{"id":115790,"date":"2017-12-09T06:30:35","date_gmt":"2017-12-08T22:30:35","guid":{"rendered":"\/\/m.iemloyee.com\/?p=115790"},"modified":"2017-12-07T23:18:25","modified_gmt":"2017-12-07T15:18:25","slug":"%e4%b8%ad%e7%a7%91%e9%99%a2%e5%8c%96%e5%ad%a6%e6%89%80%e6%9d%8e%e7%8e%89%e8%89%af%e9%99%a2%e5%a3%abangew-chem-int-ed-%ef%bc%9a%e9%93%9c%e7%ba%b3%e7%b1%b3%e7%ba%bf%e5%8e%9f%e4%bd%8d%e7%94%9f%e9%95%bf","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=115790","title":{"rendered":"\u4e2d\u79d1\u9662\u5316\u5b66\u6240\u674e\u7389\u826f\u9662\u58ebAngew.Chem.Int.Ed.\uff1a\u94dc\u7eb3\u7c73\u7ebf\u539f\u4f4d\u751f\u957f\u8d85\u8584\u77f3\u58a8\u7094\u4f5c\u4e3a\u9ad8\u6027\u80fd\u9502\u79bb\u5b50\u7535\u6c60\u8d1f\u6781\u6750\u6599"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n

\u4e3a\u4e86\u5f00\u53d1\u5177\u6709\u9ad8\u529f\u7387\u4ee5\u53ca\u9ad8\u80fd\u91cf\u5bc6\u5ea6\u9502\u79bb\u5b50\u7535\u6c60\uff0c\u9ad8\u5bb9\u91cf\u7684\u975e\u5d4c\u5165\u5f0f\u8d1f\u6781\u6750\u6599\uff08\u8bf8\u5982\u7845\u3001\u9517\u3001\u6c27\u5316\u7269\u53ca\u786b\u5316\u7269\u7b49\uff09\u53d7\u5230\u4e86\u5e7f\u6cdb\u5173\u6ce8\u3002\u7136\u800c\uff0c\u8fd9\u7c7b\u6750\u6599\u5b58\u5728\u5faa\u73af\u8fc7\u7a0b\u4e2d\u4f53\u79ef\u81a8\u80c0\u8fdb\u800c\u4f7f\u5bfc\u7535\u6027\u53d8\u5dee\u7684\u95ee\u9898\uff0c\u4e25\u91cd\u5f71\u54cd\u7740\u9502\u79bb\u5b50\u7535\u6c60\u7684\u8f93\u51fa\u529f\u7387\u53ca\u957f\u7a0b\u7a33\u5b9a\u6027\u3002\u800c\u77f3\u58a8\u4f5c\u4e3a\u4e00\u79cd\u5d4c\u5165\u5f0f\u8d1f\u6781\u6750\u6599\uff0c\u5f97\u76ca\u4e8e\u5176\u7a33\u5b9a\u7684\u4e8c\u7ef4\u5168\u78b3\u9aa8\u67b6\u7ed3\u6784\uff0c\u5c55\u73b0\u51fa\u4e86\u4f18\u5f02\u7684\u5faa\u73af\u7a33\u5b9a\u6027\uff0c\u8fdb\u800c\u6fc0\u53d1\u4e86\u7814\u7a76\u4eba\u5458\u5bf9\u9ad8\u5bb9\u91cf\u517c\u5177\u7a33\u5b9a\u4e8c\u7ef4\u7ed3\u6784\u5168\u78b3\u6750\u6599\u7684\u7814\u53d1\u5174\u8da3\u3002<\/p>\n

