{"id":116456,"date":"2017-12-14T06:30:53","date_gmt":"2017-12-13T22:30:53","guid":{"rendered":"\/\/m.iemloyee.com\/?p=116456"},"modified":"2017-12-11T12:44:28","modified_gmt":"2017-12-11T04:44:28","slug":"%e5%b4%94%e5%85%89%e7%a3%8a%e5%9b%a2%e9%98%9fadv-energy-mater-%ef%bc%9a%e7%94%b5%e8%a7%a3%e6%b6%b2%e6%b7%bb%e5%8a%a0%e5%89%82%e8%81%94%e7%94%a8%e7%ad%96%e7%95%a5%e6%8f%90%e5%8d%875v%e9%ab%98%e7%94%b5","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=116456","title":{"rendered":"\u5d14\u5149\u78ca\u56e2\u961fAdv. Energy Mater.\uff1a\u7535\u89e3\u6db2\u6dfb\u52a0\u5242\u8054\u7528\u7b56\u7565\u63d0\u53475V\u9ad8\u7535\u538b\u9502\u79bb\u5b50\u7535\u6c60\u7684\u5faa\u73af\u7a33\u5b9a\u6027\u3001\u500d\u7387\u6027\u80fd\u548c\u963b\u71c3\u6027"},"content":{"rendered":"<p><strong>\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n<p>\u57fa\u4e8e\u9ad8\u7535\u538b\u6b63\u6781\u6750\u6599\u7684\u9ad8\u7535\u538b\u9502\u79bb\u5b50\u7535\u6c60\u4e00\u76f4\u662f\u53d1\u5c55\u9ad8\u80fd\u91cf\u5bc6\u5ea6\u3001\u9ad8\u529f\u7387\u5bc6\u5ea6\u9502\u79bb\u5b50\u7535\u6c60\u7684\u4e00\u4e2a\u91cd\u8981\u7814\u7a76\u65b9\u5411\u3002\u4f5c\u4e3a\u4e00\u79cd\u9887\u5177\u7ade\u4e89\u529b\u7684\u9ad8\u7535\u538b\u6b63\u6781\u6750\u6599\uff0c\u5c16\u6676\u77f3\u7ed3\u6784\u7684LiNi<sub>0.5<\/sub>Mn<sub>1.5<\/sub>O<sub>4<\/sub>\u5177\u6709\u9ad8\u7684\u5de5\u4f5c\u7535\u538b\u5e73\u53f0\uff084.7 V vs. Li\/Li<sup>+<\/sup>\uff09\u548c\u9ad8\u7684\u7406\u8bba\u6bd4\u5bb9\u91cf\uff08148 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LiPF<sub>6<\/sub>\u7684\u78b3\u9178\u4e59\u70ef\u916f\/\u78b3\u9178\u4e8c\u4e59\u916f\/\u78b3\u9178\u7532\u4e59\u916f\uff08EC\/DEC\/EMC\uff0c\u4f53\u79ef\u6bd4\u4e3a1\uff1a1\uff1a1\uff09\u57fa\u7840\u7535\u89e3\u6db2\u4e2d\u6dfb\u52a0\u7531TMSP\uff081 wt%\uff09\u548cPCS\uff081 wt%\uff09\u6784\u6210\u7684\u4e8c\u5143\u6dfb\u52a0\u5242\uff0c\u63d0\u9ad8\u4e86LiNi<sub>0.5<\/sub>Mn<sub>1.5<\/sub>O<sub>4<\/sub>\/MCMB\u9ad8\u538b\u9502\u79bb\u5b50\u7535\u6c60\u7684\u957f\u5faa\u73af\u7a33\u5b9a\u6027\u548c\u500d\u7387\u6027\u80fd\uff0c\u5c06\u5176\u5728\u5ba4\u6e29\u4e0b\u4ee50.5 C\u7684\u5145\u653e\u7535\u500d\u7387\u5faa\u73af500\u5708\u540e\u7684\u653e\u7535\u5bb9\u91cf\u4fdd\u6301\u7387\u753110.8%\u63d0\u5347\u81f379.5%\u3002\u5f53\u5145\u653e\u7535\u500d\u7387\u75310.2 C\u589e\u5927\u52305 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Functional Additives for Treating the Poor Performances of High-Voltage (5 V-class) LiNi<sub>0.5<\/sub>Mn<sub>1.5<\/sub>O<sub>4<\/sub>\/MCMB Li-Ion Batteries<\/strong>\u201d\u4e3a\u9898\uff0c\u53d1\u8868\u5728<strong>Adv. Energy Mater.<\/strong>\u4e0a\u3002\u8be5\u5de5\u4f5c\u7684<strong>\u7b2c\u4e00\u4f5c\u8005<\/strong>\u4e3a<strong>\u4e2d\u56fd\u79d1\u5b66\u9662\u9752\u5c9b\u751f\u7269\u80fd\u6e90\u4e0e\u8fc7\u7a0b\u7814\u7a76\u6240<\/strong>\u7684<strong>\u8bb8\u9ad8\u6d01<\/strong>\u52a9\u7406\u7814\u7a76\u5458\u3002<\/p>\n<p><strong>\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n<p><strong>\u56fe1.