{"id":115447,"date":"2017-12-09T06:30:34","date_gmt":"2017-12-08T22:30:34","guid":{"rendered":"\/\/m.iemloyee.com\/?p=115447"},"modified":"2017-12-07T16:51:46","modified_gmt":"2017-12-07T08:51:46","slug":"%e8%a7%82%e7%82%b9%e9%94%82%e7%a6%bb%e5%ad%90%e7%94%b5%e6%b1%a0%e5%85%85%e7%94%b5%e6%97%b6%ef%bc%8c%e7%a6%bb%e5%ad%90%e5%b5%8c%e5%85%a5%e7%9f%b3%e5%a2%a8%e8%b4%9f%e6%9e%81%e7%9a%84%e5%bd%a2%e6%80%81","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=115447","title":{"rendered":"\u89c2\u70b9|\u9502\u79bb\u5b50\u7535\u6c60\u5145\u7535\u65f6\uff0c\u79bb\u5b50\u5d4c\u5165\u77f3\u58a8\u8d1f\u6781\u7684\u5f62\u6001\u662f\u4ec0\u4e48\uff1f\u9502\u679d\u6676\u5982\u4f55\u5f62\u6210\uff1f"},"content":{"rendered":"

\u00a0\u672c\u4eba\u5728\u8003\u8651\u9502\u679d\u6676\u662f\u5982\u4f55\u5f62\u6210\u7684\u8fd9\u4e2a\u95ee\u9898\u65f6\u60f3\u5230\uff0c\u5982\u679c\u50cf\u8bb8\u591a\u4eba\u8ba4\u4e3a\u7684\u90a3\u6837\uff0c\u9502\u79bb\u5b50\u5d4c\u5165\u77f3\u58a8\u4e4b\u540e\u4ecd\u7136\u4ee5\u79bb\u5b50\u5f62\u6001\u5b58\u5728\uff0c\u90a3\u5316\u5b66\u53cd\u5e94\u5728\u54ea\u91cc\u53d1\u751f\uff1f\u5982\u679c\u79bb\u5b50\u5728\u754c\u9762\u53d1\u751f\u5316\u5b66\u53cd\u5e94\uff0c\u90a3\u662f\u5426\u53ef\u4ee5\u8ba4\u4e3a\u9502\u79bb\u5b50\u5df2\u8f6c\u5316\u4e3a\u539f\u5b50\u5f62\u6001\uff0c\u4e4b\u540e\u5411\u56fa\u76f8\u672c\u4f53\u5185\u6269\u6563\uff1f\u9502\u679d\u6676\u5f62\u6210\u7684\u6839\u672c\u539f\u56e0\u662f\u5426\u5728\u4e8e\u539f\u5b50\u5f62\u6001\u7684\u9502\u6765\u4e0d\u53ca\u5f80\u56fa\u76f8\u672c\u4f53\u6269\u6563\uff1f<\/strong><\/p>\n

\u8fd9\u662f\u4e2a\u597d\u95ee\u9898\uff0c\u4e3a\u9898\u4e3b\u7684\u6c42\u77e5\u70b9\u8d5e\u3002
\n \u5e2e\u4f60\u9080\u8bf7\u4e86\u4e00\u4e9b\u77e5\u53cb\u3002
\n \u9502\u652f\u6676\u751f\u957f\u7684\u95ee\u9898\u662f\u4e00\u4e2a\u590d\u6742\u7684\u96c6\u5408\uff0c\u6518\u62ec\u4e86\u5982\u7535\u5316\u5b66\u3001\u6676\u4f53\u5b66\u3001\u70ed\u529b\u5b66\u3001\u52a8\u529b\u5b66\u7b49\u56db\u5927\u5757\u7684\u9886\u57df\uff0c\u8981\u89e3\u91ca\u6e05\u695a\u662f\u4e0d\u592a\u5bb9\u6613\u7684\uff0c\u501f\u7740\u8fd9\u7bc7\u7b54\u6848\uff0c\u8ddf\u5927\u5bb6\u4e00\u8d77\u5b66\u4e60\u4e00\u4e0b\u3002
\n \u56de\u7b54\u9898\u4e3b\u7684\u95ee\u9898\u4e4b\u524d\uff0c\u5148\u8bf4\u660e\u4e24\u70b9\u3002
\n \u9996\u5148\uff0c\u8fd9\u91cc\u6709\u4e00\u4e2a\u9502\u679d\u6676\u751f\u957f\u7684\u52a8\u6001\u56fe<\/strong>\uff0c\u53ef\u4ee5\u5e2e\u52a9\u5927\u5bb6\u76f4\u89c2\u7684\u611f\u53d7\u4e00\u4e0b\uff1a
\n https:\/\/www.youtube.com\/watch?v=rpPUTM_u_PM<\/a>
\n \u8fd9\u4e2a\u662f\u7f8e\u56fd\u6a61\u6811\u5cad\u56fd\u5bb6\u5b9e\u9a8c\u5ba4\u7528ADF STEM\u62cd\u6444\u7684\u3002
\n \u7136\u540e\u5462\uff0c\u7b80\u5355\u7684\u4ecb\u7ecd\u4e00\u4e0b\u9502\u79bb\u5b50\u5f62\u6210\u679d\u6676\u7684\u8fc7\u7a0b\u3002\u6628\u5929\u4e0b\u5348\u6211\u7279\u5730\u53bb\u95ee\u4e86Jeff\u6559\u6388\uff0c\u4ed6\u7ed9\u6211\u753b\u4e86\u5f20\u56fe\uff1a<\/p>\n

\"\"<\/p>\n

\u4e0a\u9762\u6709\u6211\u5199\u7684\u4e00\u4e9b\u7b14\u8bb0\uff0c\u8bf7\u5ffd\u7565\u3002
\n \u7b80\u5355\u6765\u8bf4\uff0c\u5c31\u662f\u5728\u8d1f\u6781\u4e0a\u53d1\u751f\u7684\u8fd9\u4e2a\u53cd\u5e94\uff1a<\/p>\n

\"\"<\/p>\n

\u4e2d\u7684\"\"\u5bfc\u81f4\u7684\uff0c\u6362\u53e5\u8bdd\u8bf4\u5c31\u662f\uff0c\u77f3\u58a8\u4e2d\u6240\u5d4c\u5165\u7684\u9502\u7684\u542b\u91cf\u8d85\u8fc7\u4e86\u5b83\u6240\u627f\u53d7\u7684\u8303\u56f4<\/strong>\uff0c\u90a3\u4e48\u591a\u4f59\u7684\u9502\u79bb\u5b50\u5c31\u4f1a\u548c\u8d1f\u6781\u4e2d\u7a7f\u68ad\u800c\u6765\u7684\u7535\u5b50\u7ed3\u5408\uff0c\u5728\u8d1f\u6781\u8868\u9762\u4e0a\u5f00\u59cb\u6c89\u79ef\uff08<\/strong>deposition<\/strong>\uff09\u3002<\/strong>
\n \u800c\u5bf9\u4e8e\u8981\u5f62\u6210\u9502\u679d\u6676\uff0c\u4e00\u4e2a\u5fc5\u8981\u7684\u6761\u4ef6\u5c31\u662f\uff0c\u8d1f\u6781\u7684\u8868\u9762\u662f\u4e0d\u5e73\u6574<\/strong>\u7684\uff08roughness\uff09\uff0c\u8fd9\u6837\u5c31\u4f1a\u7ed9\u9502\u679d\u6676\u7684\u5f62\u6210\u63d0\u4f9b\u4ea7\u6240\u548c\u4fbf\u5229\u3002
\n \u4e0b\u9762\u662f\u9898\u4e3b\u7684\u95ee\u9898\uff1a
\n \u9502\u79bb\u5b50\u5d4c\u5165\u77f3\u58a8\u4e4b\u540e\u7684\u5316\u5b66\u53cd\u5e94\u5728\u54ea\u91cc\u53d1\u751f\uff1f<\/strong>
\n \u6211\u627e\u4e86\u51e0\u7bc7\u6587\u732e\uff0c\u5bf9\u7535\u6781\u4f7f\u7528\u7684\u662f\u9502\u7247\uff0c\u867d\u7136\u77f3\u58a8\u548c\u9502\u7247\u7684\u8868\u9762\u5149\u6ed1\u5ea6\u4e0d\u540c\uff0c\u4f46\u662f\u8fd9\u4e2a\u4e0d\u5f71\u54cd\u53cd\u5e94\u53d1\u751f\u7684\u5730\u70b9\u6216\u8005\u8bf4\u754c\u9762\uff1a<\/p>\n

