{"id":114281,"date":"2017-12-02T06:30:30","date_gmt":"2017-12-01T22:30:30","guid":{"rendered":"\/\/m.iemloyee.com\/?p=114281"},"modified":"2017-11-29T15:41:10","modified_gmt":"2017-11-29T07:41:10","slug":"%e6%b8%85%e5%8d%8eangew-chem-int-ed-%e8%b6%85%e5%88%86%e5%ad%90%e8%83%b6%e5%9b%8a%e7%94%a8%e4%ba%8e%e9%94%82%e7%a1%ab%e7%94%b5%e6%b1%a0%e4%b8%ad%e5%a4%9a%e7%a1%ab%e5%8c%96%e7%89%a9%e5%8f%af","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=114281","title":{"rendered":"\u6e05\u534eAngew. Chem. Int. Ed. : \u8d85\u5206\u5b50\u80f6\u56ca\u7528\u4e8e\u9502\u786b\u7535\u6c60\u4e2d\u591a\u786b\u5316\u7269\u53ef\u9006\u5b58\u50a8\/\u4f20\u9012"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n

\u8d85\u5206\u5b50\u6750\u6599\u662f\u7531\u6709\u673a\u7ed3\u6784\u5355\u5143\u4ee5\u975e\u5171\u4ef7\u76f8\u4e92\u4f5c\u7528\u7ec4\u88c5\u6210\u7684\u6709\u5e8f\u7ed3\u6784\uff0c\u5176\u5177\u6709\u4e30\u5bcc\u7684\u5b98\u80fd\u56e2\u3001\u53ef\u8c03\u63a7\u7684\u7a7a\u95f4\u7ed3\u6784\u548c\u73af\u5883\u53cb\u597d\u7684\u7279\u6027\uff0c\u5438\u5f15\u4e86\u5e7f\u6cdb\u7684\u5173\u6ce8\u3002\u53d7\u591a\u79cd\u5206\u5b50\u95f4\u3001\u5206\u5b50\u5185\u76f8\u4e92\u4f5c\u7528\u7684\u9a71\u52a8\uff0c\u8d85\u5206\u5b50\u6750\u6599\u7ec4\u88c5\u4e0d\u4ec5\u5728\u6709\u673a\u5316\u5b66\u4e2d\u6709\u91cd\u8981\u7684\u610f\u4e49\uff0c\u800c\u4e14\u5728\u9762\u5411\u672a\u6765\u53ef\u6301\u7eed\u53d1\u5c55\u7684\u5927\u91cf\u524d\u6cbf\u5e94\u7528(\u5982\u9009\u62e9\u6027\u5438\u9644\u548c\u667a\u80fd\u80fd\u6e90\u5b58\u50a8)\u7684\u6750\u6599\u8bbe\u8ba1\u4e2d\u626e\u6f14\u7740\u81f3\u5173\u91cd\u8981\u7684\u89d2\u8272\u3002\u5c31\u50a8\u80fd\u8fd9\u4e00\u5e94\u7528\u6765\u8bf4\uff0c\u8d85\u5206\u5b50\u6750\u6599\u4e0d\u4ec5\u53ef\u76f4\u63a5\u4f5c\u4e3a\u5668\u4ef6\uff0c\u4e5f\u53ef\u7528\u4e8e\u5236\u5907\u7535\u6781\u6750\u6599\u3002\u7531\u4e8e\u5176\u4f18\u8d8a\u7684\u5316\u5b66\u53ef\u8c03\u63a7\u6027\u3001\u5f62\u8c8c\u7ed3\u6784\u7684\u591a\u6837\u6027\u548c\u52a8\u6001\u9002\u5e94\u6027\uff0c\u8d85\u5206\u5b50\u6750\u6599\u5728\u8c03\u63a7\u590d\u6742\u8f93\u8fd0\u73b0\u8c61\u548c\u53cd\u5e94\u673a\u7406\u7b49\u65b9\u9762\u5177\u6709\u72ec\u7279\u7684\u4f18\u52bf\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u6e05\u534e\u5927\u5b66\u5f20\u5f3a\u6559\u6388(\u901a\u8baf\u4f5c\u8005)\u7b49<\/strong>\u4ecb\u7ecd\u4e86\u4ee5\u846b\u82a6\u8132(CB)\u4f5c\u4e3a\u8d85\u5206\u5b50\u80f6\u56ca\u7528\u4e8e\u9502\u786b(Li-S)\u7535\u6c60\u4e2d\u53ef\u6eb6\u6027\u591a\u786b\u5316\u7269\u7684\u53ef\u9006\u5b58\u50a8\/\u91ca\u653e\u8fc7\u7a0b\uff0c\u4ee5\u63a7\u5236\u591a\u786b\u5316\u7269\u5206\u5b50\u7684\u6eb6\u89e3\uff0c\u5e76\u5728Angew. Chem. Int. Ed.<\/strong>\u4e0a\u53d1\u8868\u4e86\u9898\u4e3a\u201cA Supramolecular Capsule for Reversible Polysulfide Storage\/Delivery in Lithium-Sulfur Batteries<\/strong>\u201d\u7684\u7814\u7a76\u8bba\u6587\u3002\u4f7f\u7528\u8d85\u5206\u5b50\u80f6\u56ca\u9694\u819c\u6d82\u5c42\u7684Li-S\u7535\u6c60\u5177\u6709\u8f83\u9ad8\u7684\u5e93\u4ed1\u6548\u7387\uff0c\u57284.2 mg\u00b7cm-2<\/sup>\u786b\u8d1f\u8f7d\u91cf\u4e0b\u5bb9\u91cf\u7531300 mAh\u00b7g-1<\/sup>\u589e\u81f3900 mAh\u00b7g-1<\/sup>\uff0c\u6027\u80fd\u63d0\u5347\u660e\u663e\u3002\u8d85\u5206\u5b50\u80f6\u56ca\u7684\u5e94\u7528\u4e3a\u6df1\u5165\u7406\u89e3\u590d\u6742\u591a\u7535\u5b50\u8f6c\u5316\u53cd\u5e94\u63d0\u4f9b\u4e86\u65b0\u7684\u89c6\u89d2\uff0c\u662f\u4e00\u79cd\u63d0\u5347Li-S\u7535\u6c60\u4ee5\u53ca\u7c7b\u4f3c\u5e94\u7528\u4f53\u7cfb\u6027\u80fd\u7684\u9ad8\u6548\u7b56\u7565\u3002<\/p>\n

