{"id":116440,"date":"2017-12-12T06:30:49","date_gmt":"2017-12-11T22:30:49","guid":{"rendered":"\/\/m.iemloyee.com\/?p=116440"},"modified":"2017-12-11T18:56:15","modified_gmt":"2017-12-11T10:56:15","slug":"%e7%9f%b3%e6%b2%b3%e5%ad%90%e5%a4%a7%e5%ad%a6%e4%bb%a3%e6%96%8c%e6%95%99%e6%8e%88%e7%a0%94%e7%a9%b6%e5%9b%a2%e9%98%9f%ef%bc%9a%e4%b9%99%e7%82%94%e5%8c%96%e5%b7%a5%e7%bb%bf%e8%89%b2%e8%bf%87%e7%a8%8b","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=116440","title":{"rendered":"\u77f3\u6cb3\u5b50\u5927\u5b66\u4ee3\u658c\u6559\u6388\u7814\u7a76\u56e2\u961f\uff1a\u4e59\u7094\u5316\u5de5\u7eff\u8272\u8fc7\u7a0b"},"content":{"rendered":"<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-116441 aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/12\/\u56fe\u72471-9.png\" alt=\"\" width=\"256\" height=\"172\" \/><\/p>\n<p>\u4ee3\u658c\uff0c\u7537\uff0c1969\u5e7410\u6708\u751f\uff0c\u56db\u5ddd\u6e20\u53bf\u4eba\uff0c\u535a\u58eb\uff0c\u6559\u6388\uff0c\u56fd\u52a1\u9662\u7279\u6b8a\u6d25\u8d34\u4e13\u5bb6\uff0c\u56fd\u5bb6\u201c\u4e07\u4eba\u8ba1\u5212\u201d\u79d1\u6280\u9886\u519b\u4eba\u624d\uff0c\u79d1\u6280\u90e8\u201c\u521b\u65b0\u4eba\u624d\u63a8\u8fdb\u8ba1\u5212\u201d\u4e2d\u9752\u5e74\u79d1\u6280\u9886\u519b\u4eba\u624d\u3001\u56fd\u5bb6\u767e\u5343\u4e07\u4eba\u624d\u5de5\u7a0b\u4eba\u9009\uff0c\u6709\u7a81\u51fa\u8d21\u732e\u4e2d\u9752\u5e74\u4e13\u5bb6\u3001\u6559\u80b2\u90e8\u65b0\u4e16\u7eaa\u4f18\u79c0\u4eba\u624d\u3001\u6559\u80b2\u90e8\u9ad8\u7b49\u5b66\u6821\u5316\u5b66\u7c7b\u4e13\u4e1a\u6559\u5b66\u6307\u5bfc\u59d4\u5458\u4f1a\u59d4\u5458\u300128\u5c4a\u4e2d\u56fd\u5316\u5b66\u4f1a\u5316\u5b66\u6559\u80b2\u59d4\u5458\u4f1a\u59d4\u5458\u3002\u73b0\u4efb\u77f3\u6cb3\u5b50\u5927\u5b66\u6821\u957f\uff0c\u65b0\u7586\u5175\u56e2\u5316\u5de5\u7eff\u8272\u8fc7\u7a0b\u91cd\u70b9\u5b9e\u9a8c\u5ba4\uff08\u7701\u90e8\u5171\u5efa\u56fd\u5bb6\u91cd\u70b9\u5b9e\u9a8c\u5ba4\u57f9\u80b2\u57fa\u5730\uff09\u4e3b\u4efb\uff0c\u65b0\u7586\u5175\u56e2\u79d1\u534f\u526f\u4e3b\u5e2d\uff08\u517c\uff09\uff0c\u65b0\u7586\u81ea\u6cbb\u533a\u79d1\u534f\u5e38\u59d4\uff0c\u5929\u6d25\u5927\u5b66\u535a\u58eb\u751f\u5bfc\u5e08\uff08\u517c\uff09\u3002<\/p>\n<p>\u4ee3\u658c\u6559\u6388\u7814\u7a76\u56e2\u961f\u4e3b\u8981\u5728\u5316\u5de5\u7eff\u8272\u8fc7\u7a0b\u65b9\u9762\u5f00\u5c55\u4e86\u4e00\u7cfb\u5217\u7684\u7814\u7a76\u5de5\u4f5c\u3002\u7279\u522b\u662f\u5de5\u4e1a\u50ac\u5316\u548c\u7eff\u8272\u5316\u5de5\u8fc7\u7a0b\u9886\u57df\uff0c\u7acb\u8db3\u4e8e\u5730\u65b9\u7279\u8272\u3001\u56fd\u5bb6\u9700\u6c42\u548c\u4e16\u754c\u95ee\u9898\uff0c\u53d6\u5f97\u4e86\u4e00\u7cfb\u5217\u539f\u521b\u6027\u4e0e\u5b9e\u7528\u6027\u7684\u79d1\u7814\u6210\u679c\u3002\u8fd1\u5e74\u6765\uff0c\u5728Chemical