{"id":115332,"date":"2017-12-04T06:30:30","date_gmt":"2017-12-03T22:30:30","guid":{"rendered":"\/\/m.iemloyee.com\/?p=115332"},"modified":"2017-12-04T21:33:52","modified_gmt":"2017-12-04T13:33:52","slug":"patrik-schmuki-adv-funct-mater-%ef%bc%9aauwo3tio2%e7%ba%b3%e7%b1%b3%e9%98%b5%e5%88%97%e5%a2%9e%e5%bc%ba%e5%85%89%e5%82%ac%e5%8c%96%e4%ba%a7%e6%b0%a2%e6%80%a7%e8%83%bd","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=115332","title":{"rendered":"Patrik Schmuki Adv. Funct. Mater.\uff1aAu\/WO3\/TiO2\u7eb3\u7c73\u9635\u5217\u589e\u5f3a\u5149\u50ac\u5316\u4ea7\u6c22\u6027\u80fd"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n

\u81eaFejishima\u548cHonda\u8bc1\u660eTiO2<\/sub>\u662f\u4e00\u79cd\u5149\u89e3\u6c34\u7684\u5149\u7535\u9633\u6781\u6750\u6599\u4ee5\u6765\uff0cTiO2<\/sub>\u5c31\u6210\u4e86\u5149\u50ac\u5316\u5242\u7684\u7814\u7a76\u70ed\u70b9\u3002TiO2<\/sub>\u8868\u9762\u80fd\u591f\u4ea7\u6c22\u5f52\u56e0\u4e8e\u5176\u534a\u5bfc\u4f53\u7ed3\u6784\u548c\u6709\u5229\u7684\u5e26\u9699\u4f4d\u7f6e\u3002TiO2<\/sub>\u5bfc\u5e26\u7684\u4e0b\u8fb9\u7f18\u7535\u4f4d\u9ad8\u4e8eH2<\/sub>O\/H2<\/sub>\u7684\u6c27\u5316\u8fd8\u539f\u7535\u4f4d\uff0c\u56e0\u6b64\u7d2b\u5916\u5149\u7684\u7167\u5c04\u4e0b\uff0cTiO2\u5bfc\u5e26\u7684\u5149\u751f\u7535\u5b50\u53ef\u4ee5\u8fd8\u539fH2<\/sub>O\u751f\u6210H2\u3002<\/sub>\u672c\u6587\u901a\u8fc7\u6784\u7b51Au\/WO3<\/sub>\/TiO2<\/sub>\u7eb3\u7c73\u7ba1\u9635\u5217\uff0c\u8bbe\u8ba1\u4e86Au-WO3<\/sub>– TiO2<\/sub>\u534f\u540c\u5149\u89e3\u6c34\u4ea7\u6c22\u50ac\u5316\u5242\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u963f\u535c\u675c\u62c9\u56fd\u738b\u79d1\u6280\u5927\u5b66<\/strong>Patrik Schmuki\u6559\u6388\u56e2\u961f<\/strong>\u5728Adv. Funct. Mater.<\/strong>\u4e0a\u53d1\u8868\u4e00\u7bc7\u9898\u4e3a\u201cA Cocatalytic Electron-Transfer Cascade Site-Selectively Placed on TiO2<\/sub> Nanotubes Yields Enhanced Photocatalytic H2<\/sub> Evolution<\/strong>\u201d\u7684\u6587\u7ae0\u3002\u5149\u751f\u8f7d\u6d41\u5b50\u7684\u5206\u79bb\u548c\u4f20\u5bfc\u662f\u8bbe\u8ba1\u5149\u50ac\u5316\u5242\u8003\u8651\u7684\u91cd\u8981\u56e0\u7d20\uff0c\u56e0\u6b64TiO2<\/sub>\u4f5c\u4e3a\u5149\u50ac\u5316\u5242\u88ab\u5e7f\u6cdb\u7814\u7a76\u3002\u8be5\u7814\u7a76\u8bbe\u8ba1\u4e86TiO2<\/sub>\u2013WO3<\/sub>\u2013Au\u7eb3\u7c73\u9635\u5217\u50ac\u5316\u5242\uff0c\u53ef\u5b9e\u73b0\u7eb3\u7c73\u7ea7\u7cbe\u786e\u7684\u5149\u50ac\u5316\u4ea7\u6c22\uff0c\u4e14TiO2<\/sub>\u2013WO3<\/sub>\u2013Au\u6027\u80fd\u8f83Au-TiO2<\/sub>\u63d0\u9ad8\u4e86\u4e00\u500d\u3002\u901a\u8fc7\u9009\u62e9\u4f4d\u70b9\u6c89\u79ef\u548c\u81ea\u5e8f\u70ed\u53bb\u6da6\u6e7f\u6cd5\u53ef\u63a7\u5236WO3<\/sub>\/Au\u7684\u7ed3\u6784\u3002WO3<\/sub>\u4f5c\u4e3aTiO2<\/sub>\u5bfc\u5e26\u7535\u5b50\u7684\u7f13\u51b2\u5c42\uff0c\u4f7f\u7535\u5b50\u6709\u6548\u5730\u8f6c\u79fb\u5230Au\u7eb3\u7c73\u9897\u7c92\u4e0a\uff0c\u5f62\u6210\u5408\u9002\u7684\u4ea7\u6c22\u73af\u5883\u3002\u540c\u65f6\u7531\u4e8e\u5728\u7eb3\u7c73\u7ba1\u4e2d\u80fd\u5e26\u5411\u4e0a\u5f2f\u66f2\u4e14\u6269\u6563\u8def\u5f84\u77ed\uff0c\u56e0\u800c\u4fc3\u8fdb\u4e86\u7a7a\u7a74\u7684\u4f20\u8f93\uff0c\u6709\u5229\u4e8e\u548c\u7535\u89e3\u6db2\u4e2d\u7684\u7a7a\u7a74\u727a\u7272\u5242\u53d1\u751f\u53cd\u5e94\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u56fe\u3011<\/strong><\/p>\n

