{"id":115133,"date":"2017-12-07T06:30:17","date_gmt":"2017-12-06T22:30:17","guid":{"rendered":"\/\/m.iemloyee.com\/?p=115133"},"modified":"2017-12-01T22:02:27","modified_gmt":"2017-12-01T14:02:27","slug":"%e5%90%89%e6%9e%97%e5%a4%a7%e5%ad%a6adv-energy-mater-%ef%bc%9a%e5%8f%8d%e5%85%b6%e9%81%93%e8%80%8c%e8%a1%8c%e5%88%b6%e5%a4%87%e9%ab%98%e5%ba%a6%e5%8f%96%e5%90%91mof%e7%94%b5","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=115133","title":{"rendered":"\u5409\u6797\u5927\u5b66Adv. Energy. Mater.\uff1a\u201c\u53cd\u5176\u9053\u800c\u884c\u201d\u5236\u5907\u9ad8\u5ea6\u53d6\u5411MOF\u7535\u6781"},"content":{"rendered":"
\u3010\u5f15\u8a00\u3011<\/strong> \u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong> \u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong> \uff08A\uff09\u4ee5Co(OH)2<\/sub>\u4e3a\u6a21\u677f\u548c\u524d\u9a71\u4f53\u539f\u4f4d\u5236\u5907Co-Ni MOF\u793a\u610f\u56fe\uff1b<\/p>\n \uff08B\uff09Ni-MOF\u3001CFP\u3001Co(OH)2<\/sub>\u3001CoNi-MOFXRD\u8868\u5f81\uff1b<\/p>\n \uff08C-G\uff09Ni-MOF\u3001CFP\u3001Co(OH)2<\/sub>\u3001CoNi-MOF SEM\u56fe\uff1b<\/p>\n \u56fe2 Co-Ni MOF STEM-EDX\u8868\u5f81\u4e0eXRD\u8868\u5f81<\/strong><\/p>\n \uff08A\uff09CoNi-MOF STEM\u56fe\uff1b<\/p>\n \uff08B\uff09\u9ad8\u5206\u8fa8HAADF-STEM\u56fe\u663e\u793a\u6676\u683c\u6761\u7eb9d=1.06 nm\u5bf9\u5e94d100<\/sub>\u6676\u9762\uff1b<\/p>\n \uff08C\uff0cD\uff09CoNi-MOF EDS\u5143\u7d20\u8c31\u56fe\uff1b<\/p>\n \uff08E-G\uff09Co(OH)2<\/sub> Co 2pXPS\u66f2\u7ebf\u3001CoNi-MOF Co 2p XPS\u66f2\u7ebf\u3001CoNi-MOF Ni 2p \u66f2\u7ebf\u3002<\/p>\n \u56fe3 CoNi-MOF \u7535\u6781\u4e0e\u6df7\u5408\u8d85\u7ea7\u7535\u5bb9\u5668\u7535\u5316\u5b66\u8868\u5f81<\/strong><\/p>\n \uff08A\uff09Co(OH)2<\/sub>\u3001Ni-MOF\u3001CoNi-MOF\u7535\u6781\u5728\u626b\u901f\u4e3a10 mV s-1<\/sup>\u65f6\u7684CV\u66f2\u7ebf\uff1b<\/p>\n \uff08B\uff09Co(OH)2<\/sub>\u3001Ni-MOF\u3001CoNi-MOF\u7535\u6781\u5728\u7535\u6d41\u5bc6\u5ea6\u4e3a2 A g-1<\/sup>\u65f6\u7684\u6052\u7535\u6d41\u5145\u653e\u7535\u66f2\u7ebf\uff0c\u5176\u6bd4\u5bb9\u91cf\u5206\u522b\u4e3a688\u3001533\u30011044F g-1<\/sup>\uff1b<\/p>\n \uff08C\uff09CoNi-MOF\u7535\u6781\u5728\u626b\u901f\u4e3a5\u300110\u300125 mV s-1<\/sup>\u65f6\u7684CV\u66f2\u7ebf\uff1b<\/p>\n \uff08D\uff09CoNi-MOF\u7535\u6781\u5728\u7535\u6d41\u5bc6\u5ea6\u4e3a2\u30014\u30018\u300116\u300132 