{"id":117228,"date":"2017-12-15T14:00:19","date_gmt":"2017-12-15T06:00:19","guid":{"rendered":"\/\/m.iemloyee.com\/?p=117228"},"modified":"2017-12-15T12:14:15","modified_gmt":"2017-12-15T04:14:15","slug":"%e7%a6%8f%e5%bb%ba%e7%89%a9%e6%9e%84%e6%89%80%ef%bc%9a%e5%af%bc%e7%94%b5mof%e8%96%84%e8%86%9c%e5%99%a8%e4%bb%b6%e7%a0%94%e7%a9%b6%e8%8e%b7%e8%bf%9b%e5%b1%95","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=117228","title":{"rendered":"\u798f\u5efa\u7269\u6784\u6240\uff1a\u5bfc\u7535MOF\u8584\u819c\u5668\u4ef6\u7814\u7a76\u83b7\u8fdb\u5c55"},"content":{"rendered":"<p><strong><b>\u3010<\/b><\/strong><strong><b>\u6210\u679c\u7b80\u4ecb<\/b><\/strong><strong><b>\u3011<\/b><\/strong><\/p>\n<p>\u5728\u56fd\u5bb6\u81ea\u7136\u79d1\u5b66\u57fa\u91d1\u3001\u4e2d\u56fd\u79d1\u5b66\u9662\u79d1\u7814\u88c5\u5907\u7814\u5236\u9879\u76ee\u548c\u4e2d\u79d1\u9662\u524d\u6cbf\u79d1\u5b66\u91cd\u70b9\u9879\u76ee\u7b49\u7684\u8d44\u52a9\u4e0b\uff0c\u4e2d\u79d1\u9662\u798f\u5efa\u7269\u8d28\u7ed3\u6784\u7814\u7a76\u6240\u7ed3\u6784\u5316\u5b66\u56fd\u5bb6\u91cd\u70b9\u5b9e\u9a8c\u5ba4\u7814\u7a76\u5458\u5f90\u521a\u9886\u5bfc\u7684\u8bfe\u9898\u7ec4\uff0c\u5728\u8584\u800c\u53ef\u63a7\u3001\u597d\u4e14\u8010\u7528\u7684EC-MOFs\u8584\u819c\u4e0e\u5668\u4ef6\u7814\u7a76\u65b9\u9762\u53d6\u5f97\u8fdb\u5c55\u3002\u8be5\u8bfe\u9898\u7ec4\u52a9\u7406\u7814\u7a76\u5458\u59da\u660e\u6c34\u4e0e\u7855\u58eb\u751f\u5415\u5c0f\u6676\u91c7\u7528LbL\u55b7\u96fe\u6cd5\uff0c\u9996\u6b21\u5236\u5907\u539a\u5ea6\u548c\u8d28\u91cf\u5728\u7eb3\u7c73\u5c3a\u5ea6\u4e0a\u5c42\u5c42\u53ef\u63a7\u7684EC-MOFs\u8584\u819c\u3002EC-MOFs\u8584\u819c\u751f\u957f\u57fa\u4e8e\u4e00\u7c7b\u5316\u5b66\u7a33\u5b9a\u6027\u826f\u597d\u7684\u516d\u65b9\u6676\u7cfbEC-MOFs\u6750\u6599Cu<sub>3<\/sub>(HHTP)<sub>2<\/sub>\uff08HHTP=2,3,6,7,10,11-\u516d\u7f9f\u57fa\u4e09\u4e9a\u82ef\uff09\uff0c\u8be5\u6750\u6599\u5728ab\u65b9\u5411\u4e0a\u5f62\u6210Cu-HHTP\u4e8c\u7ef4\u5bfc\u7535\u7ed3\u6784\uff0c\u6cbfc\u8f74\u65b9\u5411\u6309\u8f7b\u5fae\u6ed1\u79fb\u7684ABAB\u6a21\u5f0f\u5806\u579b\u800c\u6210\u8702\u7a9d\u72b6\u5fae\u5b54\u7ed3\u6784\uff0c\u8584\u819c\u5ba4\u6e29\u7535\u5bfc\u7387\u53ef\u8fbe2 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Assembled Conductive Metal-Organic Framework Nanofilms for Room-Temperature Chemiresistive