{"id":116046,"date":"2017-12-20T06:30:57","date_gmt":"2017-12-19T22:30:57","guid":{"rendered":"\/\/m.iemloyee.com\/?p=116046"},"modified":"2018-02-06T10:46:15","modified_gmt":"2018-02-06T02:46:15","slug":"%e5%82%ac%e5%8c%96%e6%9d%90%e6%96%99%e5%89%8d%e6%b2%bf%e7%a0%94%e7%a9%b6%e6%88%90%e6%9e%9c%e7%b2%be%e9%80%89%e3%80%90%e7%ac%ac2%e6%9c%9f%e3%80%91","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=116046","title":{"rendered":"\u50ac\u5316\u6750\u6599\u524d\u6cbf\u7814\u7a76\u6210\u679c\u7cbe\u9009\u3010\u7b2c2\u671f\u3011"},"content":{"rendered":"

1. Nature\u5b50\u520a\uff1a\u91d1\u5e95\u7269\u76f8\u4e92\u4f5c\u7528\u5728\u50ac\u5316\u91d1\u4e9a\u7eb3\u7c73\u56e2\u7c07\u4e2d\u7684\u5173\u952e\u4f5c\u7528<\/strong>
\n \"\"<\/p>\n

\u56fe1. \u91d1\u4e9a\u7eb3\u7c73\u56e2\u7c07\u7406\u8bba\u8ba1\u7b97\u56fe<\/strong><\/p>\n

\n \u91d1\u5728\u50ac\u5316\u4e2d\u7684\u5e94\u7528\u5728\u8fc7\u53bb\u768425\u5e74\u4e2d\u7ecf\u5386\u4e86\u5de8\u5927\u7684\u53d1\u5c55\uff0c\u4e3b\u8981\u662f\u7531\u4e8e\u5176\u5728\u6e29\u548c\u7684\u53cd\u5e94\u6761\u4ef6\u4e0b\u7684\u9ad8\u50ac\u5316\u6027\u80fd\u548c\u5728\u6709\u673a\u5b98\u80fd\u56e2\u8f6c\u5316\u4e2d\u7684\u9ad8\u9009\u62e9\u6027\u3002 \u6839\u636e\u91d1\u7684\u6c27\u5316\u548c\u805a\u96c6\u72b6\u6001\uff0c\u5df2\u7ecf\u5f00\u53d1\u4e86\u4e0d\u540c\u7c7b\u578b\u7684\u53cd\u5e94\u3002 \u56e0\u6b64\uff0cAu\uff080\uff09\u4ee5\u5c0f\u5c3a\u5bf8\u7eb3\u7c73\u7c92\u5b50\uff08AuNPs\uff09\u7684\u5f62\u5f0f\u7528\u4e8e\u975e\u5747\u76f8\u50ac\u5316\u6d3b\u5316C-X\u952e\uff08X = C\uff0cH\uff0c\u5364\u7d20\u7b49\uff09\uff0c\u800cAu\uff08I\uff09\u548cAu\uff08III\uff09\u7269\u8d28\u88ab\u5e7f\u6cdb\u7528\u4f5c\u6d3b\u5316\u70ef\u70c3\u548c\u7094\u70c3\u7684\u5747\u76f8\u50ac\u5316\u5242\uff0c\u91d1\u50ac\u5316\u5242\u7684\u53d1\u5c55\u4f7f\u5f97\u6709\u673a\u5408\u6210\u7684\u6d3b\u6027\u548c\u590d\u6742\u6027\u5927\u5927\u63d0\u9ad8\u3002\u8fd1\u65e5\uff0c\u6765\u81ea\u897f\u73ed\u7259\u62c9\u91cc\u5965\u54c8\u5927\u5b66\u7684Gonzalo Jim\u00e9nez-Os\u00e9s\u548cJos\u00e9 M. L\u00f3pez-de-Luzuriaga\u6559\u6388\uff08\u5171\u540c\u901a\u8baf\uff09<\/strong>\u56e2\u961f\u63cf\u8ff0\u4e86\u901a\u8fc7\u70f7\u57fa\u94fe\u6216\u82b3\u65cf\u57fa\u56e2\u9644\u52a0\u5230\u7b80\u5355\u7684\u7094\u70c3\u7684\u53cd\u5e94\u6027\u03c0\u952e\u4e0a\u7684\u975e\u5e38\u5c0f\u7684\u91d1\u4e9a\u7eb3\u65cf(Au n , n\u2009<\u200910)\u7684\u77ac\u6001\u7a33\u5b9a\u3002\u4e2d\u957f\u94fe\u8102\u80aa\u65cf\u7094\u70c3\uff081-\u5df1\u7094\u548c1-\u4e8c\u5341\u70f7\uff09\u548c\u82ef\u4e59\u7094\u76f8\u5bf9\u4e8e\u82ef\u4e59\u7094\u7684\u5e03\u6717\u65af\u7279\u65e0\u9178\u6c34\u5408\u7684\u4f18\u8d8a\u6027\u80fd\u88ab\u5b9e\u9a8c\u8bc1\u660e\uff0c\u5e76\u5728\u8ba1\u7b97\u4e0a\u8fdb\u884c\u7814\u7a76\u3002\u7531\u91cf\u5b50\u529b\u5b66\u8ba1\u7b97\u548c\u65f6\u95f4\u5206\u8fa8\u53d1\u5149\u5b9e\u9a8c\u652f\u6301\u7684\u8272\u6563Au … C-H\u548c\/\u6216Au …\u03c0\u76f8\u4e92\u4f5c\u7528\u7684\u534f\u4f5c\u7f51\u7edc\u88ab\u8ba4\u4e3a\u662f\u8fd9\u79cd\u7a33\u5b9a\u7684\u8d77\u6e90\u3002
\n \u6587\u732e\u94fe\u63a5\uff1a<\/strong>The key role of Au-substrate interactions in catalytic gold subnanoclusters <\/a>\uff08Nat. Commun., 2017, DOI: 10.1038\/s41467-017-01675-1\uff09<\/p>\n

