{"id":115771,"date":"2017-12-08T14:00:47","date_gmt":"2017-12-08T06:00:47","guid":{"rendered":"\/\/m.iemloyee.com\/?p=115771"},"modified":"2017-12-07T23:17:11","modified_gmt":"2017-12-07T15:17:11","slug":"%e5%8c%97%e5%a4%a7%e6%b7%b1%e7%a0%94%e9%99%a2%e6%bd%98%e9%94%8badv-mater-%ef%bc%9a%e5%9f%ba%e4%ba%8emof%e6%9d%90%e6%96%99%e5%85%b7%e6%9c%89%e7%ba%b3%e7%b1%b3%e6%b6%a6%e6%b9%bf%e7%95%8c%e9%9d%a2","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=115771","title":{"rendered":"\u5317\u5927\u6df1\u7814\u9662\u6f58\u950bAdv. Mater.\uff1a\u57fa\u4e8eMOF\u6750\u6599\u5177\u6709\u7eb3\u7c73\u6da6\u6e7f\u754c\u9762\u7684\u9ad8\u80fd\u91cf\u5bc6\u5ea6\u9502\u7535\u6c60\u56fa\u6001\u7535\u89e3\u8d28"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n

\u56fa\u6001\u7535\u89e3\u8d28\u53ef\u4ee5\u514b\u670d\u4f20\u7edf\u6db2\u4f53\u7535\u89e3\u8d28\u5b58\u5728\u7684\u6613\u6cc4\u9732\u3001\u6613\u71c3\u7b49\u95ee\u9898\uff0c\u6b64\u5916\uff0c\u8fd8\u80fd\u591f\u6291\u5236\u9502\u679d\u6676\u7684\u751f\u957f\uff0c\u4f7f\u57fa\u4e8e\u91d1\u5c5e\u9502\u8d1f\u6781\u7684\u9ad8\u80fd\u91cf\u5bc6\u5ea6\u7535\u6c60\u6210\u4e3a\u53ef\u80fd\uff0c\u56e0\u800c\u6210\u4e3a\u76ee\u524d\u56fd\u5185\u5916\u7684\u7814\u7a76\u70ed\u70b9\u3002\u76ee\u524d\uff0c\u7531\u4e8e\u56fa\u4f53\u7535\u89e3\u8d28\u548c\u7535\u6781\u6750\u6599\u4e4b\u95f4\u7684\u4e0d\u826f\u7269\u7406\u63a5\u89e6\u800c\u9020\u6210\u7684\u754c\u9762\u7535\u963b\u5927\u662f\u963b\u788d\u56fa\u6001\u9502\u7535\u6c60\u5b9e\u9645\u5e94\u7528\u7684\u6700\u4e3b\u8981\u95ee\u9898\u3002\u5f00\u53d1\u4e00\u79cd\u5728\u7535\u89e3\u8d28\u4f53\u76f8\u548c\u7535\u89e3\u8d28\/\u7535\u6781\u754c\u9762\u5747\u5177\u6709\u4f18\u826f\u79bb\u5b50\u4f20\u5bfc\u6027\u80fd\u7684\u56fa\u4f53\u7535\u89e3\u8d28\u5bf9\u4e8e\u5b9e\u73b0\u56fa\u6001\u9502\u7535\u6c60\u7684\u5e7f\u6cdb\u5e94\u7528\u81f3\u5173\u91cd\u8981\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u5317\u4eac\u5927\u5b66\u6df1\u5733\u7814\u7a76\u9662\u6f58\u950b\u6559\u6388\u8bfe\u9898\u7ec4\u5f00\u53d1\u4e86\u4e00\u79cd\u65b0\u578b\u7c7b\u56fa\u4f53\u7535\u89e3\u8d28\uff0c\u8be5\u7535\u89e3\u8d28\u4ee5MOF\u6750\u6599\u4e3a\u9aa8\u67b6\uff0c\u542b\u6709\u9502\u76d0\u7684\u79bb\u5b50\u6db2\u4f53\u4f5c\u4e3a\u9502\u79bb\u5b50\u5bfc\u4f53\u5bc4\u5bbf\u4e8eMOF\u9aa8\u67b6\u4e2d\uff0c\u76f8\u5173\u6210\u679c\u4ee5\u201cA