\"\" \"\"\u00a0\u56fe\u7247\u6458\u81eaLithium metal anodes for rechargeable batteries – Energy & Environmental Science (RSC Publishing)<\/a>
\n \u53ef\u4ee5\u770b\u5230\u8fd9\u65f6\u5019\u7684\u9502\u662f\u6c89\u79ef\u5728\u9694\u819c\u548c\u8d1f\u6781\u7684\u63a5\u89e6\u90e8\u4f4d<\/strong>\uff0c\u4f46\u662f\u751f\u957f\u7684\u65b9\u5411\u662f\u6cbf\u7740\u4ece\u8d1f\u6781\u2192\u9694\u819c\u7684\u8d70\u5411\uff0c\u56e0\u6b64\u53cd\u5e94\u53d1\u751f\u7684\u5730\u70b9\u662f\u5728\u8d1f\u6781\u4e0e\u7535\u89e3\u6db2\u7684\u754c\u9762<\/strong>\u4e0a\u3002
\n \u4ece\u4e0b\u56fe\u4e5f\u53ef\u4ee5\u6e05\u6670\u7684\u770b\u51fa\u6765\uff1a
\n \"\"\u56fe\u7247\u6458\u81eaEvolution of dendrite growth. : Detection of subsurface structures underneath dendrites formed on cycled lithium metal electrodes : Nature Materials : Nature Publishing Group<\/a>
\n \u679d\u6676\u7684\u751f\u957f\u65b9\u5411\u662f\u4e0d\u65ad\u4ece\uff08\u7535\u89e3\u6db2\/<\/strong>\u7535\u6781\uff09\u754c\u9762\u5411\u6b63\u6781\u5ef6\u5c55\u3002<\/strong>
\n \u5982\u679c\u79bb\u5b50\u5728\u754c\u9762\u53d1\u751f\u5316\u5b66\u53cd\u5e94\uff0c\u90a3\u662f\u5426\u53ef\u4ee5\u8ba4\u4e3a\u9502\u79bb\u5b50\u5df2\u8f6c\u5316\u4e3a\u539f\u5b50\u5f62\u6001\uff0c\u4e4b\u540e\u5411\u56fa\u76f8\u672c\u4f53\u5185\u6269\u6563\uff1f<\/strong>
\n \u8fd9\u4e2a\u95ee\u9898\u6211\u5c31\u4e0d\u732e\u4e11\u4e86\uff0c\u5efa\u8bae\u5927\u5bb6\u53bb\u770bzola rao<\/a>\u7684\u90a3\u4e2a\u7b54\u6848\uff0c\u4ed6\u7684\u8bba\u8ff0\u6bd4\u8f83\u7cfb\u7edf\u3002
\n \u9502\u679d\u6676\u5f62\u6210\u7684\u6839\u672c\u539f\u56e0\u662f\u5426\u5728\u4e8e\u539f\u5b50\u5f62\u6001\u7684\u9502\u6765\u4e0d\u53ca\u5f80\u56fa\u76f8\u672c\u4f53\u6269\u6563\uff1f<\/strong>
\n \u9502\u679d\u6676\u7684\u5f62\u6210\u539f\u56e0\u53ef\u4ee5\u4ece\u70ed\u529b\u5b66\u89d2\u5ea6\u5206\u6790\uff0c\u4e3a\u4e86\u628a\u95ee\u9898\u7b80\u5316\uff0c\u628a\u6a21\u578b\u964d\u683c\u5230\u9502\u6c89\u79ef\u7684\u6761\u4ef6<\/strong>\u4e0b\u8fdb\u884c\u5206\u6790\uff1a<\/p>\n

\"\"<\/p>\n

\u56fe\u7247\u6458\u81eaHeterogeneous Nucleation and Growth of Lithium Electrodeposits on Negative Electrodes<\/a>
\n \u8fd9\u662f\u4e00\u4e2a\u5e3d\u72b6\u7684\u5c0f\u6676\u6838N\u5728\u77f3\u58a8\uff08\u8f83\u4e3a\u5e73\u6ed1\u7684\uff09\u57fa\u5e95S\u4e0a\u6c89\u79ef\u7684\u60c5\u5f62\uff0cE\u4ee3\u8868\u7535\u89e3\u8d28\u3002
\n \u5176\u4e2d\uff0c\u03b8<\/strong>\u662f\u63a5\u89e6\u89d2<\/strong>\uff0cr<\/strong>\u662f\u66f2\u7387\u534a\u5f84<\/strong>\uff0ca<\/strong>\u662f\u63a5\u89e6\u9762\u7684\u534a\u5f84<\/strong>\uff08a <\/em>= r <\/em>sin \u03b8\uff09\uff0ch<\/strong>\u662f\u7535\u6c89\u79ef\u7269\u8d28\u7684\u9ad8\u5ea6<\/strong>[ h <\/em>= r<\/em>(1\u2212 cos \u03b8) ]\uff0c\u6676\u6838N<\/strong>\u7684\u4f53\u79ef<\/strong>\u4e3a<\/p>\n

\"\"<\/p>\n

\u5176\u4e2d\uff0c\"\"<\/p>\n

\u6676\u6838N<\/strong>\u7684\u8868\u9762\u79ef<\/strong>\u4e3a<\/p>\n

\"\"<\/p>\n

\u5176\u4e2d\uff0c\"\"<\/p>\n

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\"\"
\n \u5176\u4e2d\uff0c \"\"\u662f\u6469\u5c14\u4f53\u79ef\u8f6c\u5316\u81ea\u7531\u80fd<\/strong>\uff0c
\n \"\"\u662f\u6676\u6838<\/strong>N<\/strong>\u4e0e\u7535\u89e3\u8d28E<\/strong>\u95f4\u7684\u754c\u9762\u81ea\u7531\u80fd<\/strong>\uff0c
\n \"\"\u662f\u77f3\u58a8\u57fa\u5e95<\/strong>S<\/strong>\u4e0e\u6676\u6838N<\/strong>\u95f4\u7684\u754c\u9762\u81ea\u7531\u80fd<\/strong>\uff0c
\n \"\"\u662f\u77f3\u58a8\u57fa\u5e95<\/strong>S<\/strong>\u4e0e\u7535\u89e3\u8d28E<\/strong>\u95f4\u7684\u754c\u9762\u81ea\u7531\u80fd<\/strong>\uff0c
\n \u53e6\u5916\uff0cz<\/em>\u662f\u6c89\u79ef\u79bb\u5b50\u7684\u4ef7\u6001<\/strong>\uff0cF\u662f\u6cd5\u62c9\u7b2c\u5e38\u6570<\/strong>\uff0c\u03a9\u662f\u6469\u5c14\u4f53\u79ef<\/strong>\uff0c\u03b7\u662f\u8fc7\u7535\u52bf\u3002<\/strong>
\n \u5f15\u5165\u03b3<\/strong>\u8fd9\u4e2a\u8868\u9762\u5f20\u529b<\/strong>\u540e\uff0c\u5c06\u7c98\u9644\u529b\u5ffd\u7565\u4e0d\u8ba1\uff0c\u53ef\u4ee5\u7b80\u5316\u603b\u5409\u5e03\u65af\u81ea\u7531\u80fd\uff1a<\/p>\n

\"\"
\n \u8fd9\u662f\u4e00\u4e2a\u5bf9r\uff08\u66f2\u7387\u534a\u5f84\uff09\u7684\u51fd\u6570\uff0c\u4ee4\"\"\uff0c\u4e8e\u662f\u53ef\u4ee5\u5f97\u5230\u5f62\u6210\u7a33\u5b9a\u6c89\u79ef\u7269\u7684\u4e34\u754c\u534a\u5f84<\/strong>\uff1a<\/p>\n

\"\"<\/p>\n

\u628a\u4e34\u754c\u534a\u5f84\uff08\u5f0f\u5b503\uff09\u5e26\u5165\u603b\u8f6c\u5316\u5409\u5e03\u65af\u81ea\u7531\u80fd\uff0c\u53ef\u4ee5\u5f97\u5230\u5f62\u6210\u5f02\u8d28\u6c89\u79ef\u7269\u7684\u4e34\u754c\u5409\u5e03\u65af\u81ea\u7531\u80fd<\/strong>\uff1a<\/p>\n

\"\"<\/p>\n

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\n \u5c06\u4e34\u754c\u8fc7\u7535\u4f4d\"\"<\/strong>\u4e0e\u4e0d\u540c\u63a5\u89e6\u89d2\u5728\u4e0d\u540c\u7684\u4e34\u754c\u5409\u5e03\u65af\u81ea\u7531\u80fd\u4e0b\u4f5c\u56fe\uff1a<\/p>\n