\u4e09\u79cd\u6dfb\u52a0\u5242\u7684\u5206\u5b50\u7ed3\u6784\u548c\u7535\u89e3\u6db2\u4e2d\u5404\u7ec4\u5206\u7684HOMO\u3001LUMO\u80fd\u7ea7\u5bf9\u6bd4<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-116457\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/12\/1-36.jpg\" alt=\"\" width=\"700\" height=\"337\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/12\/1-36.jpg 700w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/12\/1-36-300x144.jpg 300w\" sizes=\"(max-width: 700px) 100vw, 700px\" \/><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-116458\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/12\/2-29.jpg\" alt=\"\" width=\"700\" height=\"582\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/12\/2-29.jpg 700w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/12\/2-29-300x249.jpg 300w\" sizes=\"(max-width: 700px) 100vw, 700px\" \/><\/p>\n<p>\u8be5\u5de5\u4f5c\u91c7\u7528\u5206\u5b50\u8f68\u9053\u8ba1\u7b97\u65b9\u6cd5\u5bf9\u7535\u89e3\u6db2\u6dfb\u52a0\u5242\u7684\u79cd\u7c7b\u505a\u51fa\u4e86\u9996\u6b21\u7b5b\u9009\u8bc4\u4f30\u3002\u7531\u4e8eTMSP\u6709\u9ad8\u4e8e\u78b3\u9178\u916f\u6eb6\u5242\u7684HOMO\u80fd\u7ea7\uff0cTMSP\u503e\u5411\u4e8e\u4f18\u5148\u5728\u6b63\u6781\u4e0a\u53d1\u751f\u7535\u5316\u5b66\u6c27\u5316\u53cd\u5e94\u5e76\u5206\u89e3\uff0c\u5176\u5206\u89e3\u4ea7\u7269\u53c2\u4e0e\u6b63\u6781SEI\u819c\u7684\u5f62\u6210\uff1b\u7c7b\u4f3c\u7684\uff0c\u7531\u4e8ePCS\u6709\u4f4e\u4e8e\u78b3\u9178\u916f\u6eb6\u5242\u7684LUMO\u80fd\u7ea7\uff0cPCS\u503e\u5411\u4e8e\u4f18\u5148\u5728\u8d1f\u6781\u4e0a\u53d1\u751f\u7535\u5316\u5b66\u8fd8\u539f\u53cd\u5e94\u5e76\u5206\u89e3\uff0c\u5176\u5206\u89e3\u4ea7\u7269\u53c2\u4e0e\u8d1f\u6781SEI\u819c\u7684\u5f62\u6210\u3002\u7531\u6b64\u5f62\u6210\u7684\u6b63\u3001\u8d1f\u6781SEI\u819c\u6709\u5229\u4e8e\u9502\u79bb\u5b50\u6269\u6563\u901a\u8fc7\uff0c\u5e76\u80fd\u6709\u6548\u9632\u6b62\u78b3\u9178\u916f\u57fa\u7535\u89e3\u8d28\u5728\u6b63\u3001\u8d1f\u6781\u8868\u9762\u5206\u89e3\u3002<\/p>\n<p><strong>\u56fe2. TMSP\/PCS\u4e8c\u5143\u6dfb\u52a0\u5242\u5bf9LiNi<sub>0.5<\/sub>Mn<sub>1.5<\/sub>O<sub>4<\/sub>\/MCMB\u5168\u7535\u6c60\u957f\u5faa\u73af\u7a33\u5b9a\u6027\u7684\u5f71\u54cd<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-116459\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/12\/3-32.jpg\" alt=\"\" width=\"700\" height=\"511\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/12\/3-32.jpg 700w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/12\/3-32-300x219.jpg 300w\" sizes=\"(max-width: 700px) 100vw, 700px\" \/><\/p>\n<p>(a) \u5f53\u7535\u89e3\u6db2\u5206\u522b\u4e3aBE\u548cBE+1 wt% TMSP+1 wt% PCS\u65f6LiNi<sub>0.5<\/sub>Mn<sub>1.5<\/sub>O<sub>4<\/sub>\/MCMB\u5168\u7535\u6c60\u7684\u7b2c1\u30012\u6b21\u5145\u653e\u7535\u66f2\u7ebf\uff0c\u5145\u653e\u7535\u500d\u7387\u4e3a0.2 C\u3002<\/p>\n<p>(b) \u7ecf\u5386\u56fe(a)\u6240\u793a\u8fc7\u7a0b\u540e\uff0cLiNi<sub>0.5<\/sub>Mn<sub>1.5<\/sub>O<sub>4<\/sub>\/MCMB\u5168\u7535\u6c60\u57280.5 C\u5145\u653e\u7535\u500d\u7387\u4e0b\u7684\u957f\u5faa\u73af\u7a33\u5b9a\u6027\u3002<\/p>\n<p>(c,d) \u5f53\u7535\u89e3\u6db2\u5206\u522b\u4e3a(c) BE;(d) BE+1 wt% TMSP+1 