\u3010\u56fe\u6587\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u56fe1 \u8d85\u5206\u5b50\u80f6\u56ca\u7684\u793a\u610f\u56fe<\/strong><\/p>\n

\"\"<\/p>\n

a) \u5177\u6709G@CB\u63d2\u5c42\u7684Li-S\u7535\u6c60\u793a\u610f\u56fe\uff1b<\/p>\n

b) \u5728\u9002\u5b9c\u7684CB\u5b54\u9053\u4e2d\u591a\u786b\u5316\u7269\u7684\u53ef\u9006\u5b58\u50a8\/\u91ca\u653e\uff1b<\/p>\n

c) \u4e0d\u540c\u6750\u6599\u5438\u9644\u539f\u5b50\u66b4\u9732\u6bd4\u7684\u6bd4\u8f83\u3002<\/p>\n

\u56fe2 \u591a\u786b\u5316\u7269\u5728\u846b\u82a6\u8132\u4e2d\u7684\u5438\u9644\/\u89e3\u5438\u73b0\u8c61<\/strong><\/p>\n

\"\"<\/p>\n

a) CB-Li2<\/sub>S6<\/sub>\u3001\u539f\u59cbCB\u548c\u6eb6\u89e3\u4e8eDME\u7684Li2<\/sub>S6<\/sub>\u7684Raman\u5149\u8c31\uff1b<\/p>\n

b) \u539f\u59cbCB\u3001DME\u6eb6\u80c0\u7684CB\u3001\u5438\u9644\/\u8131\u9644\u4e86Li2<\/sub>S4<\/sub>\u7684CB\u7684XRD\u8c31\u56fe\uff1b<\/p>\n

c) \u591a\u786b\u5316\u7269\u201c\u547c\u5438\u201d\u793a\u610f\u56fe\u3002<\/p>\n