Sensing\u201d\u53d1\u8868\u5728Angew.Chem.Int.Ed\u4e0a\uff0c\u5e76\u9009\u4e3a\u5f53\u671f\u5185\u5c01\u9762\u3002\u7814\u7a76\u5de5\u4f5c\u5f97\u5230\u5b54\u9053\u3001\u7eb3\u7c73\u4eba\u548c\u7814\u4e4b\u6210\u7406\u7b49\u5b66\u672f\u5e73\u53f0\u7684\u5173\u6ce8\u548c\u62a5\u9053\u3002<\/p>\n<p><strong><b>\u3010<\/b><\/strong><strong><b>\u56fe\u6587\u5bfc\u8bfb<\/b><\/strong><strong><b>\u3011<\/b><\/strong><\/p>\n<p><strong><b>\u56fe<\/b><\/strong><strong><b>1 \u5bfc\u7535MOF\u8584\u819c\u5668\u4ef6\u00a0<\/b><\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-117229\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/12\/1-16.png\" alt=\"\" width=\"600\" height=\"430\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/12\/1-16.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/12\/1-16-300x215.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p><strong><b>\u56fe2 <\/b><\/strong><strong><b>\u6027\u80fd\u8868\u5f81<\/b><\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-117230\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/12\/2.jpeg\" alt=\"\" width=\"600\" height=\"640\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/12\/2.jpeg 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/12\/2-281x300.jpeg 281w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p><strong><b>\u3010\u7814\u7a76\u5185\u5bb9\u3011<\/b><\/strong><\/p>\n<p>\u7535\u5b50\u5bfc\u7535\u91d1\u5c5e\u6709\u673a\u6846\u67b6\uff08Electronic Conductive Metal-Organic Frameworks\uff0cEC-MOFs\uff09\u6750\u6599\u662f\u4e00\u7c7b\u65b0\u5174\u7684\u7531\u91d1\u5c5e\u79bb\u5b50\u6216\u91d1\u5c5e\u79bb\u5b50\u7c07\u548c\u6709\u673a\u914d\u4f53\u901a\u8fc7\u914d\u4f4d\u952e\u81ea\u7ec4\u88c5\u5f62\u6210\u7684\u5bfc\u7535\u591a\u5b54\u6676\u6001\u6750\u6599\uff0c\u662f\u65b0\u51fa\u73b0\u7684\u4e00\u7c7b\u96c6\u591a\u5b54\u6027\u3001\u9009\u62e9\u6027\u4e0e\u534a\u5bfc\u4f53\u7279\u6027\u4e8e\u4e00\u4f53\u7684\u6676\u4f53\u6750\u6599\u3002\u56e0\u5176\u4e30\u5bcc\u53ef\u8bbe\u8ba1\u7684\u6676\u4f53\u7ed3\u6784\u548c\u53ef\u8c03\u8282\u7684\u7535\u5b50\u80fd\u5e26\u7ed3\u6784\u7b49\u4f18\u52bf\uff0c\u4f7fEC-MOFs\u6750\u6599\u4f5c\u4e3a\u6d3b\u6027\u529f\u80fd\u7ec4\u5206\u5728\u65b0\u578b\u7684\u573a\u6548\u5e94\u6676\u4f53\u7ba1\u3001\u9502\u7535\u6c60\u3001\u8d85\u7ea7\u7535\u5bb9\u5668\u3001\u6c14\u654f\u4f20\u611f\u5668\u7b49\u534a\u5