wt% PCS\u65f6LiNi<sub>0.5<\/sub>Mn<sub>1.5<\/sub>O<sub>4<\/sub>\/MCMB\u5168\u7535\u6c60\u5728\u5145\u653e\u7535\u5faa\u73af\u6b21\u6570\u4e3a1\u3001100\u3001200\u3001300\u3001400\u3001500\u65f6\u7684\u5145\u653e\u7535\u66f2\u7ebf\u3002<\/p>\n<p><strong>\u6ce8\uff1a<\/strong>(1) BE\u8868\u793a\u4f53\u79ef\u6bd4\u4e3a1\uff1a1\uff1a1\u7684EC\/DEC\/EMC\u57fa\u7840\u7535\u89e3\u6db2\u3002<\/p>\n<p>(2) \u4ee5\u4e0a\u6240\u6709\u5145\u653e\u7535\u6d4b\u8bd5\u5747\u5728\u5ba4\u6e29\u4e0b\u8fdb\u884c\uff0c\u6d4b\u8bd5\u7535\u538b\u8303\u56f4\u5747\u4e3a3.5-4.9 V\u3002<\/p>\n<p><strong>\u56fe3. TMSP\/PCS\u4e8c\u5143\u6dfb\u52a0\u5242\u5bf9LiNi<sub>0.5<\/sub>Mn<sub>1.5<\/sub>O<sub>4<\/sub>\/MCMB\u5168\u7535\u6c60\u500d\u7387\u6027\u80fd\u7684\u5f71\u54cd<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-116460\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/12\/4-27.jpg\" alt=\"\" width=\"600\" height=\"1340\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/12\/4-27.jpg 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/12\/4-27-134x300.jpg 134w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/12\/4-27-459x1024.jpg 459w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>(a) \u5f53\u7535\u89e3\u6db2\u5206\u522b\u4e3aBE\u548cBE+1 wt% TMSP+1 wt% PCS\u65f6LiNi<sub>0.5<\/sub>Mn<sub>1.5<\/sub>O<sub>4<\/sub>\/MCMB\u5168\u7535\u6c60\u7684\u500d\u7387\u6027\u80fd\u5bf9\u6bd4\u3002<\/p>\n<p>(b,c) \u5f53\u5145\u653e\u7535\u500d\u7387\u6309\u56fe(a)\u6240\u793a\u53d8\u5316\u65f6LiNi<sub>0.5<\/sub>Mn<sub>1.5<\/sub>O<sub>4<\/sub>\/MCMB\u5168\u7535\u6c60\u653e\u7535\u66f2\u7ebf\u5bf9\u6bd4\uff0c\u5176\u4e2d\u56fe(b)\u548c\u56fe(c)\u6240\u7528\u7535\u89e3\u6db2\u5206\u522b\u4e3aBE\u548cBE+1 wt% TMSP+1 wt% PCS\u3002<\/p>\n<p>\u6ce8\uff1a\u4ee5\u4e0a\u6240\u6709\u5145\u653e\u7535\u6d4b\u8bd5\u5747\u5728\u5ba4\u6e29\u4e0b\u8fdb\u884c\uff0c\u6d4b\u8bd5\u7535\u538b\u8303\u56f4\u5747\u4e3a3.5-4.9 V\u3002<\/p>\n<p><strong>\u56fe4. <\/strong><strong>TMSP\/PCS<\/strong><strong>\u4e8c\u5143\u6dfb\u52a0\u5242\u5bf9LiNi<sub>0.5<\/sub>Mn<sub>1.5<\/sub>O<sub>4<\/sub>\/M<\/strong><strong>CMB<\/strong><strong>\u5168\u7535\u6c60\u7535\u5316\u5b66\u963b\u6297\u8c31\u7684\u5f71\u54cd<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-116461\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/12\/5-24.jpg\" alt=\"\" width=\"700\" height=\"1030\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/12\/5-24.jpg 700w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/12\/5-24-204x300.jpg 204w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/12\/5-24-696x1024.jpg 696w\" sizes=\"(max-width: 700px) 100vw, 700px\" \/><\/p>\n<p>\u6ce8\uff1a\u5148\u4ee51 C\u7684\u5145\u653e\u7535\u500d\u7387\u5faa\u73af1\u3001100\u3001200\u3001300\u5708\uff0c\u7ecf\u5145\u5206\u653e\u7535\u540e\u6d4b\u5f97LiNi<sub>0.5<\/sub>Mn<sub>1.5<\/sub>O<sub>4<\/sub>\/MCMB\u5168\u7535\u6c60\u7684\u7535\u5316\u5b66\u963b\u6297\u8c31\u3002<\/p>\n<p><strong>\u56fe5. TMSP\/PCS\u4e8c\u5143\u6dfb\u52a0\u5242\u5bf9LiNi<sub>0.5<\/sub>Mn<sub>1.5<\/sub>O<sub>4<\/sub>\u6b63\u6781\u91d1\u5c5e\u79bb\u5b50\u6eb6\u51fa\u548c\u6b63\u6781SEI\u819c\u5f62\u8c8c\u7684\u5f71\u54cd<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-116462\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/12\/6-10.jpg\" alt=\"\" width=\"700\" height=\"367\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/12\/6-10.jpg 