{"id":116236,"date":"2017-12-18T06:30:42","date_gmt":"2017-12-17T22:30:42","guid":{"rendered":"\/\/m.iemloyee.com\/?p=116236"},"modified":"2017-12-17T20:18:48","modified_gmt":"2017-12-17T12:18:48","slug":"%e5%ad%a6%e6%9c%af%e5%b9%b2%e8%b4%a7-nmr%e5%8e%9f%e7%90%86%e5%8f%8a%e5%85%b6%e5%9c%a8%e8%83%bd%e6%ba%90%e7%a0%94%e7%a9%b6%e4%b8%ad%e7%9a%84%e5%ba%94%e7%94%a8","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=116236","title":{"rendered":"\u5b66\u672f\u5e72\u8d27 | NMR\u539f\u7406\u53ca\u5176\u5728\u80fd\u6e90\u7814\u7a76\u4e2d\u7684\u5e94\u7528"},"content":{"rendered":"

\u6838\u78c1\u5171\u632f\u6280\u672f\u5728\u79d1\u7814\u8fc7\u7a0b\u4e2d\u8d77\u7740\u91cd\u8981\u4f5c\u7528\uff0c\u672c\u6587\u5c06\u7b80\u5355\u4ecb\u7ecd\u5176\u539f\u7406\u548c\u5728\u80fd\u6e90\u9886\u57df\u4e2d\u7684\u5e94\u7528\u3002<\/p>\n

\"\"<\/p>\n

\u56fe1 \u5b9e\u9a8c\u5ba4\u7528AniMR-150\u6838\u78c1\u5171\u632f\u4eea<\/p>\n

1\u00a0<\/strong>\u6838\u78c1\u5171\u632f\u539f\u7406<\/strong><\/span><\/p>\n

\u6211\u4eec\u77e5\u9053\u539f\u5b50\u6838\u90fd\u53ef\u4ee5\u81ea\u65cb\uff0c\u6839\u636e\u81ea\u65cb\u91cf\u5b50\u6570\u5c06\u539f\u5b50\u6838\u5927\u81f4\u5206\u4e3a3\u7c7b\uff1a\u4e00\u79cd\u662f\u81ea\u65cb\u91cf\u5b50\u6570\u4e3a0\u7684\u539f\u5b50\u6838\uff0c\u7ecf\u8fc7\u5b9e\u9a8c\u8bc1\u660e\uff0c\u6b64\u7c7b\u539f\u5b50\u6838\u6ca1\u6709\u81ea\u65cb\u73b0\u8c61\uff0c\u4e0d\u80fd\u4ea7\u751f\u78c1\u77e9\uff1b\u4e00\u79cd\u662f\u81ea\u65cb\u91cf\u5b50\u6570\u5927\u4e8e\u7b49\u4e8e1\u7684\uff0c\u8fd9\u79cd\u539f\u5b50\u6838\u6838\u7535\u5206\u5e03\u53ef\u4ee5\u770b\u6210\u4e00\u4e2a\u692d\u5706\u4f53\uff0c\u5171\u632f\u5438\u6536\u4f1a\u4ea7\u751f\u5f88\u590d\u6742\u7684\u60c5\u51b5\uff0c\u5e94\u7528\u8f83\u5c11\uff1b\u53e6\u4e00\u79cd\u662f\u81ea\u65cb\u91cf\u5b50\u6570\u4e3a1\/2\u7684\u539f\u5b50\u6838\uff0c\u5e38\u89c1\u7684\u67091H\u300119F\u300131P\u300113C\u7b49\uff0c\u5176\u6838\u7535\u5206\u5e03\u53ef\u4ee5\u770b\u6210\u4e00\u4e2a\u7535\u8377\u5747\u5300\u7684\u7403\u4f53\uff0c\u65cb\u8f6c\u5373\u4ea7\u751f\u78c1\u77e9\u3002\u76ee\u524d\u8fd9\u4e9b\u539f\u5b50\u6838\u5e38\u7528\u4e8e\u6838\u78c1\u5171\u632f\u7814\u7a76\u4e2d\u3002<\/p>\n