\"\"\u56fe\u7247\u6458\u81eaHeterogeneous Nucleation and Growth of Lithium Electrodeposits on Negative Electrodes<\/a><\/p>\n

\u4ece\u4e0a\u9762\u8fd9\u5f20\u56fe\u53ef\u4ee5\u770b\u51fa\uff0c\u5f53\u63a5\u89e6\u89d2\u8d8a\u5c0f\uff0c\u4f53\u76f8\u5409\u5e03\u65af\u81ea\u7531\u80fd\u8d8a\u5927\uff0c\u6240\u9700\u8981\u7684\u4e34\u754c\u8fc7\u7535\u52bf\u5c31\u8d8a\u5c0f\uff0c\u6362\u8a00\u4e4b\uff0c\u6c89\u79ef\u7684\u8fc7\u7a0b\u5c31\u8d8a\u5bb9\u6613\u8fdb\u884c\u3002<\/u><\/strong>
\n \u8fd9\u4e5f\u662f\u4e3a\u4ec0\u4e48\u5728\u7c97\u7cd9\u7684\u754c\u9762\u4e0a\u6bd4\u8f83\u5bb9\u6613\u5f62\u6210\u9502\u679d\u6676\u7684\u539f\u56e0\u6240\u5728\u3002<\/u><\/strong><\/p>\n

\u5bf9\u4e8e\u77f3\u58a8<\/strong>\u800c\u8a00\uff0c\u5728\u4e0d\u540c\u5145\u7535\u6df1\u5ea6\u4e0a\uff0c\u9502\u79bb\u5b50\u7684\u6d53\u5ea6\u5206\u5e03\u5341\u5206\u4e0d\u5747\u5300<\/strong>\uff0c\u8fd9\u4e5f\u4e3a\u9502\u679d\u6676\u7684\u6210\u957f\u63d0\u4f9b\u4e86\u53ef\u80fd\uff1a<\/p>\n

\"\"\u539f\u56fe\u6458\u81eahttp:\/\/lithiumbatteryresearch.com\/pdf\/2012-Shenoy-Shrinking-Core.pdf<\/a>
\n \u5bf9\u4e8e\u9898\u4e3b\u6240\u95ee\u7684\u9502\u679d\u6676\u662f\u5982\u4f55\u5f62\u6210\u7684\uff0c\u8fd9\u4e2a\u6d89\u53ca\u5230\u6210\u6838\u52a8\u529b\u5b66\u65b9\u9762\u7684\u77e5\u8bc6\uff0c\u800c\u5728\u8fd9\u65b9\u9762J.Newman\u7edd\u5bf9\u662f\u5927\u725b\uff0c\u4ed6\u5efa\u7acb\u7684\u8fd9\u4e2a\u6a21\u578b\u4e5f\u88ab\u4eba\u8ba4\u53ef\uff1a\uff08\u867d\u7136\u4e0d\u5b8c\u5584\uff09<\/p>\n

\"\"\u56fe\u7247\u6458\u81eaDendrite Growth in Lithium\/Polymer Systems<\/a>
\n \u4ed6\u4eec\u901a\u8fc7\u8ba1\u7b97\u548c\u62df\u5408\uff0c\u8ba4\u4e3a\u9502\u679d\u6676\u7684\u9488\u5c16\u751f\u957f\u901f\u5ea6\u4e0e\u7535\u6d41\u5bc6\u5ea6\u76f4\u63a5\u76f8\u5173\uff1a<\/p>\n

\"\"\u6240\u4ee5\uff0c\u5982\u679c\u964d\u4f4e\u7535\u6d41\u5bc6\u5ea6\uff0c\u53ef\u4ee5\u518d\u4e00\u5b9a\u7a0b\u5ea6\u4e0a\u5ef6\u7f13\u5176\u589e\u957f\u7684\u901f\u5ea6<\/strong>\uff1a<\/p>\n

\"\"\u56fe\u7247\u6458\u81eaDendrite Growth in Lithium\/Polymer Systems<\/a>
\n \u8fd8\u6709\u5176\u4ed6\u5b66\u8005\u63d0\u51fa\u7684\u6a21\u578b<\/strong>\uff0c\u8fd9\u91cc\u5c31\u4e0d\u4e00\u4e00\u8bba\u8ff0\u4e86\uff0c\u8fd9\u7bc7\u7efc\u8ff0\u91cc\u9762\u6709\u4ecb\u7ecd\uff1a
\n Lithium metal anodes for rechargeable batteries – Energy & Environmental Science (RSC Publishing)<\/a>
\n \u5927\u5bb6\u6709\u5174\u8da3\u7684\u8bdd\u53ef\u4ee5\u53bb\u9010\u4e2a\u5b66\u4e60\u3002
\n \u4f5c\u4e3a\u5f71\u54cd\u679d\u6676\u751f\u957f\u7684\u56e0\u7d20\uff0czola rao<\/a>\u63d0\u5230\u7684\u90a3\u7bc7\u6587\u732e\u4e2d\u7684SEI\u819c\u3001\u7535\u89e3\u6db2\u4e2d\u6eb6\u5242\u7684\u79cd\u7c7b\uff08\u4e4b\u524dPC\u5c31\u6bd4\u8f83\u5bb9\u6613\u8ba9\u679d\u6676\u5bcc\u96c6\u8d1f\u6781\u754c\u9762\uff0c\u800c\u540e\u6765\u7684\u94fe\u578b\u916f\u7c7b\u5c31\u4f1a\u4e0d\u4e00\u6837\uff09\u548c\u6eb6\u8d28\u7684\u6d53\u5ea6\u3001\u7535\u6d41\u5bc6\u5ea6\u7684\u5927\u5c0f\u3001\u6b63\u8d1f\u6781\u4e4b\u95f4\u7684\u6709\u6548\u8ddd\u79bb\u7b49\u7b49\u5404\u81ea\u5360\u6709\u4e0d\u540c\u7684\u6bd4\u91cd\uff0c\u7136\u800c\u8fd9\u6bd5\u7adf\u662f\u5de5\u7a0b\u7c7b\u7684\u95ee\u9898\uff0c\u4e0d\u662f\u5411\u89e3\u4e00\u4e2a\u65b9\u7a0b\u5217\u51fa\u6761\u4ef6\u5c31\u80fd\u5f97\u5230\u7ed3\u679c\u7684\u3002
\n \u4e0d\u8fc7\u5bf9\u4e8e\u5982\u4f55\u6291\u5236\u679d\u6676\u7684\u751f\u957f\uff0c\u8fd9\u4e2a\u5927\u90e8\u5206\u7684\u6587\u732e\u90fd\u63d0\u5230\u4e86\u4ee5\u4e0b\u56db\u70b9\uff1a
\n 1\uff09manipulating the surface roughness ofthe anode electrode surface\uff08\u8c03\u63a7\u8d1f\u6781\u8868\u9762\u7684\u7c97\u7cd9\u5ea6\uff0c\u4f8b\u5982\u5305\u8986\uff1f\uff09
\n 2\uff09engineering the anode particle size below the critical thermodynamic radius \uff08\u8d1f\u6781\u9897\u7c92\u7684\u5c3a\u5bf8\u6700\u597d\u5c0f\u4e8e\u4e34\u8857\u7684\u52a8\u529b\u5b66\u66f2\u7387\u534a\u5f84\uff09
\n 3\uff09 limiting the plating potential below the critical value, and a cycling frequency that is below the characteristic incubation frequency \uff08\u7535\u9540\u7535\u4f4d\u7684\u9009\u62e9\u6700\u597d\u4f4e\u4e8e\u4e34\u754c\u503c\uff0c\u53e6\u5916\u5bf9\u4e8e\u4f20\u7edf\u7684\u5145\u653e\u7535\u673a\u5236\u53ef\u4ee5\u8fdb\u884c\u6539\u5584\uff0c\u6bd4\u5982\u53ef\u4ee5\u8003\u8651\u4f7f\u7528\u8109\u51b2\u65b9\u5f0f\uff09
\n 4\uff09controlling the wetting properties of the electrodeposits \uff08\u7535\u6c89\u79ef\u6da6\u6e7f\u6027\u7684\u8c03\u63a7\uff09
\n \u53e6\u5916\uff0c\u5de5\u4e1a\u4e0a\u4e5f\u5e38\u4f7f\u7528Overhang\u7684\u65b9\u6cd5\u6765\u51cf\u5c11\u9502\u7684\u6c89\u79ef\uff0c\u5c31\u662f\u5c06\u8d1f\u6781\u505a\u7684\u6bd4\u6b63\u6781\u5927\u4e00\u4e9b\uff0c\u5c31\u50cf\u7b2c\u4e00\u5f20\u56fe\u4e2dJeff\u753b\u7684\u90a3\u6837\uff08\u7b2c\u4e00\u5f20\u56fe\u4e2d\u53f3\u4e0b\u89d2\uff09\u3002\u540c\u65f6\uff0c\u5728\u9009\u62e9cell\u7535\u4f4d\u8303\u56f4\u7684\u65f6\u5019\uff0c\u8981\u5c3d\u91cf\u907f\u514d\u591a\u4f59\u7684\u77f3\u58a8\u5bb9\u91cf\uff0c\u4ee5\u514d\u9020\u6210\u7ed9\u77f3\u58a8\u5e26\u53bb\u591a\u4f59\u7684\u9502\u91cf\u3002
\n \u53c2\u8003\u6587\u732e\uff1a
\n 1.Lithium metal anodes for rechargeable batteries – Energy & Environmental Science (RSC Publishing)<\/a>
\n 2.Heterogeneous Nucleation and Growth of Lithium Electrodeposits on Negative Electrodes<\/a>
\n 3.Dendrite Growth in Lithium\/Polymer Systems<\/a>
\n 4.Evolution of dendrite growth. : Detection of subsurface structures underneath dendrites formed on cycled lithium metal electrodes : Nature Materials : Nature Publishing Group<\/a>
\n 5.In situ study of dendritic growth inlithium\/PEO-salt\/lithium cells<\/a>
\n 6.In situ NMR observation of the formation of metallic lithium microstructures in lithium batteries : Nature Materials : Nature Publishing Group<\/a>
\n 7.Direct In Situ Observation and Numerical Simulations of Non-Shrinking-Core Behavior in an MCMB Graphite Composite Electrode<\/a>;159\/9\/A1501<\/p>\n