\n 2. Nature\u5b50\u520a\uff1a\u7eb3\u7c73\u7ea7\u65ad\u5c42\u6444\u5f71\u63ed\u793a\u4e86\u81ea\u52a8\u94dc\u4ea4\u6362\u6cb8\u77f3\u50ac\u5316\u5242\u7684\u5931\u6d3b<\/strong>
\n \"\"<\/p>\n

\u56fe2.\u53cd\u5e94\u6d4b\u8bd5\u548c\u5b9e\u9a8c\u7ed3\u679c\u6982\u8ff0<\/strong><\/p>\n

\n Copper-\u4ea4\u6362\u6cb8\u77f3\u83f1\u6cb8\u77f3(Cu-SSZ-13)\u56e0\u5176\u9009\u62e9\u6027\u50ac\u5316\u8fd8\u539f\u6c7d\u8f66\u5c3e\u6c14\u4e2dNOX \u548c\u6c28\u800c\u4e14\u56e0\u4e3a\u5b83\u76f8\u6bd4\u5176\u4ed6\u50ac\u5316\u5242\u5c24\u5176\u662fCu-ZSM-5\u8868\u73b0\u51fa\u4e86\u4f18\u8d8a\u7684\u53cd\u5e94\u6027\u80fd\u548c\u7a33\u5b9a\u6027\u800c\u5728\u8fd1\u671f\u88ab\u5546\u4e1a\u5316\u3002\u6765\u81ea\u4e4c\u5f97\u52d2\u652f\u5927\u5b66Jonathan D. Poplawsky\u548cBert M. Weckhuysen\uff08\u5171\u540c\u901a\u8baf\uff09<\/strong>\u7b49\u4eba\u901a\u8fc7\u4f7f\u7528\u539f\u5b50\u63a2\u9488\u5c42\u6790\u6210\u50cf\u6280\u672f(APT)\uff0c\u5728\u7eb3\u7c73\u5206\u8fa8\u7387\u4e0b\u786e\u5b9a\u4e09\u7ef4\u5206\u5e03\u7684\u94dc\u548c\u6846\u67b6\u5143\u7d20(Al, O, Si)\u5728\u65b0\u9c9c\u7684\u548c\u8001\u5316\u7684Cu-SSZ-13\u548cCu-ZSM-5\uff0c\u5e76\u4e14\u6821\u6b63\u4e86\u4e0e\u50ac\u5316\u6d3b\u6027\u548c\u5176\u4ed6\u7279\u6027\u76f8\u5173\u3002\u8fd9\u4e24\u79cd\u65b0\u50ac\u5316\u5242\u90fd\u542b\u6709\u4e00\u79cd\u5f02\u6784\u7684\u94dc\u5206\u5e03\uff0c\u8fd9\u79cd\u5206\u5e03\u53ea\u6709\u5728\u9002\u5f53\u7684\u539f\u5b50\u654f\u611f\u6027\u7684\u60c5\u51b5\u4e0b\u624d\u4f1a\u88ab\u8bc6\u522b\u51fa\u6765\u3002\u5728\u5728\u884c\u4e1a\u6807\u51c6135000\u82f1\u91cc\u7684\u6a21\u62df\u4e4b\u540e\uff0c Cu-SSZ-13\u5c55\u73b0\u4e86Cu\u548cAl\u56e2\u7c07, \u7136\u800cCu-ZSM-5\u7279\u70b9\u662f\u4e25\u91cd\u7684 Cu\u548cAl \u805a\u5408\u6210\u94dd\u9178\u94dc\u76f8 (CuAl2O4\u5c16\u6676\u77f3)\u3002 The application of APT\u4f5c\u4e3a\u4e00\u4e2a\u654f\u611f\u548c\u5c40\u90e8\u8868\u5f81\u624b\u6bb5\u63d0\u4f9b\u4e86\u7eb3\u7c73\u7ea7\u5f02\u8d28\u7ed3\u5bfc\u81f4\u50ac\u5316\u6d3b\u6027\u548c\u7269\u8d28\u5931\u6d3b\u7684\u8bc6\u522b
\n \u6587\u732e\u94fe\u63a5\uff1a<\/strong>Nanoscale tomography reveals the deactivation of automotive copper-exchanged zeolite catalysts<\/a>\u00a0(Nat. Comm., 2017, DOI:10.1038\/s41467-017-01765-0)<\/p>\n