\u4e0b\u9762\u4ee5\u6c22\u6838\u4e3a\u4f8b\u8fdb\u884c\u4ecb\u7ecd\u3002<\/p>\n

\u7531\u4e8e\u5e26\u7535\u6838\u7684\u65cb\u8f6c\uff0c\u4f1a\u4ea7\u751f\u4e00\u4e2a\u5fae\u5c0f\u7684\u78c1\u573a\uff0c\u4e00\u822c\u800c\u8a00\uff0c\u81ea\u65cb\u6742\u4e71\u65e0\u7ae0\uff0c\u4f46\u82e5\u5c06\u5176\u7f6e\u4e8e\u8f83\u5f3a\u78c1\u573a\u4e2d\uff0c\u5176\u5fc5\u5b9a\u6cbf\u7740\u78c1\u573a\u7684\u65b9\u5411\u91cd\u65b0\u6392\u5217\uff0c\u5f53\u6838\u7684\u81ea\u65cb\u8f74\u504f\u79bb\u4e86\u5916\u52a0\u78c1\u573a\u7684\u65b9\u5411\u65f6\uff0c\u6838\u81ea\u65cb\u4ea7\u751f\u7684\u78c1\u573a\u5373\u4f1a\u4e0e\u5916\u78c1\u573a\u76f8\u4e92\u4f5c\u7528\uff0c\u4f7f\u539f\u5b50\u6838\u9664\u4e86\u81ea\u65cb\u4e4b\u5916\uff0c\u8fd8\u4f1a\u6cbf\u7740\u5706\u9525\u5f62\u7684\u4fa7\u9762\u56f4\u7ed5\u539f\u6765\u7684\u8f74\u6446\u52a8\uff0c\uff08\u7c7b\u4f3c\u4e8e\u9640\u87ba\u7684\u6446\u52a8\uff09\uff0c\u8fd9\u79cd\u8fd0\u52a8\u65b9\u5f0f\u79f0\u4e3a\u8fdb\u52a8\u3002\u81ea\u65cb\u6838\u89d2\u901f\u5ea6\u03c90<\/sub>\uff0c\u5916\u52a0\u78c1\u573a\u78c1\u611f\u5e94\u5f3a\u5ea6B0<\/sub>\u548c\u8fdb\u52a8\u9891\u7387\u03bd0<\/sub>\u6ee1\u8db3\u5173\u7cfb\uff1a<\/p>\n

\u03c90<\/sub>=2\u03c0\u03bd0<\/sub>=\u03b3B0<\/sub><\/p>\n

\u6c22\u6838\u7f6e\u4e8e\u5916\u52a0\u78c1\u573a\u4e2d\u4f1a\u4ea7\u751f\u4e24\u79cd\u53d6\u5411\uff0c\u5206\u522b\u662fm=1\/2\u548cm=-1\/2\uff0c\u524d\u8005\u53d6\u5411\u4e0e\u78c1\u573a\u65b9\u5411\u76f8\u540c\uff0c\u540e\u8005\u4e0e\u78c1\u573a\u65b9\u5411\u76f8\u53cd\uff0c\u6545\u524d\u8005\u80fd\u91cf\u8f83\u4f4e\uff0c\u80fd\u91cf\u5dee\u4e3a\uff1a<\/p>\n

\u0394E=2\u03bcB0<\/sub><\/p>\n

\u6b64\u65f6\u5982\u679c\u5b58\u5728\u4e00\u4e2a\u5c04\u9891\u573a\uff0c\u9891\u7387\u7b49\u4e8e\u8fdb\u52a8\u9891\u7387\uff0c\u5219\u539f\u5b50\u6838\u5c31\u4f1a\u4e0e\u4e4b\u53d1\u751f\u5171\u632f\uff0c\u5438\u6536\u80fd\u91cf\u4f7f\u6838\u8dc3\u8fc1\u5230\u8f83\u9ad8\u80fd\u6001\uff0c\u8fd9\u79cd\u73b0\u8c61\u5c31\u662f\u6838\u78c1\u5171\u632f\u3002\u7531\u4e8e\u4e0d\u540c\u539f\u5b50\u6838\u53d1\u751f\u5171\u632f\u7684\u9891\u7387\u5404\u4e0d\u76f8\u540c\uff0c\u56e0\u800c\u53ef\u5229\u7528\u8fd9\u4e9b\u5dee\u8ddd\u6765\u9274\u522b\u5404\u79cd\u5143\u7d20\u548c\u540c\u4f4d\u7d20\u3002\u8fd9\u91cc\u9700\u8981\u6ce8\u610f\u7684\u662f\uff0c\u9ad8\u80fd\u6001\u7684\u539f\u5b50\u6838\u4f1a\u901a\u8fc7\u5f1b\u8c6b\u8fc7\u7a0b\u56de\u590d\u5230\u4f4e\u80fd\u6001\uff0c\u4ece\u800c\u53ef\u4ee5\u4fdd\u6301\u5171\u632f\u5438\u6536\u5cf0\u6709\u7a33\u5b9a\u7684\u4fe1\u53f7\u3002<\/p>\n