700w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/12\/6-10-300x157.jpg 300w\" sizes=\"(max-width: 700px) 100vw, 700px\" \/><\/p>\n<p>(a) \u5c06\u6b63\u6781\u4ece\u7ecf\u8fc7\u4e00\u5708\u5faa\u73af\u7136\u540e\u5145\u6ee1\u7535\u7684LiNi<sub>0.5<\/sub>Mn<sub>1.5<\/sub>O<sub>4<\/sub>\/MCMB \u5168\u7535\u6c60\u4e2d\uff08\u7535\u89e3\u6db2\u5206\u522b\u4e3aBE\u548cBE+1 wt% TMSP+1 wt% PCS\uff09\u62c6\u51fa\u540e\u5728BE\u7535\u89e3\u6db2\u4e2d60\u2103\u6d78\u6ce124\u5c0f\u65f6\uff0cICP-MS\u6d4b\u8bd5Mn\u3001Ni\u79bb\u5b50\u4eceLiNi<sub>0.5<\/sub>Mn<sub>1.5<\/sub>O<sub>4<\/sub>\u6ee1\u7535\u6001\u6b63\u6781\u4e2d\u6eb6\u51fa\u60c5\u51b5\u5bf9\u6bd4\u3002<\/p>\n<p>(b) \u7ecf200\u6b21\u5145\u653e\u7535\u5faa\u73af\u540eLiNi<sub>0.5<\/sub>Mn<sub>1.5<\/sub>O<sub>4<\/sub>\u6b63\u6781\u7684TEM\u56fe\u50cf\u3002\u8be5\u6b63\u6781\u7531\u5145\u5206\u653e\u7535\u7684LiNi<sub>0.5<\/sub>Mn<sub>1.5<\/sub>O<sub>4<\/sub>\/MCMB \u5168\u7535\u6c60\u4e2d\u53d6\u5f97\uff0c\u5145\u653e\u7535\u500d\u7387\u4e3a1 C\u3002\u8be5\u5145\u653e\u7535\u5faa\u73af\u5728\u5ba4\u6e29\u4e0b\u8fdb\u884c\uff0c\u6d4b\u8bd5\u7535\u538b\u8303\u56f4\u4e3a3.5-4.9 V\u3002<\/p>\n<p><strong>\u56fe6. TMSP\/PCS\u4e8c\u5143\u6dfb\u52a0\u5242\u5bf9LiNi<sub>0.5<\/sub>Mn<sub>1.5<\/sub>O<sub>4<\/sub>\u6b63\u6781\u548cMCMB\u8d1f\u6781\u6676\u4f53\u7ed3\u6784\u7684\u5f71\u54cd<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-116463\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/12\/7-7.jpg\" alt=\"\" width=\"700\" height=\"1080\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/12\/7-7.jpg 700w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/12\/7-7-194x300.jpg 194w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/12\/7-7-664x1024.jpg 664w\" sizes=\"(max-width: 700px) 100vw, 700px\" \/><\/p>\n<p>\u6ce8\uff1a\u4ee51 C\u7684\u5145\u653e\u7535\u500d\u7387\u8fdb\u884c200\u6b21\u5145\u653e\u7535\u5faa\u73af\u540e\uff0c\u4ece\u5145\u5206\u653e\u7535\u7684LiNi<sub>0.5<\/sub>Mn<sub>1.5<\/sub>O<sub>4<\/sub>\/MCMB \u5168\u7535\u6c60\u4e2d\u53d6\u5f97\u6b63\u3001\u8d1f\u6781\u3002\u8be5\u8fc7\u7a0b\u5728\u5ba4\u6e29\u4e0b\u8fdb\u884c\uff0c\u6d4b\u8bd5\u7535\u538b\u8303\u56f4\u4e3a3.5-4.9 V\u3002<\/p>\n<p><strong>\u56fe7. TMSP\/PCS\u4e8c\u5143\u6dfb\u52a0\u5242\u5bf9LiNi<sub>0.5<\/sub>Mn<sub>1.5<\/sub>O<sub>4<\/sub>\u6b63\u6781\u548cMCMB\u8d1f\u6781\u8868\u9762SEI\u819c\u7ec4\u6210\u7684\u5f71\u54cd<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-116465\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/12\/8-4.jpg\" alt=\"\" width=\"700\" height=\"538\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/12\/8-4.jpg 700w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/12\/8-4-300x231.jpg 300w\" sizes=\"(max-width: 700px) 100vw, 700px\" \/><\/p>\n<p>\u6ce8\uff1a\u4ee51 C\u7684\u5145\u653e\u7535\u500d\u7387\u8fdb\u884c200\u6b21\u5145\u653e\u7535\u5faa\u73af\u540e\uff0c\u4ece\u5145\u5206\u653e\u7535\u7684LiNi<sub>0.5<\/sub>Mn<sub>1.5<\/sub>O<sub>4<\/sub>\/MCMB \u5168\u7535\u6c60\u4e2d\u53d6\u5f97\u6b63\u3001\u8d1f\u6781\u3002\u8be5\u8fc7\u7a0b\u5728\u5ba4\u6e29\u4e0b\u8fdb\u884c\uff0c\u6d4b\u8bd5\u7535\u538b\u8303\u56f4\u4e3a3.5-4.9 V\u3002<\/p>\n<p><strong>\u56fe8. TMSP\/PCS\u4e8c\u5143\u6dfb\u52a0\u5242\u63d0\u9ad8LiNi<sub>0.5<\/sub>Mn<sub>1.5<\/sub>O<sub>4<\/sub>\/MCMB\u5168\u7535\u6c60\u957f\u5faa\u73af\u7a33\u5b9a\u6027\u548c\u500d\u7387\u6027\u80fd\u7684\u673a\u7406<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-116466\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/12\/9-4.jpg\" alt=\"\" width=\"700\" height=\"461\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/12\/9-4.jpg 700w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/12\/9-4-300x198.jpg 300w\" sizes=\"(max-width: 700px) 100vw, 700px\" \/><\/p>\n<p><strong>\u56fe9. \u9ad8\u6e29\u4e0bTMSP\/PCS\u4e8c\u5143\u6dfb\u52a0\u5242\u5bf9LiNi<sub>0.5<\/sub>Mn<sub>1.5<\/sub>O<sub>4<\/sub>\/MCMB\u5168\u7535\u6c60\u957f\u5faa\u73af\u7a33\u5b9a\u6027\u7684\u5f71\u54cd<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-116467\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/12\/10-3.jpg\" alt=\"\" width=\"700\" height=\"329\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/12\/10-3.jpg 700w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/12\/10-3-300x141.jpg 300w\" sizes=\"(max-width: 700px) 100vw, 700px\" \/><\/p>\n<p>(a) \u5f53\u7535\u89e3\u6db2\u5206\u522b\u4e3aBE\u548cBE+1 wt% TMSP+1 wt% PCS\u65f6LiNi<sub>0.5<\/sub>Mn<sub>1.5<\/sub>O<sub>4<\/sub>\/MCMB\u5168\u7535\u6c60\u7684\u957f\u5faa\u73af\u7a33\u5b9a\u6027\uff0c\u5145\u653e\u7535\u500d\u7387\u4e3a1 C\u3002<\/p>\n<p>(b,c) \u5f53\u7535\u89e3\u6db2\u5206\u522b\u4e3a(b)BE;(c)BE+1 wt% TMSP+1 wt% PCS\u65f6LiNi<sub>0.5<\/sub>Mn<sub>1.5<\/sub>O<sub>4<\/sub>\/MCMB\u5168\u7535\u6c60\u5728\u4e0d\u540c\u5faa\u73af\u6b21\u6570\u4e0b\u7684\u5145\u653e\u7535\u66f2\u7ebf\u3002<\/p>\n<p>(d-g) \u4e0d\u540c\u7535\u89e3\u6db2\u53ca\u5faa\u73af\u5145\u653e\u7535\u6761\u4ef6\u4e0bLiNi<sub>0.5<\/sub>Mn<sub>1.5<\/sub>O<sub>4<\/sub>\u6b63\u6781\u7684\u7167\u7247\u3002<\/p>\n<p>\u6ce8\uff1a\u56fe(a-c)\u4e2d\u7684\u5145\u653e\u7535\u6d4b\u8bd5\u5747\u572850\u2103\u4e0b\u8fdb\u884c\uff0c\u6d4b\u8bd5\u7535\u538b\u8303\u56f4\u5747\u4e3a3.5-4.9 V\u3002<\/p>\n<p>\u5f53\u5de5\u4f5c\u6e29\u5ea6\u63d0\u9ad8\u523050\u2103\uff0c\u5728\u4e0d\u542b\u6dfb\u52a0\u5242\u7684BE\u4e2d\uff0cLiNi<sub>0.5<\/sub>Mn<sub>1.5<\/sub>O<sub>4<\/sub>\u6b63\u6781\u4ece\u94dd\u7b94\u4e0a\u8131\u843d\uff0c\u53ef\u80fd\u7684\u539f\u56e0\u5982\u4e0b\uff1a(1)\u6e17\u900f\u8fdb\u5165\u6b63\u6781\u5185\u90e8\u7684\u7535\u89e3\u6db2\u53d1\u751f\u6c27\u5316\u53cd\u5e94\u800c\u5206\u89e3\uff0c\u6c27\u5316\u4ea7\u7269\u79ef\u7d2f\u5728\u6b63\u6781\u6d3b\u6027\u6750\u6599\u548c\u96c6\u6d41\u4f53\u4e4b\u95f4\u5f62\u6210\u963b\u9694\uff0c\u9020\u6210\u7535\u63a5\u89e6\u4e0d\u826f\uff1b(2)\u7531LiPF<sub>6<\/sub>\u6c34\u89e3\u4ea7\u751f\u7684\u6c22\u6c1f\u9178\u8150\u8680\u94dd\u7b94\u96c6\u6d41\u4f53\uff0c\u9020\u6210\u6b63\u6781\u6d3b\u6027\u6750\u6599\u8131\u843d\u548c\u7535\u63a5\u89e6\u4