{"id":113694,"date":"2017-11-25T06:30:53","date_gmt":"2017-11-24T22:30:53","guid":{"rendered":"\/\/m.iemloyee.com\/?p=113694"},"modified":"2017-11-24T13:13:17","modified_gmt":"2017-11-24T05:13:17","slug":"nature-chemistry%e9%87%8d%e7%a3%85-%e7%90%86%e8%ae%ba%e9%a2%84%e6%b5%8b%e5%92%8c%e5%8e%9f%e4%bd%8d%e5%90%8c%e6%ad%a5%e8%be%90%e5%b0%84%e5%ae%9e%e7%8e%b0%e7%94%b5%e5%82%ac%e5%8c%96%e4%ba%a7%e6%b0%a7","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=113694","title":{"rendered":"Nature Chemistry\u91cd\u78c5: \u7406\u8bba\u9884\u6d4b\u548c\u539f\u4f4d\u540c\u6b65\u8f90\u5c04\u5b9e\u73b0\u7535\u50ac\u5316\u4ea7\u6c27\u6d3b\u6027\u4f4d\u7684\u8c03\u63a7"},"content":{"rendered":"<p><b>\u3010\u5f15\u8a00\u3011<\/b><\/p>\n<p>\u5c06\u4e8c\u6c27\u5316\u78b3\u901a\u8fc7\u7535\u5316\u5b66\u8fd8\u539f\u6210\u589e\u503c\u7684\u71c3\u6599\u53ef\u4ee5\u51cf\u5c11\u5bf9\u4f20\u7edf\u5316\u77f3\u71c3\u6599\u7684\u4f9d\u8d56\uff0c\u5e76\u56e0\u6b64\u51cf\u7f13\u5bf9\u5916\u754c\u73af\u5883\u7684\u51c0CO<sub>2<\/sub>\u6392\u653e\uff0c \u5728\u7f13\u89e3\u5316\u77f3\u80fd\u6e90\u5371\u673a\u548c\u751f\u4ea7\u9ad8\u4ef7\u503c\u7684\u5316\u5b66\u54c1\u65b9\u9762\u5177\u6709\u6f5c\u5728\u7684\u5e94\u7528\u3002\u5c3d\u7ba1\u7814\u7a76\u4eba\u5458\u5728CO<sub>2<\/sub>\u7535\u8fd8\u539f\u7814\u7a76\u9886\u57df\u4e0d\u65ad\u53d6\u5f97\u7a81\u7834\uff0cCO<sub>2<\/sub> RR\u7684\u80fd\u91cf\u8f6c\u5316\u6548\u7387\u4ecd\u7136\u5f88\u4f4e\uff0c\u5176\u4e2d\u4e00\u4e2a\u5f88\u91cd\u8981\u7684\u539f\u56e0\u662f\uff0c\u5728\u4e2d\u6027\u6c34\u7535\u89e3\u6db2\u4e2d\uff0c\u9633\u6781\u4e0a\u7684\u6c27\u6790\u51fa\u53cd\u5e94\u9700\u8981\u5f88\u9ad8\u7684\u8fc7\u7535\u4f4d\uff08&gt; 460 mV at 10 mA\/cm<sup>2<\/sup>\uff09\uff0c\u8fd9\u9650\u5236\u4e86\u603b\u53cd\u5e94\u7684\u7535\u80fd\u5230\u5316\u5b66\u80fd\u7684\u80fd\u91cf\u8f6c\u5316\u6548\u7387\u3002<\/p>\n<p><strong>\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n<p>\u8fd1\u65e5\uff0c<strong>\u52a0\u62ff\u5927\u591a\u4f26\u591a\u5927\u5b66Edward H. Sargent<\/strong>\u56e2\u961f\u901a\u8fc7\u7cbe\u51c6\u8c03\u63a7Ni\u3001Fe\u3001Co\u3001P\uff0c\u5728\u4f4e\u7535\u4f4d\u4e0b\u5f97\u5230\u4e86\u5927\u91cf\u7684\u6d3b\u6027\u4f4dNi<sup>4+<\/sup>\uff0c\u8fdb\u800c\u5f97\u5230\u4e86 \u4e2d\u6027\u73af\u5883\u4e0b\u4f4e\u8fc7\u7535\u4f4d\u548c\u9ad8\u7a33\u5b9a\u6027\u7684\u4ea7\u6c27\u50ac\u5316\u5242\uff08 330 mV at 10 