\"\"<\/p>\n

\u56fe2 \u539f\u5b50\u6838\u7684\u8fdb\u52a8\u53ca\u53d6\u5411<\/p>\n

2\u00a0<\/strong>\u5728\u80fd\u6e90\u9886\u57df\u5e94\u7528<\/strong><\/span><\/p>\n

\u4e0e\u5176\u4ed6\u7c7b\u578b\u7684\u5206\u6790\u4eea\u5668\u76f8\u6bd4\uff0c\u6838\u78c1\u5171\u632f\u8bbe\u5907\u6700\u5927\u7684\u4f18\u70b9\u5373\u5728\u4e8e\u65e0\u635f\u68c0\u6d4b\uff0c\u540c\u65f6\u8fc5\u901f\u7684\u5206\u6790\u7269\u8d28\u7684\u5316\u5b66\/\u7ed3\u6784\u4fe1\u606f\uff0c\u56e0\u6b64\u5176\u5e94\u7528\u9762\u5e7f\u6cdb\u3002\u4e3b\u8981\u5e94\u7528\u5728\u7164\u70ad\u3001\u77f3\u6cb9\u9886\u57df\uff0c\u8fd1\u5e74\u6765\u56fa\u4f53NMR\u6280\u672f\u4e5f\u5df2\u88ab\u5e7f\u6cdb\u5e94\u7528\u4e8e\u7535\u5316\u5b66\u50a8\u80fd\u4f53\u7cfb\u3002<\/p>\n

2.1 <\/strong>\u7164\u70ad<\/strong><\/p>\n

NMR\u6280\u672f\u5728\u7164\u70ad\u5316\u5b66\u7ec4\u6210\u548c\u7269\u7406\u5f62\u6001\u5206\u6790\u4e2d\u53d1\u6325\u7740\u8d8a\u6765\u8d8a\u91cd\u8981\u7684\u4f5c\u7528\u3002\u5176\u4e3b\u8981\u4f18\u52bf\u5728\u4e8e\u68c0\u6d4b\u5bf9\u8c61\u7684\u72b6\u6001\u51e0\u4e4e\u4e0d\u53d7\u9650\u5236\uff0c\u53ef\u4ee5\u662f\u539f\u7164\u6216\u7ecf\u8fc7\u52a0\u5de5\u5904\u7406\u7684\u7164\u70ad\uff0c\u4e5f\u53ef\u4ee5\u662f\u7164\u70ad\u7684\u6c14\u5316\u3001\u70ed\u89e3\u6216\u6db2\u5316\u4ea7\u7269\uff0c\u7531\u4e8e\u5176\u975e\u63a5\u89e6\u5f0f\u5feb\u901f\u6d4b\u91cf\u7684\u7279\u70b9\uff0c\u7164\u70ad\u5316\u5de5\u8fc7\u7a0b\u4e0d\u540c\u9636\u6bb5\u7684\u4e2d\u95f4\u4ea7\u7269\u4e5f\u53ef\u4ee5\u68c0\u6d4b\u3002<\/p>\n

\u5728\u7164\u70ad\u68c0\u6d4b\u4f7f\u7528\u5230\u7684NMR\u6280\u672f\u65b9\u6cd5\u4e3b\u8981\u67092\u79cd\uff1a\u6db2\u4f53NMR\u548c\u56fa\u4f53NMR\u3002\u5176\u4e2d\uff0c\u6db2\u4f53NMR\u4e3b\u8981\u662f\u6db2\u4f531H-NMR\u8c31\u300113C-NMR\u8c31\u3001\u591a\u8109\u51b2\u5e8f\u5217\u5982DEPT\u6280\u672f\uff08\u65e0\u7578\u53d8\u6781\u5316\u8f6c\u79fb\u589e\u5f3a\u6cd5)\u3001\u6db2\u4f53\u4e8c\u7ef4\u8c31\u7b49\u7b49\u3002\u56fa\u4f53NMR\u4e3b\u8981\u5305\u62ec\u4ea4\u53c9\u6781\u5316(CP)\u3001\u9ad8\u529f\u7387\u8d28\u5b50\u53bb\u8026\u3001\u9b54\u89d2\u65cb\u8f6c(MAS)\u3001\u5076\u6781\u53bb\u76f8(DD)\u3001\u56fa\u4f53\u4e8c\u7ef4\u8c31\u7b49\u3002<\/p>\n