A g-1<\/sup>\u65f6\u7684\u6052\u7535\u6d41\u5145\u653e\u7535\u66f2\u7ebf\uff1b<\/p>\n \uff08E\uff09Ni-MOF\u3001CoNi-MOF\u7535\u6781\u500d\u7387\u7279\u6027\u66f2\u7ebf\uff1b<\/p>\n \uff08F\uff09AC\u4e0eCoNi-MOF\u7535\u6781\u572810 mV s-1<\/sup>\u65f6\u7684CV\u66f2\u7ebf\uff1b<\/p>\n \uff08G\uff09\u6df7\u5408\u8d85\u7ea7\u7535\u5bb9\u5668\u5728\u4e0d\u540c\u626b\u901f\u65f6\u7684CV\u66f2\u7ebf\uff1b<\/p>\n \uff08H\uff09\u6df7\u5408\u8d85\u7ea7\u7535\u5bb9\u5668\u4e0d\u540c\u7535\u6d41\u5bc6\u5ea6\u4e0b\u7684\u6052\u7535\u6d41\u5145\u653e\u7535\u66f2\u7ebf\uff1b<\/p>\n \uff08I\uff09\u6df7\u5408\u8d85\u7ea7\u7535\u5bb9\u5668\u7684\u5faa\u73af\u7a33\u5b9a\u6027\u3002<\/p>\n \u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n \u7814\u7a76\u8005\u5229\u7528\u4e00\u79cd\u9ad8\u6548\u3001\u53ef\u63a7\u7684\u6280\u672f\u4ee5Co(OH)2<\/sub>\u4f5c\u4e3a\u6a21\u677f\u548c\u524d\u9a71\u4f53\u5728\u78b3\u7ea4\u7ef4\u7eb8\u4e0a\u5236\u5907\u5782\u76f4\u53d6\u5411\u7684\u65e0\u7c98\u7ed3\u5242MOF\u7535\u6781\u3002\u4e0e\u5176\u4ed6MOFs\u7684\u751f\u957f\u65b9\u5f0f\u4e0d\u540c\uff0cCo(OH)2<\/sub>\u4e0d\u4ec5\u4f5c\u4e3aMOF\u53d6\u5411\u751f\u957f\u7684\u6a21\u677f\uff0c\u800c\u4e14\u5176\u672c\u8eab\u4e5f\u8f6c\u5316\u4e3aMOF\u7ed3\u6784\u3002\u57fa\u4e8e\u6b64\u65b9\u6cd5\u5236\u5907\u5f97\u5230\u7684CoNi-MOF\u7535\u6781\u8868\u73b0\u51fa\u4f18\u5f02\u7684\u7535\u5316\u5b66\u6027\u80fd\uff0c\u53d6\u5411\u6392\u5217\u6291\u5236\u4e86\u805a\u96c6\u73b0\u8c61\uff0c\u4f7f\u5f97\u7535\u6781\u5177\u6709\u9ad8\u6bd4\u7535\u5bb9\u3001\u9ad8\u500d\u7387\u7279\u6027\u4ee5\u53ca\u4f18\u5f02\u7684\u7a33\u5b9a\u6027\u3002\u901a\u5e38\u60c5\u51b5\u4e0b\uff0cMOF\u4f5c\u4e3a\u6a21\u677f\u6216\u524d\u9a71\u4f53\u7528\u4e8e\u5236\u5907\u76ee\u6807\u4ea7\u7269\uff0c\u800c\u672c\u7814\u7a76\u5de5\u4f5c\u662f\u201c\u53cd\u5176\u9053\u800c\u884c\u201d\u5236\u5907\u5f97\u5230\u9ad8\u80fd\u91cf\u5bc6\u5ea6\u4e0e\u9ad8\u529f\u7387\u5bc6\u5ea6\u7684MOF\u7535\u6781\u6750\u6599\uff0c\u4e3aMOF\u6750\u6599\u7684\u5236\u5907\u4e0e\u672a\u6765\u5b9e\u9645\u5e94\u7528\u62d3\u5bbd\u4e86\u7814\u7a76\u89c6\u91ce\u3002<\/p>\n \u7814\u7a76\u56e2\u961f\u4ecb\u7ecd<\/strong> \u56e2\u961f\u5728\u8be5\u9886\u57df\u5de5\u4f5c\u6c47\u603b<\/strong> \u6587\u732e\u94fe\u63a5<\/strong>\uff1aInverted Design for High-Performance