mA\/cm<sup>2<\/sup>\uff09; \u8be5\u56e2\u961f\u8fd8\u7528\u539f\u4f4d\u8f6fX\u5c04\u7ebf\u5438\u6536\u8bc1\u660e\u548c\u91cf\u5316\u4e86Ni<sup>4+<\/sup>\u3002\u4f5c\u8005\u6700\u540e\u5c06NiCoFeP\u7f9f\u57fa\u6c27\u5316\u7269\u7528\u4f5c\u4ea7\u6c27\u50ac\u5316\u5242\uff0c\u91d1\u7eb3\u7c73\u9488\u5c16\u4f5c\u4e3aCO<sub>2<\/sub>\u8fd8\u539f\u50ac\u5316\u5242\uff0c\u5f97\u5230\u4e8664%\u7684\u80fd\u91cf\u8f6c\u6362\u6548\u7387\uff0810 mA\/cm<sup>2<\/sup> \u7684\u7535\u6d41\u5bc6\u5ea6\u4e0b\u7535\u6c60\u7535\u538b\u4e3a1.99 V\uff09\u3002<strong>\u90d1\u96ea\u8389\u3001\u5f20\u6ce2\u3001<\/strong><strong>Phil De Luna<\/strong>\u4e3a\u8bba\u6587\u7684\u5171\u540c\u4e00\u4f5c\u3002\u8be5\u6210\u679c\u4ee5\u9898\u4e3a<strong>Theory-driven design of high-valence metal sites for water oxidation confirmed using in situ soft X-ray absorption<\/strong>\u53d1\u8868\u5728<strong>Nature Chemistry<\/strong> \u671f\u520a\u4e0a\u3002<\/p>\n<p><strong>\u00a0\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n<p><strong>Edward H. Sargent<\/strong>\u56e2\u961f\u9996\u5148\u7528DFT\u8ba1\u7b97\u7814\u7a76\u4e86\u91d1\u5c5e\u548c\u78f7\u63ba\u6742\u5bf9\u4e0d\u540c\u4ef7\u6001\u954d\u7ed3\u6784\u7684\u5f71\u54cd\uff0c\u4ece\u7406\u8bba\u4e0a\u9884\u6d4b\u4e86Fe\u3001Co\u3001P\u7684\u534f\u540c\u4f5c\u7528\uff0c\u53ef\u4ee5\u5728\u4f4e\u7535\u4f4d\u4e0b\u83b7\u5f97\u66f4\u591a\u7684\u6d3b\u6027\u4f4d\u70b9Ni<sup>4+<\/sup> \uff08\u56fe1\uff09\u3002<\/p>\n<p style=\"text-align: center;\"><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-113705 aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/11\/1-49.png\" alt=\"\" width=\"820\" height=\"464\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/11\/1-49.png 820w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/11\/1-49-300x170.png 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/11\/1-49-768x435.png 768w\" sizes=\"(max-width: 820px) 100vw, 820px\" \/>\u00a0<strong>\u56fe1. DFT\u7406\u8bba\u9884\u6d4bNi<sup>2+<\/sup>\uff0c\u5230Ni<sup>3+<\/sup>\uff0c\u5230Ni<sup>4+<\/sup>\u5728\u4e0d\u540cNi\u5316\u5408\u7269\u4e2d\u7684\u5f62\u6210\u80fd<\/strong><\/p>\n<p>\u4f5c\u8005\u901a\u8fc7\u539f\u4f4d\u8f6fx\u5c04\u7ebf\u5438\u6536\u7814\u7a76\u9996\u6b21\u91cf\u5316\u4e86\u5728\u6c34\u6c27\u5316\u8fc7\u7a0b\u7f9f\u57fa\u6c22\u6c27\u5316\u7269\u50ac\u5316\u5242\u53cd\u5e94\u8fc7\u7a0b\u4e2d\u5f62\u6210\u7684Ni<sup>4+<\/sup>\u3002Ni-L<sup>3-<\/sup>\u533a\u57df\u7684855.6\u548c857.5 