3. Nature\u5b50\u520a\uff1a\u7531\u91d1\u5c5e\u6709\u673a\u9aa8\u67b6\u5236\u9020\u9ad8\u8d1f\u8f7d\u7684\u4e8c\u6c27\u5316\u7845\u8d1f\u8f7d\u7684\u94b4\u8d39\u6258\u50ac\u5316\u5242<\/strong>
\n \"\"<\/p>\n

\u56fe3. \u50ac\u5316\u5242\u5408\u6210\u793a\u610f\u56fe<\/strong><\/p>\n

\n \u5236\u5907\u9ad8\u8d1f\u8f7d\u91d1\u5c5e\u7eb3\u7c73\u8f7d\u4f53\u50ac\u5316\u5242\u7684\u5408\u6210\u65b9\u6848\u7684\u53d1\u5c55\u5728\u8fc7\u53bb\u51e0\u5e74\u5f97\u5230\u4e86\u5f88\u5927\u7684\u5173\u6ce8\u3002 \u7531\u4e8e\u8fd9\u4e9b\u5173\u952e\u6027\u80fd\u53c2\u6570\u4e4b\u95f4\u6709\u660e\u786e\u7684\u76f8\u4e92\u4f9d\u8d56\u6027\uff0c\u72ec\u7acb\u63a7\u5236\u91d1\u5c5e\u8d1f\u8f7d\uff0c\u7eb3\u7c73\u7c92\u5b50\u5c3a\u5bf8\uff0c\u5206\u5e03\u548c\u53ef\u63a5\u8fd1\u6027\u5df2\u7ecf\u88ab\u8bc1\u660e\u662f\u5177\u6709\u6311\u6218\u6027\u7684\u3002 \u8fd1\u65e5\uff0c\u5fb7\u5c14\u798f\u7279\u7406\u5de5\u5927\u5b66\u53ca\u56fd\u738b\u963f\u535c\u675c\u62c9\u79d1\u6280\u5927\u5b66\u7684 Jorge Gascon\uff08\u901a\u8baf\u4f5c\u8005\uff09<\/strong>\u63d0\u51fa\u4e86\u4e00\u79cd\u9010\u6b65\u7684\u65b9\u6cd5\uff0c\u4f7f\u7528\u542b\u94b4\u91d1\u5c5e\u6709\u673a\u6846\u67b6\u4f5c\u4e3a\u786c\u6a21\u677f\uff08ZIF-67\uff09\uff0c\u89e3\u51b3\u4e86\u8fd9\u4e2a\u957f\u671f\u7684\u6311\u6218\u3002 \u4e8c\u6c27\u5316\u7845\u5728\u7a7a\u95f4\u7684Co-\u91d1\u5c5e\u6709\u673a\u6846\u67b6\u4e2d\u7684\u7f29\u5408\uff0c\u7136\u540e\u70ed\u89e3\u5e76\u4e14\u968f\u540e\u7145\u70e7\u8fd9\u4e9b\u590d\u5408\u7269\u4f7f\u5f97\u9ad8\u8d1f\u8f7d\u7684\u94b4\u7eb3\u7c73\u590d\u5408\u6750\u6599\uff08\u91cd\u91cf\u7ea650\uff05\u7684Co\uff09\u5177\u6709\u7ea680\uff05\u7684\u6c27\u5316\u94b4\u8fd8\u539f\u6027\u548c\u826f\u597d\u7684\u9897\u7c92\u5206\u6563\u6027\uff0c\u5728\u8d39 – \u6258\u5408\u6210\u4e2d\u8868\u73b0\u51fa\u9ad8\u6d3b\u6027\uff0cC5 +\u9009\u62e9\u6027\u548c\u7a33\u5b9a\u6027\u3002
\n \u6587\u732e\u94fe\u63a5\uff1a<\/strong>Manufacture of highly loaded silica-supported cobalt Fischer\u2013Tropsch catalysts from a metal organic framework <\/a>\uff08Nat. Commun., 2017, DOI: 10.1038\/s41467-017-01910-9\uff09<\/p>\n