e0d\u826f\u3002\u7531\u4e8eTMSP\/PCS\u4e8c\u5143\u6dfb\u52a0\u5242\u5148\u4e8e\u57fa\u7840\u7535\u89e3\u6db2\u5728\u6b63\u3001\u8d1f\u6781\u8868\u9762\u53d1\u751f\u6c27\u5316\u8fd8\u539f\u53cd\u5e94\u5e76\u751f\u6210\u5747\u5300\u81f4\u5bc6\u7684SEI\u819c\uff0c\u4ece\u800c\u963b\u6b62\u7535\u89e3\u6db2\u5206\u89e3\u548c\u526f\u53cd\u5e94\u4ea7\u7269\u7684\u79ef\u7d2f\uff0c\u5e76\u4e14TMSP\u80fd\u6709\u6548\u6d88\u8017\u6c22\u6c1f\u9178\uff0c\u6545\u5f15\u5165TMSP\/PCS\u4e8c\u5143\u6dfb\u52a0\u5242\u80fd\u6709\u6548\u675c\u7edd\u6b63\u6781\u6d3b\u6027\u6750\u6599\u4ece\u96c6\u6d41\u4f53\u4e0a\u8131\u843d\uff0c\u63d0\u9ad8\u4e86\u7535\u6c60\u7684\u957f\u5faa\u73af\u7a33\u5b9a\u6027\u3002<\/p>\n<p><strong>\u56fe10. PFPN\u5bf9\u78b3\u9178\u916f\u57fa\u7535\u89e3\u6db2\u7684\u963b\u71c3\u6548\u679c\u6d4b\u8bd5<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-116468\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/12\/11-3.jpg\" alt=\"\" width=\"700\" height=\"422\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/12\/11-3.jpg 700w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/12\/11-3-300x181.jpg 300w\" sizes=\"(max-width: 700px) 100vw, 700px\" \/><\/p>\n<p>\u6ce8\uff1a\u5939\u5b50\u5de6\u7aef\u548c\u53f3\u7aef\u7684\u73bb\u7483\u7ea4\u7ef4\u5206\u522b\u7528BE\u548cBE+1 wt% TMSP+1 wt% PCS+7 wt% PFPN\u6d78\u6ce1\u8fc7\u3002\u5de6\u7aef\u73bb\u7483\u7ea4\u7ef4\u4e00\u7ecf\u70b9\u71c3\u5c31\u7acb\u5373\u5f00\u59cb\u71c3\u70e7\uff0c\u800c\u53f3\u7aef\u73bb\u7483\u7ea4\u7ef4\u5728\u70b9\u706b5\u6b21\u4e4b\u540e\u624d\u80fd\u5f00\u59cb\u71c3\u70e7\u3002\u8fd9\u5145\u5206\u663e\u793aPFPN\u6dfb\u52a0\u5242\u80fd\u5bf9\u78b3\u9178\u916f\u57fa\u7535\u89e3\u6db2\u8d77\u5230\u8f83\u597d\u7684\u963b\u71c3\u6548\u679c\u3002<\/p>\n<p>\u5728\u7535\u89e3\u6db2\u7684\u6240\u6709\u7ec4\u5206\u4e2d\uff0cPFPN\u5177\u6709\u6700\u4f4e\u7684HOMO\u548cLUMO\u80fd\u7ea7\u3002\u8fd9\u610f\u5473\u7740\u5b83\u5f88\u5bb9\u6613\u88ab\u8fd8\u539f\uff08\u727a\u7272\u5faa\u73af\u6027\u80fd\uff0c\u4f46\u662f\u5728\u53ef\u63a5\u53d7\u7684\u8303\u56f4\u5185\uff09\uff0c\u5374\u4e0d\u6613\u88ab\u6c27\u5316\u3002\u5f53\u7535\u89e3\u6db2\u88ab\u70b9\u71c3\u65f6\uff0c\u7531\u78b3\u9178\u916f\u57fa\u6eb6\u5242\u70ed\u5206\u89e3\u4ea7\u751f\u7684H\u00b7\u81ea\u7531\u57fa\u4fc3\u4f7f\u71c3\u70e7\u8fc7\u7a0b\u6301\u7eed\u8fdb\u884c\uff0c\u800cPFPN\u70ed\u5206\u89e3\u4ea7\u751f\u7684F\u00b7\u548cP\u00b7\u81ea\u7531\u57fa\u5219\u80fd\u9ad8\u6548\u6355\u83b7H\u00b7\u81ea\u7531\u57fa\uff0c\u963b\u788d\u71c3\u70e7\u8fdb\u884c\u3002<\/p>\n<p><strong>\u56fe11. PFPN\u5bf9LiNi<sub>0.5<\/sub>Mn<sub>1.5<\/sub>O<sub>4<\/sub>\/MCMB\u5168\u7535\u6c60\u957f\u5faa\u73af\u7a33\u5b9a\u6027\u7684\u5f71\u54cd<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-116469\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/12\/12-2.jpg\" alt=\"\" width=\"700\" height=\"530\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/12\/12-2.jpg 700w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/12\/12-2-300x227.jpg 300w\" sizes=\"(max-width: 700px) 100vw, 