Metal-Organic-Framework-Based Electrolyte with Nanowetted Interfaces for High-Energy-Density Solid-State Lithium Battery\u201d\u53d1\u8868\u4e8eAdv. Mater\u4e0a\u3002\u8be5\u65b0\u578b\u7c7b\u56fa\u4f53\u7535\u89e3\u8d28\uff08Li-IL@MOF\uff09\u5177\u6709\u9ad8\u7684\u5ba4\u6e29\u7535\u5bfc\u7387\uff083.0\u00d710-4<\/sup> S cm-1<\/sup>\uff09\uff0c\u9502\u79bb\u5b50\u8fc1\u79fb\u6570\u53ef\u8fbe0.36\uff0c\u4e0e\u9502\u91d1\u5c5e\u548cLiFePO4<\/sub>\uff08LFP\uff09\u6b63\u6781\u6750\u6599\u5747\u5177\u6709\u826f\u597d\u7684\u76f8\u5bb9\u6027\u3002\u91c7\u7528\u6b64\u7535\u89e3\u8d28\u7ec4\u88c5\u7684Li\u2223LiFePO4<\/sub>\u7535\u6c60\u6b63\u6781\u6d3b\u6027\u7269\u8d28\u7684\u8d1f\u8f7d\u91cf\u53ef\u8fbe25 mg cm-2<\/sup>\uff0c\u7535\u6c60\u5177\u6709\u826f\u597d\u7684\u5faa\u73af\u6027\u80fd\uff0c\u53ef\u5728-20\u5230150\u2103\u6e29\u5ea6\u8303\u56f4\u5185\u8fd0\u884c\u826f\u597d\u3002\u91c7\u7528\u6b64\u65b0\u578b\u7535\u89e3\u8d28\u7684\u7535\u6c60\u5177\u6709\u5982\u6b64\u4f18\u5f02\u6027\u80fd\uff0c\u8fd9\u662f\u56e0\u4e3a\uff1a1\uff09\u7535\u89e3\u8d28\u5185\u90e8MOF\u7eb3\u7c73\u6676\u7d27\u5bc6\u5806\u53e0\uff0c\u56e0\u6b64\u5bc4\u5bbf\u4e8e\u4e0d\u540cMOF\u7eb3\u7c73\u6676\u4e2d\u7684\u79bb\u5b50\u6db2\u4f53\u53ef\u76f4\u63a5\u76f8\u8fde\uff0c\u56e0\u800c\u7535\u89e3\u8d28\u5177\u6709\u8f83\u9ad8\u7684\u7535\u5bfc\u7387\uff1b2\uff09MOF\u8868\u9762\u9644\u8fd1\u672a\u88ab\u675f\u7f1a\u7684\u79bb\u5b50\u6db2\u4f53\u5177\u6709\u4f18\u5f02\u7684\u754c\u9762\u6da6\u6e7f\u80fd\u529b\uff0c\u4f7f\u5f97\u56fa\u6001\u7535\u89e3\u8d28\u548c\u6b63\u6781\u6750\u6599\u4e4b\u95f4\u5177\u6709\u826f\u597d\u754c\u9762\u63a5\u89e6\uff0c\u8fd9\u964d\u4f4e\u4e86\u754c\u9762\u7535\u963b\uff1b3\uff09MOF\u6750\u6599\u7279\u6b8a\u7684\u5b54\u9053\u7ed3\u6784\u53ef\u4ee5\u9650\u5236\u5927\u5c3a\u5bf8\u7684\u79bb\u5b50\u6db2\u4f53\u9633\u79bb\u5b50[EMIM]+<\/sup>\u548c\u9634\u79bb\u5b50[TFSI]–<\/sup>\u7684\u79fb\u52a8\uff0c\u800c\u4e0d\u5f71\u54cd\u5c0f\u5c3a\u5bf8\u7684\u9502\u79bb\u5b50\u7684\u79fb\u52a8\uff0c\u56e0\u800c\u5177\u6709\u8f83\u9ad8\u7684\u9502\u79bb\u5b50\u8fc1\u79fb\u6570\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n