\n 4. Adv. Mater.\uff1a\u591a\u5b54\u8fd8\u539f\u6c27\u5316\u77f3\u58a8\u70ef\u590d\u5408Mo2N\u2013Mo2C\u5f02\u8d28\u7ed3\u7528\u4e8eHER<\/strong>
\n \"\"<\/p>\n

\u56fe4. \u5408\u6210\u793a\u610f\u56fe<\/strong><\/p>\n

\n \u6765\u81ea\u9ed1\u9f99\u6c5f\u5927\u5b66\u7684\u7530\u6625\u8d35\u548c\u4ed8\u5b8f\u521a\u6559\u6388\uff08\u5171\u540c\u901a\u8baf\uff09<\/strong>\u63d0\u51fa\u4e86\u4e00\u79cd\u539f\u4f4d\u50ac\u5316\u523b\u8680\u7b56\u7565\uff0c\u7528\u4e8e\u5236\u9020\u591a\u5b54\u8fd8\u539f\u6c27\u5316\u77f3\u58a8\u70ef\u51cf\u5c11\u77f3\u58a8\u70ef\u6c27\u5316\u7269\uff0c\u540c\u65f6\u4e0e\u5c0f\u5c3a\u5bf8\u7684Mo2N\u2013Mo2C\u5f02\u8d28\u7ed3\u8fdb\u884c\u590d\u6838(Mo2N\u2013Mo2C\/HGr)\u3002 \u6742\u5316\u6750\u6599\u5c55\u73b0\u51fa\u4e86\u51fa\u8272\u7684\u4ea7\u6c22\u6d3b\u6027\uff0c\u8d77\u59cb\u7535\u4f4d\u4e3a11 mV (0.5 M H2SO4) \u548c18 mV (1M KOH) \u3002 \u78b1\u6027\u5a92\u4ecb\u4e2d\u50ac\u5316\u5242\u7684\u6d3b\u6027\u5728\u9ad8\u7535\u6d41\u5bc6\u5ea6(>88 mA cm\u22122)\u4f18\u4e8ePt\/C \u3002\u5728\u4e00\u7cfb\u5217\u7684\u5b9e\u9a8c\u548c\u7406\u8bba\u8ba1\u7b97\u7684\u652f\u6301\u4e0b\uff0cMo2N\u2013Mo2C\/HGr\u9ad8\u6d3b\u6027\u5f52\u7ed3\u4e8e\u5c0f\u5c3a\u5bf8\uff0c Mo2N\u2013Mo2C\u5f02\u8d28\u7ed3\u4ee5\u53caHGr\u826f\u597d\u7684\u7535\u8377\/\u4f20\u8d28\u80fd\u529b\u3002
\n \u6587\u732e\u94fe\u63a5\uff1a<\/strong>Holey Reduced Graphene Oxide Coupled with an Mo2N\u2013Mo2C Heterojunction for Efficient Hydrogen Evolution<\/a>\u00a0(Adv. Mater., 2017\uff0cDOI: 10.1002\/adma.201704156)<\/p>\n

5. J. Am. Chem. Soc.\uff1aN\u914d\u4f4d\u53cc\u91d1\u5c5e\u4f4d\u70b9\u7684\u8bbe\u8ba1\uff1a\u7528\u4e8e\u9178\u6027\u6c27\u8fd8\u539f\u53cd\u5e94\u7684\u7a33\u5b9a\u4e14\u6d3b\u6027\u7684\u975e\u94c2\u50ac\u5316\u5242<\/strong>
\n \"\"<\/p>\n

\u56fe5. \u50ac\u5316\u5242\u7684\u5236\u5907\u6d41\u7a0b\u56fe\u4ee5\u53ca\u7ed3\u6784\u5f62\u8c8c\u56fe<\/strong><\/p>\n