\u56fe3 G@CB \u63d2\u5c42\u7684\u5f62\u6001\u8868\u5f81<\/strong><\/p>\n

\"\"<\/p>\n

a,b) G@CB\u7684SEM\u56fe\u50cf\uff1b<\/p>\n

c) G@CB\u7684TEM\u56fe\u50cf\uff1b<\/p>\n

d) G@CB\u7684\u6c2e\u5143\u7d20\u5206\u5e03\uff1b<\/p>\n

e) CB\u548cG@CB\u7684XRD\u8c31\u56fe\u3002<\/p>\n

\u56fe4 \u6750\u6599\u7684\u7535\u5316\u5b66\u6027\u80fd\u6bd4\u8f83<\/strong><\/p>\n

\"\"<\/p>\n

a) \u7535\u6d41\u5bc6\u5ea60.5 C\u65f6\u7684\u5faa\u73af\u6027\u80fd\uff0c\u4e0a\u56fe\u4e3a\u5bb9\u91cf\uff0c\u4e0b\u56fe\u4e3a\u5e93\u4ed1\u6548\u7387\uff1b<\/p>\n

b) Li-S\u7535\u6c60\u7684\u500d\u7387\u6027\u80fd(\u786b\u8d1f\u8f7d\u91cf\uff1a1.0 mg\u00b7cm-2<\/sup>)\uff1b<\/p>\n

c) \u7535\u6d41\u5bc6\u5ea60.1 C\u65f6\uff0c\u9ad8\u786b\u8d1f\u8f7d\u91cfLi-S\u7535\u6c60\u5faa\u73af\u6027\u80fd(\u786b\u8d1f\u8f7d\u91cf\uff1a4.2 mg\u00b7cm-2<\/sup>)\u3002<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n

\u8be5\u7814\u7a76\u5236\u5907\u4e86\u4e00\u79cd\u8d85\u5206\u5b50\u80f6\u56ca\uff0c\u5229\u7528\u8d85\u5206\u5b50\u80f6\u56ca\u5bf9\u591a\u786b\u5316\u7269\u7684\u5b58\u50a8\/\u91ca\u653e\uff0c\u5c06\u5176\u7528\u4e8eLi-S\u7535\u6c60\u3002\u5176\u4e2d\u7684\u8d85\u5206\u5b50\u846b\u82a6\u8132\u5177\u6709\u4e30\u5bcc\u7684\u66b4\u9732\u5438\u9644\u4f4d\u70b9\uff0c\u5bf9\u4e8e\u591a\u786b\u5316\u7269\u5177\u6709\u8f83\u5f3a\u7684\u5438\u9644\u80fd\u529b\u3002\u540c\u65f6\uff0c\u5c06\u534a\u5f84\u7ea615 nm\u7684\u846b\u82a6\u8132\u7eb3\u7c73\u80f6\u56ca\u6c89\u79ef\u4e8e\u77f3\u58a8\u70ef\u8868\u9762\uff0c\u53ef\u5b9e\u73b0\u52a8\u529b\u5b66\u6027\u80fd\u7684\u63d0\u5347\u3002\u56e0\u6b64\uff0cLi-S\u7535\u6c60\u4e2d\u591a\u786b\u5316\u7269\u7684\u6eb6\u89e3\u6269\u6563\u53d7\u5230\u9650\u5236\uff0c\u5373\u4f7f\u5728\u9ad8\u786b\u8d1f\u8f7d\u7387\u6216\u9ad8\u500d\u7387\u4e0b\uff0c\u6027\u80fd\u3001\u5faa\u73af\u7a33\u5b9a\u6027\u548c\u5e93\u4ed1\u6548\u7387\u4ecd\u8f83\u9ad8\u3002\u8be5\u7814\u7a76\u662f\u5bf9\u529f\u80fd\u8d85\u5206\u5b50\u6750\u6599\u7684\u4e00\u79cd\u65b0\u9896\u7684\u5c1d\u8bd5\uff0c\u4e5f\u4e3a\u5148\u8fdbLi-S\u7535\u6c60\u548c\u7c7b\u4f3c\u5e94\u7528\u7684\u6750\u6599\u9009\u62e9\u548c\u7ed3\u6784\u8bbe\u8ba1\u63d0\u4f9b\u4e86\u65b0\u89c1\u89e3\u548c\u65b0\u601d\u8def\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1aA Supramolecular Capsule for Reversible Polysulfide Storage\/Delivery in Lithium-Sulfur Batteries<\/a><\/strong>\u00a0(Angew. Chem. Int. Ed., 2017, DOI: 10.1002\/anie.201710025)<\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u7f16\u8f91\u90e8\u65b0\u80fd\u6e90\u5c0f\u7ec4abc940504\u7f16\u8bd1\u6574\u7406\uff0c\u53c2\u4e0e\u65b0\u80fd\u6e90\u8bdd\u9898\u8ba8\u8bba\u8bf7\u52a0\u5165\u201c\u6750\u6599\u4eba\u65b0\u80fd\u6e90\u6750\u6599\u4ea4\u6d41\u7fa4 422065953\u201d\u3002<\/p>\n

