{"id":115599,"date":"2017-12-06T14:00:08","date_gmt":"2017-12-06T06:00:08","guid":{"rendered":"\/\/m.iemloyee.com\/?p=115599"},"modified":"2017-12-05T11:21:46","modified_gmt":"2017-12-05T03:21:46","slug":"%e6%b8%85%e5%8d%8e%e5%a4%a7%e5%ad%a6%e5%bc%a0%e5%b8%8c%e9%99%a2%e5%a3%abangew-chem-int-ed-%ef%bc%9a%e7%bb%86%e8%8f%8c%e8%a7%a6%e5%8f%91%e7%9a%84%e9%98%b4%e7%a6%bb%e5%ad%90%e8%b6%85%e5%88%86","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=115599","title":{"rendered":"\u6e05\u534e\u5927\u5b66\u5f20\u5e0c\u9662\u58ebAngew. Chem. Int. Ed.\uff1a\u7ec6\u83cc\u89e6\u53d1\u7684\u9634\u79bb\u5b50\u8d85\u5206\u5b50\u81ea\u7531\u57fa\u7528\u4e8e\u539f\u4f4d\u9009\u62e9\u6027\u5149\u70ed\u6cbb\u7597"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n

\u81ea\u9752\u9709\u7d20\u88ab\u53d1\u73b0\u4ee5\u6765\uff0c\u6297\u751f\u7d20\u88ab\u5e7f\u6cdb\u5e94\u7528\u4e8e\u4e34\u5e8a\u6cbb\u7597\u3001\u519c\u4e1a\u7528\u6c34\u3001\u6c61\u6c34\u5904\u7406\u7b49\u5404\u4e2a\u9886\u57df\uff0c\u7136\u800c\u4f34\u968f\u7740\u6297\u751f\u7d20\u957f\u671f\u6ee5\u7528\uff0c\u8010\u836f\u5fae\u751f\u7269\u4e5f\u968f\u4e4b\u51fa\u73b0\u5e76\u6210\u4e3a\u4eba\u7c7b\u5065\u5eb7\u751f\u6d3b\u7684\u4e25\u91cd\u5a01\u80c1\u3002\u56e0\u6b64\uff0c\u8feb\u5207\u5730\u9700\u8981\u5f00\u53d1\u51fa\u4e00\u79cd\u65b0\u7684\u6297\u83cc\u65b9\u6cd5\u3002\u8fd1\u5e74\u6765\uff0c\u4eba\u4eec\u8d8a\u6765\u8d8a\u5173\u6ce8\u5149\u70ed\u7597\u6cd5\u5bf9\u6297\u836f\u6027\u5fae\u751f\u7269\u4f5c\u7528\u6548\u679c\uff0c\u5bf9\u8010\u836f\u7684\u5fae\u751f\u7269\uff0c\u5149\u70ed\u7597\u6cd5\u901a\u8fc7\u5149\u70ed\u5242\u5347\u9ad8\u5c40\u90e8\u6e29\u5ea6\u5bfc\u81f4\u5fae\u751f\u7269\u86cb\u767d\u8d28\u53d8\u6027\u8fdb\u4e00\u6b65\u5bfc\u81f4\u75c5\u6e90\u5fae\u751f\u7269\u7684\u6b7b\u4ea1\u3002\u76ee\u524d\u5df2\u6709\u8bb8\u591a\u7684\u529f\u80fd\u6750\u6599\u88ab\u53d1\u5c55\u7528\u6765\u4f5c\u4e3a\u5149\u70ed\u6750\u6599\uff0c\u5982\u65e0\u673a\u7eb3\u7c73\u6750\u6599\u3001\u78b3\u57fa\u7eb3\u7c73\u6750\u6599\u548c\u5171\u8f6d\u529f\u80fd\u805a\u5408\u7269\u7b49\uff0c\u8fd9\u4e9b\u529f\u80fd\u6750\u6599\u5177\u6709\u826f\u597d\u7684\u5149\u70ed\u8f6c\u6362\u6548\u7387\u3002\u5149\u70ed\u6cbb\u7597\u662f\u9488\u5bf9\u8010\u836f\u5fae\u751f\u7269\u4e00\u4e2a\u6f5c\u5728\u7684\u4e34\u5e8a\u7b56\u7565\uff0c\u76ee\u524d\u5149\u70ed\u6750\u6599\u7684\u5236\u5907\u5df2\u6709\u660e\u663e\u7684\u8fdb\u5c55\uff0c\u4e14\u5bf9\u591a\u79cd\u7ec6\u83cc\u5177\u6709\u8f83\u597d\u7684\u9009\u62e9\u6027\uff0c\u5f00\u53d1\u65b0\u578b\u5149\u70ed\u5242\u662f\u5341\u5206\u5fc5\u8981\u7684\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u6e05\u534e<\/strong>\u5927\u5b66<\/strong>\u5f20\u5e0c\u9662\u58eb<\/strong>\u548c<\/strong>\u5f90\u6c5f\u98de\u52a9\u7406\u7814\u7a76\u5458<\/strong>\uff08\u5171\u540c\u901a\u8baf\u4f5c\u8005\uff09<\/strong>\u7b49\u4eba\u5728\u5149\u70ed\u6297\u83cc\u6750\u6599\u65b9\u9762\u53d6\u5f97\u4e86\u8fdb\u5c55\u3002\u8be5\u5c0f\u7ec4\u5229\u7528\u5317\u4e8c\u9170\u4e9a\u80fa\u548c\u846b\u82a6\u8132[ 7 ]\uff08CB[7]\uff09\u7684\u4e3b\u5ba2\u4f53\u4f5c\u7528\u5408\u6210\u4e86\u4e00\u79cd\u65b0\u578b\u7684\u590d\u5408\u9ad8\u5206\u5b50\u6750\u6599\uff08CPPDI\uff09\uff0c\u6b64\u6750\u6599\u80fd\u9009\u62e9\u6027\u88ab\u517c\u6027\u538c\u6c27\u83cc\u8fd8\u539f\u6210\u9634\u79bb\u5b50\u81ea\u7531\u57fa\uff0c\u8fdb\u800c\u5177\u6709\u8f83\u9ad8\u7684\u5149\u70ed\u8f6c\u5316\u6548\u7387\u3002\u6b64\u9879\u7814\u7a76\u6210\u679c\u4ee5\u201cSupramolecular Radical Anions Triggered by Bacteria In Situ for<\/strong> Selective Photothermal Therapy\u201d<\/strong>\u4e3a\u9898\u53d1\u8868\u5728Angew. Chem. Int. Ed.<\/strong>\u4e0a\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n