\u56fe1 TiO2<\/sub>\u7eb3\u7c73\u9635\u5217\u7684\u5f62\u8c8c\u548c\u7ed3\u6784\u8868\u5f81<\/strong><\/p>\n

\"\"<\/p>\n

(a) \u539f\u59cbTiO2<\/sub>\u7684SEM\u56fe\uff0c\u63d2\u56fe\u4e3a\u5256\u89c6\u56fe<\/p>\n

(b) W\u5c42\u8d1f\u8f7dTiO2<\/sub>\u7684SEM\u56fe\uff0cW\u5c42\u539a10\u00b10.3nm<\/p>\n

(c)-(d)\u70ed\u89e3\u524d\u540e\u7684Au-WO3<\/sub>– TiO2<\/sub>\u7684SEM\u56fe<\/p>\n

(e) \u8d1f\u8f7d\u50ac\u5316\u5242\u7684TiO2<\/sub>\u7eb3\u7c73\u9635\u5217\u7684XRD\u56fe<\/p>\n

(f) Au-WO3<\/sub>– TiO2<\/sub>\u4ee5\u53caAu 4f\u3001W4f\u7684XPS\u56fe<\/p>\n

\u56fe2 TiO2<\/sub>\u2013WO3<\/sub>\u2013Au \u7eb3\u7c73\u9635\u5217\u7684\u5f62\u8c8c\u53caW\u542b\u91cf\u4e0e\u5c42\u539a\u5ea6\u7684\u5173\u7cfb\u56fe<\/strong><\/p>\n

\"\"<\/p>\n

(a)-(d) \u8d1f\u8f7d\u4e0d\u540cW\u542b\u91cf\u7684TiO2<\/sub>\u7eb3\u7c73\u7ba1\u7684\u626b\u63cf\u56fe<\/p>\n

(e) \u8d1f\u8f7d\u4e0d\u540cW\u542b\u91cf\u7684TiO2<\/sub>\u7eb3\u7c73\u7ba1\u7684\u8868\u9762\u6210\u5206\u5206\u6790<\/p>\n

\u56fe3 1Au\u20131WO3<\/sub>\u2013TiO2<\/sub>\u7684\u5f62\u8c8c\u8868\u5f81\u53caTiO2<\/sub>\u7eb3\u7c73\u9635\u5217\u4ea7\u6c22\u6027\u80fd\u56fe<\/strong><\/p>\n

\"\"<\/p>\n

(a) 1Au\u20131WO3<\/sub>\u2013TiO2<\/sub>\u7684SEM\u56fe<\/p>\n

(b) 1Au\u20131WO3<\/sub>\u2013TiO2<\/sub>\u7684TEM\u56fe<\/p>\n

(c) \u9510\u949b\u77ff\u578bTiO2<\/sub>\u7684\uff08101\uff09\u6676\u9762\u3001\u5355\u659cWO3<\/sub>\u7684\uff08120\uff09\u6676\u9762\u548cAu\u7684\uff08111\uff09\u6676\u9762<\/p>\n

(d)\u2013(e)\u4e0d\u540cTiO2<\/sub>\u7eb3\u7c73\u9635\u5217\u7684\u5149\u50ac\u5316\u4ea7\u6c22\u6027\u80fd\u56fe<\/p>\n

(f) 1Au\u20131WO3<\/sub>\u2013TiO2<\/sub>\u7684\u793a\u610f\u56fe\u53ca\u53ef\u80fd\u7684\u4ea7\u6c22\u673a\u7406<\/p>\n

