{"id":11571,"date":"2016-05-06T08:00:08","date_gmt":"2016-05-06T00:00:08","guid":{"rendered":"\/\/m.iemloyee.com\/?p=11571"},"modified":"2016-05-07T14:23:12","modified_gmt":"2016-05-07T06:23:12","slug":"%e9%a1%b6%e5%88%8a%e5%8a%a8%e6%80%81jacsangew-%e9%87%91%e5%b1%9e%e6%9c%89%e6%9c%ba%e9%aa%a8%e6%9e%b6%e6%9d%90%e6%96%99%e7%a0%94%e7%a9%b6%e8%bf%9b%e5%b1%95%e6%b1%87%e6%80%bb%e3%80%90160506%e6%9c%9f","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=11571","title":{"rendered":"\u9876\u520a\u52a8\u6001|JACS\/Angew \u91d1\u5c5e\u6709\u673a\u9aa8\u67b6\u6750\u6599\u7814\u7a76\u8fdb\u5c55\u6c47\u603b\u3010160506\u671f\u3011"},"content":{"rendered":"<ul>\n<li><b><\/b><strong><b>Angew\uff1a\u7b80\u5355<\/b><\/strong><strong><b>\u539f\u4f4d\u4e00\u9505\u6cd5\u5408\u6210\u591a\u529f\u80fd\u5316MOF<\/b><\/strong><\/li>\n<\/ul>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone wp-image-11572\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/05\/\u56fe\u72471-2-300x127.jpg\" alt=\"\u56fe\u72471\" width=\"456\" height=\"193\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/05\/\u56fe\u72471-2-300x127.jpg 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2016\/05\/\u56fe\u72471-2-768x326.jpg 768w, \/\/m.iemloyee.com\/wp-content\/uploads\/2016\/05\/\u56fe\u72471-2.jpg 994w\" sizes=\"(max-width: 456px) 100vw, 456px\" \/><\/p>\n<p style=\"text-align: center;\">\u56fe1\u00a0UiO-66\u5f15\u5165TCPP\uff08\u7ea2\u8272\uff09\u7684\u793a\u610f\u56fe<\/p>\n<p>\u5305\u542b\u591a\u529f\u80fd\u7684\u9ad8\u7a33\u5b9a\u6027MOF\u5728\u6076\u52a3\u73af\u5883\u4e0b\u7684\u5e94\u7528\u5f15\u8d77\u4eba\u4eec\u7814\u7a76\u5174\u8da3\uff0c\u5230\u76ee\u524d\u4e3a\u6b62\uff0c\u79d1\u7814\u4eba\u5458\u5728\u8fd9\u65b9\u9762\u505a\u51fa\u4e86\u5f88\u591a\u7684\u52aa\u529b\uff0c\u5f15\u5165\u591a\u529f\u80fd\u6027\u7684\u57fa\u56e2\u5230MOF\u7ed3\u6784\u5f53\u4e2d\uff0c\u5176\u4e2d\u6df7\u5408\u914d\u4f53\u7b56\u7565\u662f\u7814\u7a76\u8f83\u591a\u7684\u4e00\u79cd\u65b9\u6cd5\u3002\u503c\u5f97\u6ce8\u610f\u7684\u662f\uff0cYaghi\u53ca\u5176\u5408\u4f5c\u8005\u6210\u529f\u7684\u5c06\u516b\u79cd\u529f\u80fd\u5f15\u5165\u5230\u4e86MOF-5\u4e2d\u3002<\/p>\n<p>\u7f8e\u56fd\u5fb7\u5dde\u519c\u5de5\u5468\u5b8f\u624d\u6559\u6388\u8fd1\u65e5\u5728Angew\u4e0a\u53d1\u8868\u4e86\u4e00\u7bc7\u8bba\u6587\uff0c\u5229\u7528\u7b80\u5355\u539f\u4f4d\u4e00\u9505\u6cd5\u6df7\u5408\u914d\u4f53\u7b56\u7565\u5c06\u591a\u529f\u80fd\u6027\u914d\u4f53\u5f15\u5165\u5230\u4e86\u7a33\u5b9a\u7684\u9506\u57faMOF\u4e2d\uff0c\u503c\u5f97\u6ce8\u610f\u7684\u662f\uff0c\u8fd9\u4e9b\u6df7\u5408\u7