Supercapacitor Via Co(OH)2<\/sub>-Derived Highly Oriented MOF Electrodes<\/a>\uff0c(Adv. Eneryg. Mater., 2017, DOI: 10.1002\/aenm.201702294)<\/p>\n \u672c\u6587\u7531\u6750\u6599\u4eba\u65b0\u80fd\u6e90\u5c0f\u7ec4\u66fe\u6c99\u4f9b\u7a3f\u3002<\/p>\n \u6750\u6599\u725b\u7f51\u4e13\u6ce8\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u53ca\u884c\u4e1a\u8fdb\u5c55\uff0c\u8fd9\u91cc\u6c47\u96c6\u4e86\u5404\u5927\u9ad8\u6821\u7855\u535a\u751f\u3001\u4e00\u7ebf\u79d1\u7814\u4eba\u5458\u4ee5\u53ca\u884c\u4e1a\u4ece\u4e1a\u8005\uff0c\u5982\u679c\u60a8\u5bf9\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u8fdb\u5c55\uff0c\u89e3\u8bfb\u9ad8\u6c34\u5e73\u6587\u7ae0\u6216\u662f\u8bc4\u8ff0\u884c\u4e1a\u6709\u5174\u8da3\uff0c\u70b9\u6211\u52a0\u5165\u7f16\u8f91\u90e8\u5927\u5bb6\u5ead<\/a>\u3002<\/p>\n \u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1tougao@cailiaoren.com\u3002<\/p>\n \u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1aRDD-2011-CHERISH\uff0c\u4efb\u4e39\u4e39\uff0c\u6211\u4eec\u4f1a\u9080\u8bf7\u5404\u4f4d\u8001\u5e08\u52a0\u5165\u4e13\u5bb6\u7fa4\u3002<\/strong><\/p>\n
\n \u8fd1\u5e74\u6765\u5df2\u6709\u8bb8\u591a\u7814\u7a76\u81f4\u529b\u4e8e\u5236\u5907\u9ad8\u53d6\u5411\u3001\u9ad8\u5bfc\u7535MOF\u7535\u6781\u6750\u6599\u7528\u4e8e\u8d85\u7ea7\u7535\u5bb9\u5668\uff0c\u751f\u957f\u5728\u5bfc\u7535\u57fa\u5e95\u4e0a\u7684\u53d6\u5411MOF\u7535\u6781\u6750\u6599\u53ef\u4ee5\u62d3\u5bbd\u8d5d\u7535\u5bb9\u7535\u4f4d\u533a\u95f4\uff0c\u63d0\u9ad8\u7535\u5316\u5b66\u6027\u80fd\uff0c\u6709\u5e7f\u6cdb\u7684\u5e94\u7528\u524d\u666f\u3002\u901a\u5e38\u8f83\u7b80\u4fbf\u7684\u4e00\u79cd\u5236\u5907\u65b9\u6cd5\u662f\u4f7f\u7528\u6a21\u677f\u6cd5\u5916\u5ef6\u751f\u957fMOF\uff0c\u4f46\u662f\u8fd9\u79cd\u65b9\u6cd5\u4e0d\u4ec5\u9700\u8981\u6a21\u677f\uff0c\u800c\u4e14\u5728\u540e\u7eed\u7684\u5904\u7406\u8fc7\u7a0b\u4e2d\u9700\u8981\u53bb\u9664\u6a21\u677f\uff0c\u8fd9\u4e0d\u53ef\u907f\u514d\u4f1a\u5bfc\u81f4MOF\u7ed3\u6784\u7684\u5f62\u53d8\u6216\u635f\u574f\u3002