eV\u5904\u53cc\u5cf0\u7279\u5f81\u7684\u5f3a\u5ea6\u6bd4\uff0c\u4e3a\u4e24\u79cdNi\u6c27\u5316\u6001\u7684\u76f8\u5bf9\u6bd4\u4f8b\u7684\u5b9a\u6027\u5206\u6790\u63d0\u4f9b\u4e86\u53ef\u80fd\u3002\u5728\u5411NiCoFeP\u6837\u54c1\u65bd\u52a0+1.6 V\u7535\u4f4d \u4e4b\u540e\uff0c\u6355\u83b7\u4e86\u4eceNi<sup>2+<\/sup>\u5230Ni<sup>4+<\/sup>\u7684\u8f6c\u5316\u8fc7\u7a0b\u3002\u5176\u4e2d\u5728Ni L<sup>2-<\/sup>\u8fb9875.1 eV\u9644\u8fd1\u51fa\u73b0\u7684\u989d\u5916\u7684\uff0c\u8f83\u5bbd\u7684\u5cf0\uff0c\u80af\u5b9a\u4e86Ni4+\u7684\u5f62\u6210\u3002\u8fd9\u4e9b\u76f8\u5173\u7684L<sup>3-<\/sup>\u8fb9Ni<sup>2+<\/sup>\u548cNi<sup>4+<\/sup>\u4e4b\u95f4\u7684\u5316\u5b66\u4f4d\u79fb\uff0c\u4e5f\u548cBSE\u8ba1\u7b97\u7684\u7ed3\u679c\u543b\u5408\uff0c\u5176\u9884\u6d4b\u4e86\u5c06Ni<sup>2+<\/sup>\u8f6c\u5316\u4e3aNi<sup>4+<\/sup>\uff0c\u4f1a\u4ea7\u751f\u7ea62.6 eV\u7684\u84dd\u79fb\u3002\u5f53\u9634\u6781\u504f\u538b\uff080 V \u76f8\u5bf9RHE\uff09\u65bd\u52a0\u5728NiCoFeP\u6837\u54c1\u4e0a\u65f6\uff0cNi-L<sup>3-<\/sup>\u548cL<sup>2-<\/sup>\u8fb9\u7684x\u5c04\u7ebf\u5438\u6536\u8c31\u5747\u6062\u590d\u5230\u4e86\u4ed6\u4eec\u7684\u539f\u6765\u72b6\u6001\u3002\u8fd9\u610f\u5473\u7740Ni<sup>2+<\/sup>\u548cNi<sup>4+<\/sup>\u7684\u8f6c\u6362\u662f\u53ef\u9006\u7684\uff08\u56fe2\uff09\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-113706\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/11\/2-41.png\" alt=\"\" width=\"897\" height=\"525\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/11\/2-41.png 897w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/11\/2-41-300x176.png 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/11\/2-41-768x449.png 768w\" sizes=\"(max-width: 897px) 100vw, 897px\" \/><\/p>\n<p style=\"text-align: center;\"><strong>\u56fe2. \u539f\u4f4d\u8f6fx\u5c04\u7ebf\u5438\u6536\u7684\u6d4b\u8bd5\u88c5\u7f6e\u53ca\u954d\u7684\u5438\u6536\u8c31<\/strong><\/p>\n<p>\u6700\u540e\u4f5c\u8005\u5bf9NiCoFeP\u7f9f\u57fa\u6c27\u5316\u7269\u7684\u50ac\u5316\u6027\u80fd\u8fdb\u884c\u4e86\u8bc4\u4f30\u3002\u5728\u9540\u91d1\u6ce1\u6cabNi\u4e0a\u7684NiCoFeP\u50ac\u5316\u5242\u4ec5\u9700\u8981330 mV\u8fc7\u7535\u4f4d\u5373\u53ef\u8fbe\u523010 mA cm<sup>-2<\/sup> \uff08\u56fe3\uff09\uff0c\u5176\u6bd4\u5546\u7528\u8d35\u91d1\u5c5e\u6c27\u5316\u7269IrO<sub>2<\/sub>\u50ac\u5316\u5242\u5728\u540c\u4e00\u6761\u4ef6\u4e0b\u6d4b\u8bd5\u7684\u8fc7\u7535\u4f4d\u8981\u4f4e70 