\u56fe<\/strong>1.<\/strong>\u8d85\u5206\u5b50\u590d\u5408\u7269\uff08<\/strong>CPPDI<\/strong>\uff09\u7ed3\u6784\u8bbe\u8ba1\u53ca\u5176\u9009\u62e9\u6027\u5149\u70ed\u6297\u83cc\u6548\u679c\u793a\u610f\u56fe<\/strong><\/p>\n

\"\"<\/p>\n

\uff08a\uff09\u8d85\u5206\u5b50\u590d\u5408\u7269\uff08CPPDI\uff09\u7684\u5316\u5b66\u7ed3\u6784\u53ca\u5176\u8f6c\u53d8\u4e3a\u9634\u79bb\u5b50\u81ea\u7531\u57fa\u7684\u8fc7\u7a0b<\/p>\n

\uff08b\uff09CPPDI\u5728\u517c\u6027\u538c\u6c27\u83ccE.coli\u7684\u4f5c\u7528\u4e0b\u5177\u6709\u8f83\u597d\u7684\u5149\u70ed\u8f6c\u5316\u6548\u7387\u4ece\u800c\u6740\u6b7b\u7ec6\u83cc\uff0cCPPDI\u5728\u9700\u6c27\u83ccB.subtills\u7684\u73af\u5883\u4e2d\u8fdb\u884c808 nm\u6fc0\u5149\u7167\u5c04\uff0c\u7cfb\u7edf\u6ca1\u6709\u660e\u663e\u7684\u6e29\u5ea6\u63d0\u5347\uff0c\u5149\u70ed\u7597\u6548\u5dee<\/p>\n

