{"id":114337,"date":"2017-12-03T06:30:57","date_gmt":"2017-12-02T22:30:57","guid":{"rendered":"\/\/m.iemloyee.com\/?p=114337"},"modified":"2017-12-01T21:50:54","modified_gmt":"2017-12-01T13:50:54","slug":"corros-sci-%ef%bc%9a%e9%80%9a%e8%bf%87%e8%bf%b7%e5%ae%ab%e6%95%88%e5%ba%94%e5%92%8c%e9%92%9d%e5%8c%96%e4%bd%9c%e7%94%a8%e5%8d%8f%e5%90%8c%e5%a2%9e%e5%bc%ba%e9%98%b2%e8%85%90","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=114337","title":{"rendered":"Corros. Sci.\uff1a\u901a\u8fc7\u201c\u8ff7\u5bab\u6548\u5e94\u201d\u548c\u949d\u5316\u4f5c\u7528\u534f\u540c\u589e\u5f3a\u9632\u8150\u6027\u80fd\u7684\u6709\u673a\u7eb3\u7c73\u590d\u5408\u6d82\u5c42"},"content":{"rendered":"<p><strong>\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n<p>\u6709\u673a\u6d82\u5c42\u5728\u91d1\u5c5e\u6750\u6599\u7684\u9632\u8150\u8680\u9886\u57df\u5f97\u5230\u4e86\u5e7f\u6cdb\u5e94\u7528\uff0c\u5b83\u53ef\u6709\u6548\u5730\u4fdd\u62a4\u91d1\u5c5e\u57fa\u6750\u514d\u53d7\u8150\u8680\u3002\u7136\u800c\uff0c\u5355\u7eaf\u7684\u6709\u673a\u6d82\u5c42\u5e76\u4e0d\u662f\u4e00\u4e2a\u5b8c\u7f8e\u7684\u7269\u7406\u5c4f\u969c\uff0c\u6d82\u5c42\u5728\u6210\u819c\u8fc7\u7a0b\u4e2d\u6eb6\u5242\u7684\u6325\u53d1\u53ef\u80fd\u5bfc\u81f4\u6d82\u5c42\u5185\u4ea7\u751f\u5fae\u5b54\u548c\u9488\u5b54\u7b49\u7f3a\u9677\uff0c\u8fd9\u4f7f\u5f97\u6d82\u5c42\u5bf9\u8150\u8680\u4ecb\u8d28\u5b58\u5728\u6e17\u900f\u6027\u3002\u53e6\u5916\uff0c\u6709\u673a\u6d82\u5c42\u957f\u65f6\u95f4\u5730\u66b4\u9732\u5728\u8150\u8680\u73af\u5883\u4e2d\uff0c\u7531\u4e8e\u6d82\u5c42\u7ec4\u5206\u7684\u6d78\u51fa\u4e5f\u4f1a\u5bfc\u81f4\u5b54\u9699\u5f62\u6210\uff0c\u4ece\u800c\u52a0\u901f\u6d82\u5c42\u635f\u4f24\u548c\u91d1\u5c5e\u57fa\u5e95\u7684\u8150\u8680\u3002\u76ee\u524d\uff0c\u5df2\u7ecf\u5c1d\u8bd5\u4e86\u5404\u79cd\u65b9\u6cd5\u6765\u6539\u5584\u6709\u673a\u6d82\u5c42\u7684\u963b\u9694\u6027\u80fd\u3002\u5176\u4e2d\uff0c\u7eb3\u7c73\u586b\u6599\u80fd\u6709\u6548\u5730\u6539\u5584\u6709\u673a\u6d82\u5c42\u7684\u9632\u8150\u8680\u6027\u80fd\u3002\u516d\u65b9\u6c2e\u5316\u787c(h-BN)\u88ab\u79f0\u4e3a\u201c\u767d\u8272\u77f3\u58a8\u70ef\u201d\uff0c\u5177\u6709\u7c7b\u4f3c\u4e8e\u77f3\u58a8\u70ef\u7684\u5c42\u72b6\u7ed3\u6784\u7279\u5f81\u548c\u7c7b\u4f3c\u6027\u80fd\u5982\u9ad8\u6297\u6e17\u6027\uff0c\u673a\u68b0\u6027\u80fd\u548c\u5bfc\u70ed\u6027\u3002\u6b64\u5916\uff0c\u4e0e\u5bfc\u7535\u6027\u77f3\u58a8\u70ef\u76f8\u6bd4\uff0ch-BN\u7684\u4f18\u826f\u7684\u7535\u7edd\u7f18\u6027\u4f7f\u5f97h-BN\u4e0e\u4e0b\u5c42\u91d1\u5c5e\u57fa\u4f53\u4e4b\u95f4\u53d1\u751f\u7535\u5076\u8150\u8680\u7684\u53ef\u80fd\u6027\u5f88\u5c0f\u3002\u7136\u800c\uff0c\u76f8\u6bd4\u4e8e\u77f3\u58a8\u70ef\u5728\u9632\u8150\u6d82\u5c42\u5f15\u8d77\u7684\u5e7f\u6cdb\u5173\u6ce8\uff0ch-BN\u5bf9\u91d1\u5c5e\u957f\u671f\u6297\u8680\u6027\u80fd\u7684\u7814\u7a76\u62a5\u9053\u5f88\u5c11\u3002<\/p>\n<p><strong>\u3010\u6210\u679c\u7b80\u4ecb\u3011 <\/strong><\/p>\n<p>\u8fd1\u671f\uff0c<strong>\u4e2d\u56fd\u79d1\u5b66\u9662\u5b81\u6ce2\u6750\u6599\u6280\u672f\u4e0e\u5de5\u7a0b\u7814\u7a76\u6240\u738b\u7acb\u5e73\u7814\u7a76\u5458\u3001\u8d75\u6d77\u8d85\u7814\u7a76\u5458\uff08\u5171\u540c\u901a\u8baf\u4f5c\u8005\uff09<\/strong>\u7b49\u4eba\u5728h-BN\u6539\u6027\u91cd\u9632\u8150\u6d82\u5c42\u65b9\u9762\u7684\u53d6\u5f97\u4e86\u8fdb\u5c55\uff0c\u8be5\u5c0f\u7ec4\u5229\u7528\u53ef\u6eb6\u6027\u5bfc\u7535\u805a\u5408\u7269\u805a(2-\u4e01\u57fa\u82ef\u80fa)(PBA)\u5c06\u5c42\u53e0\u7684h-BN\u7c89\u672b\u5265\u79bb\u83b7\u5f97\u4e86\u5c11\u5c42\u7684h-BN\u7eb3\u7c73\u7247\uff0c\u5e76\u4e14\u5c06\u5176\u52a0\u5165\u73af\u6c27\u6d82\u5c42\u4e2d\u5236\u5907\u5bfc\u7535\u805a\u5408\u7269\u548ch-BN\u534f\u540c\u589e\u5f3a\u7684\u7eb3\u7c73\u590d\u5408\u6d82\u5c42\u3002\u7ed3\u679c\u8868\u660e\uff0c\u7531\u4e8eh-BN\u7684\u201c\u8ff7\u5bab\u6548\u5e94\u201d\u548cPBA\u5bf9\u91d1\u5c5e\u57fa\u5e95\u7684\u949d\u5316\u4f5c\u7528\uff0c\u4f7f\u5f97\u5236\u5907\u7684\u590d\u5408\u6d82\u5c42\u5177\u6709\u9ad8\u963b\u6297\u6a21\u91cf\u548c\u4f4e\u5438\u6c34\u6027\uff0c\u8fdb\u800c\u8868\u73b0\u51fa\u4f18\u5f02\u7684\u963b\u9694\u548c\u8150\u8680\u9632\u62a4\u6027\u80fd\u3002\u76f8\u5173\u7814\u7a76\u6210\u679c\u4ee5\u201c<strong>Processable Poly(2-butylaniline)\/Hexagonal Boron Nitride Nanohybrids for Synergetic Anticorrosive Reinforcement of Epoxy Coating\u201d<\/strong>\u4e3a\u9898\u53d1\u5e03\u5728\u8150\u8680\u79d1\u5b66\u7684\u6743\u5a01\u671f\u520a<strong>Corrosion Science<\/strong>\u4e0a\u3002<\/p>\n<p><strong>\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n<p><strong>\u56fe1.\u501f\u52a9PBA\u5c06h-BN\u5206\u6563\u5728\u56db\u6c22\u544b\u5583(THF)\u4e2d\u7684\u793a\u610f\u56fe\u53caPBA\u3001h-BN\u7684\u5f62\u8c8c\u7ed3\u6784\u8868\u5f81<\/strong>\u00a0<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-114357\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/11\/1-6.gif\" alt=\"\" width=\"550\" height=\"622\" \/><\/p>\n<p>(a) (\u5de6)\u5728THF\u4e2d\u7684h-BN; (\u53f3)\u5728PBA\u7684\u8f85\u52a9\u4e0b\uff0c\u5728THF\u4e2d\u7684h-BN<\/p>\n<p>(b) PBA\u7684SEM\u7167\u7247<\/p>\n<p>(c\uff0cd\uff0ce) \u5265\u79bb\u7684h-BN\u7684TEM\uff0cHRTEM\u548c\u7535\u5b50\u884d\u5c04\u56fe\u50cf<\/p>\n<p>(f)\u5265\u79bb\u7684h-BN\u7684SPM\u56fe\u50cf<\/p>\n<p><strong>\u56fe2.\u7eb3\u7c73\u590d\u5408\u6d82\u5c42\u7684\u8868\/\u65ad\u9762\u5f62\u8c8c<\/strong><\/p>\n<p><strong>1\uff09\u8868\u9762\u5f62\u8c8c<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-114358\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/11\/2-4.gif\" alt=\"\" width=\"700\" height=\"525\" \/><\/p>\n<p style=\"text-align: left;\">(a)\u7eaf\u73af\u6c27\u6811\u8102 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 (b) BN<sub>0.5<\/sub>EC<\/p>\n<p style=\"text-align: left;\">(c) BN<sub>1.0<\/sub>EC \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0(d) BN<sub>2.0<\/sub>EC<\/p>\n<p>\uff08\u6ce8BN<span style=\"font-size: 13.3333px;\"><sub>x<\/sub><\/span>EC\u4e2dx\u8868\u793a\u7684\u610f\u4e49\u4e3a\u73af\u6c27\u7eb3\u7c73\u590d\u5408\u6d82\u5c42\u4e2dh-BN\u7eb3\u7c73\u7247\u7684\u542b\u91cf\uff1a\u5982\u4ee5\u76f8\u4f3c\u7684\u65b9\u5f0f\u5236\u5907\u5177\u6709\u4e0d\u540c\u542b\u91cf\u7684h-BN\u7eb3\u7c73\u7247\uff080.5wt\uff05\uff0c1.0wt\uff05\u548c2.0wt\uff05\uff09\u7684\u73af\u6c27\u7eb3\u7c73\u590d\u5408\u6d82\u5c42\uff0c\u547d\u540d\u4e3a\u7eaf\u73af\u6c27\u6811\u8102\uff0c\u8bb0\u4e3aBN<sub>0.5<\/sub>EC\uff0cBN<sub>1.0<\/sub>EC\u548cBN<sub>2.0<\/sub>EC\uff09<\/p>\n<p><strong>2\uff09\u65ad\u9762\u5f62\u8c8c<\/strong><\/p>\n<p style=\"text-align: center;\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-114359\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/11\/2-2-1.gif\" alt=\"\" width=\"700\" height=\"704\" \/><\/p>\n<p style=\"text-align: left;\">(a)\u7eaf\u73af\u6c27\u6811\u8102 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 (b)BN0.5EC<\/p>\n<p style=\"text-align: left;\">(c)BN1.0EC \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 (d)BN2.0EC<\/p>\n<p><strong>\u56fe3. OCP\u6d4b\u8bd5\u7ed3\u679c<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-114360\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/11\/3-4.gif\" alt=\"\" width=\"700\" height=\"262\" \/><br \/>\n (a)\u6d78\u6ce14\u5929\u540e\uff0cEIS\u6d4b\u91cf\u524d\u540e\u8fde\u7eed\u6d4b\u91cf30\u5206\u949f\u7684OCP<\/p>\n<p>(b)\u968f\u6d78\u6ce1\u65f6\u95f4\u53d8\u5316\u7684\u4e0d\u540c\u6d82\u5c42\/\u94a2\u7cfb\u7edf\u7684OCP\u503c<\/p>\n<p><strong>\u56fe4. \u7eaf\u73af\u6c27\u6811\u8102\u4e0d\u540c\u6d78\u6ce1\u65f6\u95f4\u7684EIS\u7ed3\u679c\u548c\u76f8\u5e94\u7684\u7b49\u6548\u7535\u8def(EECs)<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-114361\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/11\/4-4.gif\" alt=\"\" width=\"697\" height=\"568\" \/>\u00a0<br \/>\n (a\u548cb)\u7eaf\u73af\u6c27\u6811\u8102\u57283.5wt\uff05NaCl\u6eb6\u6db2\u4e2d\u6d78\u6ce1\u4e0d\u540c\u65f6\u95f4\u7684\u6ce2\u7279\u56fe(\u5b9e\u7ebf\u548c\u6563\u70b9\u5206\u522b\u4ee3\u8868\u62df\u5408\u548c\u5b9e\u9a8c\u6570\u636e)<\/p>\n<p>(c\u548cd)\u5bf9\u5e94\u7684\u7b49\u6548\u7535\u8defEECs<\/p>\n<p><strong>\u56fe5. BNxEC\u4f53\u7cfb\u4e0d\u540c\u6d78\u6ce1\u65f6\u95f4\u7684EIS\u7ed3\u679c\u548c\u76f8\u5e94\u7684\u7b49\u6548\u7535\u8def(EECs)<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-114362\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/11\/5-5.gif\" alt=\"\" width=\"498\" height=\"831\" \/><br \/>\n (a-f)BNxEC\u6d82\u5c42\u57283.5wt\uff05NaCl\u6eb6\u6db2\u4e2d\u6d78\u6ce1\u4e0d\u540c\u65f6\u95f4\u7684\u6ce2\u7279\u56fe(a \/ b\uff1aBN0.5EC; c \/ d\uff1aBN1.0EC; e \/ f\uff1aBN2.0EC\uff1b)\u00a0<\/p>\n<p>(h)\u76f8\u5e94\u7684\u7b49\u6548\u7535\u8def(EEC)<\/p>\n<p><strong>\u56fe6.