\n \u76ee\u524d\uff0c\u62a5\u9053\u7684\u975e\u8d35\u91d1\u5c5e\u50ac\u5316\u5242\u50ac\u5316\u7684ORR\u6d3b\u6027\u7531\u4e8e\u4e25\u91cd\u7684\u6d78\u51fa\u800c\u5728\u9178\u6027\u4ecb\u8d28\u4e2d\u7f13\u6162\uff0c\u8868\u73b0\u4e3a\u8f83\u5927\u7684\u8d85\u7535\u4f4d\uff0840-400mV\uff09\u548c\u7a33\u5b9a\u6027\u5dee\u4e8e\u5e02\u552e\u7684Pt \/ C\u3002\u4e3a\u4e86\u5b9e\u73b0\u5546\u7528Pt\u57fa\u6750\u6599\u7684\u66ff\u4ee3\uff0c\u4e2d\u56fd\u79d1\u5b66\u6280\u672f\u5927\u5b66\u5434\u5b87\u6069\u6559\u6388\u548c\u897f\u5b89\u4ea4\u901a\u5927\u5b66\u5e38\u6625\u7136\u526f\u6559\u6388\uff08\u5171\u540c\u901a\u8baf\uff09<\/strong>\u56e2\u961f\u5f00\u53d1\u4e86\u4e00\u79cd\u4e3b\u5ba2\u4f53\u7b56\u7565\uff0c\u6784\u5efa\u4e86\u4e00\u79cd\u5728N\u63ba\u6742\u591a\u5b54\u78b3\u4e0a\u5d4c\u5165Fe-Co\u53cc\u91cd\u4f4d\u70b9\u7684\u7535\u50ac\u5316\u5242\uff0c\u5e76\u5c55\u793a\u4e86\u5176\u5728\u9178\u6027\u7535\u89e3\u8d28\u4e2d\u6c27\u8fd8\u539f\u53cd\u5e94\u7684\u6d3b\u6027\u3002\u8be5\u50ac\u5316\u5242\u8868\u73b0\u51fa\u4f18\u5f02\u7684\u6c27\u8fd8\u539f\u53cd\u5e94\u6027\u80fd\uff0c\u5177\u6709\u4e0e\u5e02\u552e\u7684Pt \/ C\u76f8\u5f53\u7684\u8d77\u59cb\u7535\u4f4d\uff08Eonset\uff0c1.06 vs 1.03V\uff09\u548c\u534a\u6ce2\u7535\u4f4d\uff08E1 \/ 2,0.863 vs 0.858V\uff09\u3002\u71c3\u6599\u7535\u6c60\u6d4b\u8bd5\u8868\u660e\uff08Fe\uff0cCo\uff09\/ N-C\u6bd4H2 \/ O2\u548cH2 \/\u7a7a\u6c14\u4e2d\u62a5\u9053\u7684\u5927\u591a\u6570\u65e0Pt\u50ac\u5316\u5242\u4f18\u5f02\u3002 \u6b64\u5916\uff0c\u8fd9\u79cd\u5177\u6709\u53cc\u91d1\u5c5e\u4f4d\u70b9\u7684\u9634\u6781\u50ac\u5316\u5242\u5728\u957f\u671f\u8fd0\u884c\u4e2d\u662f\u7a33\u5b9a\u7684\uff0c\u7535\u6781\u6d4b\u91cf\u4e3a50,000\u6b21\u5faa\u73af\uff0cH2 \/\u7a7a\u6c14\u5355\u5ba4\u64cd\u4f5c\u4e3a100\u5c0f\u65f6\u3002 \u5bc6\u5ea6\u6cdb\u51fd\u7406\u8bba\u8ba1\u7b97\u63ed\u793a\u4e86\u53cc\u91cd\u4f4d\u70b9\u6709\u5229\u4e8eO-O\u7684\u6fc0\u6d3b\uff0c\u5bf9\u56db\u7535\u5b50\u6c27\u8fd8\u539f\u81f3\u5173\u91cd\u8981\u3002
\n \u6587\u732e\u94fe\u63a5\uff1a<\/strong>Design of N Coordinated Dual-Metal Sites: A Stable and Active Pt Free Catalyst for Acidic Oxygen Reduction Reaction<\/a>\u00a0(J. Am. Chem. Soc., 2017, DOI: 10.1021\/jacs.7b10385\uff09<\/p>\n

6. Adv. Mater.\uff1a\u9ad8\u6307\u6570\u9762\u73af\u62b1\u591a\u9762\u5fae\u6676\u4fc3\u8fdb\u5149\u50ac\u5316\u6c34\u89e3\u6d3b\u6027<\/strong><\/p>\n