700px\" \/><\/p>\n<p>\u6ce8\uff1a\u5145\u653e\u7535\u5faa\u73af\u5728\u5ba4\u6e29\u4e0b\u8fdb\u884c\uff0c\u5145\u653e\u7535\u500d\u7387\u4e3a1 C\uff0c\u6d4b\u8bd5\u7535\u538b\u8303\u56f4\u4e3a3.5-4.9 V\u3002<\/p>\n<p><strong>\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n<p>\u7535\u89e3\u6db2\u88ab\u79f0\u4e3a\u9502\u79bb\u5b50\u7535\u6c60\u7684\u201c\u8840\u6db2\u201d\u3002\u9488\u5bf9\u201c\u8840\u6db2\u75c5\u201d\uff08\u78b3\u9178\u916f\u57fa\u7535\u89e3\u6db2\u5728\u6b63\u3001\u8d1f\u6781\u4e0a\u5206\u89e3\uff09\u5f15\u8d77\u7684\u9ad8\u538b\u9502\u79bb\u5b50\u7535\u6c60\u957f\u5faa\u73af\u7a33\u5b9a\u6027\u5dee\u3001\u500d\u7387\u6027\u80fd\u5dee\u7b49\u95ee\u9898\uff0c\u7814\u7a76\u4eba\u5458\u5bf9\u75c7\u4e0b\u836f\uff0c\u5411\u5e38\u7528\u7684\u542bLiPF<sub>6<\/sub>\u78b3\u9178\u916f\u57fa\u7535\u89e3\u6db2\u4f53\u7cfb\u4e2d\u5f15\u5165TMSP\/PCS\u4e8c\u5143\u6dfb\u52a0\u5242\uff0c\u4fee\u9970\u4e86LiNi<sub>0.5<\/sub>Mn<sub>1.5<\/sub>O<sub>4<\/sub>\u6b63\u6781\u548cMCMB\u8d1f\u6781\u8868\u9762\u7684SEI\u819c\uff0c\u8be5SEI\u819c\u4e0d\u4ec5\u6709\u5229\u4e8eLi<sup>+<\/sup>\u6269\u6563\uff0c\u8fd8\u80fd\u6291\u5236\u6d3b\u6027\u9502\u6d88\u8017\u53ca\u78b3\u9178\u916f\u57fa\u6eb6\u5242\u5728\u7535\u6781\u8868\u9762\u5206\u89e3\u7684\u526f\u53cd\u5e94\u3002\u6b64\u5916\uff0cTMSP\u80fd\u6d88\u8017LiPF<sub>6<\/sub>\u6c34\u89e3\u4ea7\u751f\u7684HF\uff0c\u8fd9\u4e0d\u4ec5\u80fd\u7a33\u5b9aLiPF<sub>6<\/sub>\uff0c\u8fd8\u80fd\u4fdd\u62a4LiNi<sub>0.5<\/sub>Mn<sub>1.5<\/sub>O<sub>4<\/sub>\u6b63\u6781\u548c\u94dd\u7b94\u96c6\u6d41\u4f53\u3002\u5411\u7535\u89e3\u6db2\u4e2d\u5f15\u5165PFPN\u4f5c\u4e3a\u963b\u71c3\u6dfb\u52a0\u5242\uff0c\u80fd\u5728\u63d0\u5347\u9ad8\u538b\u9502\u79bb\u5b50\u7535\u6c60\u5b89\u5168\u6027\u7684\u540c\u65f6\u57fa\u672c\u4fdd\u6301\u8f83\u597d\u7684\u7535\u5316\u5b66\u6027\u80fd\u3002TMSP\/PCS\/PFPN\u4e09\u5143\u7535\u89e3\u6db2\u6dfb\u52a0\u5242\u7684\u6210\u529f\u5145\u5206\u8868\u660e\u591a\u5143\u6dfb\u52a0\u5242\u7684\u7ec4\u5408\u914d\u65b9\u80fd\u5927\u529b\u63a8\u8fdb\u9ad8\u538b\u9502\u79bb\u5b50\u7535\u6c60\u7684\u53d1\u5c55\uff01<\/p>\n<p><strong>\u6587\u732e\u94fe\u63a5\uff1a<\/strong><a href=\"http:\/\/onlinelibrary.wiley.com\/wol1\/doi\/10.1002\/aenm.201701398\/abstract\" target=\"_blank\" rel=\"noopener\">Prescribing Functional Additives for Treating the Poor Performances of High-Voltage (5 V-class) LiNi<sub>0.5<\/sub>Mn<sub>1.5<\/sub>O<sub>4<\/sub>\/MCMB Li-Ion Batteries<\/a> (Adv. Energy Mater., 2017, DOI:10.1002\/aenm.201701398)<\/p>\n<p><strong>\u901a\u8baf\u4f5c\u8005\u7b80\u4ecb\uff1a<\/strong><\/p>\n<p><strong>\u5d14\u5149\u78ca<\/strong>\u8001\u5e08\u73b0\u4e3a\u4e2d\u56fd\u79d1\u5b66\u9662\u9752\u5c9b\u751f\u7269\u80fd\u6e90\u4e0e\u8fc7\u7a0b\u7814\u7a76\u6240\u7814\u7a76\u5458\uff0c\u535a\u58eb\u751f\u5bfc\u5e08\uff0c\u56fd\u5bb6\u6770\u51fa\u9752\u5e74\u79d1\u5b66\u57fa\u91d1\u83b7\u5f97\u8005\uff0c\u4e2d\u79d1\u9662&#8221;\u767e\u4eba\u8ba1\u5212&#8221;\u5165\u9009\u8005\uff0c\u4e2d\u79d1\u9662\u9752\u5c9b\u751f\u7269\u80fd\u6e90\u4e0e\u8fc7\u7a0b\u6240\u5148\u8fdb\u50a8\u80fd\u4e2d\u5fc3\u4e3b\u4efb\uff0c\u9752\u5c9b\u592a\u9633\u80fd\u50a8\u80fd\u91cd\u70b9\u5b9e\u9a8c\u5ba4\u4e3b\u4efb