Engineering Science\u3001Industrial &amp; Engineering Chemistry Research\u3001Chemical Engneering Journal\u3001ACS Catalysis\u3001Applied Catalysis B:\u00a0Environmental\u3001Journal of Catalysis\u3001Green Chemistry\u3001Catalysis Science &amp; Technology\u3001ChemCatChem\u7b49\u56fd\u9645\u77e5\u540d\u671f\u520a\u4e0a\u53d1\u8868SCI\u6536\u5f55\u8bba\u6587200\u4f59\u7bc7\u3002\u8fd1\u5e74\u6765\uff0c\u8be5\u56e2\u961f\u4e3b\u6301\u548c\u627f\u62c5\u4e86973\u8ba1\u5212\u3001863\u8ba1\u5212\u3001\u56fd\u5bb6\u81ea\u7136\u79d1\u5b66\u57fa\u91d1\u3001\u6559\u80b2\u90e8\u957f\u6c5f\u5b66\u8005\u548c\u521b\u65b0\u56e2\u961f\u3001\u5175\u56e2\u79d1\u6280\u521b\u65b0\u56e2\u961f\u8d44\u52a9\u8ba1\u5212\u3001\u5175\u56e2\u6770\u51fa\u9752\u5e74\u521b\u65b0\u57fa\u91d1\u7b49\u56fd\u5bb6\u7ea7\u548c\u7701\u90e8\u7ea7\u9879\u76ee\u56fd\u5bb6\u90e8\u59d4\u9879\u76ee20\u4f59\u9879\uff0c\u83b7\u7701\u7ea7\u79d1\u6280\u8fdb\u6b65\u59568\u9879\uff0c\u56fd\u5bb6\u6559\u5b66\u6210\u679c\u4e8c\u7b49\u59561\u9879\uff0c\u51fa\u7248\u6559\u67505\u90e8\u3002\u66fe\u8363\u83b7\u201c\u4e2d\u56fd\u79d1\u5b66\u6280\u672f\u53d1\u5c55\u57fa\u91d1\u4f1a\u4faf\u7965\u9e9f\u77f3\u6cb9\u52a0\u5de5\u79d1\u5b66\u6280\u672f\u5956\u201d\u3001\u201c\u4e2d\u56fd\u79d1\u5b66\u6280\u672f\u53d1\u5c55\u57fa\u91d1\u4f1a\u4faf\u7965\u9e9f\u77f3\u6cb9\u52a0\u5de5\u79d1\u5b66\u6280\u672f\u63d0\u540d\u5956\u201d\u3001\u77f3\u6cb3\u5b50\u5927\u5b66\u201c\u5341\u4e94\u201d\u5148\u8fdb\u79d1\u6280\u5de5\u4f5c\u8005\u3001\u65b0\u7586\u81ea\u6cbb\u533a\u4f18\u79c0\u7855\u58eb\u8bba\u6587\u6307\u5bfc\u6559\u5e08\u3001\u65b0\u7586\u751f\u4ea7\u5efa\u8bbe\u5175\u56e2\u6770\u51fa\u9752\u5e74\u79d1\u6280\u521b\u65b0\u5956\u3001\u5175\u56e2\u9752\u5e74\u79d1\u6280\u5956\u3001\u5175\u56e2\u4f18\u79c0\u6559\u5e08\u7b49\u8363\u8a89\u79f0\u53f7\u3002<\/p>\n<p>\u4ee3\u658c\u6559\u6388\u7814\u7a76\u56e2\u961f\u5df2\u7ecf\u5f62\u6210\u4e86\u7279\u8272\u9c9c\u660e\u7684\u7814\u7a76\u65b9\u5411\uff0c\u4f8b\u5982\uff0c\u4e59\u7094\u5316\u5de5\u7eff\u8272\u8fc7\u7a0b\u3001CO\/CO<sub>2<\/sub>\u7684\u5316\u5de5\u7eff\u8272\u50ac\u5316\u8f6c\u5316\u5229\u7528\u3001\u4f4e\u6e29\u70df\u6c14\u8