NMR\u5728\u7164\u70ad\u4e2d\u7684\u5e94\u7528\u4e3b\u8981\u5206\u4e3a\u4e24\u5927\u7c7b\uff1a\u4e00\u662f\u5206\u6790\u7164\u70ad\u7ec4\u6210\uff0c\u5982\u82b3\u9999\u65cf\u3001\u8102\u73af\u65cf\u7269\u8d28\u542b\u91cf\u5206\u6790\uff0c\u6db2\u5316\u4ea7\u7269\u7684\u8272\u8c31\u548cNMR\u5206\u6790\uff0c\u52a0\u6c22\u4ea7\u7269\u5206\u6790\uff0c\u7164\u70ad\u548c\u6ca5\u9752\u78b3\u5316\u521d\u671f\u7ec4\u6210\u53d8\u5316\u7684\u9ad8\u6e291H-NMR\u5206\u6790\uff0c\u915a\u7c7b\u5206\u6790\uff0c\u7164\u70ad\u4f4e\u6e29\u6c27\u5316\u7279\u5f81\u5206\u6790\u7b49\uff1b\u4e8c\u662f\u7164\u70ad\u7684\u70ed\u89e3\u4ea7\u7269\u5b9e\u65f6\u76d1\u6d4b\uff0c\u5982\u89c2\u6d4b\u70ed\u89e3\u8fc7\u7a0b\u4e2d\u8102\u80aa\u78b3\u548c\u82b3\u9999\u78b3\u76f8\u5bf9\u542b\u91cf\u7684\u53d8\u5316\uff0c\u5206\u6790\u7164\u70ad\u4e2d\u4e0d\u540c\u79cd\u7c7b\u7684\u5b98\u80fd\u56e2\u7b49\u3002\u53e6\u5916\uff0c\u5b83\u8fd8\u662f\u76ee\u524d\u552f\u4e00\u4e00\u79cd\u53ef\u4ee5\u540c\u65f6\u6d4b\u5b9a\u542b\u6c34\u7387\u548c\u7164\u6837\u5b54\u9699\u7ed3\u6784\u7684\u6d4b\u8bd5\u65b9\u6cd5\u3002<\/p>\n

2.2 <\/strong>\u77f3\u6cb9<\/strong><\/p>\n

NMR\u6280\u672f\u4e8e20\u4e16\u7eaa\u672b\u5f00\u59cb\u5e94\u7528\u4e8e\u77f3\u6cb9\u5730\u8d28\u7814\u7a76\u3002\u5982\u4eca\u5e94\u7528\u8303\u56f4\u6d89\u53ca\u5230\u77f3\u6cb9\u5730\u8d28\u3001\u77f3\u6cb9\u6d4b\u4e95\u3001\u77f3\u6cb9\u5316\u5de5\u7b49\u9886\u57df\u3002<\/p>\n

\u5728\u5730\u8d28\u52d8\u63a2\u9886\u57df\u4e2d\uff0c\u4e3b\u8981\u4f7f\u7528\u5085\u91cc\u53f6\u6838\u78c1\u53d8\u6362\u5171\u632f\u6ce2\u8c31\u4eea\u4ee5\u53ca\u591a\u8109\u51b2\u7535\u78c1\u5206\u8fa8\u8c31\u7b49\u8bbe\u5907\u3002\u4e3b\u8981\u5e94\u7528\u5305\u62ec\uff1a\u5206\u7c7b\u5e72\u916a\u6839\u3001\u786e\u5b9a\u6709\u673a\u8d28\u6210\u719f\u5ea6\u3001\u8bc4\u4ef7\u751f\u6cb9\u6d45\u91cf\u7b49\u3002<\/p>\n