\uff0c\u9752\u5c9b\u50a8\u80fd\u4ea7\u4e1a\u6280\u672f\u7814\u7a76\u9662\u6267\u884c\u9662\u957f\u30022009\u5e74\u5165\u9009\u4e2d\u56fd\u79d1\u5b66\u9662\u201c\u767e\u4eba\u8ba1\u5212\u201d\u5e76\u83b7\u5c71\u4e1c\u7701\u81ea\u7136\u79d1\u5b66\u6770\u51fa\u9752\u5e74\u57fa\u91d1\u8d44\u52a9\uff0c2015\u5e74\u5165\u9009\u5c71\u4e1c\u7701\u201c\u6cf0\u5c71\u5b66\u8005\u7279\u8058\u4e13\u5bb6\u201d\uff0c2016\u5e74\u83b7\u56fd\u5bb6\u81ea\u7136\u79d1\u5b66\u6770\u51fa\u9752\u5e74\u57fa\u91d1\u8d44\u52a9\u3002\u5d14\u5149\u78ca\u8001\u5e08\u4e3b\u8981\u4ece\u4e8b\u4f4e\u6210\u672c\u9ad8\u6548\u80fd\u6e90\u50a8\u5b58\u4e0e\u8f6c\u6362\u5668\u4ef6\u7684\u7814\u7a76\uff0c\u4f5c\u4e3a\u8d1f\u8d23\u4eba\u548c\u4e3b\u8981\u53c2\u4e0e\u8005\u627f\u62c5\u56fd\u5bb6\u81ea\u7136\u79d1\u5b66\u6770\u51fa\u9752\u5e74\u57fa\u91d1\u3001\u56fd\u5bb6973\u8ba1\u5212\u3001863\u8ba1\u5212\uff0c\u56fd\u5bb6\u81ea\u7136\u79d1\u5b66\u57fa\u91d1\u9762\u4e0a\u9879\u76ee\uff0c\u7701\u90e8\u7ea7\u53ca\u4e2d\u79d1\u9662\u5148\u5bfc\u4e13\u9879\u3001\u4f01\u4e1a\u6a2a\u5411\u9879\u76ee\u7b49\u591a\u9879\u79d1\u7814\u9879\u76ee\u3002\u5148\u540e\u5728\u6750\u6599\u3001\u5316\u5b66\u3001\u80fd\u6e90\u6750\u6599\u7b49\u65b9\u9762\u7684\u56fd\u9645\u6743\u5a01\u6742\u5fd7Angew. Chem. Int. Ed.\u3001J. Am. Chem. Soc.\u3001Adv. Mater.\u3001Small\u3001Energy Environ. Sci.\u3001ChemSusChem\u3001Chem. Commun.\u3001J. Mater. 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&#8220;<a href=\"http:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/aenm.201602055\/full\" target=\"_blank\" rel=\"noopener\">Novel design concepts of efficient Mg-ion electrolytes toward high-performance magnesium-selenium and magnesium-sulfur batteries<\/a>&#8220;, ZHANG Z., CUI Z., QIAO L., GUAN J., XU H., WANG X., HU P., DU H., LI S., ZHOU X., DONG S., LIU Z., CUI G*., CHEN L., Advanced Energy Materials, 2017, 7: 1602055.<\/p>\n<p>\/\/m.iemloyee.com\/63400.html<\/p>\n<p>[2] &#8220;<a href=\"http:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/aenm.201600751\/abstract\" target=\"_blank\" rel=\"noopener\">Recent advances in non-aqueous electrolyte for rechargeable Li-O2\u00a0batteries<\/a>&#8220;, LI Y., WANG X., DONG S*., CHEN X., CUI G*., Advanced Energy Materials, 2016,\u00a06\u00a0(18): 1600751.<\/p>\n<p>[3]\u201c<a href=\"http:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/aenm.201501082\/abstract\" target=\"_blank\" rel=\"noopener\">Safety-reinforced poly(propylene carbonate)-based all-solid-state polymer electrolyte for ambient-temperature solid polymer lithium batteries<\/a>\u201d, ZHANG J., ZHAO J., YUE L., WANG Q., CHAI J., LIU Z., ZHOU X., LI H., GUO Y., CUI G*., CHEN L., Advanced Energy Materials, 2015, 1501082.\u00a0\u00a0<\/p>\n<p>[4]\u201c<a href=\"https:\/\/www.sciencedirect.com\/science\/article\/pii\/S0010854515000612\" target=\"_blank\" rel=\"noopener\">Functional lithium borate salts and their potential application in high performance lithium batteries<\/a>\u201d, LIU Z., CHAI J., XU G., WANG Q., CUI G*., Coordination Chemistry Reviews, 2015, 292: 56. 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