\u56fe<\/strong>2.<\/strong>\u7535\u5b50\u987a\u9a70\u5171\u632f\u68c0\u6d4b<\/strong>CPPDI<\/strong>\u9634\u79bb\u5b50\u81ea\u7531\u57fa<\/strong><\/p>\n

\"\"<\/p>\n

(a) \u7ea2\u8272\u7684CPPDI\u4e0ecoli\u5171\u5b75\u80b2\u540e\u88ab\u8fd8\u539f\u6210CPPDI\u9634\u79bb\u5b50\u81ea\u7531\u57fa\uff0c\u989c\u8272\u53d8\u84dd\uff0cEPR\u68c0\u6d4b\u6709\u660e\u663e\u7684CPPDI\u9634\u79bb\u5b50\u81ea\u7531\u57fa\u4fe1\u53f7<\/p>\n

(b) \u7ea2\u8272\u7684CPPDI\u4e0esubtills\u5171\u5b75\u80b2\u540e\u989c\u8272\u65e0\u660e\u663e\u53d8\u5316\uff0cEPR\u68c0\u6d4b\u6ca1\u6709\u660e\u663e\u7684CPPDI\u9634\u79bb\u5b50\u81ea\u7531\u57fa\u4fe1\u53f7<\/p>\n

\u56fe<\/strong>3.<\/strong>CPPDI<\/strong>\u4e0e\u4e0d\u540c\u7ec6\u83cc\u6df7\u5408\u7684\u6c34\u6eb6\u6db2\u8fd1\u7ea2\u5916\u5149\u7167\u5c04\u540e<\/strong>\u7684\u6e29\u5ea6\u53d8\u5316<\/strong><\/p>\n

\"\"<\/p>\n

(a) CPPDI\u4e0ecoli\u7684\u6c34\u6eb6\u6db2\u7ecf808 nm\u7684\u8fd1\u7ea2\u5916\u6fc0\u5149\u7167\u5c04\uff0c\u572830 min\u5185\u6e29\u5ea6\u5feb\u901f\u4e0a\u5347\u81f365\u2103<\/p>\n

(b) CPPDI\u4e0esubtills\u7684\u6c34\u6eb6\u6db2\u7ecf808 nm\u7684\u8fd1\u7ea2\u5916\u6fc0\u5149\u7167\u5c0430 min\u540e\u6e29\u5ea6\u6ca1\u6709\u660e\u663e\u7684\u5347\u9ad8<\/p>\n

\u56fe<\/strong>4.<\/strong>CPPDI<\/strong>\u4e0e\u4e0d\u540c\u7ec6\u83cc\u6df7\u5408\u540e\u8fd1\u7ea2\u5916\u5149\u7167\u5c04\u4e0d\u540c\u65f6\u95f4\u540e\u7684\u83cc\u843d\u7e41\u6b96\u901f\u7387<\/strong><\/p>\n

\"\"<\/p>\n

(a) CPPDI\u4e0ecoli\u5171\u5b75\u80b2\u7ecf808 nm\u7684\u8fd1\u7ea2\u5916\u6fc0\u5149\u7167\u5c04\u4e0d\u540c\u7684\u65f6\u95f4\u540e\u8ba1\u7b97\u83cc\u843d\u7e41\u6b96\u901f\u7387\uff0c\u968f\u7740\u5149\u7167\u65f6\u95f4\u7684\u589e\u52a0\u83cc\u843d\u7e41\u6b96\u901f\u7387\u660e\u663e\u4e0b\u964d\uff0c\u5149\u7167\u65f6\u95f4\u523030 min\u65f6\u83cc\u843d\u7e41\u6b96\u901f\u7387\u63a5\u8fd1\u4e8e\u96f6<\/p>\n

(b) CPPDI\u4e0esubtills\u5171\u5b75\u80b2\u7ecf808 nm\u7684\u8fd1\u7ea2\u5916\u6fc0\u5149\u7167\u5c04\u4e0d\u540c\u7684\u65f6\u95f4\u540e\u8ba1\u7b97\u83cc\u843d\u7e41\u6b96\u901f\u7387\uff0c\u968f\u7740\u5149\u7167\u65f6\u95f4\u7684\u589e\u52a0\u83cc\u843d\u7e41\u6b96\u901f\u7387\u6ca1\u6709\u8f83\u5927\u5e45\u5ea6\u7684\u53d8\u5316<\/p>\n

