{"id":114263,"date":"2017-12-02T14:00:26","date_gmt":"2017-12-02T06:00:26","guid":{"rendered":"\/\/m.iemloyee.com\/?p=114263"},"modified":"2017-11-29T15:38:51","modified_gmt":"2017-11-29T07:38:51","slug":"%e5%8c%97%e5%a4%a7adv-funct-mater-%ef%bc%9a%e9%94%82%e7%a6%bb%e5%ad%90%e7%94%b5%e6%b1%a0%e9%98%b4%e7%a6%bb%e5%ad%90%e6%b0%a7%e5%8c%96%e8%bf%98%e5%8e%9f%e8%bf%87%e7%a8%8b%e4%b8%ad%e7%94%b5%e8%8d%b7","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=114263","title":{"rendered":"\u5317\u5927Adv. Funct. Mater.\uff1a\u9502\u79bb\u5b50\u7535\u6c60\u9634\u79bb\u5b50\u6c27\u5316\u8fd8\u539f\u8fc7\u7a0b\u4e2d\u7535\u8377\u8f6c\u79fb\u7684\u70ed\u529b\u5b66\u6d3b\u5316"},"content":{"rendered":"

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\u8fd1\u65e5\uff0c\u5317\u4eac\u5927\u5b66\u590f\u5b9a\u56fd\u6559\u6388\uff08\u901a\u8baf\u4f5c\u8005\uff09<\/strong>\u8868\u660e\u7535\u5316\u5b66\u60f0\u6027\u7684\u7acb\u65b9\u5ca9\u76d0\u76f8Li2<\/sub>TiO3<\/sub>\u5728\u7ecf\u8fc7Fe3+<\/sup>\u7684\u63ba\u6742\u540e\uff0c\u8868\u73b0\u51fa\u663e\u8457\u7684\u9634\u79bb\u5b50\uff08\u6c27\u79bb\u5b50\uff09\u6c27\u5316\u8fd8\u539f\u6d3b\u6027\uff0c\u4ece\u800c\u91ca\u653e\u51fa250mAh\/g\u7684\u6bd4\u5bb9\u91cf\u3002\u7b2c\u4e00\u6027\u539f\u7406\u8ba1\u7b97\u53d1\u73b0\u8131\u9502\u65f6\u7535\u5b50\u7a7a\u7a74\u66f4\u503e\u5411\u4e8e\u9009\u62e9\u6027\u5730\u4ea7\u751f\u5728\u4e0eFe\u76f8\u8fde\u7684\u6c27\u79bb\u5b50\u800c\u975e\u4e0eTi\u76f8\u8fde\u7684\u6c27\u79bb\u5b50\u4e0a\u3002\u8fdb\u4e00\u6b65\u5206\u6790\u8868\u660e\uff0c\u5bf9\u4e8e\u9634\u79bb\u5b50\u6c27\u5316\u8fd8\u539f\u7535\u5b50\u8f6c\u79fb\u8fc7\u7a0b\uff0cd-d\u7535\u5b50\u4ea4\u6362\u4e0e\u5e93\u4ed1\u6392\u65a5\u80fd\uff08U<\/i><\/em>\uff09\u548cp-d\u7535\u8377\u8f6c\u79fb\u80fd\uff08\u0394<\/i><\/em>\uff09\u7684\u76f8\u5bf9\u5927\u5c0f\u51b3\u5b9a\u4e86\u7535\u8377\u8f6c\u79fb\u8def\u5f84\uff1a\u5373\u5f53U>D\u65f6\uff0c\u9634\u79bb\u5b50\u7684p\u7535\u5b50\u8f6c\u79fb\u624d\u88ab\u6fc0\u6d3b\uff0c\u4ece\u800c\u5b9e\u73b0\u9634\u79bb\u5b50\u6c27\u5316\u8fd8\u539f\u53cd\u5e94\u3002\u8fd9\u8fdb\u4e00\u6b65\u5728\u975e\u6d3b\u6027\u7684\u5c42\u72b6Li2<\/sub>TiS3<\/sub>\u4e2d\u5f97\u5230\u8bc1\u5b9e\uff0c\u901a\u8fc7\u63ba\u6742Co2+<\/sup>\u5f62\u6210Li1.2<\/sub>Ti0.6<\/sub>Co0.2<\/sub>S2<\/sub>\u80fd\u591f\u6fc0\u6d3b\u786b\u7684\u6c27\u5316\u8fd8\u539f\u8fc7\u7a0b\uff0c\u5e76\u5b9e\u73b0200mAh\/g\u7684\u5bb9\u91cf\uff0c\u800c\u4e14Co2+<\/sup>\u672c\u8eab\u4e0d\u53c2\u4e0e\u7535\u8377\u8f6c\u79fb\uff0cS\u662f\u552f\u4e00\u7684\u6c27\u5316\u8fd8\u539f\u53cd\u5e94\u4e2d\u5fc3\u3002\u8be5\u5de5\u4f5c\u9996\u6b21\u63ed\u793a\u4e86\u9502\u79bb\u5b50\u7535\u6c60\u6b63\u6781\u6750\u6599\u4e2d\u9634\u79bb\u5b50\u6c27\u5316\u8fd8\u539f\u53d1\u751f\u7684\u4e00\u822c\u6027\u673a\u5236\u3002\u76f8\u5173\u6210\u679c\u4ee5\u9898\u4e3a\u201cThermodynamic Activation of Charge Transfer in Anionic Redox Process for Li-Ion Batteries<\/strong>\u201d\u53d1\u8868\u5728\u4e86Advanced Functional Materials<\/strong>\u4e0a\u3002<\/p>\n