\u5728\u6d4b\u4e95\u9886\u57df\uff0c\u4e3b\u8981\u5229\u7528\u6838\u78c1\u6d4b\u4e95\u6280\u672f\u3002\u57fa\u672c\u539f\u7406\u662f\u5728\u4e95\u4e2d\u653e\u7f6e\u4e00\u5757\u78c1\u4f53\uff0c\u53d1\u5c04\u7b49\u4e8e\u8be5\u5747\u5300\u6781\u5316\u533a\u57df\u6c22\u6838\u7684\u6838\u78c1\u5171\u632f\u9891\u7387\uff0c\u63a5\u53d7\u6c22\u6838\u5728\u9000\u6fc0\u8fc7\u7a0b\u4e2d\u7684\u8870\u51cf\u4fe1\u53f7\uff0c\u5229\u7528\u6cb9\u4e0e\u6c34\u5f1b\u8c6b\u65f6\u95f4\u7684\u5dee\u522b\u6765\u68c0\u9a8c\u6cb9\u5c42\u3002\u4f7f\u7528\u8be5\u6280\u672f\u53ef\u4ee5\u514b\u670d\u4ee5\u4f53\u79ef\u6a21\u578b\u4e3a\u57fa\u7840\u7684\u4f20\u7edf\u65b9\u6cd5\u53d7\u4e95\u773c\uff0c\u5ca9\u6027\u53ca\u5730\u5c42\u6c34\u77ff\u5316\u5ea6\u5f71\u54cd\u7684\u7f3a\u9677\uff0c\u89e3\u51b3\u6cb9\u6c14\u85cf\u7684\u50a8\u5c42\u8bc4\u4ef7\u548c\u6cb9\u6c14\u8bc6\u522b\u95ee\u9898\u3002\u4f7f\u7528\u5e73\u5747\u7ed3\u6784\u4fe1\u606f\u6765\u8bc4\u4f30\u539f\u6cb9\u603b\u4f53\u7279\u6027\u4e5f\u6709\u52a9\u4e8e\u77f3\u6cb9\u5de5\u4e1a\u7684\u751f\u4ea7\u3002<\/p>\n

\u7531\u4e8e\u6cb9\u6c14\u6c34\u5728\u6838\u78c1\u5171\u632f\u7279\u6027\u4e0a\u5dee\u5f02\u5de8\u5927\uff0c\u5728\u50a8\u5c42\u7269\u6027\u4e0a\uff0c\u53ef\u4ee5\u7528\u6838\u78c1\u6d4b\u4e95\u6280\u672f\u8bc4\u4ef7\u5b54\u9699\u5ea6\uff0c\u6e17\u900f\u7387\u53ca\u9971\u548c\u5ea6\u3002\u5728\u50a8\u5c42\u6d41\u4f53\u8bc6\u522b\u65b9\u9762\uff0c\u53ef\u4ee5\u5229\u7528\u6cb9\u6c14\u6c34\u7684\u7eb5\u5411\u5f1b\u8c6b\u65f6\u95f4\u548c\u6269\u6563\u7cfb\u6570\u7684\u5dee\u5f02\u8bc6\u522b\u4e09\u8005\uff0c\u5bf9\u4e8e\u4f4e\u963b\u6cb9\u5c42\u7b49\u7535\u963b\u7387\u6d4b\u4e95\u4f20\u7edf\u65b9\u6cd5\u8bc6\u522b\u6709\u56f0\u96be\u7684\u50a8\u5c42\u5f88\u5b9e\u7528\u3002\u53e6\u5916\uff0c\u6838\u78c1\u5171\u632f\u5f55\u4e95\u53c2\u6570\u4e2d\u5305\u542b\u4e86\u6cb9\u6c14\u542b\u91cf\u548c\u4ea7\u51fa\u80fd\u529b\u7b49\u4fe1\u606f\uff0c\u53ef\u4ee5\u4e3a\u8bd5\u6cb9\u5c42\u4f4d\u7684\u786e\u5b9a\u63d0\u4f9b\u8d44\u6599\uff0c\u4e3a\u94bb\u4e95\u65bd\u5de5\u8bbe\u8ba1\u63d0\u4f9b\u53c2\u8003\u7684\u5730\u5c42\u538b\u529b\u68af\u5ea6\u548c\u7834\u88c2\u538b\u529b\u68af\u5ea6\u3002<\/p>\n

\u5728\u77f3\u6cb9\u5316\u5de5\u9886\u57df\uff0c\u53ef\u4ee5\u4f7f\u7528\u6838\u78c1\u5171\u632f\u6280\u672f\u5206\u6790\u539f\u6cb9\u7684\u5404\u4e2a\u998f\u5206\u6bb5\uff0c\u6bd4\u5982\u67f4\u6cb9\u7ec4\u5206\u3001\u51cf\u538b\u998f\u5206\u3001\u6e23\u6cb9\u7684\u5316\u5b66\u7ec4\u6210\u4e0e\u7ed3\u6784\u7b49\u3002\u5177\u4f53\u8bf4\u6765\uff0c\u5229\u752813<\/sup>C-NMR\u8c31\u5206\u6790\u539f\u6cb9\u70c3\u7c7b\u542b\u91cf\u3002\u6839\u636e\u70c3\u7c7b\u7ec4\u6210\u53ef\u4ee5\u5c06\u539f\u6cb9\u6709\u6548\u5206\u7c7b\u3002\u5bf9\u4e8e\u71c3\u6599\u6cb9\uff0c\u53ef\u4ee5\u76f4\u63a5\u6d4b\u5b9a\u5176\u4e2d\u67d0\u4e9b\u7ec4\u5206\u7684\u542b\u91cf\u3001\u6d4b\u5b9a\u7ed3\u6784\u53c2\u6570\u5e76\u5bfb\u627e\u5176\u4f59\u6cb9\u54c1\u6027\u8d28\u7684\u5173\u7cfb\uff1b\u5bf9\u4e8e\u8721\u6cb9\u548c\u91cd\u6cb9\uff0c\u53ef\u4ee5\u5b9a\u6027\u5b9a\u91cf\u5730\u53cd\u6620\u51fa\u78b3\u6c22\u53ca\u6742\u539f\u5b50\u6240\u5904\u7684\u5316\u5b66\u73af\u5883\u3002<\/p>\n

