{"id":115212,"date":"2017-12-04T06:30:13","date_gmt":"2017-12-03T22:30:13","guid":{"rendered":"\/\/m.iemloyee.com\/?p=115212"},"modified":"2017-12-02T13:05:51","modified_gmt":"2017-12-02T05:05:51","slug":"%e5%8e%a6%e9%97%a8%e5%a4%a7%e5%ad%a6%e9%83%91%e5%8d%97%e5%b3%b0%e8%af%be%e9%a2%98%e7%bb%84%ef%bc%9a%e5%be%ae%e5%ad%94%e9%92%9b%e6%b0%a7%e5%9b%a2%e7%b0%87%e5%8f%96%e5%be%97%e9%87%8d%e8%a6%81%e8%bf%9b","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=115212","title":{"rendered":"\u53a6\u95e8\u5927\u5b66\u90d1\u5357\u5cf0\u8bfe\u9898\u7ec4\uff1a\u5fae\u5b54\u949b\u6c27\u56e2\u7c07\u53d6\u5f97\u91cd\u8981\u8fdb\u5c55"},"content":{"rendered":"<p><strong>\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n<p>\u90d1\u5357\u5cf0\u6559\u6388\u8bfe\u9898\u7ec4\u5728\u5fae\u5b54\u949b\u6c27\u56e2\u7c07\u5316\u5408\u7269\u65b9\u9762\u7684\u7814\u7a76\u53d6\u5f97\u91cd\u8981\u8fdb\u5c55, \u76f8\u5173\u7ed3\u679c\u4ee5\u201cMicroporous Cyclic Titanium-Oxo Clusters with Labile Surface Ligands\u201d \u4e3a\u9898\uff0c\u53d1\u8868\u5728\u5fb7\u56fd\u5e94\u7528\u5316\u5b66\u4e0a(<em>Angew. Chem. Int. Ed.<\/em>, 2017, DOI: 10.1002\/anie.201709096)\u3002<\/p>\n<p><strong>\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n<p><strong>\u56fe1 \u5c40\u90e8\u7ed3\u6784<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-115213\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/12\/\u56fe\u72471-1.png\" alt=\"\" width=\"600\" height=\"334\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/12\/\u56fe\u72471-1.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/12\/\u56fe\u72471-1-300x167.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>\uff08a\uff09CTOC-1\u7684Ti<sub>4<\/sub>\u5355\u5143\u7684\u5c40\u90e8\u7ed3\u6784<br \/>\n \uff08b,c\uff09\u516b\u4e2aTi<sub>4<\/sub>\u5355\u5143\u7684\u5faa\u73af\u952f\u9f7f\u6392\u5217\uff08b\uff09\u9876\u90e8\u548c\uff08c\uff09\u7684\u4fa7\u89c6\u56fe<\/p>\n<p><strong>\u56fe2 ESI-MS\u5206\u6790<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-115214\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/12\/\u56fe\u72472-1.png\" alt=\"\" width=\"600\" height=\"510\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/12\/\u56fe\u72472-1.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/12\/\u56fe\u72472-1-300x255.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>\u63d2\u56fe\u663e\u793aMeO\u5b8c\u5168\u4ea4\u6362\u7684EGH-\u79cd\u7c7b\u548c\u6a21\u62df\u56fe\u6848\uff08\u7d2b\u8272\uff09\u3002<\/p>\n<p><strong>\u3010\u7814\u7a76\u5185\u5bb9\u3011<\/strong><\/p>\n<p>\u4f5c\u4e3a\u4e8c\u6c27\u5316\u949b\u7684\u6a21\u578b\u5206\u5b50\uff0c\u8fd1\u5e74\u6765\uff0c\u5177\u6709\u786e\u5b9a\u7ed3\u6784\u7684\u949b\u6c27\u56e2\u7c07\u7c7b\u5316\u5408\u7269\u53d7\u5230\u4eba\u4eec\u7684\u5e7f\u6cdb\u5173\u6ce8\u3002\u90d1\u5357\u5cf0\u8bfe\u9898\u7ec4\u7684\u524d\u671f\u7814\u7a76\u5de5\u4f5c\u8868\u660e\u4fee\u9970\u5728TiO<sub>2<\/sub>\u8868\u9762\u7684\u4e59\u4e8c\u9187\u57fa\u5728\u5149\u8bf1\u5bfc\u4e0b\u53ef\u4ee5\u9ad8\u6548\u5730\u951a\u5b9a\u5355\u539f\u5b50\u5206\u6563\u50ac\u5316\u5242\uff08<em>Science<\/em>, <strong>2016<\/strong>,\u00a0<em>352<\/em>, 797-801\uff09\uff0c\u4f46\u7c7b\u4f3c\u7684\u7ed3\u6784\u6a21\u578b\u5728\u5df2\u62a5\u9053\u7684\u949b\u6c27\u56e2\u7c07\u5206\u5b50\u4e2d\u5c1a\u5c5e\u5c11\u89c1\u3002\u8be5\u5de5\u4f5c\u901a\u8fc7\u5728\u4e59\u4e8c\u9187\u4e2d\u5f15\u5165\u5c0f\u5206\u5b50\u5355\u7fa7\u9178\u914d\u4f53\uff0c\u6210\u529f\u5408\u6210\u4e86\u7cfb\u5217\u5fae\u5b54\u949b\u6c27\u56e2\u7c07\u5316\u5408\u7269\u3002\u8be5\u7c7b\u56e2\u7c07\u5206\u5b50\u62e5\u6709\u76f8\u540c\u7684\u5206\u5b50\u9aa8\u67b6{Ti<sub>32<\/sub>O<sub>16<\/sub>}\uff0c\u7531\u516b\u4e2aTi<sub>4<\/sub>\u7ed3\u6784\u5355\u5143\u76f8\u4e92\u8fde\u63a5\u5f62\u6210\u95ed\u5408\u73af\u72b6\u7ed3\u6784\u3002\u73af\u7684\u5185\u5f84\u4e3a0.8 