\"\"<\/p>\n

\u56fe.6 BiVO4\u591a\u9762\u4f53\u5f62\u8c8c<\/strong><\/p>\n

\n \u6765\u81ea\u5357\u4eac\u5927\u5b66\u7684\u5468\u52c7\u6559\u6388\u548c\u8fbd\u5b81\u5927\u5b66\u7684\u5468\u946b\u6559\u6388\uff08\u5171\u540c\u901a\u8baf\uff09<\/strong>\u91c7\u7528\u5fae\u91cf\u91d1\u7eb3\u7c73\u7c92\u5b50\u5236\u5907\u4e86\u88ab{132}, {321}, and {121}\u9ad8\u6307\u6570\u9762\u5305\u56f4\u7684\u53f2\u65e0\u524d\u4f8b\u768430-\u9762BiVO4\u591a\u9762\u4f53\u3002\u9ad8\u6307\u6570\u9762\u7684\u589e\u957f\u7ed3\u679c\u663e\u793a\uff0c\u6bd4\u4f4e\u6307\u6807\u76f8\u5bf9\u5e94\u7684\u5149\u50ac\u5316\u6c34\u5206\u89e3\uff0cBiVO4\u591a\u9762\u4f53\u5149\u50ac\u5316\u6c34\u5206\u89e3\u4ea7\u6c27\u5f97\u52303-5\u500d\u7684\u589e\u5f3a\u3002\u7406\u8bba\u8ba1\u7b97\u8868\u660e\u6c34\u5206\u89e3\u5728\u9ad8\u6307\u6570\u8868\u9762\u6bd4\u4f4e\u6307\u6570\u8868\u9762(010), (110), \u548c(101)\u66f4\u5bb9\u6613\u53d1\u751f\uff0c\u4e0e\u6b64\u540c\u65f6OER\u8fc7\u7535\u4f4d\u4e5f\u663e\u8457\u964d\u4f4e\u3002\u5728430nm\u5149\u6e90\u7167\u5c04\u4e0b\uff0c\u6ca1\u6709\u989d\u5916\u7535\u5b50\u4f9b\u5e94\u7684O2 \u4ea7\u751f\u7684\u8868\u89c2\u91cf\u5b50\u6548\u7387\u8fbe\u5230\u4e8618.3%\uff0c\u8fd9\u6bd4\u8fc4\u4eca\u4e3a\u6b62\u6240\u62a5\u9053\u7684\u50ac\u5316\u5242\u9ad8\u51fa\u4e00\u4e2a\u6570\u91cf\u7ea7\u3002
\n \u6587\u732e\u94fe\u63a5\uff1a<\/strong>Polyhedral 30-Faceted BiVO4 Microcrystals Predominantly Enclosed by High-Index Planes Promoting Photocatalytic Water-Splitting Activity <\/a>(Adv. Mater., 2017\uff0cDOI: 10.1002\/adma.201703119)<\/p>\n

7. Nano Energy\uff1a\u6eb6\u6db2\u6cd5\u5236\u5907\u6210\u5206\u53ef\u63a7\u7684BiVO4\u5149\u9633\u6781\u9ad8\u6548\u5149\u7535\u5316\u5b66\u6c34\u6c27\u5316<\/strong>
\n \"\"<\/p>\n

\n \u56fe7. \u4e0d\u540c\u7ec4\u5206\u7684BiVO4\u7684\u5e26\u7ed3\u6784<\/strong><\/p>\n