2.3 <\/strong>\u9502<\/strong>\/<\/strong>\u94a0\u79bb\u5b50\u7535\u6c60\u6750\u6599<\/strong><\/p>\n

\u9502\/\u94a0\u79bb\u5b50\u7535\u6c60\u6750\u6599\u5c40\u57df\u7ed3\u6784\u662f\u5f71\u54cd\u6750\u6599\u5faa\u73af\u6027\u80fd\u548c\u500d\u7387\u6027\u80fd\u7684\u91cd\u8981\u56e0\u7d20\u3002\u56fa\u4f53\u6838\u78c1\u5171\u632f\u6280\u672f\u3001XAS\u548c\u5bf9\u5bc6\u5ea6\u5206\u5e03\u51fd\u6570\u662f\u5e38\u7528\u7684\u8868\u5f81\u6750\u6599\u5c40\u57df\u7ed3\u6784\u7684\u529e\u6cd5\u3002\u5176\u4e2d\uff0c\u56fa\u4f53NMR\u6280\u672f\u7531\u4e8e\u65e0\u635f\uff0c\u5b9a\u91cf\uff0c\u539f\u4f4d\u7684\u4f18\u70b9\uff0c\u5341\u5206\u6709\u6548\u4fbf\u5229\u3002\u5728\u7535\u6c60\u6750\u6599NMR\u7814\u7a76\u4e2d\u5e38\u7528\u8bd5\u9a8c\u65b9\u6cd5\u5982\u88681\u6240\u793a\u3002<\/p>\n

\u88681 \u7535\u6c60\u6750\u6599NMR\u7814\u7a76\u5e38\u7528\u7814\u7a76\u65b9\u6cd5<\/p>\n

\"\"<\/p>\n

2.4 <\/strong>\u5149\u50ac\u5316\u5206\u89e3\u6c34<\/strong><\/p>\n

\u81ea\u4ece1972\u5e74Fujishima \u7b49\u4eba\u9996\u6b21\u53d1\u73b0\u4f7f\u7528\u7d2b\u5916\u5149\u7167\u5c04TiO2<\/sub>\u7535\u6781\u53ef\u4ee5\u5206\u89e3\u6c34\u4ea7\u751fH2<\/sub>\u4ee5\u6765\uff0c\u5f00\u53d1\u5ec9\u4ef7\u5b9e\u7528\u7684\u65b0\u578b\u50ac\u5316\u5242\u4e00\u76f4\u662f\u5b9e\u73b0\u592a\u9633\u80fd\u5206\u89e3\u6c34\u9ad8\u6548\u5229\u7528\u7684\u5173\u952e\u56e0\u7d20\u3002\u8fd1\u5e74\u6765\u4f17\u591a\u7814\u7a76\u8005\u4f7f\u7528STM\u3001FTIR\u3001TPD\u3001DFT\u7b49\u624b\u6bb5\u7814\u7a76\u5206\u89e3\u6c34\u7684\u5fae\u89c2\u8fc7\u7a0b\uff0c\u4f46\u5176\u6d4b\u8bd5\u6761\u4ef6\u8fc7\u4e8e\u7406\u60f3\u5316\uff0c\u4e0e\u5b9e\u9645\u5b58\u5728\u8f83\u5927\u5dee\u8ddd\u3002\u6838\u78c1\u5171\u632f\u6280\u672f\u53ef\u5b9e\u73b0\u539f\u4f4d\u65e0\u635f\u68c0\u6d4b\u4e14\u53ef\u4ee5\u51c6\u786e\u9274\u5b9a\u672a\u77e5\u5316\u5408\u7269\u7ed3\u6784\uff0c\u56e0\u6b64\u5728\u5fae\u89c2\u53cd\u5e94\u8fc7\u7a0b\u7814\u7a76\u4e2d\u6709\u4e00\u5b9a\u4f18\u52bf\u3002<\/p>\n