mV\u3002\u8be5\u4ea7\u6c27\u50ac\u5316\u5242\u8d1f\u8f7d\u5728\u9540\u91d1\u6ce1\u6cab\u954d\u4e0a\uff0c\u53ef\u4ee5\u5728\u6052\u7535\u6d4110 mA cm<sup>-2<\/sup>\u65f6\u6301\u7eed\u7a33\u5b9a100\u5c0f\u65f6\u3002\u7528NiCoFeP\u7f9f\u57fa\u6c22\u6c27\u5316\u7269\u505a\u4e3a\u4ea7\u6c27\u50ac\u5316\u5242\uff0c\u53ca\u6700\u8fd1\u62a5\u9053\u7684Au\u7eb3\u7c73\u9488\u4f5c\u4e3aCO<sub>2<\/sub>\u8fd8\u539f\u50ac\u5316\u5242\uff0c\u5728\u8be5\u7535\u89e3\u4f53\u7cfb\u4e0b\uff0c\u5c06CO<sub>2<\/sub>\u548cH<sub>2<\/sub>O\u8f6c\u5316\u4e3aCO\u548cO<sub>2<\/sub>\uff0c\u5728\u7535\u6d4110 mA\/cm<sup>2<\/sup>\u65f6\u4ec5\u97001.99 V\u7684\u7535\u6c60\u7535\u538b\uff0c\u5e76\u53d6\u5f97\u9ad8\u7684\u7535\u80fd\u5230\u5316\u5b66\u71c3\u6599\u7684\u8f6c\u5316\u6548\u738764 %\uff0c\u8fdc\u9ad8\u4e8e\u73b0\u62a5\u9053\u7684\u6700\u9ad8CO2\u5230CO\u7684\u7535\u89e3\u6548\u7387\uff0852%\uff09\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-113707\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/11\/3-33.png\" alt=\"\" width=\"938\" height=\"502\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2017\/11\/3-33.png 938w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/11\/3-33-300x161.png 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2017\/11\/3-33-768x411.png 768w\" sizes=\"(max-width: 938px) 100vw, 938px\" \/><\/p>\n<p style=\"text-align: center;\"><strong>\u56fe3. NiCoFeP\u7f9f\u57fa\u6c27\u5316\u7269\u53ca\u5176\u5bf9\u6bd4\u6837\u7684\u50ac\u5316\u6027\u80fd\u6bd4\u8f83<\/strong><\/p>\n<p><strong>\u3010\u603b\u7ed3\u3011<\/strong><\/p>\n<p>Edward H. Sargent\u7814\u7a76\u56e2\u961f\u63d0\u51fa\uff0c\u5982\u80fd\u5728\u5c3d\u53ef\u80fd\u4f4e\u7684\u5916\u52a0\u504f\u538b\u4e0b\u4ea7\u751f\u5177\u6709\u9ad8\u4ef7\u6001\u7684\u8fc7\u6e21\u91d1\u5c5e\u6d3b\u6027\u4f4d\u5c31\u53ef\u6709\u6548\u6539\u5584\u4e2d\u6027\u4ea7\u6c27\u50ac\u5316\u5242\u7684\u50ac\u5316\u6d3b\u6027\u3002\u901a\u8fc7\u5bc6\u5ea6\u6cdb\u51fd\u7406\u8bba\u7684\u8ba1\u7b97\u53d1\u73b0\uff0c\u5f62\u6210Ni<sup>4+<\/sup>\u6d3b\u6027\u4e2d\u5fc3\u6240\u9700\u7684\u5f62\u6210\u80fd\u53ef\u4ee5\u901a\u8fc7\u5c06Co\uff0cFe\u548c\u975e\u91d1\u5c5e\u78f7\u8fdb\u884c\u4f18\u5316\u7ec4\u5408\u6765\u8fdb\u884c\u7cfb\u7edf\u5316\u8c03\u63a7\u7684\u3002\u4f5c\u8005\u5236\u5907\u4e86NiCoFeP\u7f9f\u57fa\u6c22\u6c27\u5316\u7269\uff0c\u5e76\u4f7f\u7528\u539f\u4f4d\u8f6fX\u5c04\u7ebf\u5438\u6536\u6d4b\u8bd5\u548c\u5b9a\u91cf\u4e86\u9ad8\u4ef7\u6d3b\u6027\u4f4d\u70b9Ni<sup>4+<\/sup>\uff0c\u83b7\u5f97\u4e86\u5728CO<sub>2<\/sub>-\u9971\u548c\u76840.5 