\n \u867d\u7136BiVO4\u5bf9\u4e8e\u5149\u9a71\u52a8\u5149\u7535\u5316\u5b66\uff08PEC\uff09\u6c34\u89e3\u662f\u4e00\u79cd\u6781\u5177\u524d\u666f\u7684\u5149\u9633\u6781\uff0c\u4f46\u662f\u5316\u5b66\u6210\u5206\uff08Bi\/V\u6bd4\u4f8b\uff09\u7684\u7cbe\u786e\u8c03\u63a7\u4ee5\u53ca\u901a\u8fc7\u63ba\u6742\u63d0\u5347\u7535\u5b66\u7279\u6027\u5bf9\u4e8e\u63d0\u5347PEC\u6027\u80fd\u662f\u5fc5\u8981\u7684\u3002\u8fd1\u65e5\uff0c\u6765\u81ea\u97e9\u56fdKAIST\u7684Byungha Shin\u6559\u6388\uff08\u901a\u8baf\u4f5c\u8005\uff09<\/strong>\u56e2\u961f\u8fdb\u884c\u4e86\u57fa\u4e8e\u4e0d\u540cBi\/V\u6bd4\u4f8b\u4ee5\u53ca\u6d89\u53ca\u4e0d\u540cMo\u63ba\u6742\u6d53\u5ea6\u7684BVO\u590d\u5408\u7269\u5de5\u7a0b\u3002\u901a\u8fc7\u7269\u7406\u548c\u5316\u5b66\u5206\u6790\uff0c\u7814\u7a76\u4eba\u5458\u53d1\u73b0BiVO4\u7684\u6750\u6599\u7279\u6027\u4ee5\u53ca\u5b83\u7684PEC\u6027\u80fd\u5bf9\u5316\u5b66\u7ec4\u6210\u53ca\u5176\u654f\u611f\u3002\u7814\u7a76\u4eba\u5458\u4f18\u5316\u7684BiVO4\u57fa\u5149\u9633\u6781\u5728\u6700\u5148\u8fdb\u7684SnO2\/BiVO4\u5f02\u8d28\u7ed3\u5149\u9633\u6781\u4e2d\u5c55\u73b0\u51fa\u4e86\u6700\u9ad8\u7684\u5149\u7535\u6d41\u2014\u2014\u5728\u76f8\u5bf9\u4e8eRHE\u4e0b1.23V \u4ea7\u6c27\u7535\u6d41\u5bc6\u5ea6\u4e3a2.62 mA cm\u22122\u548c\u786b\u6c27\u5316\u7535\u6d41\u5bc6\u5ea6\u4e3a4.20 mA cm\u22122\u3002 \u7814\u7a76\u4eba\u5458\u901a\u8fc7BiVO4\u7684\u5e26\u7ed3\u6784\u6765\u89e3\u91ca\u4f17\u591a\u4e0d\u540c\u7ec4\u6210\u6210\u5206\u7684PEC\u6027\u80fd\uff0c\u8fd9\u9879\u5de5\u4f5c\u6307\u51fa\u4e86\u4e3a\u5b9e\u73b0\u9ad8\u6548BiVO4\u57fa\u5149\u9633\u6781\uff0c\u5bf9\u5316\u5b66\u6210\u5206\u8fdb\u884c\u7cbe\u7ec6\u8c03\u63a7\u7684\u91cd\u8981\u6027\uff0c\u5bf9\u4e8e\u672a\u6765\u5236\u5907\u5176\u4ed6\u9ad8\u6027\u80fd\u5149\u7535\u6781\u7684\u7814\u7a76\u6307\u660e\u65b9\u5411\u3002
\n \u6587\u732e\u94fe\u63a5\uff1a<\/strong>Compositional engineering of solution-processed BiVO4 photoanodes toward highly efficient photoelectrochemical water oxidation<\/a>\u00a0(Nano Energy, 2017, DOI:doi.org\/10.1016\/j.nanoen.2017.11.034)<\/p>\n

8.\u00a0ACS Nano\uff1aCo\u63ba\u6742Cu7S4\u7eb3\u7c73\u76d8\u4fee\u9970\u7535\u50ac\u5316\u6d3b\u6027\u4e2d\u5fc3\u7528\u4e8e\u9ad8\u6548OER<\/strong>
\n \"\"<\/p>\n