\u77f3\u58a8\u7094\uff08Graphdiyne, GDY\uff09\uff0c\u4f5c\u4e3a\u4e00\u79cdsp\u548csp2<\/sup>\u4e24\u79cd\u6742\u5316\u6001\u5f62\u6210\u7684\u4e8c\u7ef4\u78b3\u540c\u7d20\u5f02\u5f62\u4f53\uff0c\u88ab\u8bc1\u660e\u662f\u4e00\u79cd\u9ad8\u6548\u5d4c\u5165\u578b\u50a8\u9502\u6750\u6599\u3002\u5728\u50a8Li+<\/sup>\u8fc7\u7a0b\u4e2d\uff0c\u901a\u8fc7\u5c06Li+<\/sup>\u675f\u7f1a\u5728\u5176\u5c42\u5185\u7eb3\u7c73\u5b54\u9699\u4e2d\uff0c\u53ef\u4f7f\u6750\u6599\u5728\u5faa\u73af\u8fc7\u7a0b\u4f53\u79ef\u81a8\u80c0\u7684\u95ee\u9898\u5f97\u5230\u7f13\u89e3\u3002\u540c\u65f6\uff0c\u5c42\u5185\u7eb3\u7c73\u5b54\u9699\u53ef\u4fc3\u8fdbLi+<\/sup> \u5728\u4e09\u7ef4\u5b54\u9053\u4e2d\u7684\u6269\u6563\u4e0e\u4f20\u8f93\uff0c\u8fdb\u800c\u53ef\u5b9e\u73b0\u6bd4\u77f3\u58a8\u66f4\u9ad8\u7684\u8f93\u51fa\u529f\u7387\u3002\u56e0\u6b64\uff0c\u77f3\u58a8\u7094\u88ab\u5bc4\u671b\u4f5c\u4e3a\u9ad8\u6027\u80fd\u9502\u79bb\u5b50\u7535\u6c60\u8d1f\u6781\u6750\u6599\u3002\u77f3\u58a8\u7094\u50a8Li+<\/sup>\u4e0e\u50a8Na+<\/sup>\u6027\u80fd\u5df2\u88ab\u7814\u7a76\u62a5\u9053\uff0c\u7136\u800c\u5173\u4e8e\u8d85\u8584\u77f3\u58a8\u7094\u7eb3\u7c73\u7247\u7684\u5236\u5907\u53ca\u5176\u4f5c\u4e3a\u9502\u79bb\u5b50\u7535\u6c60\u8d1f\u6781\u6750\u6599\u6027\u80fd\u7684\u7814\u7a76\u4ecd\u662f\u7a7a\u767d\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u4e2d\u79d1\u9662\u5316\u5b66\u6240\u674e\u7389\u826f\u9662\u58eb\u3001\u674e\u52c7\u519b\u7814\u7a76\u5458\u548c<\/strong>Zicheng Zuo<\/strong>\uff08\u5171\u540c\u901a\u8baf\u4f5c\u8005\uff09\u5e26\u9886\u7684\u56e2\u961f\u5f00\u53d1\u4e86\u4e00\u79cd\u5927\u89c4\u6a21\u5236\u5907\u77f3\u58a8\u7094\u7eb3\u7c73\u7ba1\u548c\u8d85\u8584\u77f3\u58a8\u7094\u7eb3\u7c73\u7247\u7684\u65b0\u7b56\u7565\u3002\u4e0d\u540c\u4e8e\u4e4b\u524d\u62a5\u9053\u4e2d\u6240\u91c7\u7528\u94dc\u7b94\u4f5c\u4e3a\u57fa\u5e95\u7684\u65b9\u6cd5\uff0c\u8be5\u7b56\u7565\u5229\u7528\u81ea\u652f\u6491\u94dc\u7eb3\u7c73\u7ebf\u7eb8\u4f5c\u4e3a\u539f\u4f4d\u751f\u957f\u77f3\u58a8\u7094\u7684\u50ac\u5316\u5242\u53ca\u57fa\u5e95\u3002\u94dc\u7eb3\u7c73\u7ebf\u4e0d\u4ec5\u53ef\u4ee5\u4f5c\u4e3a\u77f3\u58a8\u7094\u751f\u957f\u7684\u6a21\u677f\uff0c\u8fd8\u53ef\u4ee5\u4e3a\u4e4b\u63d0\u4f9b\u66f4\u591a\u7684\u6d3b\u6027\u4f4d\u70b9\uff0c\u8fdb\u800c\u63d0\u9ad8\u4e86\u77f3\u58a8\u7094\u7684\u8d28\u91cf\u4e0e\u8868\u9762\u79ef\u3002\u66f4\u4e3a\u91cd\u8981\u7684\u662f\uff0c\u7531\u4e8e\u7eb3\u7c73\u7ebf\u6613\u4e8e\u88ab\u8868\u5f81\uff0c\u5229\u7528\u94dc\u7eb3\u7c73\u7ebf\u4f5c\u4e3a\u751f\u957f\u57fa\u5e95\uff0c\u7814\u7a76\u4eba\u5458\u5bf9\u77f3\u58a8\u7094\u751f\u957f\u8fc7\u7a0b\u4e2d\u7684\u5f62\u8c8c\u6f14\u53d8\u8fdb\u884c\u4e86\u8868\u5f81\uff0c\u63ed\u793a\u4e86\u77f3\u58a8\u7094\u7eb3\u7c73\u7247\u7684\u751f\u957f\u673a\u5236\u3002\u5236\u5907\u5f97\u5230\u7684Cu@GDY\u6837\u54c1\u5177\u6709\u4f18\u5f02\u7684\u50a8\u9502\u6027\u80fd\uff0c\u57280.1A\u00b7g-1<\/sup>\u7535\u6d41\u5bc6\u5ea6\u4e0b\u6bd4\u7535\u5bb9\u91cf\u9ad8\u8fbe1388mA h\u00b7g-1<\/sup>\u3002\u8be5\u6210\u679c\u4ee5\u9898\u4e3a\u201cUltrathin Graphdiyne Nanosheets in-situ Grown on Copper Nanowires and its Performance as Lithium-Ion Battery Anodes<\/strong>\u201d\u53d1\u8868\u5728Angew.Chem.Int.Ed.<\/strong>\u4e0a\u3002<\/p>\n