\u4f5c\u8005\uff1a\u571f\u8c46\u6ce5<\/strong>
\n \u94fe\u63a5\uff1ahttps:\/\/www.zhihu.com\/question\/39111731\/answer\/80330803<\/a><\/strong><\/p>\n

\u8fd9\u786e\u5b9e\u662f\u4e2a\u5f88\u597d\u5f88\u597d\u7684\u95ee\u9898\uff0c\u6211\u7814\u7a76\u9502\u7535\u6c60\u53ef\u80fd\u6ca1\u6709\u4ee5\u4e0a\u8bf8\u4f4d\u90a3\u4e48\u6df1\u5165\uff0c\u518d\u52a0\u4e0a\u6700\u8fd1\u5728\u4fee\u6539\u6587\u7ae0\u62bd\u4e86\u8fd9\u51e0\u5929\u7684\u7a7a\u9699\u6765\u627e\u627e\u8d44\u6599\u7b54\u7b54\u9898\u3002
\n \u5c31\u6211\u7684\u89c1\u89e3\uff0c\u6765\u8bf4\u8bf4\u7684\u6211\u7684\u770b\u6cd5\uff08\u770b\u5230JEFF\u5927\u795e\u6211\u90fd\u8dea\u4e0b\u4e86\u6709\u6728\u6709\uff09\u3002\u8fd9\u91cc\u5c06\u9898\u4e3b\u7684\u95ee\u9898\u5206\u6210\u4e24\u4e2a\u90e8\u5206
\n \u9502\u79bb\u5b50\u7535\u6c60\u5145\u7535\u65f6\uff0c\u79bb\u5b50\u5d4c\u5165\u77f3\u58a8\u8d1f\u6781\u7684\u5f62\u6001\u662f\u4ec0\u4e48\uff0c\u5982\u679c\u50cf\u8bb8\u591a\u4eba\u8ba4\u4e3a\u7684\u90a3\u6837\uff0c\u9502\u79bb\u5b50\u5d4c\u5165\u77f3\u58a8\u4e4b\u540e\u4ecd\u7136\u4ee5\u79bb\u5b50\u5f62\u6001\u5b58\u5728\uff0c\u90a3\u5316\u5b66\u53cd\u5e94\u5728\u54ea\u91cc\u53d1\u751f\uff1f\u5982\u679c\u79bb\u5b50\u5728\u754c\u9762\u53d1\u751f\u5316\u5b66\u53cd\u5e94\uff0c\u90a3\u662f\u5426\u53ef\u4ee5\u8ba4\u4e3a\u9502\u79bb\u5b50\u5df2\u8f6c\u5316\u4e3a\u539f\u5b50\u5f62\u6001\uff0c\u4e4b\u540e\u5411\u56fa\u76f8\u672c\u4f53\u5185\u6269\u6563\uff1f<\/strong>
\n \"\"\u5728\u7ed9\u7535\u6c60\u5145\u7535\u7684\u8fc7\u7a0b\u4e2d\uff0c\u5916\u754c\u7ed9\u4e88\u5916\u754c\u4e00\u4e2a\u7535\u538b\uff0c\u4f7f\u5f97\u6b63\u6781\u6750\u6599\u5185\u90e8\u7684\u9502\u79bb\u5b50\u5f97\u4ee5\u8131\u51fa\u8fdb\u5165\u7535\u89e3\u6db2\u4ecb\u8d28\u4e2d\uff0c\u540c\u6837\u7535\u89e3\u6db2\u4e2d\u7684\u9502\u79bb\u5b50\u4f1a\u5728\u5916\u754c\u7535\u538b\u5dee\u7684\u6761\u4ef6\u4e0b\u5411\u78b3\u5c42\u79fb\u52a8\uff0c\u7531\u4e8e\u77f3\u58a8\u662f\u5177\u6709\u5c42\u72b6\u901a\u9053\u7684\uff0c\u9502\u4fbf\u4f1a\u8fdb\u5165\u901a\u9053\u4e0e\u78b3\u5f62\u6210\u78b3\u9502\u5316\u5408\u7269\uff0c\u5f62\u6210LiCx\uff08x=1~6\uff09\u8fd9\u7c7b\u77f3\u58a8\u5c42\u95f4\u5316\u5408\u7269<\/strong>*<\/strong>\uff0c<\/strong>\u800c\u540e\u5728\u77f3\u58a8\u4e2d\u8fdb\u884c\u56fa\u76f8\u4f20\u8f93\u3002\u6240\u4ee5\uff0c\u53ef\u4ee5\u8ba4\u4e3a\u5316\u5b66\u53cd\u5e94\u53d1\u751f\u5728<\/strong>Li+<\/strong>\u4e0e\u77f3\u58a8\u7684\u5316\u5b66\u53cd\u5e94\u5728\u7535\u89e3\u6db2\u4e0e\u77f3\u58a8\u7684\u754c\u9762\u5904\uff08SEI<\/strong>\u819c\u5185\u8fd8\u662f\u819c\u5916\u5c31\u73b0\u9636\u6bb5\u5c31\u6211\u4e86\u89e3\u8fd8\u662f\u5b58\u7591\u7684\uff0c\u56e0\u6b64\u5927\u90e8\u5206\u6587\u732e\u4e2d\u7528\u7684\u662f<\/em>lithium<\/em><\/strong>\u800c\u4e0d\u662flithium ion<\/em><\/strong>\uff0c\u53ef\u4ee5\u53c2\u8003\u4e0b\u9762\u6587\u732e\u4e2d\u9502\u79bb\u5b50\u5728SEI<\/strong>\u819c\u5185\u8fd8\u662f\u819c\u5916\u90fd\u6709\uff09<\/strong>
\n \uff0c\u53ef\u4ee5\u53c2\u8003\uff1a<\/strong>
\n \u9502\u7535\u6c60\u57fa\u7840\u79d1\u5b66\u95ee\u9898(\u2165)\u2014\u2014\u79bb\u5b50\u5728\u56fa\u4f53\u4e2d\u7684\u8f93\u8fd0<\/a><\/p>\n

\u5728\u9502\u79bb\u5b50\u7535\u6c60\u4e2d\uff0c\u79bb\u5b50\u53ef\u4ee5\u4ece\u5916\u90e8\u8fdb\u5165\u3002\u56e0\u6b64\u5b58\u5728\u4e00\u4e2a\u95ee\u9898\uff0c\u79bb\u5b50\u662f\u5982\u4f55\u7a7f\u8fc7\u56fa\u4f53\u7684\uff0c\u662f\u901a\u8fc7\u8fde
\n \u7eed\u7684\u95f4\u9699\u4f4d\u6216\u7a7a\u4f4d\u4ece\u4e00\u4fa7\u4f20\u8f93\u5230\u53e6\u4e00\u4fa7\uff0c\u8fd8\u662f\u901a\u8fc7\u4e0e\u6676\u683c\u5185\u9502\u79bb\u5b50\u7684\u4ea4\u6362\u4f20\u8f93\uff0c\u9700\u8981\u8fdb\u4e00\u6b65\u6f84\u6e05\u3002\u4e0d\u540c\u7684\u4f20\u8f93\u65b9\u5f0f\uff0c\u4e0e\u56fa\u4f53\u7684\u5fae\u89c2\u7f3a\u9677\u7ed3\u6784\u6709\u5173\u3002\u5728\u8ba8\u8bba\u5177\u4f53\u7684\u6269\u6563\u673a\u5236\u4e2d\uff0c\u51c6\u786e\u5224\u65ad\u5230\u5e95\u662f\u91c7\u7528\u54ea\u79cd\u6269\u6563\u673a\u5236\u5e76\u4e0d\u5bb9\u6613\u3002<\/p>\n