bfc\u4f53\u7535\u5b66\u5668\u4ef6\u9886\u57df\u5177\u6709\u5f88\u9ad8\u7684\u7814\u7a76\u4ef7\u503c\u548c\u5e94\u7528\u6f5c\u529b\u3002\u7136\u800c\uff0c\u5df2\u62a5\u9053\u7684EC-MOFs\u6750\u6599\u7684\u5e94\u7528\u5927\u90e8\u5206\u91c7\u7528\u7c89\u672b\u6216\u539a\u819c\u5f62\u5f0f\uff0c\u5de8\u5927\u7684\u9897\u7c92\u5c3a\u5bf8\u548c\u6676\u754c\u9650\u5236\u4e86\u7535\u5b66\u5668\u4ef6\u4e2d\u7684\u7535\u5b50\u548c\u7269\u8d28\u4f20\u8f93\u3002\u4f17\u6240\u5468\u77e5\uff0c\u8584\u819c\u7684\u8d28\u91cf\u662f\u9ad8\u6027\u80fd\u7684\u5668\u4ef6\u7684\u91cd\u8981\u51b3\u5b9a\u56e0\u7d20\u4e4b\u4e00\u3002\u5c42\u5c42\u81ea\u7ec4\u88c5\uff08layer-by-layer\uff0cLbL\uff09\u6db2\u76f8\u5916\u5ef6\u7684\u65b9\u6cd5\u662f\u4e00\u79cd\u6709\u6548\u5236\u5907\u539a\u5ea6\u53ef\u63a7\u3001\u540c\u8d28\u5747\u4e00MOFs\u8584\u819c\u7684\u65b9\u6cd5\u3002\u7136\u800c\uff0c\u4ec5\u6709\u90e8\u5206\u5177\u5907\u7279\u6b8a\u7684\u6b21\u7ea7\u7ed3\u6784\uff08second building units\uff0cSBU\uff09\u7684MOFs\u80fd\u91c7\u7528LbL\u6cd5\u5236\u5907\u8584\u819c\u3002\u5c06LbL\u6cd5\u5e94\u7528\u4e8eEC-MOFs\u5bfc\u7535\u8584\u819c\u7684\u53ef\u63a7\u5916\u5ef6\u751f\u957f\u8fc4\u4eca\u5e76\u65e0\u76f8\u5173\u62a5\u9053\u3002<\/p>\n<p>\u539f\u6587\u94fe\u63a5\uff1a<a href=\"http:\/\/www.cas.cn\/syky\/201712\/t20171212_4626732.shtml\" target=\"_blank\" rel=\"noopener\">http:\/\/www.cas.cn\/syky\/201712\/t20171212_4626732.shtml<\/a><\/p>\n<p>\u6587\u732e\u94fe\u63a5\uff1a<a href=\"http:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/anie.201709558\/abstract\" target=\"_blank\" rel=\"noopener\">Layer-by-Layer Assembled Conductive Metal-Organic Framework Nanofilms for Room-Temperature Chemiresistive Sensing <\/a>(Angew.Chem.Int.Ed., 2017, DOI:10.1002\/anie.201709558)<\/p>\n<p>\u672c\u6587\u7531\u6750\u6599\u4eba\u7f16\u8f91\u90e8\u77f3\u5c0f\u6885\u7f16\u8f91\uff0c<a href=\"\/\/m.iemloyee.com\/25127.html\" target=\"_blank\" rel=\"noopener\">\u70b9\u6211\u52a0\u5165\u6750\u6599\u4eba\u7f16\u8f91\u90e8<\/a>\u3002<\/p>\n<p>\u6750\u6599\u6d4b\u8bd5\uff0c\u6570\u636e\u5206\u6790\uff0c\u4e0a<a href=\"http:\/\/www.ceshigu.com\/\" target=\"_blank\" rel=\"noopener\">\u6d4b\u8bd5\u8c37<\/a>\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u3010\u6210\u679c\u7b80\u4ecb\u3011 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