684\u914d\u4f53\u7684\u51e0\u4f55\u6784\u578b\u548c\u8fde\u63a5\u65b9\u5f0f\u662f\u4e0d\u540c\u7684\u3002\u4e14\u5f15\u5165\u914d\u4f53\u7684\u542b\u91cf\u662f\u53ef\u4ee5\u63a7\u5236\u7684\uff0c\u5f15\u5165\u914d\u4f53\u540e\u7684MOF\u7ed3\u6784\u6ca1\u6709\u53d1\u751f\u53d8\u5316\u3002\u5728\u6240\u5408\u6210\u7684\u591a\u529f\u80fd\u6027MOF\u4e2d\uff0c\u6709\u4e00\u79cdMOF\u8fd8\u8868\u73b0\u51fa\u50ac\u5316\u6c27\u5316ABTS\u6d3b\u6027\u3002\u7814\u7a76\u4eba\u5458\u9884\u6d4b\uff0c\u8fd9\u6837\u7684\u7b56\u7565\u4e3a\u5408\u6210\u548c\u6784\u7b51\u529f\u80fd\u6027\u7a33\u5b9aZr-MOF\u63d0\u4f9b\u4e86\u4e00\u6761\u7b80\u5355\u7684\u9014\u5f84\uff0c\u62d3\u5c55\u4e86\u5176\u5728\u66f4\u591a\u9886\u57df\u7684\u5e94\u7528\u3002<\/p>\n<p><strong><b>\u6587\u732e\u94fe\u63a5\uff1a<a href=\"http:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/anie.201602274\/full\" target=\"_blank\">An In Situ One-Pot Synthetic Approach towards Multivariate Zirconium MOFs<\/a><\/b><\/strong><\/p>\n<ul>\n<li><b><\/b><strong><b>Angew\uff1a\u5206\u7ea7\u6574\u5408\u5149\u654f\u5316\u7684MOFs\u548c\u542b\u954d\u591a\u91d1\u5c5e\u6c27\u9178\u76d0\uff08POM\uff09\u7528\u4e8e\u6709\u6548\u53ef\u89c1\u5149\u9a71\u52a8\u50ac\u5316\u5236\u6c22<\/b><\/strong><\/li>\n<\/ul>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone wp-image-11573\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/05\/\u56fe\u72472-2-300x274.jpg\" alt=\"\u56fe\u72472\" width=\"347\" height=\"317\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/05\/\u56fe\u72472-2-300x274.jpg 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2016\/05\/\u56fe\u72472-2-768x702.jpg 768w, \/\/m.iemloyee.com\/wp-content\/uploads\/2016\/05\/\u56fe\u72472-2.jpg 989w\" sizes=\"(max-width: 347px) 100vw, 347px\" \/><\/p>\n<p>\u56fe2\uff08a\uff09H2L1\u548cH2L2\u7684\u7ed3\u6784\uff08b\uff09Ni<sub>4<\/sub>P<sub>2<\/sub>\u7684\u7ed3\u6784\u591a\u9762\u4f53\u89c6\u56fe\uff08c\uff09\uff081,1,1\uff09\u65b9\u5411\u4e0aNi<sub>4<\/sub>P<sub>2<\/sub>@MOF\u7ed3\u6784\uff08d\uff09\u672a\u5360\u636e\u7684\u56db\u9762\u4f53\u7a7a\u8154\u548c\u5360\u636eNi<sub>4<\/sub>P<sub>2<\/sub>\u516b\u9762\u4f53\u7a7a\u8154<\/p>\n<p>MOFs\u524d\u6240\u672a\u6709\u7684\u9ad8\u6bd4\u8868\u9762\u79ef\u548c\u89c4\u5219\u5b54\u9053\u7ed3\u6784\uff08\u53ef\u901a\u8fc7\u5bf9\u6865\u8054\u7684\u914d\u4f53\u548c\u91d1\u5c5e\u8fde\u63a5\u8282\u70b9\u7684\u9009\u62e9\u8fdb\u884c\u8c03\u8282\uff09\uff0c\u5438\u5f15\u4e86\u7814\u7a76\u4eba\u5458\u7684\u6781\u5927\u5174\u8da3\uff0c\u5176\u5728\u5982\u50a8\u6c22\u3001\u50ac\u5316\u7b49\u9886\u57df