131\u785d\u7eff\u8272\u5316\u5de5\u5173\u952e\u6280\u672f\u7b49\u3002\u7279\u522b\u662f\u5728\u4e59\u7094\u5316\u5de5\u7eff\u8272\u8fc7\u7a0b\u65b9\u9762\uff0c\u57fa\u4e8e\u65b0\u7586\u7279\u8272\u8d44\u6e90\u4e59\u7094\u7684\u4e0b\u6e38\u4ea7\u54c1\u5f00\u5c55\u4e86\u7cfb\u7edf\u7814\u7a76\uff0c\u5efa\u7acb\u4e86\u4e59\u7094\u52a0\u6c22\u5236\u4e59\u70ef\u3001\u4e59\u7094\u6c22\u6c2f\u5316\u3001\u4e59\u7094\u4e8c\u805a\u3001\u4e59\u7094\u6c34\u5408\u7b49\u7eff\u8272\u50ac\u5316\u4f53\u7cfb\uff08\u56fe1\uff09\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-116442\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/12\/\u56fe\u72472-7.png\" alt=\"\" width=\"600\" height=\"357\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/12\/\u56fe\u72472-7.png 931w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/12\/\u56fe\u72472-7-300x179.png 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/12\/\u56fe\u72472-7-768x457.png 768w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p style=\"text-align: center\"><strong>\u56fe1<\/strong> \u4e59\u7094\u5316\u5de5\u7eff\u8272\u8fc7\u7a0b\u7684\u4e59\u7094\u6c22\u6c2f\u5316\u3001\u4e59\u7094\u6c34\u5408\u3001\u4e59\u7094\u52a0\u6c22\u548c\u4e59\u7094\u918b\u9178\u5316\u7b49\u5de5\u4e1a\u7eff\u8272\u8fc7\u7a0b\u50ac\u5316\u4f53\u7cfb\u3002<\/p>\n<p>\u4e59\u7094\u548c\u6c2f\u5316\u6c22\u53cd\u5e94\u751f\u6210\u6c2f\u4e59\u70ef\uff08VCM\uff09\u7684\u4e59\u7094\u6c22\u6c2f\u5316\u53cd\u5e94\u662fPVC\u5408\u6210\u8fc7\u7a0b\u4e2d\u7684\u91cd\u8981\u4e00\u73af\uff0c\u76ee\u524d\u4e59\u7094\u6c22\u6c2f\u5316\u53cd\u5e94\u5de5\u4e1a\u4e0a\u591a\u91c7\u7528HgCl<sub>2<\/sub>\u50ac\u5316\u5242\uff0c\u5728\u4e59\u7094\u6c22\u6c2f\u5316\u53cd\u5e94\u4e2d\u5177\u6709\u4f18\u5f02\u7684\u50ac\u5316\u6d3b\u6027\u548c\u9009\u62e9\u6027\uff0c\u4f46\u5b58\u5728\u53cd\u5e94\u8fc7\u7a0b\u4e2d\u4e0d\u65ad\u5347\u534e\u6d41\u5931\u7684\u73b0\u8c61\u3002\u6c5e\u50ac\u5316\u5242\u7684\u5347\u534e\u4e0d\u4ec5\u5bf9\u7a7a\u6c14\u3001\u571f\u58e4\u548c\u5730\u4e0b\u6c34\u9020\u6210\u91cd\u91d1\u5c5e\u6c61\u67d3\uff0c\u800c\u4e14\u5371\u5bb3\u4eba\u7c7b\u5065\u5eb7\uff0c\u8054\u5408\u56fd\u201c\u73af\u5883\u89c4\u5212\u7f72\u201d\u63d0\u51fa\u5c06\u4e8e2020\u5e74\u5728\u5168\u7403\u5168\u9762\u7981\u6b62\u6c5e\u50ac\u5316\u5242\u7684\u4f7f\u7528\u3002\u9762\u5bf9\u5168\u7403\u7981\u6c5e\u6240\u5e26\u6765\u7684\u538b\u529b\uff0c\u4e59\u7094\u6c22\u6c2f\u5316\u53cd\u5e94\u4e2d\u6c5e\u