\n MOF\u5728\u7535\u5316\u5b66\u50a8\u80fd\u9886\u57df\u7528\u9014\u5e7f\u6cdb\uff0c\u4f7f\u7528MOFs\u4e3a\u6a21\u677f\u548c\u524d\u9a71\u4f53\u80fd\u591f\u7b80\u4fbf\u3001\u53ef\u63a7\u3001\u9ad8\u6548\u5730\u5408\u6210\u5177\u7279\u6b8a\u6027\u80fd\u7684\u76ee\u6807\u4ea7\u7269\uff0c\u4f8b\u5982\u91d1\u5c5e\u6c27\u5316\u7269\u3001\u91d1\u5c5e\u6c22\u6c27\u5316\u7269\u548c\u78b3\u6750\u6599\u3002MOFs\u6a21\u677f\u7684\u5e94\u7528\u5c31\u50cfDNA\u914d\u5bf9\uff0c\u786e\u4fdd\u76ee\u6807\u4ea7\u7269\u7684\u5171\u5f62\u53d8\u6362\u5e76\u4fdd\u6301\u539f\u59cbMOF\u7684\u5b54\u9699\u7ed3\u6784\u4e0e\u6bd4\u8868\u9762\u79ef\u3002\u5982\u82e5\u201c\u53cd\u5176\u9053\u800c\u884c\u201d\uff0c\u5c31\u50cfRNA\u53cd\u8f6c\u5f55\u4e00\u6837\uff0c\u662f\u5426\u53ef\u4ee5\u4f7f\u7528\u76ee\u6807\u4ea7\u54c1\u4f5c\u4e3a\u524d\u9a71\u4f53\u6216\u6a21\u677f\u6765\u5236\u5907\u6240\u9700\u7684MOF\u6750\u6599\uff1f<\/p>\n
\n \u8fd1\u65e5\uff0c\u5409\u6797\u5927\u5b66\u7684\u90d1\u4f1f\u6d9b\u6559\u6388\u3001\u5f20\u4f1f\u6559\u6388\uff08\u5171\u540c\u901a\u8baf\u4f5c\u8005\uff09<\/strong>\u5728Adv. Energy. Mater.<\/strong>\u4e0a\u53d1\u8868\u6700\u65b0\u7814\u7a76\u6210\u679c \u201cInverted Design for High-Performance Supercapacitor Via Co(OH)2<\/sub>-Derived Highly Oriented MOF Electrodes<\/strong>\u201d\u3002 \u8be5\u5de5\u4f5c\u5f97\u5230\u4e86\u5317\u4eac\u5de5\u4e1a\u5927\u5b66\u968b\u66fc\u9f84\u6559\u6388\u548c\u5362\u5cb3\u535a\u58eb\u7684\u5b9d\u8d35\u652f\u6301\uff0c\u672c\u8bba\u6587\u7684\u7b2c\u4e00\u4f5c\u8005\u4e3a\u5409\u6797\u5927\u5b66\u6750\u6599\u79d1\u5b66\u4e0e\u5de5\u7a0b\u5b66\u9662\u535a\u58eb\u7814\u7a76\u751f\u9093\u9706\u3002\u5728\u8be5\u6587\u4e2d\uff0c\u7814\u7a76\u8005\u4eceMOF\u6a21\u677f\u6cd5\u4e2d\u83b7\u5f97\u542f\u53d1\uff0c\u201c\u53cd\u5176\u9053\u800c\u884c\u201d\u4ee5\u91d1\u5c5e\u6c22\u6c27\u5316\u7269\u4e3a\u539f\u6599\u5728\u78b3\u7ea4\u7ef4\u7eb8(CFP)\u4e0a\u5236\u5907\u4e86\u53d6\u5411MOF\u6750\u6599\uff0c\u6574\u4e2a\u5236\u5907\u65b9\u6cd5\u64cd\u4f5c\u7b80\u4fbf\u9ad8\u6548\u4e14\u65e0\u9700\u53bb\u9664\u6a21\u677f\u3002\u9996\u5148\uff0c\u5728\u78b3\u7ea4\u7ef4\u7eb8\u4e0a\u7535\u6c89\u79ef\u5782\u76f4\u53d6\u5411\u7684Co(OH)2<\/sub>\uff0c\u4e4b\u540e\u52a0\u5165Ni\u79bb\u5b50\u4e0ePTA\u5236\u5907\u51fa\u4e0e\u590d\u5236\u5c42\u72b6Co(OH)2<\/sub>\u5f62\u8c8c\u7684\u4e8c\u7ef4Ni-MOF\uff0c\u6b64\u8fc7\u7a0b\u4e2d\uff0cNi\u79bb\u5b50\u53d6\u4ee3Co(OH)2<\/sub>\u4e2d\u7684H\u4e14\u4f5c\u4e3aMOF\u81ea\u7ec4\u88c5\u751f\u957f\u4f4d\u70b9\u5c06CoO\u5c42\u8f6c\u53d8\u4e3a\u5747\u76f8\u7ed3\u6784\u3002\u6700\u7ec8\uff0c\u5236\u5907\u5f97\u5230\u751f\u957fCoNi-MOF\