\u56fe<\/strong>1 <\/strong>\u91c7\u7528<\/strong>Li-IL@MOF<\/strong>\u7535\u89e3\u8d28\u7684\u56fa\u6001\u7535\u6c60\u7ed3\u6784\u53ca\u7eb3\u7c73\u6da6\u6e7f\u754c\u9762\u673a\u7406\u793a\u610f\u56fe<\/strong><\/p>\n

\"\"<\/p>\n

\u56fe<\/strong>2 Li-IL@MOF<\/strong>\u7c7b\u56fa\u4f53\u7535\u89e3\u8d28\u7684\u7535\u5316\u5b66\u6027\u8d28<\/strong><\/p>\n

\"\"<\/p>\n

a.\u6dfb\u52a0\u4e0d\u540c\u91cfLi-IL\u7684Li-IL@MOF\u7c7b\u56fa\u4f53\u7535\u89e3\u8d28\u7535\u5bfc\u7387\u968f\u6e29\u5ea6\u7684\u53d8\u5316<\/p>\n

b.Li-IL@MOF(1.5ml:1.2g)\u7c7b\u56fa\u4f53\u7535\u89e3\u8d28\u5728-20\u5230100\u2103\u6e29\u5ea6\u8303\u56f4\u5185\u7684EIS\u56fe\u8c31\uff0c\u63d2\u56fe\u4e3a\u9ad8\u9891\u533a\u57df\u7684\u653e\u5927\u56fe<\/p>\n

c.\u5bf9b)\u6240\u5f97\u7535\u5bfc\u7387\u7684Arrhenius\u62df\u5408<\/p>\n

d.\u5ba4\u6e29\u4e0bLi\u2223Li-IL@MOF\u2223SS\u975e\u5bf9\u79f0\u7535\u6c60\u524d\u4e09\u4e2a\u5faa\u73af\u7684CV\uff08-0.5-3V\uff09\u548cLSV\uff083-7V\uff09\u56fe\uff08\u626b\u63cf\u901f\u5ea6\u4e3a0.2 mV s-1<\/sup>\uff09<\/p>\n

\u56fe<\/strong>3 Li<\/strong>\u2223<\/strong>Li-IL@MOF<\/strong>\u2223<\/strong>Li<\/strong>\u5bf9\u79f0\u7535\u6c60\u6d4b\u8bd5\u7ed3\u679c<\/strong><\/p>\n

\"\"<\/p>\n

a.\u57280.05\u548c0.2 mA cm-2<\/sup>\u7535\u6d41\u5bc6\u5ea6\u4e0b\uff0cLi\u2223Li-IL@MOF\u2223Li\u5bf9\u79f0\u7535\u6c60\u7684\u7535\u538b\u968f\u65f6\u95f4\u7684\u53d8\u5316\u66f2\u7ebf<\/p>\n

b.Li\u6c89\u79ef\/\u6eb6\u51fa\u5faa\u73af\u524d\u540eLi\u2223Li-IL@MOF\u2223Li\u5bf9\u79f0\u7535\u6c60\u7684EIS\u56fe\u8c31<\/p>\n

c.Li\u6c89\u79ef\/\u6eb6\u51fa\u5faa\u73af\u540e\u754c\u9762\u7ed3\u6784\u53d8\u5316\u793a\u610f\u56fe<\/p>\n

\u56fe<\/strong>4 <\/strong>\u6b63\u6781\u548c\u7535\u89e3\u8d28\u7684\u5f62\u8c8c\u548c\u7ec4\u6210\u8868\u5f81<\/strong><\/p>\n