\u56fe8. Co\u63ba\u6742Cu7S4\u8ba1\u7b97\u56fe<\/span><\/strong><\/p>\n

Cu\u57fa\u7535\u50ac\u5316\u5242\u5728\u6c34\u6c27\u5316\u4e2d\u5f88\u5c11\u6709\u7814\u7a76\uff0c\u867d\u7136\u5b83\u4eec\u5f88\u5ec9\u4ef7\uff0c\u4f46\u662f\u56e0\u4e3a\u5b83\u4eec\u6781\u5dee\u7684\u6d3b\u6027\u548c\u7a33\u5b9a\u6027\u3002\u56e0\u6b64\uff0c\u5f00\u53d1\u6709\u6548\u7684\u9014\u5f84\u6765\u63d0\u5347\u94dc\u57fa\u7535\u50ac\u5316\u5242\u7684\u6d3b\u6027\u5bf9\u4e8e\u5176\u5b9e\u9645\u5e94\u7528\u81f3\u5173\u91cd\u8981\u3002\u901a\u8fc7\u91d1\u5c5e\u63ba\u6742\u6765\u6539\u53d8\u7535\u50ac\u5316\u6d3b\u6027\u4e2d\u5fc3\u7684\u7535\u5b50\u7ed3\u6784\u7ee7\u800c\u4fc3\u8fdb\u7535\u5b50\u5728\u50ac\u5316\u6d3b\u6027\u4f4d\u70b9\u548c\u7535\u6781\u4e4b\u95f4\u7684\u4f20\u8f93\u662f\u4e00\u79cd\u91cd\u8981\u7684\u65b9\u6cd5\u6765\u4f18\u5316\u6c22\u6c14\u548c\u6c27\u6c14\u7684\u8131\u9644\u80fd\uff0c\u8fdb\u800c\u63d0\u5347\u56fa\u6709\u7535\u50ac\u5316\u6d3b\u6027\u3002\u6765\u81ea\u82cf\u5dde\u5927\u5b66\u7684\u738b\u663e\u798f\u526f\u6559\u6388\u548c\u664f\u6210\u6797\u6559\u6388\uff08\u5171\u540c\u901a\u8baf\uff09<\/strong>\u7b49\u4eba\u901a\u8fc7\u94b4\u63ba\u6742Cu7S4\u7eb3\u7c73\u76d8\u5f97\u5230\u4e86\u9ad8\u6548\u7684OER\u50ac\u5316\u5242\u3002DFT\u8868\u660e\u94b4\u63ba\u6742Cu7S4\u80fd\u591f\u52a0\u901f\u7535\u5b50\u5728\u94b4\u548c\u94dc\u4e4b\u95f4\u4f20\u8f93\uff0c\u8fdb\u800c\u964d\u4f4e\u4e2d\u95f4\u4f53\u548c\u4ea7\u7269\u5728OER\u8fc7\u7a0b\u4e2d\u7684\u80fd\u91cf\u52bf\u5792\u3002\u6b63\u5982\u6240\u671f\u5f85\u7684\uff0c\u8be5\u4f53\u7cfb\u5c55\u73b0\u51fa\u4e86\u572810 mA cm\u22122\u7684\u7535\u6d41\u5bc6\u5ea6\u4e0b\u8fc7\u7535\u4f4d\u53ea\u6709270 mV \u3002<\/span><\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/strong>Electronic Modulation of Electrocatalytically Active Center of Cu7S4 Nanodisks by Cobalt- Doping for Highly Efficient Oxygen Evolution Reaction<\/a>\u00a0(ACS Nano, 2017, DOI:10.1021\/acsnano.7b05606)<\/span><\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u65b0\u80fd\u6e90\u5b66\u672f\u7ec4Z. Chen\u4f9b\u7a3f\uff0c\u6750\u6599\u725b\u6574\u7406\u7f16\u8f91\u3002<\/p>\n

\u6750\u6599\u725b\u7f51\u4e13\u6ce8\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u53ca\u884c\u4e1a\u8fdb\u5c55\uff0c\u8fd9\u91cc\u6c47\u96c6\u4e86\u5404\u5927\u9ad8\u6821\u7855\u535a\u751f\u3001\u4e00\u7ebf\u79d1\u7814\u4eba\u5458\u4ee5\u53ca\u884c\u4e1a\u4ece\u4e1a\u8005\uff0c\u5982\u679c\u60a8\u5bf9\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u8fdb\u5c55\uff0c\u89e3\u8bfb\u9ad8\u6c34\u5e73\u6587\u7ae0\u6216\u662f\u8bc4\u8ff0\u884c\u4e1a\u6709\u5174\u8da3\uff0c\u70b9\u6211\u52a0\u5165\u7f16\u8f91\u90e8<\/a>\u3002<\/p>\n

\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1aRDD-2011-CHERISH\uff0c\u4efb\u4e39\u4e39\uff0c\u6211\u4eec\u4f1a\u9080\u8bf7\u5404\u4f4d\u8001\u5e08\u52a0\u5165\u4e13\u5bb6\u7fa4\u3002<\/p>\n

\u6750\u6599\u6d4b\u8bd5\uff0c\u6570\u636e\u5206\u6790\uff0c\u4e0a<\/strong>\u6d4b\u8bd5\u8c37<\/strong><\/a>\uff01<\/strong><\/p>\n","protected":false},"excerpt":{"rendered":"

1. Nature\u5b50\u520a\uff1a\u91d1\u5e95\u7269\u76f8\u4e92\u4f5c\u7528\u5728\u50ac\u5316\u91d1\u4e9a\u7eb3\u7c73\u56e2\u7c07\u4e2d\u7684\u5173\u952e\u4f5c\u7528 \u56fe1. \u91d1\u4e9a\u7eb3\u7c73\u56e2\u7c07\u7406\u8bba\u8ba1\u7b97\u56fe \u91d1\u5728\u50ac\u5316\u4e2d\u7684\u5e94\u7528\u5728\u8fc7\u53bb\u768425\u5e74\u4e2d\u7ecf\u5386\u4e86\u5de8\u5927\u7684\u53d1\u5c55\uff0c\u4e3b\u8981\u662f\u7531…<\/p>\n","protected":false},"author":3029,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[2],"tags":[2490,2548],"class_list":["post-116046","post","type-post","status-publish","format-standard","hentry","category-keji","tag-2490","tag-2548"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/116046"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/3029"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=116046"}],"version-history":[{"count":19,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/116046\/revisions"}],"predecessor-version":[{"id":117858,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/116046\/revisions\/117858"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=116046"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=116046"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=116046"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}