\"\"<\/p>\n

\u56fe3 \u6838\u78c1\u539f\u4f4d\u68c0\u6d4b\u5149\u50ac\u5316\u5206\u89e3\u6c34\u5236\u6c22\u53cd\u5e94\u793a\u610f\u56fe<\/p>\n

3 <\/strong>\u5c0f\u7ed3<\/strong><\/span><\/p>\n

\u6838\u78c1\u5171\u632f\u5177\u6709\u5feb\u901f\u3001\u51c6\u786e\u3001\u65e0\u635f\u7684\u7279\u70b9\uff0c\u5728\u80fd\u6e90\u9886\u57df\u5e94\u7528\u5e7f\u6cdb\u3002\u76ee\u524d\u5728\u4f20\u7edf\u80fd\u6e90\u9886\u57df\u5982\u77f3\u6cb9\u3001\u7164\u70ad\u9886\u57df\u7684\u52d8\u63a2\u3001\u539f\u4f4d\u68c0\u6d4b\u4e0a\u6709\u5f88\u591a\u5e94\u7528\u3002\u5728\u65b0\u80fd\u6e90\u9886\u57df\uff0c\u5982\u9502\u79bb\u5b50\u7535\u6c60\u3001\u5149\u50ac\u5316\u4e0a\uff0c\u7531\u4e8e\u5bf9\u6750\u6599\u5c40\u57df\u7ed3\u6784\u7684\u8868\u5f81\uff0c\u4e5f\u6b63\u5728\u6269\u5927\u5e94\u7528\uff0c\u672a\u6765\u53ef\u80fd\u4f1a\u6709\u66f4\u591a\u7684\u5e94\u7528\u3002<\/p>\n

\u53c2\u8003\u6587\u732e<\/strong><\/p>\n

[1] \u6731\u660e\u534e. \u4eea\u5668\u5206\u6790[M]. \u5317\u4eac: \u9ad8\u7b49\u6559\u80b2\u51fa\u7248\u793e, 2007.<\/p>\n

[2] \u738b\u79c0\u6885. \u6cb8\u77f3\u5206\u5b50\u7b5b\u4e0a\u4f4e\u78b3\u70f7\u70c3\u53ca\u4e00\u6c27\u5316\u78b3\u6d3b\u5316\u4e0e\u8f6c\u5316\u673a\u7406\u7684\u56fa\u4f53\u6838\u78c1\u5171\u632f\u7814\u7a76[D]. \u6b66\u6c49: \u4e2d\u56fd\u79d1\u5b66\u9662\u7814\u7a76\u751f\u9662(\u6b66\u6c49\u7269\u7406\u4e0e\u6570\u5b66\u7814\u7a76\u6240), 2013.<\/p>\n

[3] \u5f20\u65ed. \u57fa\u4e8e\u4f4e\u573a\uff5e1H\u6838\u78c1\u5171\u632f\u7684\u9521\u76df\u8910\u7164\u6c34\u5206\u5f62\u6001\u5b9e\u9a8c\u7814\u7a76[D].\u676d\u5dde: \u6d59\u6c5f\u5927\u5b66, 2016.<\/p>\n

[4] \u9ec4\u5c11\u51ef. \u6838\u78c1\u5171\u632f\u6280\u672f\u5728\u7164\u70ad\u7ed3\u6784\u5206\u6790\u4e2d\u7684\u5e94\u7528\u7814\u7a76[A]. \u4e2d\u56fd\u7269\u7406\u5b66\u4f1a\u6ce2\u8c31\u4e13\u4e1a\u59d4\u5458\u4f1a. \u7b2c\u5341\u4e03\u5c4a\u5168\u56fd\u6ce2\u8c31\u5b66\u5b66\u672f\u4f1a\u8bae\u8bba\u6587\u6458\u8981\u96c6[C].\u4e2d\u56fd\u7269\u7406\u5b66\u4f1a\u6ce2\u8c31\u4e13\u4e1a\u59d4\u5458\u4f1a, 2012.<\/p>\n

[5] \u8d75\u5e38\u4fca, \u5434\u4e50\u4e50. \u6838\u78c1\u5171\u632f\u6280\u672f\u5728\u77f3\u6cb9\u884c\u4e1a\u4e2d\u7684\u5e94\u7528[J]. \u5c71\u4e1c\u5316\u5de5, 2016, 45(03): 86-89.<\/p>\n