50ac\u5316\u5242\u4f7f\u7528\u95ee\u9898\u5df2\u6210\u4e3a\u5236\u7ea6\u7535\u77f3\u4e59\u7094\u6cd5PVC\u4ea7\u4e1a\u53d1\u5c55\u7684\u74f6\u9888\u3002\u201c\u975e\u6c5e\u201d\u50ac\u5316\u5242\u7684\u7814\u7a76\u4e0e\u5f00\u53d1\u662f\u4ece\u6839\u672c\u4e0a\u89e3\u51b3\u8fd9\u4e2a\u95ee\u9898\u7684\u552f\u4e00\u9014\u5f84\uff0c\u76f4\u63a5\u5f71\u54cd\u7740\u7535\u77f3\u4e59\u7094\u6cd5PVC\u4ea7\u4e1a\u7684\u751f\u5b58\u548c\u53d1\u5c55\u3002\u4ee3\u658c\u6559\u6388\u7814\u7a76\u56e2\u961f\u53d7\u9080\u5728ACS Catalysis\u4e0a\u53d1\u8868\u9898\u4e3a\u201cDevelopment of a Heterogeneous Non-Mercury Catalyst for Acetylene Hydrochlorination\u201d\u7684\u6587\u7ae0\uff08\u56fe2\uff09\uff0c\u4e3a\u4e59\u7094\u6c22\u6c2f\u5316\u6307\u660e\u4e86\u53d1\u5c55\u65b9\u5411\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-116443 aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/12\/\u56fe\u72473-7.png\" alt=\"\" width=\"500\" height=\"230\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/12\/\u56fe\u72473-7.png 500w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/12\/\u56fe\u72473-7-300x138.png 300w\" sizes=\"(max-width: 500px) 100vw, 500px\" \/><\/p>\n<p style=\"text-align: center\"><strong>\u56fe2<\/strong> \u4e59\u7094\u6c22\u6c2f\u5316\u975e\u6c5e\u50ac\u5316\u5242\uff08ACS Catalysis, <a href=\"http:\/\/pubs.acs.org\/doi\/abs\/10.1021\/acscatal.5b01178\">DOI:\u00a010.1021\/acscatal.5b01178<\/a>\uff09\u3002<\/p>\n<p>\u9488\u5bf9\u6c5e\u6392\u653e\u5e26\u6765\u7684\u4e25\u91cd\u73af\u5883\u6c61\u67d3\u95ee\u9898\uff0c\u8be5\u56e2\u961f\u8bbe\u8ba1\u4e86\u65b0\u578b\u91d1\u57fa\u50ac\u5316\u5242\uff0c\u5de5\u4e1a\u4fa7\u7ebf\u5b9e\u9a8c\u53ef\u7a33\u5b9a\u8fd0\u884c8000\u5c0f\u65f6\u4ee5\u4e0a\uff0c\u4e3a\u65e0\u6c5e\u50ac\u5316\u5242\u7684\u5de5\u4e1a\u5316\u751f\u4ea7\u63d0\u4f9b\u4e86\u57fa\u7840\u5b9e\u9a8c\u6570\u636e\u3002\u4f9d\u636eAu\uff08III\uff09\u5177\u6709\u8f83\u9ad8\u7684\u6807\u51c6\u8fd8\u539f\u7535\u52bf\uff0c\u5931\u6d3b\u539f\u56e0\u4e3b\u8981\u662f\u9ad8\u4ef7\u7684Au\u5728\u53cd\u5e94\u8fc7\u7a0b\u4e2d\u88ab\u8fd8\u539f\u6210\u5355\u8d28\u3002\u7ed3\u5408\u51e0\u79cd\u91d1\u5c5e\u5316\u5408\u7269\u7684\u6807\u51c6\u8fd8\u539f\u7535\u52bf\uff0c\u9009\u53d6Co\uff08III\uff09\uff0cCo\uff08II\uff09\u548cLa(III)\u7b49\u7ec4\u5206\u5206\u522b\u52a0\u5165Au\u57fa\u50ac\u5316\u5242\u4e2d\u4f5c\u4e3a\u52a9\u50ac\u5316\u5242\u3002\u5176\u4e2d\uff0c\u5177\u6709\u8f83\u9ad8\u6807\u51c6\u8