nm\uff0c\u5916\u5f84\u4e3a2.6 nm\u3002\u516b\u4e2aTi<sub>4<\/sub>\u7ed3\u6784\u5355\u5143\u91c7\u7528\u952f\u9f7f\u5f62\uff08Zigzag\uff09\u6392\u5217\uff0c\u73af\u56e0\u800c\u5177\u6709\u7ea61.0 nm\u7684\u539a\u5ea6\u3002\u6709\u8da3\u7684\u662f\uff0c\u73af\u72b6\u949b\u6c27\u56e2\u7c07\u53ef\u7d27\u5bc6\u5806\u79ef\u5f62\u6210\u89c4\u5219\u7684\u4e00\u7ef4\u7eb3\u7c73\u7ba1\u72b6\u5b54\u9053\u3002\u6709\u673a\u9178\u914d\u4f53\u7684\u51e0\u4f55\u5f62\u72b6\u53ef\u4ee5\u8c03\u63a7\u7eb3\u7c73\u7ba1\u91c7\u53d6\u56db\u65b9\u6216\u8005\u516d\u65b9\u5806\u79ef\uff0c\u5f62\u6210\u4e09\u7ef4\u591a\u5b54\u7ed3\u6784\uff0c\u4f7f\u8be5\u7c7b\u5316\u5408\u7269\u5177\u6709\u5178\u578b\u7684\u5fae\u5b54\u7279\u5f81\uff0c\u6bd4\u8868\u9762\u79ef\u9ad8\u8fbe660 m<sup>2<\/sup> g<sup>-1<\/sup>\uff0c\u800c\u5206\u5e03\u5728\u73af\u72b6\u56e2\u7c07\u7684\u5916\u56f4\u4e0d\u540c\u6709\u673a\u9178\u914d\u4f53\u53ef\u4ee5\u8c03\u63a7\u5176\u5bf9CO<sub>2<\/sub>\u7684\u5438\u9644\u7113\u3002\u6b64\u5916\uff0c\u4ed6\u4eec\u7814\u7a76\u8fd8\u53d1\u73b0\u8fd9\u7c7b\u73af\u72b6\u56e2\u7c07\u7684\u5916\u56f4\u914d\u4f53\u5bb9\u6613\u88ab\u540c\u7c7b\u914d\u4f53\u4ea4\u6362\uff0c\u8fdb\u800c\u8c03\u8282\u949b\u6c27\u56e2\u7c07\u4eb2\u6c34\/\u758f\u6c34\u7684\u6027\u8d28\u3002<\/p>\n<p>\u539f\u6587\u94fe\u63a5\uff1a<a href=\"http:\/\/chem.xmu.edu.cn\/show.asp?id=2332\" target=\"_blank\" rel=\"noopener\">http:\/\/chem.xmu.edu.cn\/show.asp?id=2332<\/a><\/p>\n<p>\u6587\u732e\u94fe\u63a5\uff1a<a href=\"http:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/anie.201709096\/full\" target=\"_blank\" rel=\"noopener\">Microporous Cyclic Titanium-Oxo Clusters with Labile Surface Ligands<\/a>\uff08Angew. Chem. Int. Ed.,2017,DOI:<span class=\"article-header__meta-info-data\">10.1002\/anie.201709096\uff09<\/span><\/p>\n<p>\u672c\u6587\u7531\u6750\u6599\u4eba\u7f16\u8f91\u90e8Allen\u7f16\u8f91\uff0c<a href=\"\/\/m.iemloyee.com\/25127.html\" target=\"_blank\" rel=\"noopener noreferrer\">\u70b9\u6211\u52a0\u5165\u6750\u6599\u4eba\u7f16\u8f91\u90e8<\/a>\u3002<\/p>\n<p>\u6750\u6599\u6d4b\u8bd5\uff0c\u6570\u636e\u5206\u6790\uff0c\u4e0a<a href=\"http:\/\/www.ceshigu.com\/\" target=\"_blank\" rel=\"noopener noreferrer\">\u6d4b\u8bd5\u8c37<\/a>\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u3010\u6210\u679c\u7b80\u4ecb\u3011 \u90d1\u5357\u5cf0\u6559\u6388\u8bfe\u9898\u7ec4\u5728\u5fae\u5b54\u949b\u6c27\u56e2\u7c07\u5316\u5408\u7269\u65b9\u9762\u7684\u7814\u7a76\u53d6\u5f97\u91cd\u8981\u8fdb\u5c55, \u76f8\u5173\u7ed3\u679c\u4ee5\u201cMicroporous Cyclic Titanium-Oxo Clus&#8230;<\/p>\n","protected":false},"author":349,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[2],"tags":[],"class_list":["post-115212","post","type-post","status-publish","format-standard","hentry","category-keji"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/115212"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/349"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=115212"}],"version-history":[{"count":2,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/115212\/revisions"}],"predecessor-version":[{"id":115233,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/115212\/revisions\/115233"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=115212"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=115212"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=115212"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}