\u3010\u81f4\u6b49\uff1a\u5f88\u62b1\u6b49\uff0c\u672a\u80fd\u627e\u5230\u901a\u8baf\u4f5c\u8005<\/strong>ZiCheng Zuo<\/strong>\u7684\u786e\u5207\u4e2d\u6587\u540d\u5b57\uff0c\u5c0f\u7f16\u8868\u793a\u8bda\u631a\u7684\u6b49\u610f\uff01<\/strong>\u3011<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n

\u56fe<\/strong>1.<\/strong>\u77f3\u58a8\u7094\u751f\u957f\u8fc7\u7a0b\u793a\u610f\u56fe\u53ca\u6837\u54c1\u7ed3\u6784\u8868\u5f81<\/strong><\/p>\n

\"\"<\/p>\n

a-c)\u94dc\u7eb3\u7c73\u7ebf\u4e0a\u539f\u4f4d\u751f\u957f\u77f3\u58a8\u7094\u8fc7\u7a0b\u793a\u610f\u56fe<\/p>\n

d)\u672a\u751f\u957f\u6709\u77f3\u58a8\u7094\u7684\u94dc\u7eb3\u7c73\u7ebf\u7eb8<\/p>\n

e)\u751f\u957f\u6709\u77f3\u58a8\u7094\u7684\u94dc\u7eb3\u7c73\u7ebf\u7eb8<\/p>\n

f)Cu@GDY\u6837\u54c1\u5448\u73b0\u51fa\u826f\u597d\u7684\u67d4\u6027<\/p>\n

g)Cu@GDY\u6837\u54c1\u5177\u6709\u8d85\u8f7b\u7684\u8d28\u91cf(1.4mg)<\/p>\n

h)Cu@GDY\u6837\u54c1\u62c9\u66fc\u8c31\u56fe<\/p>\n

i )Cu@GDY\u6837\u54c1XRD\u7ed3\u679c<\/p>\n

\u56fe<\/strong>2.<\/strong>\u4e0d\u540c\u524d\u9a71\u4f53\u7528\u91cf\u4e0b\u6837\u54c1<\/strong>SEM<\/strong>\u5f62\u8c8c<\/strong><\/p>\n

\"\"<\/p>\n

a,b)1mg\u7528\u91cf\u4e0bCu@GDY\u6837\u54c1SEM\u5f62\u8c8c<\/p>\n

d,e)2.5mg\u7528\u91cf\u4e0bCu@GDY\u6837\u54c1SEM\u5f62\u8c8c<\/p>\n

g,h)5mg\u7528\u91cf\u4e0bCu@GDY\u6837\u54c1SEM\u5f62\u8c8c<\/p>\n

c,f,i)\u4f9d\u6b21\u4e3a1mg\u30012.5mg\u30015mg\u7528\u91cf\u4e0b\uff0c\u53bb\u9664\u94dc\u7eb3\u7c73\u7ebf\u540eGDY\u6837\u54c1SEM\u5f62\u8c8c<\/p>\n

\u56fe<\/strong>3.Cu@GDY<\/strong>\u6837\u54c1<\/strong>TEM<\/strong>\u5f62\u8c8c<\/strong><\/p>\n