fd8\u539f\u7535\u52bf\u7684Co(III)\u7684\u52a0\u5165\u53ef\u4ee5\u6709\u6548\u63d0\u9ad8\u50ac\u5316\u5242\u4e2dAu<sup>+<\/sup>\u7684\u542b\u91cf\uff0c\u6709\u5229\u4e8e\u7a33\u5b9aAu<sup>1+<\/sup>\uff0c\u6291\u5236\u6d3b\u6027\u7ec4\u5206Au<sup>3+<\/sup>\u7684\u8fd8\u539f\uff0c\u964d\u4f4e\u53cd\u5e94\u8fc7\u7a0b\u4e2dAu\u50ac\u5316\u5242\u8868\u9762\u7684\u79ef\u78b3\u751f\u6210\uff0c\u51cf\u7f13\u50ac\u5316\u5242\u5931\u6d3b\u901f\u7387\uff0c\u63d0\u5347\u50ac\u5316\u6027\u80fd\u548c\u5bff\u547d\u3002Au1Co(III)3\/SAC\u7684\u4e59\u7094\u8f6c\u5316\u7387\u53ef\u4ee5\u8fbe\u523092%\uff0c\u6c2f\u4e59\u70ef\u9009\u62e9\u6027\u5927\u4e8e99.9%\u3002\u6b64\u5916\uff0cCu<sup>2+<\/sup>\u7684\u52a0\u5165\u4e5f\u53ef\u4ee5\u589e\u52a0Au<sup>3+<\/sup>\u4e2d\u5fc3\u5468\u56f4\u7684\u7535\u5b50\u4e91\u5bc6\u5ea6\u7684\u4f18\u52bf\uff0c\u589e\u5f3a\u4e0eAu\u4e4b\u95f4\u7684\u76f8\u4e92\u4f5c\u7528\uff0c\u5927\u5927\u63d0\u5347\u5bf9HCl\u7684\u5438\u9644\uff0c\u4ece\u800c\u8d77\u5230\u5171\u50ac\u5316\u7684\u4f5c\u7528\u3002\u8be5\u56e2\u961f\u53d1\u73b0Au-Co(III)-Cu(II)\/SAC\u4e2dCo(III)\u548cCu(II)\u7684\u540c\u65f6\u5f15\u5165\u663e\u8457\u63d0\u9ad8\u4e86\u50ac\u5316\u5242\u4e2dAu<sup>+<\/sup>\u548cAu<sup>3+<\/sup>\u7684\u76f8\u5bf9\u542b\u91cf\uff0c\u5927\u5927\u63d0\u9ad8\u4e86Au\u57fa\u50ac\u5316\u5242\u7684\u50ac\u5316\u6027\u80fd\uff08\u56fe3\uff09\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-116444 aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/12\/\u56fe\u72474-7.png\" alt=\"\" width=\"458\" height=\"213\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/12\/\u56fe\u72474-7.png 458w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/12\/\u56fe\u72474-7-300x140.png 300w\" sizes=\"(max-width: 458px) 100vw, 458px\" \/><\/p>\n<p style=\"text-align: center\"><strong>\u56fe3<\/strong> \u4e59\u7094\u6c22\u6c2f\u5316Au\u57fa\u50ac\u5316\u5242\u7684\u50ac\u5316\u6027\u80fd \uff08Green Chemsitry, <a href=\"http:\/\/pubs.rsc.org\/-\/content\/articlehtml\/2013\/gc\/c3gc36840h\">DOI:10.1039\/C3GC36840H<\/a>; Journal of Industrial and Engineering Chemistry, <a href=\"https:\/\/www.sciencedirect.com\/science\/article\/pii\/S1226086X11002607\">DOI:10.1016\/j.jiec.2011.11.075<\/a>; Journal of Catalysis, <a