\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1aRDD-2011-CHERISH\uff0c\u4efb\u4e39\u4e39\uff0c\u6211\u4eec\u4f1a\u9080\u8bf7\u5404\u4f4d\u8001\u5e08\u52a0\u5165\u4e13\u5bb6\u7fa4\u3002<\/strong><\/p>\n

\u6750\u6599\u725b\u7f51\u4e13\u6ce8\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u53ca\u884c\u4e1a\u8fdb\u5c55\uff0c\u5982\u679c\u60a8\u5bf9\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u8fdb\u5c55\uff0c\u89e3\u8bfb\u9ad8\u6c34\u5e73\u6587\u7ae0\u6216\u662f\u8bc4\u8ff0\u884c\u4e1a\u6709\u5174\u8da3\uff0c\u70b9\u6211\u52a0\u5165\u7f16\u8f91\u90e8<\/a><\/strong>\u3002\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1tougao@cailiaoren.com\u3002<\/p>\n

\u4eea\u5668\u8bbe\u5907\u3001\u8bd5\u5242\u8017\u6750\u3001\u6750\u6599\u6d4b\u8bd5\u3001\u6570\u636e\u5206\u6790\uff0c\u627e\u6750\u6599\u4eba<\/a><\/strong>\u3001\u4e0a\u6d4b\u8bd5\u8c37<\/a><\/strong>\uff01<\/p>\n","protected":false},"excerpt":{"rendered":"

\u3010\u5f15\u8a00\u3011 \u8d85\u5206\u5b50\u6750\u6599\u662f\u7531\u6709\u673a\u7ed3\u6784\u5355\u5143\u4ee5\u975e\u5171\u4ef7\u76f8\u4e92\u4f5c\u7528\u7ec4\u88c5\u6210\u7684\u6709\u5e8f\u7ed3\u6784\uff0c\u5176\u5177\u6709\u4e30\u5bcc\u7684\u5b98\u80fd\u56e2\u3001\u53ef\u8c03\u63a7\u7684\u7a7a\u95f4\u7ed3\u6784\u548c\u73af\u5883\u53cb\u597d\u7684\u7279\u6027\uff0c\u5438\u5f15\u4e86\u5e7f\u6cdb\u7684\u5173\u6ce8\u3002\u53d7\u591a\u79cd\u5206\u5b50\u95f4\u3001\u5206\u5b50…<\/p>\n","protected":false},"author":4931,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[],"class_list":["post-114281","post","type-post","status-publish","format-standard","hentry","category-jiedu"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/114281"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/4931"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=114281"}],"version-history":[{"count":7,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/114281\/revisions"}],"predecessor-version":[{"id":114719,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/114281\/revisions\/114719"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=114281"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=114281"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=114281"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}