\u6709\u7740\u5e7f\u6cdb\u7684\u5e94\u7528\u524d\u666f\u3002\u901a\u8fc7\u5f15\u5165\u5177\u6709\u50ac\u5316\u6d3b\u6027\u7684\u6865\u8054\u914d\u4f53\u6216\u91d1\u5c5e\u8fde\u63a5\u70b9\uff0cMOFs\u53ef\u4f5c\u4e3a\u4e00\u79cd\u65b0\u578b\u7684\u53ef\u5faa\u73af\u5229\u7528\u7684\u50ac\u5316\u5242\u7528\u4e8e\u6709\u673a\u53cd\u5e94\u3002\u5c06\u91d1\u5c5e\u6216\u91d1\u5c5e\u6c27\u5316\u7269\u5f15\u5165\u5230MOF\u7684\u5b54\u8154\u5f53\u4e2d\uff0c\u662f\u5236\u5907\u5177\u6709\u9ad8\u6548\u50ac\u5316\u6d3b\u6027\u5f02\u76f8\u50ac\u5316\u5242\uff08MOF\u57fa\uff09\u7684\u53e6\u4e00\u6709\u6548\u624b\u6bb5\u3002<\/p>\n<p>MOFs\u53ef\u4f5c\u4e3a\u4e00\u4e2a\u53ef\u8c03\u8282\u7684\u5206\u7ea7\u6574\u5408\u4e0d\u540c\u5316\u5408\u7269\u7684\u5e73\u53f0\uff0c\u5f62\u6210\u590d\u5408\u6750\u6599\u4ee5\u5b9e\u73b0\u4e0d\u540c\u7ec4\u5206\u4e4b\u95f4\u7684\u534f\u540c\u4f5c\u7528\u3002\u8fd1\u65e5\uff0c\u7f8e\u56fd\u829d\u52a0\u54e5\u5927\u5b66\u6797\u6587\u658c\u6559\u6388\u53ca\u5176\u5408\u4f5c\u8005\uff0c\u5c06\u542b\u954d\u7684\u591a\u91d1\u5c5e\u6c27\u9178\u76d0\uff08POM\uff09[Ni4(H2O)2(PW9O34)2]10-\uff08\u7b80\u8bb0\u4e3aNi4P2\uff09\u5f15\u5165\u5230\u4e24\u4e2a\u9ad8\u7a33\u5b9a\u6027\u3001\u591a\u5b54\u78f7\u5149MOFs\u5f53\u4e2d\uff0cNi4P2\u4e0eNi4P2@MOF\u4e2d\u591a\u79cd\u5149\u654f\u5242\u9760\u8fd1\uff0c\u5bb9\u6613\u5b9e\u73b0\u591a\u7535\u5b50\u8f6c\u79fb\uff0c\u8fd9\u5c31\u80fd\u591f\u6709\u6548\u7684\u5229\u7528\u53ef\u89c1\u5149\u9a71\u52a8\u50ac\u5316\u5236\u6c22\u53cd\u5e94\uff08HER\uff09\uff0cTON\u503c\u9ad8\u8fbe1476\u3002\u7ecf\u5149\u7269\u7406\u548c\u7535\u5316\u5b66\u7814\u7a76\u8868\u660e\uff0cNi4P2\u6fc0\u53d1\u6001\u5149\u654f\u5242\u7684\u6c27\u5316\u6dec\u706d\u662fHER\u7684\u5f00\u59cb\u6b65\u9aa4\uff0c\u540c\u65f6\u4e5f\u89e3\u91ca\u4e86\u4e24\u79cd\u4e0d\u540c\u7684POM@MOF\u9ad8\u6548\u7684\u50ac\u5316\u6d3b\u6027\u4e0d\u540c\u4e4b\u5904\u3002\u5728\u8fd9\u9879\u7814\u7a76\u5f53\u4e2d\uff0cPOM@MOF\u7684\u7ec4\u88c5\u4e0d\u4ec5\u4e3a\u8bbe\u8ba1\u9ad8\u6548HER\u50ac\u5316\u5242\u63d0\u4f9b\u4e86\u53ef\u8c03\u6027\u7684\u5e73\u53f0\uff0c\u8fd8\u4fc3\u8fdb\u4eba\u4eec\u5bf9\u4e8eHER\u8fc7\u7a0b\u7684\u8be6\u7ec6\u673a\u7406\u7684\u7406\u89e3\u3002<\/p>\n<p><strong>\u6587\u732e\u94fe\u63a5\uff1a<a href=\"http:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/ange.201600431\/abstract\" target=\"_blank\">Hierarchical Integration of Photosensitizing Metal\u2013Organic Frameworks and Nickel-Containing Polyoxometalates for Efficient Visible-Light-Driven Hydrogen