\"\"<\/p>\n

a)Cu@GDY\u8d85\u8584\u7eb3\u7c73\u7247\u4f4e\u500dTEM\u5f62\u8c8c<\/p>\n

b,c)\u56fea)\u6240\u9009\u533a\u57dfC\u3001Cu\u5143\u7d20mapping\u7ed3\u679c<\/p>\n

d)Cu@GDY\u8d85\u8584\u7eb3\u7c73\u7247\u9ad8\u5206\u8fa8TEM\u5f62\u8c8c<\/p>\n

e)\u53bb\u9664\u94dc\u7eb3\u7c73\u7ebf\u540eGDY\u7eb3\u7c73\u7247\u4f4e\u500dTEM\u5f62\u8c8c\u53caf)\u9ad8\u5206\u8fa8TEM\u5f62\u8c8c<\/p>\n

g)\u53bb\u9664\u94dc\u7eb3\u7c73\u7ebf\u540eGDY\u7eb3\u7c73\u7ba1TEM\u5f62\u8c8c<\/p>\n

\u56fe<\/strong>4.<\/strong>\u77f3\u58a8\u7094\u7eb3\u7c73\u7247\u751f\u957f\u673a\u5236<\/strong><\/p>\n

\"\"<\/p>\n

a)Cu@GDY\u8d85\u8584\u7eb3\u7c73\u7247\u4f4e\u500dTEM\u5f62\u8c8c<\/p>\n

b,c)\u56fea)\u6240\u9009\u533a\u57df\u9ad8\u500dTEM\u5f62\u8c8c<\/p>\n

d)\u56fec)\u6240\u9009\u533a\u57df\u9ad8\u5206\u8fa8TEM\u5f62\u8c8c<\/p>\n

e)\u77f3\u58a8\u7094\u7eb3\u7c73\u7247\u5728\u94dc\u7eb3\u7c73\u9897\u7c92\u6676\u4f53\u8fb9\u754c\u5904\u751f\u957f\u673a\u7406\u793a\u610f\u56fe<\/p>\n

f)\u77f3\u58a8\u7094\u7eb3\u7c73\u7247\u5728\u6676\u4f53\u8fb9\u754c\u5904\u7684\u751f\u957f\u8fc7\u7a0b\u7c7b\u6bd4\u690d\u7269\u7834\u571f\u800c\u751f<\/p>\n

\u56fe<\/strong>5.Cu@GDY<\/strong>\u7535\u5316\u5b66\u6027\u80fd<\/strong><\/p>\n

\"\"<\/p>\n

GDY1:\u524d\u9a71\u4f53\u7528\u91cf\u4e3a1mg\u65f6\u6240\u5f97\u5230\u7684\u6837\u54c1<\/p>\n

GDY2:\u524d\u9a71\u4f53\u7528\u91cf\u4e3a5mg\u65f6\u6240\u5f97\u5230\u7684\u6837\u54c1<\/p>\n

a)GDY1\u548cGDY2\u7684\u500d\u7387\u6027\u80fd\u3001<\/p>\n

b)\u4e0d\u540c\u7535\u6d41\u5bc6\u5ea6\u4e0b\uff0c\u4e24\u79cd\u6837\u54c10~1V\u7535\u538b\u533a\u95f4\u7684\u5bb9\u91cf\u8d21\u732e<\/p>\n

c)GDY1\u548cGDY2\u57285A\u00b7g-1<\/sup>\u4e0b\u7684\u5faa\u73af\u6027\u80fd<\/p>\n

d)GDY2\u572810A\u00b7g-1<\/sup>\u548c20A\u00b7g-1<\/sup>\u4e0b\u7684\u5faa\u73af\u6027\u80fd<\/p>\n

e)GDY\u4e0e\u5176\u4ed6\u8d1f\u6781\u6750\u6599\u6027\u80fd\u5bf9\u6bd4<\/p>\n

f)GDY\u4f18\u5f02\u500d\u7387\u6027\u80fd\u7684\u673a\u7406\u793a\u610f\u56fe<\/p>\n

\u3010\u7ed3\u8bba\u3011<\/strong><\/p>\n

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\u3010\u6587\u732e\u4fe1\u606f\u3011<\/strong><\/p>\n

\u6587\u732e\u94fe\u63a5\uff1aUltrathin Graphdiyne Nanosheets in-situ Grown on Copper Nanowires and its Performance as Lithium-Ion Battery Anodes<\/a><\/u>\uff08Angew.Chem.Int.Ed.\uff0c2017\uff0cDOI: 10.1002\/anie.201711366\uff09<\/p>\n

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