[6] \u7a0b\u534e\u56fd. \u77f3\u6cb9\u5de5\u7a0b\u4e2d\u7684\u6838\u78c1\u5171\u632f\u6280\u672f[J]. \u6838\u7535\u5b50\u5b66\u4e0e\u63a2\u6d4b\u6280\u672f, 2007, (05): 890-894.<\/p>\n

[7] \u738b\u4eac, \u9ec4\u851a\u971e, \u738b\u6c38\u5cf0, \u5218\u51ac\u4e91. \u6838\u78c1\u5171\u632f\u5206\u6790\u6280\u672f\u5728\u77f3\u5316\u9886\u57df\u4e2d\u7684\u5e94\u7528[J]. \u6ce2\u8c31\u5b66\u6742\u5fd7, 2004, (04): 527-534.<\/p>\n

[8] \u949f\u8d35\u660e, \u5218\u5b50\u5e9a, \u738b\u5927\u4e3a, \u674e\u7426, \u5085\u65e5\u5f3a, \u6768\u52c7. \u9502\/\u94a0\u79bb\u5b50\u7535\u6c60\u6750\u6599\u7684\u56fa\u4f53\u6838\u78c1\u5171\u632f\u7814\u7a76\u8fdb\u5c55[J]. \u7535\u5316\u5b66, 2016, 22(03): 231-243.<\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u7f16\u8f91\u90e8\u5b66\u672f\u5e72\u8d27\u7ec4Eric\u4f9b\u7a3f\uff0c\u6750\u6599\u725b\u7f16\u8f91\u6574\u7406\u3002<\/p>\n

\u5b66\u672f\u5e72\u8d27\u81f4\u529b\u4e8e\u6210\u4e3a\u5e7f\u5927\u6750\u6599\u4eba\u8bfb\u8005\u9ad8\u6548\u83b7\u53d6\u77e5\u8bc6\u7684\u9014\u5f84\uff0c\u4e3a\u4e86\u66f4\u8d34\u5408\u5927\u4f17\u77e5\u8bc6\u9700\u6c42\uff0c\u73b0\u5411\u5927\u5bb6\u5f81\u96c6\u5e72\u8d27\u5199\u4f5c\u65b9\u5411\u3002\u5982\u679c\u4f60\u60f3\u4e86\u89e3\u54ea\u4e2a\u9886\u57df\u7684\u77e5\u8bc6\uff0c\u67d0\u4e2a\u8f6f\u4ef6\u7684\u5e94\u7528\u6216\u8005\u4efb\u4f55\u6709\u8da3\u7684\u60f3\u6cd5\u548c\u601d\u7ef4\u65b9\u5411\uff0c\u8bf7\u5728\u5fae\u4fe1\u4e0b\u65b9\u7559\u8a00\u677f\u7559\u8a00\uff0c\u6211\u4eec\u4f1a\u6536\u96c6\u5e76\u63a8\u51fa\u5927\u5bb6\u9700\u6c42\u7684\u5b66\u672f\u5e72\u8d27\uff0c\u6709\u5efa\u8bbe\u6027\u7684\u610f\u89c1\u6216\u8005\u60f3\u6cd5\u4e00\u7ecf\u91c7\u7eb3\uff0c\u6211\u4eec\u5c06\u63d0\u4f9b\u795e\u79d8\u5956\u52b1\u3002\u5feb\u5feb\u7559\u8a00\u5427\uff01\uff01<\/p>\n

\u6750\u6599\u4eba\u7f51\u5411\u5404\u5927\u56e2\u961f\u8bda\u5fc3\u7ea6\u7a3f\uff0c\u8bfe\u9898\u7ec4\u6700\u65b0\u6210\u679c\u3001\u65b9\u5411\u603b\u7ed3\u3001\u56e2\u961f\u8bbf\u8c08\u3001\u5b9e\u9a8c\u6280\u80fd\u7b49\u7686\u53ef\u6295\u7a3f\uff0c\u8bf7\u8054\u7cfb\uff1a\u90ae\u7bb1tougao@cailiaoren.com \u6216 QQ\uff1a97482208\u3002<\/p>\n

\u6750\u6599\u4eba\u91cd\u78c5\u63a8\u51fa\u6750\u6599\u6d4b\u8bd5\u53ca\u6570\u636e\u5206\u6790\u89e3\u51b3\u65b9\u6848\uff0c\u5982\u6709\u9700\u6c42\uff0c\u6b22\u8fce\u626b\u7801\u63d0\u4ea4\u9700\u6c42\uff0c\u6216\u76f4\u63a5\u8054\u7cfb\u5fae\u4fe1\u53f7\uff1aiceshigu<\/p>\n

\"\"<\/p>\n

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