Evolution<\/a><\/strong><\/p>\n<ul>\n<li><b><\/b><strong><b>JACS\uff1a\u9ad8\u7a33\u5b9a\u6027Zr(IV)-MOFs\u7528\u4e8e\u6c34\u4e2d\u6297\u751f\u7d20\u548c\u6709\u673a\u7206\u70b8\u7269\u7684\u68c0\u6d4b\u4e0e\u53bb\u9664<\/b><\/strong><\/li>\n<\/ul>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone wp-image-11574\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/05\/\u56fe\u72473-2-300x296.jpg\" alt=\"\u56fe\u72473\" width=\"346\" height=\"341\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/05\/\u56fe\u72473-2-300x296.jpg 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2016\/05\/\u56fe\u72473-2.jpg 441w\" sizes=\"(max-width: 346px) 100vw, 346px\" \/><\/p>\n<p style=\"text-align: center;\">\u56fe3\u00a0BUT-12\u7684\u7ed3\u6784\u793a\u610f\u56fe<\/p>\n<p>\u6297\u751f\u7d20\u548c\u6709\u673a\u7206\u70b8\u7269\u662f\u6c61\u6c34\u4e2d\u4e3b\u8981\u7684\u6c61\u67d3\u7269\uff0c\u5bf9\u4e8e\u5b83\u4eec\u7684\u68c0\u6d4b\u4e0e\u53bb\u9664\u662f\u975e\u5e38\u91cd\u8981\u7684\uff0c\u4f46\u662f\u4e5f\u5b58\u5728\u8fd9\u6280\u672f\u4e0a\u7684\u6311\u6218\u3002\u800c\u4f5c\u4e3a\u65b0\u578b\u7684\u591a\u5b54\u6750\u6599MOF\uff0c\u5728\u6c61\u67d3\u7269\u7684\u68c0\u6d4b\u548c\u53bb\u9664\u9886\u57df\u6709\u7740\u6f5c\u5728\u7684\u5e94\u7528\u3002<\/p>\n<p>\u8fd1\u65e5\uff0c\u5317\u4eac\u5de5\u4e1a\u5927\u5b66\u674e\u5efa\u8363\u6559\u6388\u53ca\u5176\u5408\u4f5c\u8005\u5728\u5316\u5b66\u7c7b\u9876\u7ea7\u671f\u520aJACS\u4e0a\u53d1\u8868\u4e86\u5173\u4e8e\u8fd9\u65b9\u9762\u7684\u8bba\u6587\u3002\u57fa\u4e8e\u62d3\u6251\u8bbe\u8ba1\u65b9\u6cd5\uff0c\u5408\u6210\u4e86\u4e24\u79cd\u9ad8\u7a33\u5b9a\u6027\u7684Zr(IV)-MOFs\uff0cZr6O4(OH)8(H2O)4(CTTA)8\/3 (BUT-12)\u548cZr6O4(OH)8(H2O)4(TTNA)8\/3 (BUT-13)\uff0c\u4e14\u8fd9\u4e24\u4e2dMOF\u7684BET\u6bd4\u8868\u9762\u79ef\u5206\u522b\u4e3a3387\u548c3948 m2 g-1\u3002\u503c\u5f97\u4e00\u63d0\u7684\u662f\uff0cBUT-13\u662f\u76ee\u524d\u62a5\u9053\u7684\u5728\u6c34\u4e2d\u6700\u7a33\u5b9a\u7684MOF\uff0c\u8fd9\u4e9bMOF\u5c55\u73b0\u51fa\u4e86\u5f88\u597d\u7684\u8367\u5149\u6027\u80fd\uff0c\u5176\u53d1\u5149\u53ef\u4ee5\u88ab\u6c34\u4e2d\u75d5\u91cf\u7684NZF\u3001NFT\u8fd9\u4e9b\u6297\u751f\u7d20\u548cTNP\u30014-NP\u8fd9\u4e9b\u6709\u673a\u7206\u70b8\u7269\u6dec\u706d\uff0c\u8fd9\u5c31\u4f7f\u5f97\u5176\u5728\u6c34\u4e2d\u6297\u751f\u7d20\u548c\u6709\u673a\u7206\u70b8\u7269\u7684\u68c0\u6d4b\u6709\u7740\u6f5c\u5728\u7684\u5e94\u7528\u4ef7\u503c\uff0c\u68c0\u6d4b\u7684\u7075\u654f\u5ea6\u4e5f\u5f88\u9ad8\u3002<\/p>\n<p>\u8fd9\u4e24\u79cdMOF\u5bf9\u4e8e\u6c34\u4e2d\u7684\u6297\u751f\u7d20\u548c\u6709\u673a\u7206\u70b8\u7269\u5206\u5b50\u6709\u7740\u5f88\u597d