\u4e0d\u540c\u6d82\u5c42\/\u94a2\u7cfb\u7edf\u5728\u4e0d\u540c\u6d78\u6ce1\u65f6\u95f4\u4e0b\u7684\u7814\u7a76<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-114363\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/11\/6-4.gif\" alt=\"\" width=\"700\" height=\"268\" \/>\u00a0(a)Rc\u7684\u53d8\u5316<\/p>\n<p>(b)CPEc\u7684\u53d8\u5316\u8bef\u5dee\u68d2\u4e3aCPEc\u548cRc\u503c\u7684\u62df\u5408\u8bef\u5dee<\/p>\n<p><strong>\u56fe7. \u8150\u8680\u5f62\u8c8c\u53ca\u8150\u8680\u4ea7\u7269\u5206\u6790<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-114368\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/11\/7-4.gif\" alt=\"\" width=\"700\" height=\"1027\" \/>(a)\u7eaf\u73af\u6c27\u6811\u8102 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 (b)BN0.5EC<\/p>\n<p>(c)BN1.0EC \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 (d)BN2.0EC<\/p>\n<p>(e)\u4e0d\u540c\u6d82\u5c42\u6d82\u8986\u7684\u57fa\u5e95\u57283.5wt\uff05NaCl\u6eb6\u6db2\u4e2d\u957f\u65f6\u95f4\u8150\u8680\u540e\u7684XRD\u56fe\u8c31<\/p>\n<p><strong>\u56fe8.\u672a\u8150\u8680\u7684\u88f8\u57fa\u677f\u7684\u8868\u9762\u5f62\u6001<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-114369\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/11\/8-3.gif\" alt=\"\" width=\"700\" height=\"472\" \/><br \/>\n \u00a0(a)\u629b\u5149\u540e\u88f8\u94a2\u7684\u8868\u9762\u5f62\u8c8c<\/p>\n<p>(b)\u6d78\u6ce150\u5929\u540e\u7eaf\u73af\u6c27\u6d82\u8986\u57fa\u5e95\u7684\u8868\u9762\u5f62\u8c8c<\/p>\n<p>(c)\u6d78\u6ce1120\u5929\u540eBNxEC\u6d82\u8986\u57fa\u5e95\u7684\u8868\u9762\u5f62\u8c8c<\/p>\n<p>(d) \u56feb\u4e2d\u533a\u57df\u7684EDS\u56fe<\/p>\n<p><strong>\u56fe9.\u4e0d\u540c\u6d82\u5c42\u4e0e\u6d78\u6ce1\u65f6\u95f4\u4e4b\u95f4\u7684\u5438\u6c34\u66f2\u7ebf<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-114370\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/11\/9.gif\" alt=\"\" width=\"700\" height=\"518\" \/><\/p>\n<p><strong>\u56fe10. 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href=\"http:\/\/www.sciencedirect.com\/science\/article\/pii\/S0010938X1631304X\" target=\"_blank\" rel=\"noopener\">Processable Poly(2-butylaniline)\/Hexagonal Boron Nitride Nanohybrids for Synergetic Anticorrosive Reinforcement of Epoxy Coating<\/a> (Corrosion Science, doi: 10.1016\/j.corsci.2017.11.022)<\/p>\n<p>\u672c\u6587\u7531\u6750\u6599\u4eba\u7f16\u8f91\u90e8\u91d1\u5c5e\u6750\u6599\u5b66\u672f\u7ec4Nancy\u6574\u7406\u7f16\u8bd1\uff0c<a href=\"\/\/m.iemloyee.com\/25127.html\" target=\"_blank\" rel=\"noopener\">\u70b9\u6211\u52a0\u5165\u6750\u6599\u4eba\u7f16\u8f91\u90e8<\/a>\u3002<\/p>\n<p><strong>\u6750\u6599\u6d4b\u8bd5\uff0c\u6570\u636e\u5206\u6790\uff0c\u4e0a<a href=\"http:\/\/www.ceshigu.com\/\" target=\"_blank\" rel=\"noopener\">\u6d4b\u8bd5\u8c37<\/a>\uff01<\/strong><\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u3010\u5f15\u8a00\u3011 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