\u56fe<\/strong>5.CPPDI<\/strong>\u4e0e\u5404\u79cd\u7ec6\u83cc\u5171\u5b75\u80b2\u540e\u7684<\/strong>EPR<\/strong>\u8c31<\/strong><\/p>\n

\"\"<\/p>\n

CPPDI\u4e0eE. faecalis, S. aureus, P. aeruginosa, E. coli, B. subtilis\u51e0\u79cd\u7ec6\u83cc\u5206\u522b\u5171\u5b75\u80b2\u540e\u7684EPR\u8c31\u56fe<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n

\u672c\u6587\u6210\u529f\u5730\u8bbe\u8ba1\u5e76\u6784\u5efa\u4e86\u4e00\u4e2a\u80fd\u88ab\u517c\u6027\u538c\u6c27\u7ec6\u83cc\u9009\u62e9\u6027\u8fd8\u539f\u4e3a\u9634\u79bb\u5b50\u81ea\u7531\u57fa\u7684\u8d85\u5206\u5b50\u914d\u5408\u7269\uff08CPPDI\uff09\u3002\u8fd9\u79cd\u65b0\u578b\u8d85\u5206\u5b50\u590d\u5408\u7269\u901a\u8fc7\u5149\u70ed\u6cbb\u7597\u663e\u793a\u51fa\u5bf9\u517c\u6027\u538c\u6c27\u7ec6\u83cc\u9ad8\u9009\u62e9\u6027\u7684\u6297\u83cc\u6d3b\u6027\uff0c\u8be5\u8bbe\u8ba1\u65b9\u6cd5\u53ef\u4ee5\u6269\u5c55\u5230\u5206\u5b50\u7ec4\u88c5\u4f53\u3001\u805a\u5408\u7269\u548c\u8d85\u5206\u5b50\u805a\u5408\u7269\u7b49\u6750\u6599\u7684\u9009\u62e9\u6027\u6297\u83cc\u529f\u80fd\u8bbe\u8ba1\u3002\u6b64\u5916\uff0c\u82dd\u4e8c\u9170\u4e9a\u80fa\u884d\u751f\u7269\u90e8\u5206\u4e5f\u53ef\u4ee5\u7531\u5176\u4ed6\u5177\u6709\u8fd1\u7ea2\u5916\u5438\u6536\u7684\u6750\u6599\u4ee3\u66ff\uff0c\u8fd9\u79cd\u65b0\u7684\u7ec6\u83cc-\u5316\u5b66\u54cd\u5e94\u6a21\u578b\u5728\u8c03\u8282\u5fae\u751f\u7269\u5e73\u8861\u4e0a\u53ef\u80fd\u6709\u7740\u5de8\u5927\u7684\u6f5c\u529b\u3002<\/p>\n

\u00a0<\/strong>\u6587\u732e\u94fe\u63a5\uff1a<\/strong>Supramolecular Radical Anions Triggered by Bacteria In Situ for Selective Photothermal Therapy<\/a><\/strong>\uff08<\/strong>Angew. Chem. Int. Ed. , 2017, DOI: 10.1002\/anie.201708971<\/strong>\uff09<\/strong><\/p>\n

\u00a0<\/strong>\u672c\u6587\u7531\u6750\u6599\u4eba\u7f16\u8f91\u90e8\u5f20\u96ea\u8c6a\u7f16\u8bd1\uff0c \u5218\u5b87\u9f99\u5ba1\u6838\uff0c\u70b9\u6211\u52a0\u5165\u6750\u6599\u4eba\u7f16\u8f91\u90e8<\/strong><\/a>\u3002<\/p>\n

\u6750\u6599\u6d4b\u8bd5\uff0c\u6570\u636e\u5206\u6790\uff0c\u4e0a<\/strong>\u6d4b\u8bd5\u8c37<\/strong><\/a>\uff01<\/strong><\/p>\n","protected":false},"excerpt":{"rendered":"

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