\u7684\u5438\u9644\u6027\u80fd\uff0c\u8fd9\u6837\u9ad8\u6548\u7684\u5438\u9644\u6027\u80fd\u53ef\u4ee5\u8fdb\u4e00\u6b65\u63d0\u9ad8\u8367\u5149\u6dec\u706d\u6548\u7387\u3002\u8fd9\u4e9b\u7ed3\u679c\u8868\u660e\uff0cBUT-12\u548cBUT-13\u5728\u5bf9\u7279\u5b9a\u6297\u751f\u7d20\u548c\u6709\u673a\u7206\u70b8\u7269\u7684\u9009\u62e9\u6027\u68c0\u6d4b\u548c\u53bb\u9664\u65b9\u9762\u662f\u5f88\u91cd\u8981\u7684\u6750\u6599\uff0c\u5728\u68c0\u6d4b\u6c34\u8d28\u548c\u5904\u7406\u6c61\u6c34\u9886\u57df\u6709\u7740\u6f5c\u5728\u7684\u5e94\u7528\u3002<\/p>\n<p><strong><b>\u6587\u732e\u94fe\u63a5\uff1a<a href=\"http:\/\/pubs.acs.org\/doi\/abs\/10.1021\/jacs.6b01663\" target=\"_blank\">Highly Stable Zr(IV)-Based Metal-Organic Frameworks for the Detection and Removal of Antibiotics and Organic Explosives in Water<\/a><\/b><\/strong><\/p>\n<ul>\n<li><b><\/b><strong><b>Angew\uff1a\u5fae\u9650\u57df\u754c\u9762\u5408\u6210<\/b><\/strong><strong><b>\u7279\u5b9a\u5f62\u72b6\u4e14<\/b><\/strong><strong><b>\u72ec\u7acb<\/b><\/strong><strong><b>\u7684<\/b><\/strong><strong><b>MOF<\/b><\/strong><strong><b>\u8d85\u7ed3\u6784<\/b><\/strong><\/li>\n<\/ul>\n<p>&nbsp;<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone wp-image-11575\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/05\/\u56fe\u72474-2-300x175.jpg\" alt=\"\u56fe\u72474\" width=\"360\" height=\"210\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/05\/\u56fe\u72474-2-300x175.jpg 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2016\/05\/\u56fe\u72474-2-768x448.jpg 768w, \/\/m.iemloyee.com\/wp-content\/uploads\/2016\/05\/\u56fe\u72474-2.jpg 993w\" sizes=\"(max-width: 360px) 100vw, 360px\" \/><\/p>\n<p style=\"text-align: center;\">\u56fe4\u00a0MOF\u8d85\u7ed3\u6784\u7684\u5408\u6210\u65b9\u6848\u793a\u610f\u56fe<\/p>\n<p>MOFs\u662f\u5177\u6709\u4e00\u79cd\u591a\u529f\u80fd\u5b54\u7ed3\u6784\u7684\u6750\u6599\uff0c\u662f\u7531\u91d1\u5c5e\u79bb\u5b50\u4e0e\u914d\u4f53\u901a\u8fc7\u914d\u4f4d\u952e\u7684\u5f62\u5f0f\u7ed3\u5408\u5728\u4e00\u8d77\u7684\uff0c\u5177\u4f53\u5f00\u653e\u7684\u5b54\u7ed3\u6784\u548c\u5185\u5728\u7684\u5fae\u5b54\u7ed3\u6784\u3002\u6700\u8fd1\uff0c\u5177\u6709\u591a\u529f\u80fd\u5b54\u7684MOFs\u88ab\u5e7f\u6cdb\u7684\u7814\u7a76\u3002\u8fd9\u6837\u7684MIS\u5408\u6210\u8def\u5f84\u4e3aMOF\u5728\u8bb8\u591a\u9886\u57df\u7684\u5e94\u7528\u6253\u5f00\u4e86\u5168\u65b0\u7684\u201c\u5927\u95e8\u201d\u3002<\/p>\n<p>\u8fd1\u65e5\uff0cDong-Pyo