\u56fe1 \u8868\u5f81\u5206\u6790\"\"<\/strong><\/p>\n

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\u56fe4 <\/strong>S\u7684<\/b><\/strong>\u6c27\u5316\u8fd8\u539f\u53cd\u5e94<\/b><\/strong><\/p>\n

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c\uff09Li1.2<\/sub>Ti0.6<\/sub>Co0.2<\/sub>S2<\/sub>\u5728\u7b2c\u4e00\u6b21\u5faa\u73af\u548c\u7b2c\u4e8c\u6b21\u5faa\u73af\u5145\u7535\u671f\u95f4\u7684S\u7684K\u8fb9XAS\u5149\u8c31<\/p>\n

d\uff09Li1.2<\/sub>Ti0.6<\/sub>Co0.2<\/sub>S2<\/sub>\u548cTi0.6<\/sub>Co0.2<\/sub>S2<\/sub>\u4e4b\u95f4\u7684\u5dee\u5206\u7535\u8377\u5bc6\u5ea6\u56fe<\/p>\n

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\u6587\u732e\u94fe\u63a5\uff1a<\/strong>Thermodynamic Activation of Charge Transfer in Anionic Redox Process for Li-Ion Batteries<\/a>\uff08Adv. Funct. Mater.,2017,DOI: <\/span>10.1002\/adfm.201704864\uff09<\/span><\/p>\n

\u3010\u56e2\u961f\u4ecb\u7ecd\u3011<\/strong><\/p>\n

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\u848b\u5b81\u535a\u58eb<\/strong>\uff0c2016\u5e74\u535a\u58eb\u6bd5\u4e1a\u4e8e\u6e05\u534e\u5927\u5b66<\/p>\n

\u9ec4\u4f1f\u5cf0\u535a\u58eb<\/strong>\uff0c2015\u5e74\u535a\u58eb\u6bd5\u4e1a\u4e8e\u4e2d\u56fd\u79d1\u5b66\u6280\u672f\u5927\u5b66<\/p>\n

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\u901a\u8baf\u4f5c\u8005\u4e3a\u590f\u5b9a\u56fd\u6559\u6388<\/strong>\uff1a\u5317\u4eac\u5927\u5b66\u5de5\u5b66\u9662\u80fd\u6e90\u4e0e\u8d44\u6e90\u5de5\u7a0b\u7cfb&\u6750\u6599\u79d1\u5b66\u4e0e\u5de5\u7a0b\u7cfb\u6559\u6388, \u6559\u80b2\u90e8\u957f\u6c5f\u5b66\u8005\u7279\u8058\u6559\u6388\uff0c\u5148\u8fdb\u7535\u6c60\u6750\u6599\u7406\u8bba\u4e0e\u6280\u672f\u5317\u4eac\u5e02\u91cd\u70b9\u5b9e\u9a8c\u5ba4\u4e3b\u4efb\uff0c \u5728\u9502\u79bb\u5b50\u7535\u6c60\u6750\u6599\u3001\u71c3\u6599\u7535\u6c60\u50ac\u5316\u5242\u53ca\u6750\u6599\u5236\u5907\u7b49\u9886\u57df\u505a\u51fa\u4e86\u91cd\u8981\u6210\u7ee9\u3002\u5b8c\u6210\u56fd\u5bb6\u4e0e\u7701\u90e8\u7ea7\u8bfe\u989810\u4f59\u9879\uff1b\u83b7\u56fd\u5bb6\u53d1\u660e\u4e13\u522920\u9879\uff1b\u83b7\u5f97\u56fd\u5bb6\u79d1\u6280\u8fdb\u6b65\u4e8c\u7b49\u5956\u4e00\u9879\uff0c\u5317\u4eac\u5e02\u79d1\u5b66\u6280\u672f\u4e00\u7b49\u5956\u4e00\u9879\uff08\u57fa\u7840\u7c7b\uff09\u3002 \u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0<\/p>\n