\"\"<\/p>\n

a.d. \u6b63\u6781\u5c42\u548c\u7535\u89e3\u8d28\u5c42\u7684\u5149\u5b66\u7167\u7247<\/p>\n

b.\u6b63\u6781\u4e0e\u7535\u89e3\u8d28\u53cc\u5c42\u7ed3\u6784\u7684SEM\u56fe<\/p>\n

c.e. f. \u6b63\u6781\u4e0e\u7535\u89e3\u8d28\u53cc\u5c42\u7ed3\u6784\u7684EDS\u9762\u5206\u5e03\u56fe<\/p>\n

\u56fe<\/strong>5 Li<\/strong>\u2223<\/strong>Li-IL@MOF<\/strong>\u2223<\/strong>LFB<\/strong>\u56fa\u6001\u7535\u6c60\u7684\u5faa\u73af\u6027\u80fd\u548c\u5e93\u4f26\u6548\u7387<\/strong><\/p>\n

\"\"<\/p>\n

a.\u5ba4\u6e29\u4e0b0.1C\u500d\u7387\u4e0bLi\u2223Li-IL@MOF\u2223LFB\u56fa\u6001\u7535\u6c60\u7684\u5faa\u73af\u6027\u80fd\u548c\u5e93\u4f26\u6548\u7387<\/p>\n

b.Li\u2223Li-IL@MOF\u2223LFB\u56fa\u6001\u7535\u6c60\u5728\u4e0d\u540c\u6e29\u5ea6\u4e0b\u7684\u5faa\u73af\u6027\u80fd<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n

\u8be5\u7814\u7a76\u5c06\u6dfb\u52a0\u4e86\u9502\u76d0\u7684\u79bb\u5b50\u6db2\u4f53\u88c5\u586b\u4e8eMOF\u9aa8\u67b6\u4e2d\uff0c\u5728\u7535\u6781\/\u7535\u89e3\u8d28\u754c\u9762\u5904\uff0cMOF\u6750\u6599\u7684\u4e09\u7ef4\u5f00\u653e\u7ed3\u6784\u4f7f\u5f97\u53d7\u9650\u4e8eMOF\u9aa8\u67b6\u4e2d\u7684Li-IL\u53ef\u4e0e\u7535\u6781\u6d3b\u6027\u7269\u8d28\u76f4\u63a5\u63a5\u89e6\uff0c\u5f62\u6210\u4e30\u5bcc\u7684\u7eb3\u7c73\u6da6\u6e7f\u754c\u9762\uff0c\u8fd9\u6709\u6548\u964d\u4f4e\u4e86\u754c\u9762\u7535\u963b\uff0c\u4fc3\u8fdb\u4e86\u9502\u79bb\u5b50\u7684\u4f20\u8f93\u3002\u8be5\u7535\u89e3\u8d28\u6784\u7b51\u65b9\u6cd5\u662f\u4e00\u79cd\u901a\u7528\u7684\u65b9\u6cd5\uff0c\u901a\u8fc7\u6539\u53d8\u79bb\u5b50\u6db2\u4f53\u4e2d\u91d1\u5c5e\u79bb\u5b50\u7684\u79cd\u7c7b\uff0c\u6b64\u65b9\u6cd5\u53ef\u6269\u5c55\u7528\u4e8e\u5176\u4ed6\u5982K\u3001Na\u3001Mg\u3001Al\u7b49\u7535\u6c60\u4e2d\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/strong>A Metal-Organic-Framework-Based Electrolyte with Nanowetted Interfaces for High-Energy-Density Solid-State Lithium Battery<\/strong><\/a>\uff08<\/strong>Adv. Mater., 2017, DOI: 10.1002\/adma.201704436<\/strong>\uff09<\/strong><\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u7f16\u8f91\u90e8\u5f20\u4eb2\u4eb2\u7f16\u8bd1\uff0c\u9ec4\u8d85\u5ba1\u6838\uff0c\u70b9\u6211\u52a0\u5165\u6750\u6599\u4eba\u7f16\u8f91\u90e8<\/a><\/p>\n

\u6750\u6599\u6d4b\u8bd5\uff0c\u6570\u636e\u5206\u6790\uff0c\u4e0a<\/strong>\u6d4b\u8bd5\u8c37<\/strong><\/a>\uff01<\/strong><\/p>\n","protected":false},"excerpt":{"rendered":"

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