Kim\u6559\u6388\u53ca\u5176\u5408\u4f5c\u8005\u53d1\u5c55\u4e86\u4e00\u79cd\u5fae\u9650\u57df\u754c\u9762\u5408\u6210\u65b9\u6cd5\uff08MIS\uff09\uff0c\u7528\u4e8e\u6784\u7b51\u4e00\u7cfb\u5217\u7279\u5b9a\u5f62\u72b6\u7684\u72ec\u7acbMOF\u8d85\u7ed3\u6784\uff0c\u8fd9\u6837\u7684\u7b56\u7565\u5177\u6709\u4ee5\u4e0b\u4e09\u4e2a\u91cd\u8981\u7279\u70b9\uff1a<\/p>\n<ul>\n<li>\u5229\u7528\u4e00\u79cd\u819c\uff0c\u539f\u4f4d\u5408\u6210\u72ec\u7acb\u8d85\u7ed3\u6784MOF\uff0c\u5e76\u53ef\u4ee5\u63a7\u5236\u5176\u7ec4\u6210\u3001\u5f62\u72b6\u548c\u539a\u5ea6\uff1b<\/li>\n<li>\u901a\u8fc7\u8d1f\u8f7dFe3O4\u7eb3\u7c73\u9897\u7c92\uff0c\u5c06\u78c1\u6027\u529f\u80fd\u5f15\u5165\u5230MOF\u8d85\u7ed3\u6784\u4e2d\uff1b<\/li>\n<li>\u5c06\u6240\u5408\u6210\u7684MOF\u8d85\u7ed3\u6784\u9635\u5217\u8f6c\u79fb\u5230\u4e0d\u540c\u57fa\u8d28\u7684\u5e73\u5766\u6216\u5f2f\u66f2\u7684\u8868\u9762\u3002<\/li>\n<\/ul>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone wp-image-11576\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/05\/\u56fe\u72475-2-300x263.jpg\" alt=\"\u56fe\u72475\" width=\"378\" height=\"331\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/05\/\u56fe\u72475-2-300x263.jpg 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2016\/05\/\u56fe\u72475-2-768x673.jpg 768w, \/\/m.iemloyee.com\/wp-content\/uploads\/2016\/05\/\u56fe\u72475-2-1024x898.jpg 1024w, \/\/m.iemloyee.com\/wp-content\/uploads\/2016\/05\/\u56fe\u72475-2.jpg 1169w\" sizes=\"(max-width: 378px) 100vw, 378px\" \/><\/p>\n<p style=\"text-align: center;\">\u56fe5 \u6240\u5408\u6210\u7684\u4e0d\u540c\u5f62\u8c8cMOF\u8d85\u7ed3\u6784\u793a\u610f\u56fe<\/p>\n<p><strong><b>\u6587\u732e\u94fe\u63a5\uff1a<a href=\"http:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/anie.201601754\/full\" target=\"_blank\">Direct fabrication of Free-Standing MOF Superstructures with Desired Shapes by Micro-Confined Interfacial Synthesis<\/a><\/b><\/strong><\/p>\n<ul>\n<li><strong><b>JACS\uff1a\u5236\u5907\u7eb3\u7c73\u7ea4\u7ef4\u7684MOF\u8fc7\u6ee4\u5668\u7528\u4e8e\u6709\u6548\u7684\u7a7a\u6c14\u6c61\u67d3\u63a7\u5236<\/b><\/strong><\/li>\n<\/ul>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone wp-image-11577\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/05\/\u56fe\u72476-2-300x113.jpg\" alt=\"\u56fe\u72476\" width=\"419\" height=\"158\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/05\/\u56fe\u72476-2-300x113.jpg 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2016\/05\/\u56fe\u72476-2.jpg 543w\" sizes=\"(max-width: 419px) 100vw, 419px\" \/><\/p>\n<p style=\"text-align: center;\">\u56fe6 \u7eb3\u7c73\u7ea4\u7ef4\u7684MOF\u8fc7\u6ee4\u5668\u7684\u5fae\u89c2\u793a\u610f\u56fe<\/p>\n<p>\u7a7a\u6c14\u6c61\u67d3\u901a\u5e38\u662f\u6307\u7531\u4e8e\u4eba\u7c7b\u6d3b\u52a8\u6216\u81ea\u7136\u8fc7\u7a0b\u5f15\u8d77\u67d0\u4e9b\u7269\u8d28\u8fdb\u5165\u5927\u6c14\u4e2d\uff0c\u5448\u73b0\u51fa\u8db3\u591f\u7684\u6d53\u5ea6\uff0c\u8fbe\u5230\u8db3\u591f\u7684\u65f6\u95f4\uff0c\u5e76\u56e0\u6b64\u5371\u5bb3\u4e86\u4eba\u7c7b\u7684\u8212\u9002\u3001\u5065\u5eb7\u548c\u798f\u5229\u6216\u73af\u5883\u7684\u73b0\u8c61\u3002\u5728\u56fd\u5bb6\u7684\u5de5\u4e1a\u5316\u548c\u73b0\u4ee3\u5316\u8fdb\u7a0b\u4e2d\uff0c\u5bf9\u4e8e\u7a7a\u6c14\u7684\u6c61\u67d3\u6cbb\u7406\u4e00\u76f4\u662f\u5404\u4e2a\u56fd\u5bb6\u91cd\u70b9\u5173\u6ce8\u7684\u65b9\u9762\uff0c\u73af\u4fdd\u90e8\u95e8\u4e5f\u6295\u5165\u4e86\u5927\u91cf\u7684\u4eba\u529b\u548c\u7269\u529b\u6765\u6cbb\u7406\u7a7a\u6c14\u6c61\u67d3\u3002<\/p>\n<p>MOF\u6750\u6599\u5177\u6709\u591a\u5b54\u6027\u3001\u53ef\u8c03\u5b54\u7ed3\u6784\u3001\u591a\u529f\u80fd\u6027\u8fd9\u6837\u7684\u7279\u70b9\uff0c\u56e0\u6b64\u53ef\u4ee5\u7528\u4e8e\u7a7a\u6c14\u4e2d\u6c61\u67d3\u7269\u7684\u6355\u6349\uff0c\u6539\u5584\u7a7a\u6c14\u8d28\u91cf\u3002\u8fd1\u65e5\uff0c\u5317\u4eac\u7406\u5de5\u5927\u5b66\u738b\u535a\u6559\u6388\u53ca\u5176\u7814\u7a76\u8005\u5236\u5907\u51fa\u4e86\u7eb3\u7c73\u7ea4\u7ef4\u7684MOF\u8fc7\u6ee4\u5668\uff0c\u7528\u4e8e\u6709\u6548\u7684\u7a7a\u6c14\u6c61\u67d3\u63a7\u5236\u3002<\/p>\n<p>\u7814\u7a76\u4eba\u5458\u5c06\u4e0d\u540c\u542b\u91cf\u7684MOF\u7eb3\u7c73\u6676\u8d1f\u8f7d\u5230\u9ad8\u5206\u5b50\u7ea4\u7ef4\u4e0a\uff0c\u8bbe\u8ba1\u51fa\u4e86MOFilter\uff0c\u4e14\u5728\u6076\u52a3\u7684\u73af\u5883\u4e0b\u6d4b\u8bd5\u4e86MOFilter\u5bf9\u4e8ePM2.5\u548cPM10\u7684\u53bb\u9664\u6027\u80fd\uff0c\u5b9e\u9a8c\u7ed3\u679c\u8868\u660e\uff0cMOFilter\u5bf9\u4e8ePM2.5\u548cPM10\u6548\u7387\u5206\u522b\u9ad8\u8fbe88.33\u00b1 1.52% \u548c 89.67\u00b11.33%\u3002\u5728\u8fde\u7eed\u8fc7\u6ee4\u8d85\u8fc748\u5c0f\u65f6\u540e\uff0cMOFilter\u6027\u80fd\u57fa\u672c\u6ca1\u6709\u53d1\u751f\u53d8\u5316\uff0c\u9996\u6b21\u63a2\u7d22\u4e86\u591a\u5b54\u7ed3\u6676\u6750\u6599\u548c\u9897\u7c92\u6c61\u67d3\u7269\u4e4b\u95f4\u7684\u76f8\u4e92\u4f5c\u7528\u3002\u503c\u5f97\u4e00\u63d0\u7684\u662f\uff0c\u8fd9\u6837\u7684MOFilter\u5177\u6709\u9009\u62e9\u6027\u6355\u6349\u80fd\u529b\uff0c\u53ef\u4ee5\u5728SO2\/N2\u6df7\u5408\u6c14\u4f53\u4e2d\u6355\u6349SO2\u3002\u5728\u9ad8\u6c14\u4f53\u6d41\u7387\u4e0b\uff08\u538b\u529b\u964d\u5c0f\u4e8e20Pa\uff09\uff0c\u5176\u5206\u5c42\u7684\u7eb3\u7c73\u7ed3\u6784\u53ef\u4ee5\u5f88\u5bb9\u6613\u5730\u6e17\u900f\u65b0\u9c9c\u7a7a\u6c14\u3002<\/p>\n<p><strong><b>\u6587\u732e\u94fe\u63a5\uff1a<a