee5\u53ca\u4e0e\u6c27\u6709\u5173\u7684\u77ed\u7a0b\u7ed3\u6784\u53d8\u5316\uff0c\u8bc1\u5b9e\u4e86\u7531\u6c27\u53ef\u9006\u53d8\u4ef7\u5bfc\u81f4\u7684\u6750\u6599\u53ef\u9006\u4f53\u76f8\u7ed3\u6784\u53d8\u5316\u3002<span style=\"color: #333399;\"><span style=\"color: #000080;\"><strong>\u8be5\u7814\u7a76\u65b9\u6cd5\u7528\u4e8e\u7814\u7a76\u6c27\u7535\u8377\u8865\u507f\u76f8\u5173\u7684\u6676\u4f53\u7ed3\u6784\u53d8\u5316\u5c5e\u9996\u6b21<\/strong><\/span>\u3002<\/span><\/p>\n<p><span style=\"color: #33cccc;\"><strong>\u56fe3 \u57fa\u4e8e\u4e2d\u5b50\u884d\u5c04\u7cbe\u4fee\u7ed3\u679c\u7684\u5145\u7535\u6001\u7ed3\u6784\u89e3\u6790<\/strong><\/span><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-117908\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/12\/3-59.jpg\" alt=\"\" width=\"499\" height=\"663\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/12\/3-59.jpg 499w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/12\/3-59-226x300.jpg 226w\" sizes=\"(max-width: 499px) 100vw, 499px\" \/><\/p>\n<p>\u4e2d\u5b50\u7c89\u672b\u884d\u5c04\u7cbe\u4fee\u7ed3\u679c\u8868\u660e\uff0c\u5145\u7535\u540e\u7684\u6750\u6599\u7ed3\u6784\u4ecd\u4e3aP\u76f8\u5c42\u72b6\u7ed3\u6784\uff0c\u4f46\u662f\u4f34\u968f\u6709\u5927\u91cf\u7684\u5806\u53e0\u5c42\u9519\u7684\u51fa\u73b0\u3002\u7cbe\u4fee\u540e\u5f97\u5230\u7684\u6c27\u5360\u4f4d\u4ecd\u4e3a1\uff0c\u8bc1\u660e\u5728\u5145\u7535\u540e\u51e0\u4e4e\u6ca1\u6709\u6676\u683c\u6c27\u7684\u635f\u5931\u3002\u901a\u8fc7\u5206\u6790\u4ee5\u4e0a\u7ed3\u679c\u53d1\u73b0\uff0c<span style=\"color: #000080;\"><strong>\u8be5\u6750\u6599\u7684\u6676\u4f53\u7ed3\u6784\u7279\u70b9\u5bf9\u5176\u53ef\u9006\u6c27\u53d8\u4ef7\u884c\u4e3a\u6709\u7740\u5173\u952e\u8c03\u63a7\u4f5c\u7528<\/strong><\/span>\uff1aP\u7ed3\u6784\u5177\u6709\u8f83\u5927\u7684\u5c42\u95f4\u8ddd\uff08\u76f8\u5bf9O3\u76f8\uff09\uff0c\u80fd\u591f\u5bb9\u5fcdO-O\u952e\u957f\u53d8\u5316\u5e26\u6765\u7684\u6676\u683c\u7578\u53d8\uff1b\u540c\u65f6\u8f83\u5927\u7684\u5c42\u95f4\u8ddd\u80fd\u6709\u6548\u6291\u5236\u5145\u7535\u8fc7\u7a0b\u4e2d\u9633\u79bb\u5b50\u5411\u78b1\u91d1\u5c5e\u5c42\u8fc1\u79fb\uff08\u5bcc\u9502\u6750\u6599\u4e2d\u53d1\u751f\u7684\u5c42\u72b6\u5411\u5c16\u6676\u77f3\u7ed3\u6784\u76f8\u53d8\uff09\uff0c\u4fdd\u6301\u7a33\u5b9a\u7684\u5c42\u72b6\u7ed3\u6784\uff0c\u4ece\u800c\u4f7f\u5f97\u6c27\u79bb\u5b50\u7684\u6c27\u5316\u8fd8\u539f\u53cd\u5e94\u53ef\u9006\u3002<\/p>\n<p><span style=\"color: #33cccc;\"><strong>\u3010\u5c0f\u7ed3\u3011<\/strong><\/span><\/p>\n<p>\u8be5\u7814\u7a76\u4ece\u6750\u6599\u7ed3\u6784\u7684\u89d2\u5ea6\u9610\u660e\u4e86\u53ef\u5b9e\u73b0\u6c27\u79bb\u5b50\u53ef\u9006\u6c27\u5316\u8fd8\u539f\u53cd\u5e94\u7684\u673a\u7406\uff0c\u4e3a\u8bbe\u8ba1\u5177\u6709\u7a33\u5b9a\u53ef\u9006\u6c27\u53d8\u4ef7\u884c\u4e3a\u7684\u9ad8\u7535\u538b\u3001\u9ad8\u5bb9\u91cf\u9502\/\u94a0\u79bb\u5b50\u6b63\u6781\u6750\u6599\u63d0\u4f9b\u4e86\u65b0\u7684\u601d\u8def\uff1b\u540c\u65f6\u4e5f\u4e3a\u8be5\u7c7b\u7814\u7a76\u5f15\u5165\u4e86\u4e2d\u5b50\u5bf9\u5206\u5e03\u51fd\u6570\uff08nPDF\uff09\u8fd9\u4e00\u6709\u529b\u5de5\u5177\uff0c\u62d3\u5bbd\u4e86\u7814\u7a76\u7ef4\u5ea6\u3002<br \/>\n \u8be5\u7814\u7a76\u5de5\u4f5c\u5f97\u5230\u4e86\u79d1\u6280\u90e8973\u9879\u76ee\uff082014CB932300\uff09\u3001\u56fd\u5bb6\u6770\u51fa\u9752\u5e74\u79d1\u5b66\u57fa\u91d1\uff0851725206\uff09\u3001\u56fd\u5bb6\u81ea\u7136\u79d1\u5b66\u57fa\u91d1\u521b\u65b0\u7814\u7a76\u7fa4\u4f53\uff0851421002\uff09\u4ee5\u53ca\u4e2d\u79d1\u9662\u767e\u4eba\u8ba1\u5212\u7b49\u9879\u76ee\u7684\u652f\u6301\u3002<\/p>\n<p>\u6587\u7ae0\u94fe\u63a5\uff1a<a href=\"https:\/\/www.sciencedirect.com\/science\/article\/pii\/S2542435117301320\" target=\"_blank\" rel=\"noopener\">Structure-Induced Reversible Anionic Redox Activity in Na Layered Oxide Cathode\u00a0<\/a>(X. Rong, X. Yu*, Y.