\u8fd9\u91cc\u6709\u4e24\u7bc7\u5f88\u6709\u610f\u601d\u7684\u6587\u732e\u4f9b\u4f60\u53c2\u8003\uff0cLithium Diffusion in Graphitic Carbon<\/a>\u548cDiffusion Mechanism of Lithium Ion through Basal Plane of Layered Graphene<\/a>\u505a\u7684\u7814\u7a76Li+\u5728\u56fa\u76f8\u95f4\u7684\u4f20\u8f93\uff0c\u5927\u4f53\u4e0a\u8bf4\u5bf9\u4e8e\u591a\u5c42\u77f3\u58a8\uff0c<\/strong>Li+<\/strong>\u4e3b\u8981\u662f\u5728\u77f3\u58a8\u5fae\u6676\u7684\u6676\u754c\u4e0a\u4f20\u8f93\uff0c\u800c\u77f3\u58a8\u7684\u201c<\/strong>\u9636\u7ed3\u6784\u201d<\/strong>\u548c\u7f3a\u9677\u4e4b\u95f4\u7684\u4f20\u8f93\u51e0\u4e4e\u53ef\u4ee5\u5ffd\u7565\u3002\u800c\u5bf9\u4e8e\u5355\u5c42\u6216\u51e0\u5c42\u7684\u77f3\u58a8\u70ef\uff0c\u77f3\u58a8\u70ef\u4e4b\u95f4\u7684\u7f3a\u9677\u548c\u77f3\u58a8\u70ef\u5185\u90e8\u7684\u7f3a\u9677\u662f\u5176\u4e3b\u8981\u7684\u4f20\u8f93\u65b9\u5f0f\u3002<\/strong>
\n \u6240\u4ee5\uff0c\u4e0d\u80fd\u5355\u7eaf\u7684\u8ba4\u4e3a\u9502\u79bb\u5b50\u8f6c\u53d8\u4e3a\u539f\u5b50\u5f62\u6001\uff0c\u5176\u5728\u5185\u90e8\u6269\u6563\u65b9\u5f0f\u9502\u5728\u56fa\u76f8\u4e2d\u7684\u6269\u6563\u8fc7\u7a0b\uff08\u5d4c\u5165\/<\/em><\/strong>\u8131\u5d4c\u3001\u5408\u91d1\u5316\/<\/em><\/strong>\u53bb\u5408\u91d1\u5316\uff09\u662f\u5f88\u590d\u6742\u7684\uff0c\u65e2\u6709\u79bb\u5b50\u6676\u4f53\u4e2d\u201c<\/em><\/strong>\u6362\u4f4d\u673a\u5236\u201d<\/em><\/strong>\u7684\u6269\u6563\uff0c\u4e5f\u6709\u6d53\u5ea6\u68af\u5ea6\u5f71\u54cd\u7684\u6269\u6563\uff0c\u8fd8\u5305\u62ec\u5316\u5b66\u52bf\u5f71\u54cd\u7684\u6269\u6563\u3002<\/em><\/strong>
\n *\u6ce8\uff1a\u77f3\u58a8\u5c42\u95f4\u5316\u5408\u7269(\u7b80\u79f0GICs)\u662f\u4e00\u79cd\u5229\u7528\u7269\u7406\u6216\u5316\u5b66\u7684\u65b9\u6cd5\u4f7f\u975e\u70ad\u8d28\u53cd\u5e94\u7269\u63d2\u5165\u77f3\u58a8\u5c42\u95f4\uff0c\u4e0e\u70ad\u7d20\u7684\u516d\u89d2\u7f51\u7edc\u5e73\u9762\u7ed3\u5408\u7684\u540c\u65f6\u53c8\u4fdd\u6301\u4e86\u77f3\u58a8\u5c42\u72b6\u7ed3\u6784\u7684\u6676\u4f53\u5316\u5408\u7269\u3002
\n \u9502\u679d\u6676\u5982\u4f55\u5f62\u6210\uff1f\u9502\u679d\u6676\u5f62\u6210\u7684\u6839\u672c\u539f\u56e0\u662f\u5426\u5728\u4e8e\u539f\u5b50\u5f62\u6001\u7684\u9502\u6765\u4e0d\u53ca\u5f80\u56fa\u76f8\u672c\u4f53\u6269\u6563\uff1f<\/strong>
\n \u53ef\u80fd\u8fd9\u91cc\u4f1a\u6709\u7591\u95ee\uff0c\u5982\u679c\u6ca1\u6709\u9502\u539f\u5b50\uff0c\u600e\u4e48\u5f62\u6210\u7684\u679d\u6676\uff1f
\n \u679d\u6676\u751f\u957f\u7684\u6a21\u578b\u6709\u5f88\u591a\uff0c\u5230\u73b0\u5728\u4e3a\u6b62\u5e76\u6ca1\u6709\u7edf\u4e00\u7684\u7b54\u6848\uff0c\u5148\u8bf4\u8bf4\u9898\u4e3b\u8bf4\u7684\u8d1f\u6781\u3002
\n \u4e00\u4e2a\u5f88\u91cd\u8981\u7684\u5f71\u54cd\u56e0\u7d20\u5c31\u662f\u79bb\u5b50\u6d53\u5ea6\u68af\u5ea6\u3002\u7535\u89e3\u6db2\u5728\u5145\u653e\u7535\u7684\u8fc7\u7a0b\u53ea\u662f\u8d77\u5230\u4e00\u4e2a\u4f20\u9012Li+\u7684\u4f5c\u7528\uff0c\u4e00\u4e2a\u5b8c\u6574\u7684\u7535\u5316\u5b66\u53cd\u5e94\uff0c\u6b63\u6781\u8131\u51fa\u4e00\u4e2a\u9502\u79bb\u5b50\uff0c\u540c\u65f6\u91ca\u653e\u4e00\u4e2a\u7535\u5b50\uff0c\u5230\u8d1f\u6781\u80af\u5b9a\u662f\u6d88\u8017\u4e00\u4e2a\u9502\u79bb\u5b50\uff0c\u540c\u65f6\u5438\u6536\u4e00\u4e2a\u7535\u5b50\u3002H.J.S. Sand\u8ba4\u4e3a\u5728\u8fd9\u79cd\u60c5\u51b5\u4e0b\u79bb\u5b50\u7684\u6d53\u5ea6\u5728\u8d1f\u6781\u8868\u9762\u51cf\u5c11\uff0c\u800c\u5728\u6b63\u6781\u8868\u9762\u589e\u52a0\u3002\u5728\u7535\u6d41\u5bc6\u5ea6\u5927\u7684\u7a00\u6eb6\u6db2\u4e2d\uff0c\u79bb\u5b50\u6d53\u5ea6\u4f1a\u53d8\u4e3a0\uff0c\u5bfc\u81f4\u7535\u8377\u8f6c\u79fb\u63a7\u5236\u8fc7\u7a0b\u8f6c\u6362\u4e3a\u4f20\u8d28\u63a7\u5236\u8fc7\u7a0b\uff0c \u6b64\u8fc7\u7a0b\u6210\u4e3aSand\u2019s behavior\uff0c\u800c\u79bb\u5b50\u6d53\u5ea6\u53d8\u4e3a0\u7684\u65f6\u95f4\u79f0\u4e3aSand’s time[III. On the concentration at the electrodes in a solution, with special reference to the liberation of hydrogen by electrolysis of a mixture of copper sulphate and sulphuric acid<\/a>]\uff0cDespi c\u548cPopov\u7b49\u4eba\u8bc1\u5b9e\u4e86\u79bb\u5b50\u6d53\u5dee\u6781\u5316\u5bf9\u679d\u6676\u751f\u957f\u7684\u5f71\u54cd[http:\/\/link.springer.com\/chapter\/10.1007\/978-1-4684-3003-5_4<\/a>]\u3002\u5728\u6b64\u57fa\u7840\u4e0aFleury et al.\u548cChazalviel\u5efa\u7acb\u6a21\u578b\u8868\u660e\u5f53\u79bb\u5b50\u6d53\u5ea6\u964d\u4f4e\u52300\u65f6\uff0c\u8d1f\u6781\u5c06\u5f62\u6210\u5c40\u90e8\u7a7a\u95f4\u7535\u8377\uff0c\u5e76\u5f62\u6210\u679d\u6676\u7ed3\u6784\uff0c\u679d\u6676\u7ed3\u6784\u751f\u957f\u901f\u5ea6\u548c\u7535\u89e3\u6db2\u4e2d\u79bb\u5b50\u504f\u79fb\u901f\u7387\u76f8\u540c\u3002[The role of the anions in the growth speed of fractal electrodeposits<\/a>,Phys. Rev. A 42, 7355 (1990)<\/a>]Brissot\u539f\u4f4d\u7814\u7a76lithium\/PEOeLiTFSI\/lithium\u7535\u6c60\u8bc1\u5b9e\u9502\u679d\u6676\u751f\u957f\u901f\u7387\u63a5\u8fd1\u4e8eChazalviel\u7684\u6a21\u578b\uff0c\u8be5\u901f\u7387\u4ec5\u548cLi\u8fc1\u79fb\u7387\u548c\u7535\u573a\u5f3a\u5ea6\u6709\u5173\uff0c\u4f46\u662f\u4ed6\u8fd8\u8bf4\u660eChazalviel\u9700\u8981\u8fdb\u4e00\u6b65\u8003\u8651Li+\u8fc1\u79fb\u548c\u6269\u6563\u7684\u901f\u7387\u53d8\u5316\uff0c\u5728\u5b9e\u9a8c\u89c2\u5bdf\u8fc7\u7a0b\u4e2d\uff0c\u5faa\u73af\u8fc7\u7a0b\u65f6\u4f1a\u53d1\u73b0\u9502\u679d\u6676\u88ab\u4e00\u4e9b\u201c\u963b\u788d\u201d\u6291\u5236\uff0c\u540c\u65f6\uff0c\u7535\u89e3\u6db2\u7684\u6d41\u52a8\u4e5f\u4f1a\u963b\u788d\u9502\u679d\u6676\u7684\u5f62\u6210\u3002[In situ study of dendritic growth inlithium\/PEO-salt\/lithium cells<\/a>]<\/p>\n