href=\"http:\/\/pubs.acs.org\/doi\/abs\/10.1021\/jacs.6b02553\" target=\"_blank\">Preparation of Nanofibrous Metal\u2013Organic Framework Filters for Efficient Air Pollution Control<\/a><\/b><\/strong><\/p>\n<ul>\n<li><b><\/b><strong><b>JACS\uff1a\u65b0\u578bMOF\uff08UTSA-74\uff09\u7684\u5408\u6210\u53ca\u5176\u5728\u6c14\u4f53\u9009\u62e9\u6027\u5206\u79bb\u65b9\u9762\u7684\u5e94\u7528<\/b><\/strong><\/li>\n<\/ul>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone wp-image-11578\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/05\/\u56fe\u72477-2-300x120.jpg\" alt=\"\u56fe\u72477\" width=\"405\" height=\"162\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/05\/\u56fe\u72477-2-300x120.jpg 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2016\/05\/\u56fe\u72477-2.jpg 470w\" sizes=\"(max-width: 405px) 100vw, 405px\" \/><\/p>\n<p style=\"text-align: center;\">\u56fe7\u00a0UTSA-74\u7684\u7ed3\u6784\u793a\u610f\u56fe<\/p>\n<p>\u8fd1\u65e5\uff0c \u5fb7\u514b\u8428\u65af\u5927\u5b66\u5723\u5b89\u4e1c\u5c3c\u5965\u5206\u6821\u7684\u9648\u90a6\u6797\u6559\u6388\u53ca\u5176\u5408\u4f5c\u8005\u5408\u6210\u51fa\u4e86\u4e00\u79cd\u65b0\u578bMOF\uff0cZn2(H2O)(dobdc)\u00b70.5(H2O)\uff08\u7b80\u8bb0\u4e3aUTSA-74\uff09\uff0c\u5e76\u5bf9\u5176\u8fdb\u884c\u4e86\u7ed3\u6784\u8868\u5f81\uff0cUTSA-74\u4e3aZn-MOF-74\/CPO-27-Zn\u7684\u5f02\u6784\u4f53\uff0c\u5b83\u5177\u6709\u65b0\u578b\u56db\u914d\u4f4dfgI\u62d3\u6251\u7ed3\u6784\uff0c\u4e00\u7ef4\u5b54\u9053\u5b54\u5f84\u7ea6\u4e3a8.0 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cm3\/cm3\uff0c\u8fd9\u6837\u4f18\u5f02\u7684\u6027\u80fd\u4e0eMOF-74\u662f\u53ef\u4ee5\u6bd4\u62df\u7684\u3002\u7136\u800c\uff0c\u4ee4\u7814\u7a76\u4eba\u5458\u60ca\u8bb6\u7684\u662f\uff0c\u4e0eMOF-74\u76f8\u6bd4\uff0cUTSA-74\u53ef\u4ee5\u5438\u6536\u66f4\u5c11\u91cf\u7684CO2\u6c14\u4f53 (90 cm3\/cm3)\uff0c\u56e0\u6b64UTSA-74\u6709\u7740\u5f88\u597d\u7684\u6c14\u4f53\u5438\u6536\u80fd\u529b\u548c\u5bf9\u4e8eC2H2\/CO2\u6c14\u4f53\u4f53\u7cfb\u7684\u9009\u62e9\u6027\u5206\u79bb\uff0cX\u5c04\u7ebf\u6676\u4f53\u7ed3\u6784\uff0c\u6c14\u4f53\u5438\u9644\u7b49\u6e29\u7ebf\uff0c\u5206\u5b50\u5efa\u6a21\u548c\u4eff\u771f\u548c\u5b9e\u9a8c\u7684\u7a81\u7834\u90fd\u652f\u6301\u6b64\u7ed3\u679c\u3002<\/p>\n<p><strong><b>\u6587\u732e\u94fe\u63a5\uff1a<a href=\"http:\/\/pubs.acs.org\/doi\/abs\/10.1021\/jacs.6b02030\" target=\"_blank\">UTSA-74: A MOF-74 Isomer with Two Accessible Binding Sites per Metal Center for Highly Selective Gas 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