-S. Hu* et al, <strong>Joule<\/strong>, 2018, 2, 125\u2013140).<\/p>\n<p>\u672c\u6587\u7531\u4f5c\u8005\u4e2d\u79d1\u9662\u7269\u7406\u6240\u5bb9\u6653\u6656\u63d0\u4f9b\u3002<\/p>\n<p>\u6750\u6599\u725b\u7f51\u4e13\u6ce8\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u53ca\u884c\u4e1a\u8fdb\u5c55\uff0c\u8fd9\u91cc\u6c47\u96c6\u4e86\u5404\u5927\u9ad8\u6821\u7855\u535a\u751f\u3001\u4e00\u7ebf\u79d1\u7814\u4eba\u5458\u4ee5\u53ca\u884c\u4e1a\u4ece\u4e1a\u8005\uff0c\u5982\u679c\u60a8\u5bf9\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u8fdb\u5c55\uff0c\u89e3\u8bfb\u9ad8\u6c34\u5e73\u6587\u7ae0\u6216\u662f\u8bc4\u8ff0\u884c\u4e1a\u6709\u5174\u8da3\uff0c<a href=\"\/\/m.iemloyee.com\/25127.html\" target=\"_blank\" rel=\"noopener\">\u70b9\u6211\u52a0\u5165\u7f16\u8f91\u90e8\u5927\u5bb6\u5ead<\/a>\u3002<\/p>\n<p>\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1tougao@cailiaoren.com\u3002<\/p>\n<p><strong><b>\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1aRDD-2011-CHERISH\uff0c\u4efb\u4e39\u4e39\uff0c\u6211\u4eec\u4f1a\u9080\u8bf7\u5404\u4f4d\u8001\u5e08\u52a0\u5165\u4e13\u5bb6\u7fa4\u3002<\/b><\/strong><\/p>\n<p><strong><b>\u6750\u6599\u6d4b\u8bd5\u3001\u6570\u636e\u5206\u6790\uff0c<\/b><\/strong><strong><b>\u4e0a<\/b><\/strong><a href=\"http:\/\/www.ceshigu.com\/\" target=\"_blank\" rel=\"noopener\"><strong><b>\u6d4b\u8bd5\u8c37<\/b><\/strong><\/a><strong><b>\uff01<\/b><\/strong><\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u3010\u5f15\u8a00\u3011 \u5d4c\u5165\u578b\u8fc7\u6e21\u91d1\u5c5e\u5c42\u72b6\u6c27\u5316\u7269\uff08AMO2, A=Li+\u6216 Na+, M=\u8fc7\u6e21\u91d1\u5c5e\uff09\u662f\u91cd\u8981\u7684\u9502\u79bb\u5b50\/\u94a0\u79bb\u5b50\u7535\u6c60\u6b63\u6781\u6750\u6599\u3002\u5728\u4f20\u7edf\u89c2\u5ff5\u4e2d\uff0c\u8fc7\u6e21\u91d1\u5c5e\u7684\u6c27\u5316\u8fd8\u539f\u53cd\u5e94\u63d0&#8230;<\/p>\n","protected":false},"author":82,"featured_media":117907,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215,2],"tags":[18,129],"class_list":["post-117899","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-jiedu","category-keji","tag-xinnengyuan","tag-battery"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/117899"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/82"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=117899"}],"version-history":[{"count":12,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/117899\/revisions"}],"predecessor-version":[{"id":122225,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/117899\/revisions\/122225"}],"wp:featuredmedia":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/media\/117907"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=117899"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=117899"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=117899"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}