\"\"Rosso et al.\u53d1\u73b0\u77ed\u8def\u65f6\u95f4\uff08\u5373\u9502\u679d\u6676\u7684\u751f\u957f\uff09\u65f6\u95f4\u63a5\u8fd1Sand\u2019s time\uff0c\u800cSand\u2019s behavior\u6ca1\u6709\u51fa\u73b0\u3002\u56e0\u6b64\uff0c\u4ed6\u4eec\u4fee\u6b63\u4e86\u8be5\u6a21\u578b\uff0c\u9610\u660e\u5e73\u884c\u4e8e\u7535\u6781\u6750\u6599\u7684\u79bb\u5b50\u6d53\u5ea6\u5206\u5e03\u5e76\u4e0d\u7a33\u5b9a\u7684\u7279\u6027\u3002[Onset of dendritic growth in lithium\/polymer cells<\/a>]
\n Barton\u548cBockris\u7684\u8fdb\u4e00\u6b65\u8bf4\u660e\u6a21\u578b\u8ba4\u4e3a\uff0c\u6db2\u6001\u7535\u89e3\u8d28\u4e2d\u754c\u9762\u5c42\u518d\u5176\u4f4e\u4e8e\u751f\u957f\u7535\u6d41\u5bc6\u5ea6\u65f6\uff0c\u754c\u9762\u8584\u548c\u7a81\u8d77\u90e8\u5206\u7684Li\u6c89\u79ef\u901f\u7387\u8981\u8fdc\u9ad8\u4e8e\u5176\u4ed6\u90e8\u4f4d\uff0c\u8fd9\u662f\u5f97\u76ca\u4e8e\u8be5\u5904\u7684\u7403\u9762\u6269\u6563\u3002\u7406\u60f3\u5e73\u9762\u60c5\u51b5\u4e0b\u7ebf\u6027\u6269\u6563\u5c06\u5360\u4e3b\u5bfc\uff0c\u800c\u5728\u6709\u51f8\u8d77\u65f63D\u6269\u6563\u5c06\u5360\u4e3b\u5bfc\u3002\u7403\u9762\u6269\u6563\u65f6\uff0c\u9502\u679d\u6676\u7684\u5c16\u7aef\u6709\u6700\u5c0f\u7684\u76f4\u5f84\uff0c\u4f7f\u5176\u5177\u6709\u5f88\u5927\u7684\u7535\u6d41\u5bc6\u5ea6\uff0c\u4f7f\u5176\u5feb\u901f\u751f\u957f\u3002\u800c\u5b9e\u9a8c\u89c2\u6d4b\u4e2d\u9502\u679d\u6676\u5c16\u7aef\u90fd\u662f\u5706\u5f62\u6216\u8005\u5e73\u9762\u800c\u975e\u7a81\u8d77\u72b6\uff0c\u4ed6\u4eec\u5f15\u5165\u4e86\u8868\u9762\u80fd\u89e3\u91ca\uff0c\u5176\u6539\u53d8\u4e86\u8fd9\u79cd\u53d8\u201c\u5c16\u201d\u7684\u8d8b\u52bf\u4e5f\u9650\u5236\u4e86\u9502\u679d\u6676\u7684\u751f\u957f\u901f\u7387\u3002 [http:\/\/rspa.royalsocietypublishing.org\/content\/268\/1335\/485.short<\/a>]
\n Monroe\uff0cNewman\u548cAkolkar\u8fdb\u4e00\u6b65\u62d3\u5c55\u4e86Barton\u548cBockris\u7684\u6a21\u578b\uff0c\u4ed6\u4eec\u8003\u8651\u5230\u4e86\u7535\u89e3\u6db2\u4e2d\u79bb\u5b50\u6d53\u5ea6\u7684\u53d8\u5316\u3002Akolkar\u8ba4\u4e3a\uff0c\u9502\u679d\u6676\u5728\u4f4e\u6e29\u60c5\u51b5\u4e0b\u751f\u957f\u4f1a\u53d8\u5feb\uff0c\u56e0\u4e3a\u6b64\u65f6\u9502\u79bb\u5b50\u4f20\u8d28\u963b\u529b\u589e\u52a0\u800c\u4e14SEI\u8584\u5c42\u5e26\u6765\u7684\u754c\u9762\u53cd\u5e94\u963b\u529b\u51cf\u5c0f\u3002\u5728\u4e00\u5b9a\u7684\u7535\u6d41\u5bc6\u5ea6\u4e0b\uff08\u5bf9\u5e94\u9502\u5145\u7535\u7535\u6d41\uff09\uff0c\u6b64\u6a21\u578b\u9884\u6d4b\u4e86\u9502\u79bb\u5b50\u751f\u957f\u7684\u4e34\u754c\u6e29\u5ea6\u8d77\u59cb\u503c[Modeling dendrite growth during lithium electrodeposition at\u00c2 sub-ambient temperature<\/a>]
\n \"\"Monroe and Newman\u7684\u6a21\u578b\uff0c\u571f\u8c46\u6ce5<\/a>\u4e5f\u63d0\u5230\u4e86\u8fd9\u4e2a\u7ec4\u7684\u5de5\u4f5c\uff0c\u4ed6\u4eec\u8ba4\u4e3a\u9502\u679d\u666f\u968f\u7740\u65f6\u95f4\u548c\u4f20\u8f93\u8ddd\u79bb\u7684\u589e\u52a0\u800c\u589e\u52a0\u3002\u9ad8\u7535\u6d41\u5bc6\u5ea6\u4e0b\uff0c\u9502\u679d\u6676\u751f\u957f\u4e5f\u4f1a\u52a0\u901f\uff0c\u5728\u8fd9\u79cd\u7535\u9540\u8fc7\u7a0b\u4e2d\uff08Li\u679d\u6676\u7684\u751f\u957f\u4e5f\u53ef\u4ee5\u770b\u505a\u4e00\u79cd\u7535\u9540\u8fc7\u7a0b\uff09\uff0c\u51cf\u5c0f\u7535\u6d41\u5bc6\u5ea6\u4e5f\u4f1a\u51cf\u901f\u679d\u6676\u751f\u957f\u3002[Dendrite Growth in Lithium\/Polymer Systems<\/a>]
\n \"\"\u53e6\u4e00\u65b9\u9762\uff0c\u6211\u4eec\u77e5\u9053\u9759\u7535\u6548\u5e94\u5728\u6781\u5316\u7684\u7269\u4f53\u4e2d\uff0c\u8f7d\u6d41\u5b50\u7684\u5206\u5e03\u5f0f\u662f\u4e0d\u5747\u5300\u7684\uff0c\u5176\u5916\u90e8\u7684\u7535\u8377\u5bc6\u5ea6\u8fdc\u9ad8\u4e8e\u5185\u90e8\uff0c\u4e14\u5728\u7a81\u8d77\u5904\u4f1a\u66f4\u9ad8\uff0c\u8fd9\u91cc\u5c31\u5f62\u6210\u4e86\u6bd4\u8f83\u5f3a\u7684\u7535\u573a\uff0c\u8fd9\u91cc\u66f4\u6613\u4e8eLi+\u5f97\u5230\u7535\u8377\u800c\u6c89\u79ef\uff08\u8fd9\u4e5f\u662f\u4e3a\u4f55\u7c97\u7cd9\u7684\u8868\u9762\u66f4\u5bb9\u6613\u6790\u51fa\u9502\uff09\uff0c\u8fd9\u79cd\u9759\u7535\u6548\u5e94\u662f\u4f1a\u81ea\u53d1\u589e\u5f3a\u7684\uff0c\u6790\u51fa\u7684\u9502\uff08\u5f62\u6210\u7a81\u8d77\uff09\u53c8\u4f1a\u66f4\u5bb9\u6613\u805a\u96c6\u7535\u8377\uff0c\u9020\u6210\u9502\u8fdb\u4e00\u6b65\u6790\u51fa\u3002\uff0813\u5e74JACS\u6709\u4eba\u901a\u8fc7LiPF6\u4e2d\u52a0CsPF6\uff0c\u628a\u5b83\u53d8\u6210\u4e00\u79cd\u81ea\u6108\u8fc7\u7a0b\u4e86\uff09[Microscopic studies of transition metal chalcogenides<\/a>,Dendrite-Free Lithium ,Deposition via Self-Healing Electrostatic Shield Mechanism<\/a>]
\n \u518d\u8bf4\u8bf4\u6b63\u6781\u3002
\n Cohen\u63d0\u51fa\u7684\u6a21\u578b\u662f\u57fa\u4e8e\u590d\u6742\u7684SEI\u819c\u751f\u957f\u7684\uff0c\u4ed6\u4eec\u7684\u89c2\u70b9\u5728\u975e\u6c34\u7535\u89e3\u6db2\u4e2d\uff0c\u7531\u4e8e\u5728\u6d3b\u6027\u7269\u8d28\u8868\u9762\u5f62\u6210\uff0c\u5176\u754c\u9762\u4e0a\u53cd\u5e94\u6d3b\u6027\u70b9\u591a\uff0c\u5f62\u6210\u4e86\u9a6c\u8d5b\u514b\u72b6\u591a\u5c42\u7ed3\u6784\uff0c\u5bfc\u81f4\u4e86SEI\u5f62\u6210\u7684\u4e0d\u5747\u8861\uff0cSEI\u7684\u539a\u5ea6\u4e0d\u5747\u548c\u79bb\u5b50\u5bfc\u7535\u6027\u5dee\u5f02\uff0c\u8fdb\u800c\u5f15\u8d77 SEI\u7684\u5c40\u90e8\u6c89\u79ef\u548c\u6eb6\u89e3\uff0c\u4e5f\u4f7f\u6d3b\u6027\u7269\u8d28\u5c42\u548cSEI\u819c\u90e8\u5206\u3002
\n Micromorphological Studies of Lithium Electrodes in Alkyl Carbonate Solutions Using in Situ Atomic Force Microscopy<\/a><\/p>\n