M KHCO<sub>3<\/sub>\u7535\u89e3\u6db2\u4e2d\u4e8e330 mV\u8fc7\u7535\u4f4d\u4e0b\u5c31\u8fbe\u5230\u4e8610 mA\/cm<sup>2<\/sup>\u7535\u6d41\u5bc6\u5ea6\u3002\u4e0e\u7eb3\u7c73\u91d1\u5c16\u7ec4\u5408\u5f62\u6210\u5b8c\u6574\u7684CO<sub>2<\/sub>\u7535\u89e3\u4f53\u7cfb\uff0c\u5728\u5c06CO<sub>2<\/sub>\u8fd8\u539f\u4e3aCO\u7684\u540c\u65f6\u5c06H<sub>2<\/sub>O\u6c27\u5316\u4e3aO<sub>2<\/sub>\uff0c\u5f97\u5230\u4e86\u6700\u9ad8\u7684\u7535\u80fd\u5230\u5316\u5b66\u71c3\u6599\u80fd\u7684\u8f6c\u5316\u6548\u738764%\u3002<\/p>\n<p>\u6587\u732e\u94fe\u63a5\uff1a<a href=\"https:\/\/www.nature.com\/articles\/nchem.2886\" target=\"_blank\" rel=\"noopener\">Theory-driven design of high-valence metal sites for water oxidation confirmed using in situ soft X-ray absorption<\/a>(Nature Chemistry,2017, doi:10.1038\/nchem.2886)<\/p>\n<p>\u672c\u6587\u7531nanollsz\u6295\u7a3f\uff0c\u6750\u6599\u725b\u7f16\u8f91\u3002<\/p>\n<p>\u6750\u6599\u725b\u7f51\u4e13\u6ce8\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u53ca\u884c\u4e1a\u8fdb\u5c55\uff0c\u8fd9\u91cc\u6c47\u96c6\u4e86\u5404\u5927\u9ad8\u6821\u7855\u535a\u751f\u3001\u4e00\u7ebf\u79d1\u7814\u4eba\u5458\u4ee5\u53ca\u884c\u4e1a\u4ece\u4e1a\u8005\uff0c\u5982\u679c\u60a8\u5bf9\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u8fdb\u5c55\uff0c\u89e3\u8bfb\u9ad8\u6c34\u5e73\u6587\u7ae0\u6216\u662f\u8bc4\u8ff0\u884c\u4e1a\u6709\u5174\u8da3\uff0c<a href=\"\/\/m.iemloyee.com\/25127.html\" target=\"_blank\" rel=\"noopener\">\u70b9\u6211\u52a0\u5165\u7f16\u8f91\u90e8\u5927\u5bb6\u5ead<\/a>\u3002<\/p>\n<p>\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1tougao@cailiaoren.com\u3002<\/p>\n<p><strong><b>\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1aRDD-2011-CHERISH\uff0c\u4efb\u4e39\u4e39\uff0c\u6211\u4eec\u4f1a\u9080\u8bf7\u5404\u4f4d\u8001\u5e08\u52a0\u5165\u4e13\u5bb6\u7fa4\u3002<\/b><\/strong><\/p>\n<p><strong><b>\u6750\u6599\u6d4b\u8bd5\u3001\u6570\u636e\u5206\u6790\uff0c<\/b><\/strong><strong><b>\u4e0a<\/b><\/strong><a href=\"http:\/\/www.ceshigu.com\/\" target=\"_blank\" rel=\"noopener\"><strong><b>\u6d4b\u8bd5\u8c37<\/b><\/strong><\/a><strong><b>\uff01<\/b><\/strong><\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u3010\u5f15\u8a00\u3011 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