\u56fe4 TiO2<\/sub>\u7eb3\u7c73\u9635\u5217\u7684\u7b49\u6548\u7535\u8def\u6a21\u578b\u53ca\u5176EIS\u6027\u80fd<\/strong><\/p>\n

\"\"<\/p>\n

(a)-(b) \u7528\u4e8eEIS\u6570\u636e\u62df\u5408\u7684\u7b49\u6548\u7535\u8def\u6a21\u578b<\/p>\n

(e)-(f) 369nm\u5149\u7167\u4e0b\u7684\u51e0\u79cdTiO2<\/sub>\u7eb3\u7c73\u9635\u5217\u7684Bode\u56fe<\/p>\n

\u56fe5 Au-WO3<\/sub>– TiO2<\/sub>\u7684\u5149\u50ac\u5316\u4ea7\u6c22\u6027\u80fd<\/strong><\/p>\n

\"\"<\/p>\n

(a) xAu-1WO3<\/sub>-TiO2<\/sub>\u7eb3\u7c73\u9635\u5217\u7684\u4ea7\u6c22\u6027\u80fd<\/p>\n

(b) 1Au-xWO3<\/sub>-TiO2<\/sub>\u7eb3\u7c73\u9635\u5217\u7684\u4ea7\u6c22\u6027\u80fd<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n

\u672c\u7814\u7a76\u901a\u8fc7\u91d1\u5c5e\u6e85\u5c04\u6c89\u79ef\u6cd5\u548c\u70ed\u53bb\u6da6\u6e7f\u6cd5\u6784\u7b51\u5f97\u5230Au\/WO3<\/sub>\/TiO2<\/sub>\u7eb3\u7c73\u9635\u5217\uff0c\u5f62\u6210\u4e86\u4e00\u79cd\u9ad8\u6548\u7684\u5149\u89e3\u6c34\u4ea7\u6c22\u50ac\u5316\u5242\u3002\u6b64\u5916\uff0c\u9009\u62e9\u6027\u6e85\u5c04\u6c89\u79ef\u91d1\u5c5e\u8584\u819c\u6cd5\u80fd\u591f\u5b9e\u73b0\u5bf9\u52a9\u50ac\u5316\u5242\/\u5149\u50ac\u5316\u5242\u7ed3\u6784\u7684\u9ad8\u5ea6\u63a7\u5236\u4ee5\u53ca\u4e00\u4e9b\u5148\u8fdb\u7684\u529f\u80fd\uff0c\u5982\u5feb\u901f\u548c\u5b9a\u5411\u7535\u5b50\u8fd0\u8f93\u8f6c\u79fb\u7b49\uff0c\u4ece\u800c\u5927\u5927\u63d0\u9ad8\u4e86\u5149\u50ac\u5316\u6548\u7387\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/strong>A Cocatalytic Electron-Transfer Cascade Site-Selectively Placed on TiO2 Nanotubes Yields Enhanced Photocatalytic H2 Evolution<\/a>\uff08Adv. Fun. Mat., 2017, DOI: 10.1002\/adfm.201704259 \uff09<\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u7f16\u8f91\u90e8\u5f20\u9882\u6b4c\u7f16\u8bd1\uff0c \u8d75\u98de\u9f99\u5ba1\u6838\uff0c\u70b9\u6211\u52a0\u5165\u6750\u6599\u4eba\u7f16\u8f91\u90e8<\/a>\u3002<\/p>\n

\u6750\u6599\u6d4b\u8bd5\uff0c\u6570\u636e\u5206\u6790\uff0c\u4e0a<\/strong>\u6d4b\u8bd5\u8c37<\/strong><\/a>\uff01<\/strong><\/p>\n","protected":false},"excerpt":{"rendered":"

\u3010\u5f15\u8a00\u3011 \u81eaFejishima\u548cHonda\u8bc1\u660eTiO2\u662f\u4e00\u79cd\u5149\u89e3\u6c34\u7684\u5149\u7535\u9633\u6781\u6750\u6599\u4ee5\u6765\uff0cTiO2\u5c31\u6210\u4e86\u5149\u50ac\u5316\u5242\u7684\u7814\u7a76\u70ed\u70b9\u3002TiO2\u8868\u9762\u80fd\u591f\u4ea7\u6c22\u5f52\u56e0\u4e8e\u5176\u534a\u5bfc\u4f53\u7ed3\u6784\u548c…<\/p>\n","protected":false},"author":230,"featured_media":115336,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215,2],"tags":[2407,2529],"class_list":["post-115332","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-jiedu","category-keji","tag-tio2-nts","tag-2529"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/115332"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/230"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=115332"}],"version-history":[{"count":8,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/115332\/revisions"}],"predecessor-version":[{"id":115624,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/115332\/revisions\/115624"}],"wp:featuredmedia":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/media\/115336"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=115332"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=115332"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=115332"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}