\"\"Yamaki \u7b49\u4eba\u63d0\u51fa\u4e86\u6676\u987b\u751f\u957f\u7684\u7406\u8bba\uff0c\u4ed6\u4eec\u8ba4\u4e3a\u9502\u679d\u6676\u751f\u957f\u6a21\u5f0f\u662f\u6676\u987b\u751f\u957f\uff0c\u9502\u7684\u6c89\u79ef\u4f4d\u7f6e\u662f\u819c\u4e0a\u5177\u6709\u66f4\u9ad8\u79bb\u5b50\u7535\u5bfc\u7387\u548c\u6676\u754c\u4ee5\u53ca\u7f3a\u9677\u7684\u4f4d\u7f6e\uff0c\u8fd9\u5bfc\u81f4\u4e86\u9502\u539f\u5b50\u5206\u5e03\u7684\u4e0d\u5747\u5300\u548c\u9020\u6210SEI\u819c\u4e0b\u5e94\u529b\u5206\u5e03\u7684\u4e0d\u5747\uff0c\u4e3a\u4e86\u7f13\u89e3\u8fd9\u7c7b\u5e94\u529b\uff0c\u9502\u7684\u8868\u9762\u5f20\u529b\u4f1a\u4fc3\u4f7f\u5176\u7a7f\u900fSEI\u819c\u5f62\u6210\u6676\u987b\uff0c\u800c\u9502\u6c89\u79ef\u7ee7\u7eed\u5728\u9502\u57fa\u5e95\u4e0a\u800c\u975e\u6676\u987b\uff0c\u6700\u7ec8\u4f7f\u9502\u7535\u6781\u8868\u9762\u957f\u6ee1\u6676\u987b\uff0c\u957f\u65f6\u95f4\u7684\u6c89\u79ef\u4f7f\u7535\u6781\u8868\u9762\u88ab\u957f\u6676\u987b\u8986\u76d6\uff0c\u963b\u788d\u9502\u79bb\u5b50\u7684\u7ee7\u7eed\u4f20\u8f93\uff0c\u7136\u540e\u9502\u624d\u4f1a\u6c89\u79ef\u624d\u6676\u987b\u7684\u8fde\u63a5\u5904\u548c\u5c16\u7aef\uff08\u8fd9\u4e9b\u5730\u65b9\u4e00\u822c\u90fd\u6709\u7f3a\u9677\uff09\uff0c\u7531\u4e8e\u8fd9\u7c7b\u201c\u7c97\u5927\u201d\u8fde\u63a5\u7684\u51fa\u73b0\uff0c\u9502\u6c89\u79ef\u7684\u7535\u6d41\u5bc6\u5ea6\u53d8\u5f97\u5f88\u5c0f\uff0c\u4f7f\u5176\u7ee7\u7eed\u6210\u4e3a\u9897\u7c92\u72b6\u7684\u9502\u679d\u6676\u6216\u8005\u975e\u6676\u9502\u3002[A consideration of the morphology of electrochemically deposited lithium in an organic electrolyte<\/a>]<\/p>\n