u7684\u590d\u5408\u78b3\u7ea4\u7ef4\u7eb8\uff08CoNi-MOF\/CFP\uff09\u3002\u76f8\u6bd4\u4e8eNi-MOF\u7c89\u672b\u7535\u6781\u6750\u6599\uff0cCoNi-MOF\/CFP\u7535\u6781\u5728\u6df7\u5408\u8d85\u7ea7\u7535\u5bb9\u5668\u4e2d\u8868\u73b0\u51fa\u66f4\u4f18\u5f02\u7684\u7535\u5316\u5b66\u6027\u80fd\uff0c\u8be5\u7535\u6781\u7684\u6bd4\u7535\u5bb9\u9ad8\u8fbe1044 F g-1<\/sup>\uff0c\u7ec4\u88c5\u7684CoNi-MOF\/\/AC\u6df7\u5408\u8d85\u7ea7\u7535\u5bb9\u5668\u7684\u529f\u7387\u5bc6\u5ea6\u4e3a1500 W kg-1<\/sup>\u65f6\u6700\u5927\u80fd\u91cf\u5bc6\u5ea6\u9ad8\u8fbe28.5 Wh kg-1<\/sup>\uff0c\u80fd\u91cf\u5bc6\u5ea6\u7ef4\u6301\u572813.3 Wh kg-1<\/sup>\u65f6\u6700\u5927\u529f\u7387\u5bc6\u5ea6\u9ad8\u8fbe2400 W kg-1<\/sup>\u3002<\/p>\n
\n \u56fe1 CoNi-MOF\u7684\u5236\u5907\u6d41\u7a0b\u53caNi-MOF\u3001CFP\u3001Co(OH)2<\/sub>\u3001CoNi-MOF\u7684\u8868\u5f81<\/strong><\/p>\n<\/p>\n
<\/p>\n
<\/p>\n
\n \u90d1\u4f1f\u6d9b\u6559\u6388\u7684\u56e2\u961f\u957f\u671f\u81f4\u529b\u4e8e\u9ad8\u6027\u80fd\u50a8\u80fd\u6750\u6599\u7684\u8bbe\u8ba1\u4e0e\u5408\u6210\u7814\u7a76\uff0c\u6b64\u524d\u5df2\u5728\u300a\u81ea\u7136-\u901a\u8baf\u300b\u3001\u300a\u5148\u8fdb\u80fd\u6e90\u6750\u6599\u300b\u3001\u300a\u5148\u8fdb\u529f\u80fd\u6750\u6599\u300b\u3001\u300a\u5c16\u7aef\u79d1\u5b66\u300b\u7b49\u56fd\u9645\u91cd\u8981\u671f\u520a\u53d1\u5e03\u76f8\u5173\u8fdb\u5c55\u62a5\u544a\u548c\u4e13\u9898\u8bc4\u8ff0\uff0c\u70b9\u6211\u4e86\u89e3\u66f4\u591a\u8be6\u60c5<\/a>\u3002<\/p>\n
\n 1. T. Deng, W. Zhang*, O. Arcelus, J.-G. Kim, J. Carrasco, S. J. Yoo, W.T. Zheng*, J. Wang, H. Tian, H. Zhang, X. Cui, T. Rojo Atomic-level energy storage mechanism of cobalt hydroxide electrode for pseudocapacitors. Nature Communications, 2017, 8, 15194. (Editor’s Recommendation)
\n 2. T. Deng, Y. Lu, W. Zhang*, M.L. Sui, X.Y. Shi, D. Wang, W.T. Zheng*, Inverted Design for High-performance Supercapacitor via Co(OH)2<\/sub>-Derived Highly-oriented MOF Electrodes. Adv Energy Mater, 2017, 7, 1702294.
\n 3. D. Wang, W. Zhang*, W.T. Zheng*, X.Q. Cui, T. Rojo, Q. Zhang*, Towards High-Safe Lithium Metal Anodes: Suppressing Lithium Dendrites via Tuning Surface Energy. Adv Sci, 2017, 5, 1600168.
\n (Hottest Paper in Modelling & Simulations, Progress Report, ESI\u9ad8\u88ab\u5f15\u7528\u8bba\u6587)
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