href=\"https:\/\/www.sciencedirect.com\/science\/article\/pii\/S0021951714001262\">DOI:10.1016\/j.jcat.2014.05.005<\/a>\uff09<\/p>\n<p>\u540c\u65f6\uff0c\u4ee3\u658c\u6559\u6388\u7814\u7a76\u56e2\u961f\u5f00\u5c55\u4e86\u8fc7\u6e21\u91d1\u5c5e\u6c2e\u5316\u7269\uff08M<sub>x<\/sub>N<sub>y<\/sub>\uff09\u50ac\u5316\u5242\u7684\u7814\u7a76\u3002M<sub>x<\/sub>N<sub>y<\/sub>\u5177\u6709\u201c\u51c6\u94c2\u50ac\u5316\u5242\u201d\u7684\u7f8e\u8a89\uff0c\u5728\u4e00\u4e9b\u53cd\u5e94\u4e2d\u63a5\u8fd1\u6216\u8d85\u8fc7\u4e86\u8d35\u91d1\u5c5e\u50ac\u5316\u5242\u3002\u6c2e\u5316\u7269\u5728\u70c3\u7c7b\u8131\u6c22\u3001\u6c22\u89e3\u548c\u5f02\u6784\u5316\u53cd\u5e94\u4e2d\u7684\u50ac\u5316\u6d3b\u6027\uff0c\u751a\u81f3\u53ef\u4e0e\u8d35\u91d1\u5c5e\u91d1\u3001\u94c2\u3001\u948c\u7b49\u76f8\u5ab2\u7f8e\u3002\u901a\u8fc7DFT\u8ba1\u7b97\uff0c\u5206\u6790M<sub>x<\/sub>N<sub>y<\/sub>\u4e0d\u540c\u6676\u578b\u7ed3\u6784\u5bf9\u53cd\u5e94\u6c14\u4e59\u7094\u548c\u6c2f\u5316\u6c22\u7684\u5438\u9644\u80fd\u529b\uff0c\u5bf9\u6bd4\u76ee\u524d\u6d3b\u6027\u6700\u597d\u7684AuCl<sub>3<\/sub>\u50ac\u5316\u5242\uff0c\u53d1\u73b0Mo<sub>2<\/sub>N\uff0cW<sub>2<\/sub>N\uff0cVN\u7b49\u50ac\u5316\u5242\u5bf9\u4e59\u7094\u548cHCl\u5438\u9644\u80fd\u529b\u8fdc\u8fdc\u8d85\u51faAuCl<sub>3<\/sub>\u3002\u8be5\u7814\u7a76\u56e2\u961f\u5c06\u4e00\u4e9b\u8fc7\u6e21\u91d1\u5c5e\u6c2e\u5316\u7269\u8d1f\u8f7d\u5728\u6d3b\u6027\u70ad\u4e0a\u5e94\u7528\u4e8e\u4e59\u7094\u6c22\u6c2f\u5316\u53cd\u5e94\u4e2d\uff0c\u540c\u65f6\u7528\u7b49\u79bb\u5b50\u4f53\u6280\u672f\u5904\u7406\u50ac\u5316\u5242\uff0c\u53ef\u4ee5\u663e\u8457\u63d0\u9ad8\u8f7d\u4f53\u548c\u6d3b\u6027\u7ec4\u5206\u4e4b\u95f4\u7684\u76f8\u4e92\u4f5c\u7528\uff0c\u6291\u5236\u8868\u9762\u79ef\u78b3\u7684\u751f\u6210\uff0c\u540c\u65f6\u964d\u4f4e\u50ac\u5316\u5242\u4e2d\u6d3b\u6027\u7ec4\u5206\u7684\u8d1f\u8f7d\u91cf\uff0c\u63d0\u9ad8\u50ac\u5316\u6d3b\u6027\uff08\u56fe4\uff09\u3002\u5176\u4e2d\uff0cMo3Ti1N\/AC\u50ac\u5316\u5242\u7684\u4e59\u7094\u8f6c\u5316\u7387\u53ef\u8fbe89%\uff0c\u9009\u62e9\u6027\u53ef\u8fbe98.5%\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-116445 aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/12\/\u56fe\u72475-4.png\" alt=\"\" width=\"445\" height=\"383\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/12\/\u56fe\u72475-4.png 445w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/12\/\u56fe\u72475-4-300x258.png 300w\" sizes=\"(max-width: 445px) 100vw, 445px\" \/><\/p>\n<p style=\"text-align: center\"><strong>\u56fe4<\/strong> \u8fc7\u6e21\u91d1\u5c5e\u6c2e\u5316\u7269\uff08M<sub>x<\/sub>N<sub>y<\/sub>\uff09\u50ac\u5316\u5242\u7684TPR\u66f2\u7ebf\u4e0e\u4e59\u7094\u8f6c\u5316\u7387\uff08Journal