\u3010\u56e2\u961f\u5728\u8be5\u9886\u57df\u5de5\u4f5c\u6c47\u603b\u3011<\/strong><\/p>\n

(1) Li, B.; Xia, D. Anionic Redox in Rechargeable Lithium Batteries. Advanced Materials 2017, DOI:10.1002\/adma.201701054 10.1002\/adma.201701054.<\/p>\n

(2) Li, B.; Shao, R.; Yan, H.; An, L.; Zhang, B.; Wei, H.; Ma, J.; Xia, D.; Han, X. Understanding the Stability for Li-Rich Layered Oxide Li2RuO3\u00a0Cathode. Advanced Functional Materials 2016,\u00a026\u00a0(9), 1330.<\/p>\n

(3) Li, B.; Yan, H.; Ma, J.; Yu, P.; Xia, D.; Huang, W.; Chu, W.; Wu, Z. Manipulating the Electronic Structure of Li-Rich Manganese-Based Oxide Using Polyanions: Towards Better Electrochemical Performance. Advanced Functional Materials 2014,\u00a024\u00a0(32), 5112.<\/p>\n

(4) Li, B.; Yan, H. J.; Zuo, Y. X.; Xia, D. G. Tuning the Reversibility of Oxygen Redox in Lithium-Rich Layered Oxides. Chemistry of Materials 2017,\u00a029\u00a0(7), 2811.<\/p>\n

(5) Yan, H.; Li, B.; Yu, Z.; Chu, W.; Xia, D. First-Principles Study: Tuning the Redox Behavior of Lithium-Rich Layered Oxides by Chlorine Doping. The Journal of Physical Chemistry C 2017,\u00a0121\u00a0(13), 7155.<\/p>\n

\u3010\u76f8\u5173\u4f18\u8d28\u6587\u732e\u63a8\u8350\u3011<\/strong><\/p>\n

(1) Sathiya, M.; Rousse, G.; Ramesha, K.; Laisa, C. P.; Vezin, H.; Sougrati, M. T.; Doublet, M. L.; Foix, D.; Gonbeau, D.; Walker, W.et al. Reversible anionic redox chemistry in high-capacity layered-oxide electrodes. Nature materials 2013,\u00a012\u00a0(9), 827.<\/p>\n

(2) McCalla, E.; Abakumov, A. M.; Saubanere, M.; Foix, D.; Berg, E. J.; Rousse, G.; Doublet, M. L.; Gonbeau, D.; Novak, P.; Van Tendeloo, G.et al. Visualization of O-O peroxo-like dimers in high-capacity layered oxides for Li-ion batteries. Science 2015,\u00a0350\u00a0(6267), 1516.<\/p>\n

(3) Pearce, P. E.; Perez, A. J.; Rousse, G.; Saubanere, M.; Batuk, D.; Foix, D.; McCalla, E.; Abakumov, A. M.; Van Tendeloo, G.; Doublet, M. L.et al. Evidence for anionic redox activity in a tridimensional-ordered Li-rich positive electrode beta-Li2IrO3. Nature materials 2017,\u00a016\u00a0(5), 580.<\/p>\n

(4) Seo, D. H.; Lee, J.; Urban, A.; Malik, R.; Kang, S.; Ceder, G. The structural and chemical origin of the oxygen redox activity in layered and cation-disordered Li-excess cathode materials. Nature chemistry 2016,\u00a08\u00a0(7), 692.<\/p>\n

(5) Luo, K.; Roberts, M. R.; Hao, R.; Guerrini, N.; Pickup, D. M.; Liu, Y. S.; Edstrom, K.; Guo, J.; Chadwick, A. V.; Duda, L. C.et al. Charge-compensation in 3d-transition-metal-oxide intercalation cathodes through the generation of localized electron holes on oxygen. Nature chemistry 2016,\u00a08\u00a0(7), 684.<\/p>\n

(6) Yabuuchi, N.; Nakayama, M.; Takeuchi, M.; Komaba, S.; Hashimoto, Y.; Mukai, T.; Shiiba, H.; Sato, K.; Kobayashi, Y.; Nakao, A.et al. Origin of stabilization and destabilization in solid-state redox reaction of oxide ions for lithium-ion batteries. Nat Commun 2016,\u00a07, 13814.<\/p>\n

(7) Sauban\u00e8re, M.; McCalla, E.; Tarascon, J. M.; Doublet, M. L. The intriguing question of anionic redox in high-energy density cathodes for Li-ion batteries. Energy Environ. Sci. 2016,\u00a09\u00a0(3), 984.<\/p>\n

(8) Xie, Y.; Sauban\u00e8re, M.; Doublet, M. L. Requirements for reversible extra-capacity in Li-rich layered oxides for Li-ion batteries. Energy Environ. Sci. 2017,\u00a010\u00a0(1), 266.<\/p>\n

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