\"\"\u8fd8\u6709\u4e00\u4e9b\u6a21\u578b\u5c31\u6ca1\u6709\u76f8\u9002\u5e94\u7684\u5b9e\u9a8c\u7ed3\u679c\u4e0e\u4e4b\u5bf9\u5e94\u4e86\u3002\u8fd9\u91cc\u5c31\u4e0d\u7ec6\u8bf4\u4e86\u3002\u6709\u5174\u8da3\u6211\u53ef\u4ee5\u7ed9\u4f60\u53d1\u4e9b\u6587\u732e,\u7136\u540e\u5462\uff0c\u6211\u5728\u770b\u539f\u4f4d\u6587\u7ae0\u7684\u65f6\u5019\u53d1\u73b0\u4e86\u4e00\u4e9b\u539f\u4f4dTEM\u7684\u7814\u7a76\u679d\u6676\u7684\u6587\u7ae0\uff0c\u4f9b\u4f60\u53c2\u8003\u3002
\n \u4e0b\u56fe\u662f\u9502\u5728\u8fc7\u7535\u4f4d\u6c89\u79ef\u7684\u56fe\uff0c\u6587\u7ae0\u7684\u524d\u6587\u8bc1\u660e\u4e86SEI\u7684\u5f62\u6210\u662f\u5148\u4e8eLi\u679d\u6676\u7684\u5f62\u6210\u7684\uff0c\u56fe1\u7684\u865a\u7ebf\u8868\u660e\u9502\u6c89\u79ef\u662f\u679d\u6676\u7684\u6811\u7a81\u90e8\u4f4d\uff0c\u8fd9\u53ef\u80fd\u662f\u7531\u4e8e\u5728\u8fd9\u4e9b\u90e8\u4f4d\u6709\u66f4\u9ad8\u7684\u9502\u79bb\u5b50\u7535\u5bfc\u7387\u6216\u8005\u7535\u5b50\u7535\u5bfc\u7387\uff0c\u9760\u8fd1\u754c\u9762\u65f6\uff0c\u62d0\u89d2\u5904\u660e\u6697\u7684\u5bf9\u6bd4\u544a\u8bc9\u6211\u4eec\u8fd9\u91cc\u6709\u66f4\u591a\u7684\u679d\u6676\u751f\u957f\uff0cc\u56fe\u4e2d\u51fa\u73b0\u4e86\u4e00\u4e9b\u9897\u7c92\u72b6\u7269\u8d28\uff08\u7531\u4e8eTEM\u5206\u8fa8\u7387\u7684\u5f71\u54cd\uff0c\u4f5c\u8005\u5e76\u672a\u544a\u8bc9\u6211\u4eec\u8fd9\u662f\u4ec0\u4e48\u7269\u8d28\uff09\uff0c\u4ed6\u540e\u9762\u901a\u8fc7\u5faa\u73af\u7684\u89c2\u5bdf\u5176\u6eb6\u89e3\u548c\u5f62\u6210\u63a8\u6d4b<\/strong>\u8fd9\u662fLi\uff0c\u8fd9\u4e00\u53d1\u73b0\u8868\u660e<\/strong>Li<\/strong>\u7684\u6c89\u79ef\u4e0d\u4ec5\u4ec5\u5728\u7535\u6781\u8868\u9762\u4e5f\u662f\u5728SEI<\/strong>\u4e2d\u7684\uff0c\u90a3\u4e48\uff0c\u8fd9\u4e9bLi<\/strong>\u7684\u91d1\u5c5e\u9897\u7c92\u5c06\u4f5c\u4e3a\u7535\u5b50\u4f20\u8f93\u901a\u9053<\/strong>\u548c\u9502\u679d\u6676\u751f\u957f\u7684\u79cd\u5b50\u5c42\uff0c\u56e0\u6b64\uff0cSEI\u5c06\u6781\u5927\u5f71\u54cd\u9502\u679d\u6676\u7684\u751f\u957f\u3002\u6587\u7ae0\u4e2d\uff0c\u8fd8\u63d0\u5230\u4e86\u7535\u89e3\u6db2\u5bf9\u6b20\u7535\u52bf\u6c89\u79ef\u7684\u5f71\u54cd\uff0c\u8868\u660e\u4e0d\u540c\u7535\u89e3\u6db2\u4e2d\u9502\u6c89\u79ef\u7684\u7535\u538b\u4e0d\u540c\u3002[Direct visualization of initial SEI morphology and growth kinetics during lithium deposition by in situ electrochemical transmission electron microscopy – Chemical Communications (RSC Publishing)<\/a>]<\/p>\n

\"\"\u56feE\u4e2d\u53ef\u4ee5\u770b\u5230Li\u679d\u6676\u5728\u4e24\u4e2a\u6c14\u6ce1\u4e4b\u95f4\u5f62\u6838\uff0c\u800c\u4e14\u679d\u6676\u5f62\u6210\u7684\u754c\u9762\u662f<\/strong>LI-Au<\/strong>\u8868\u9762\uff0c\u5373SEI<\/strong>\u5c42<\/strong>\uff0c\u7136\u540e\u8fc5\u901f\u957f\u5927\uff0c\u4e4b\u540e\u9502\u679d\u6676\u7684\u5c16\u7aef\u5c40\u90e8\u8131\u79bb\uff0c\u5e76\u5728\u653e\u7535\u8fc7\u7a0b\u4e2d\u6eb6\u89e3\u3002[Visualization of Electrode<\/a>]<\/p>\n

\"\"\u5f53\u7136\uff0cTEM\u539f\u5473\u89c2\u5bdf\u4e0d\u53ef\u907f\u514d\u7684\u4f1a\u504f\u79bb\u6b63\u5e38\u7535\u6c60\u7684\u90e8\u5206\u7279\u6027\uff0c\u4f46\u5176\u4e5f\u7b97\u662f\u76f4\u89c2\u7684\u8868\u9762\u51fa\u4e86Li\u7684\u751f\u957f\u8fc7\u7a0b\uff0c\u7531\u4e8e\u80fd\u529b\u6709\u9650\uff0c\u4e86\u89e3\u5230\u7684\u4fe1\u606f\u4e3b\u8981\u662f\u8fd9\u4e9b\uff0c\u5e0c\u671b\u80fd\u591f\u7ed9\u4f60\u4e00\u4e9b\u5e2e\u52a9\u3002
\n \u9898\u4e3b\u95ee\u5230\u4e86\u754c\u9762\u95ee\u9898\u5219\u4e0d\u5f97\u4e0d\u8bf4\u5230SEI\uff0c\u8fd9\u91cc\u6ca1\u6709\u65f6\u95f4\u7ec6\u7ec6\u7ed9\u9898\u4e3b\u8bf4\u5230SEI\u7684\u95ee\u9898\uff0c\u53ef\u4ee5\u53c2\u8003\uff0c\u9502\u7535\u6c60\u57fa\u7840\u79d1\u5b66\u95ee\u9898(\u2164)\u2014\u2014\u7535\u6c60\u754c\u9762<\/a>\uff0c\u8fd9\u91cc\u5bf9SEI\u5f62\u6210\u8bf4\u7684\u5f88\u591a\uff0c\u867d\u7136\u4e0d\u662f\u6700\u5168\u9762\u7684\u4e0d\u8fc7\u4e5f\u7b97\u662f\u4e2d\u6587\u91cc\u5199\u7684\u5f88\u4e0d\u9519\u7684\u4e86\u3002
\n 2016.1.10 \u8865\u5145\u53c2\u8003\u6587\u732e\uff0c\u4fee\u6539\u90e8\u5206\u5185\u5bb9\u3002
\n \u4eca\u5929\u6709\u70b9\u665a\u4e86\uff0c\u8fd9\u4e24\u5929\u518d\u628a\u53c2\u8003\u6587\u732e\u5217\u4e0a\uff0c\u8fd9\u90e8\u5206\u53ef\u8f85\u52a9\u571f\u8c46\u6ce5<\/a><\/p>\n

\u7684\u5927\u4f5c\u6765\u52a0\u6df1\u5bf9Li\u679d\u6676\u5f62\u6210\u7684\u5370\u8c61\u5427\uff0c\u7531\u4e8e\u8fd8\u5728\u5b66\u4e60\u9636\u6bb5\u6c34\u5e73\u6709\u9650\uff0c\u5982\u6709\u9519\u8bef\u5e0c\u671b\u5f97\u5230\u6307\u5bfc~<\/p>\n

\u4f5c\u8005\uff1azola rao<\/strong>
\n \u94fe\u63a5\uff1ahttps:\/\/www.zhihu.com\/question\/39111731\/answer\/80634909<\/a><\/strong><\/p>\n

\n \u672c\u6587\u8f6c\u81ea\u77e5\u4e4e\uff0c\u94fe\u63a5\uff1ahttps:\/\/www.zhihu.com\/question\/39111731<\/a><\/strong><\/p>\n

\u672c\u6587\u7531\u6750\u6599\u725bdeer\u7f16\u8f91\u6574\u7406\u3002<\/strong><\/p>\n","protected":false},"excerpt":{"rendered":"

\u00a0\u672c\u4eba\u5728\u8003\u8651\u9502\u679d\u6676\u662f\u5982\u4f55\u5f62\u6210\u7684\u8fd9\u4e2a\u95ee\u9898\u65f6\u60f3\u5230\uff0c\u5982\u679c\u50cf\u8bb8\u591a\u4eba\u8ba4\u4e3a\u7684\u90a3\u6837\uff0c\u9502\u79bb\u5b50\u5d4c\u5165\u77f3\u58a8\u4e4b\u540e\u4ecd\u7136\u4ee5\u79bb\u5b50\u5f62\u6001\u5b58\u5728\uff0c\u90a3\u5316\u5b66\u53cd\u5e94\u5728\u54ea\u91cc\u53d1\u751f\uff1f\u5982\u679c\u79bb\u5b50\u5728\u754c\u9762\u53d1\u751f\u5316\u5b66\u53cd\u5e94\uff0c\u90a3…<\/p>\n","protected":false},"author":3706,"featured_media":115454,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[234],"tags":[2604,1030],"class_list":["post-115447","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-guandian","tag-2604","tag-1030"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/115447"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/3706"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=115447"}],"version-history":[{"count":4,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/115447\/revisions"}],"predecessor-version":[{"id":115992,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/115447\/revisions\/115992"}],"wp:featuredmedia":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/media\/115454"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=115447"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=115447"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=115447"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}