of Industrial and Engineering Chemistry\uff0c <a href=\"https:\/\/www.sciencedirect.com\/science\/article\/pii\/S1226086X17300473\">DOI:\u00a010.1016\/j.jiec.2017.01.031<\/a>\uff09\u3002<\/p>\n<p>\u6b64\u5916\uff0c\u6742\u539f\u5b50\u63ba\u6742\u7684\u78b3\u57fa\u975e\u91d1\u5c5e\u6750\u6599\u5728\u4e59\u7094\u6c22\u6c2f\u5316\u53cd\u5e94\u4e2d\u8868\u73b0\u51fa\u4e86\u4f18\u5f02\u7684\u50ac\u5316\u6d3b\u6027\u3002\u8be5\u7814\u7a76\u56e2\u961f\u901a\u8fc7\u5bc6\u5ea6\u6cdb\u51fd\u7406\u8bba\u8ba1\u7b97\u8868\u660e\uff0c g-C<sub>3<\/sub>N<sub>4<\/sub>\u4e2d\u7684\u6c2e\u539f\u5b50\u4e3a\u53cd\u5e94\u7269\u6c2f\u5316\u6c22\u63d0\u4f9b\u6d3b\u6027\u4f4d\uff0c\u78b3\u539f\u5b50\u4e3a\u53cd\u5e94\u7269\u4e59\u7094\u63d0\u4f9b\u6d3b\u6027\u4f4d\uff0cg-C<sub>3<\/sub>N<sub>4<\/sub>\u80fd\u591f\u540c\u65f6\u5438\u9644\u548c\u6d3b\u5316\u53cd\u5e94\u7269\u4e59\u7094\u548c\u6c2f\u5316\u6c22\uff0c\u4ece\u800c\u5927\u5927\u63d0\u9ad8\u4e86\u50ac\u5316\u6d3b\u6027\uff08\u56fe5\uff09\u3002\u5728\u53cd\u5e94\u6e29\u5ea6\u4e3a180 <sup>o<\/sup>C\uff0c\u4e59\u7094\u7a7a\u901f\u4e3a50 h<sup>-1<\/sup>\u7684\u53cd\u5e94\u6761\u4ef6\u4e0b\uff0c\u4e59\u7094\u8f6c\u5316\u7387\u53ef\u4ee5\u8fbe\u523076%\u3002\u540c\u65f6\uff0c\u5728\u6c2e\u63ba\u6742\u77f3\u58a8\u70ef\u7684\u6676\u683c\u4e2d\u5f15\u5165\u787c\u539f\u5b50\uff0c\u6539\u53d8\u4e86\u5421\u5576N-C\u3001\u5421\u54afN-C\u6d3b\u6027\u4f4d\u7684\u7535\u5b50\u5206\u5e03\u72b6\u6001\uff0c\u4e5f\u53ef\u4ee5\u4fc3\u8fdb\u5bf9HCl\u7684\u5438\u9644\uff0c\u4f7f\u5176\u6210\u4e3a\u975e\u5e38\u6d3b\u6cfc\u7684\u6d3b\u6027\u4f4d\u70b9\uff08\u56fe6\uff09\u3002\u7814\u7a76\u53d1\u73b0B, N-G\u50ac\u5316\u5242\u6d3b\u6027\u6700\u4e3a\u4f18\u5f02\uff0c\u4e59\u7094\u8f6c\u5316\u7387\u53ef\u8fbe95%\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-116446 aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/12\/\u56fe\u72476-2.png\" alt=\"\" width=\"457\" height=\"407\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/12\/\u56fe\u72476-2.png 457w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/12\/\u56fe\u72476-2-300x267.png 300w\" sizes=\"(max-width: 457px) 100vw, 457px\" \/><\/p>\n<p style=\"text-align: center\"><strong>\u56fe 5<\/strong>\u00a0g-C<sub>3<\/sub>N<sub>4<\/sub>\/AC \u975e\u91d1\u5c5e\u50ac\u5316\u5242\u50ac\u5316\u673a\u7406\u56fe\uff08Journal of Catalysis, <a href=\"http:\/\/www.sciencedirect.com\/science\/article\/pii\/S0021951713004399\">DOI:\u00a010.1016\/j.jcat.2013.12.006<\/a>\uff09<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-116447\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/12\/\u56fe\u72477-1.png\" alt=\"\" width=\"600\" height=\"339\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/12\/\u56fe\u72477-1.png 676w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/12\/\u56fe\u72477-1-300x170.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p style=\"text-align: center\"><strong>\u56fe6<\/strong>\u00a0HCl-TPD\u66f2\u7ebf\uff1a(a)GO,(b)N-G\u548c(c)B,N-G\uff08ACS Catalysis, <a href=\"http:\/\/pubs.acs.org\/doi\/abs\/10.1021\/acscatal.5b00199\">DOI:10.1021\/acscatal.5b00199<\/a>\uff09\u3002<\/p>\n<p>\u672c\u6587\u7531\u6750\u6599\u4eba\u7279\u7ea6\u7f16\u8f91\u5434\u79b9\u7ff0\u7ea6\u7a3f\u3001\u5ba1\u6838\u3001\u53d1\u5e03\uff1b\u77f3\u6cb3\u5b50\u5927\u5b66\u4ee3\u658c\u6559\u6388\u8bfe\u9898\u7ec4\u4f9b\u7a3f\uff0c\u7279\u6b64\u611f\u8c22\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u4ee3\u658c\uff0c\u7537\uff0c1969\u5e7410\u6708\u751f\uff0c\u56db\u5ddd\u6e20\u53bf\u4eba\uff0c\u535a\u58eb\uff0c\u6559\u6388\uff0c\u56fd\u52a1\u9662\u7279\u6b8a\u6d25\u8d34\u4e13\u5bb6\uff0c\u56fd\u5bb6\u201c\u4e07\u4eba\u8ba1\u5212\u201d\u79d1\u6280\u9886\u519b\u4eba\u624d\uff0c\u79d1\u6280\u90e8\u201c\u521b\u65b0\u4eba\u624d\u63a8\u8fdb\u8ba1\u5212\u201d\u4e2d\u9752\u5e74\u79d1\u6280\u9886\u519b\u4eba\u624d\u3001\u56fd\u5bb6\u767e\u5343\u4e07&#8230;<\/p>\n","protected":false},"author":4695,"featured_media":116441,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[3],"tags":[],"class_list":["post-116440","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-yejie"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/116440"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/4695"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=116440"}],"version-history":[{"count":3,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/116440\/revisions"}],"predecessor-version":[{"id":116451,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/116440\/revisions\/116451"}],"wp:featuredmedia":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/media\/116441"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=116440"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=116440"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=116440"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}