{"id":11346,"date":"2016-05-04T08:00:12","date_gmt":"2016-05-04T00:00:12","guid":{"rendered":"\/\/m.iemloyee.com\/?p=11346"},"modified":"2016-05-03T22:54:01","modified_gmt":"2016-05-03T14:54:01","slug":"angewandte-chemie%ef%bc%9a%e9%80%9a%e8%bf%87%e4%ba%8c%e7%a1%ab%e9%94%ae%e4%bd%bf%e5%a4%a7%e5%88%86%e5%ad%90%e9%80%89%e6%8b%a9%e6%80%a7%e8%87%aa%e7%bb%84%e8%a3%85%e4%b8%ba%e8%9e%ba%e6%97%8b%e5%bd%a2","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=11346","title":{"rendered":"Angewandte Chemie\uff1a\u901a\u8fc7\u4e8c\u786b\u952e\u4f7f\u5927\u5206\u5b50\u9009\u62e9\u6027\u81ea\u7ec4\u88c5\u4e3a\u87ba\u65cb\u5f62\u7ed3\u6784"},"content":{"rendered":"

\u65b0\u95fb\u7b80\u4ecb\uff1a<\/strong>\u8fd1\u671f\uff0c\u7531\u6cd5\u56fd\u6ce2\u5c14\u591a\u5927\u5b66\u7684\u7814\u7a76\u8005\u4eec\u5e26\u9886\u7684\u56fd\u9645\u56e2\u961f\u7814\u7a76\u51fa\u4e86\u4e00\u79cd\u5c06\u4eba\u5de5\u5206\u5b50\u7684\u6563\u4e71\u6392\u5217\u8f6c\u53d8\u4e3a\u5de6\u624b\u87ba\u65cb\u548c\u53f3\u624b\u87ba\u65cb\u7ed3\u6784\u7684\u65b9\u6cd5\u3002\u76f8\u5173\u8bba\u6587\u53d1\u8868\u5728Angewandte Chemie\u6742\u5fd7\u4e0a\u3002<\/p>\n

\u81ea\u7136\u4e2d\u7684\u751f\u7269\u5206\u5b50\u4e00\u822c\u5448\u73b0\u87ba\u65cb\u5f62\u6001\uff0c\u5e76\u4e14\u80fd\u591f\u4ee5\u6b64\u7ed3\u6784\u5411\u751f\u7269\u4f53\u5404\u90e8\u4f4d\u5206\u914d\u7279\u5b9a\u7684\u529f\u80fd\uff0c\u800c\u5c06\u4eba\u5de5\u5206\u5b50\u6539\u9020\u6210\u87ba\u65cb\u5f62\u7ed3\u6784\u662f\u4e00\u9879\u7279\u6b8a\u7684\u6311\u6218\uff0c\u5728\u6563\u4e71\u5206\u5b50\u7684\u87ba\u65cb\u5316\u6392\u5217\u8fc7\u7a0b\u4e2d\uff0c\u63a7\u5236\u5206\u5b50\u95f4\u7d27\u5bc6\u7ed3\u5408\u5341\u5206\u56f0\u96be\uff0c\u7a0d\u6709\u4e0d\u614e\uff0c\u5206\u5b50\u7ed3\u6784\u53c8\u5c06\u4f1a\u571f\u5d29\u74e6\u89e3\uff0c\u56de\u5230\u6700\u521d\u6563\u4e71\u7684\u72b6\u6001\u3002<\/p>\n

\u8be5\u9879\u7814\u7a76\u4e2d\u4f7f\u7528\u7684\u4eba\u5de5\u5206\u5b50\uff0c\u90fd\u662f\u82b3\u9999\u4f4e\u805a\u9170\u80fa\uff0c\u5c31\u50cf\u4ece\u6c28\u4e2d\u5206\u79bb\u51fa\u6765\u7684\u8102\u80aa\u5206\u5b50\u4e00\u6837\uff0c\u4e00\u5f00\u59cb\u7684\u5f62\u72b6\u5c31\u50cf\u662f\u6563\u4e71\u5730\u653e\u5728\u684c\u5b50\u4e0a\u7684\u73cd\u73e0\u9879\u94fe\uff0c\u800c\u901a\u8fc7\u5728\u7a7a\u95f4\u7ed3\u6784\u4e0a\u51e0\u4e2a\u7279\u5b9a\u7684\u4f4d\u7f6e\u52a0\u5165\u53cc\u786b\u6865\uff0c\u5206\u5b50\u5177\u6709\u4e86\u50cf\u7eb8\u5f20\u4e00\u6837\u6298\u53e0\u7684\u80fd\u529b\u5e76\u4e14\u80fd\u591f\u4e00\u5c42\u5c42\u5730\u53e0\u52a0\u8d77\u6765\u3002<\/p>\n

\u5728\u9644\u52a0\u7684\u5b9e\u9a8c\u4e4b\u4e2d\uff0c\u5b9e\u9a8c\u4eba\u5458\u5c06\u87ba\u65cb\u5f62\u5206\u5b50\u7684\u5c3e\u90e8\u8054\u63a5\u5728\u4e00\u8d77\uff0c\u60ca\u5947\u5730\u53d1\u73b0\u5373\u4f7f\u53ea\u6709\u4e00\u4e2a\u70b9\u7684\u63a5\u89e6\uff0c\u4e5f\u80fd\u591f\u4f7f\u5f97\u8054\u63a5\u5206\u5b50\u7684\u7ed3\u6784\u76f8\u4e92\u540c\u5316\uff0c\u5b83\u4eec\u7684\u5de6\u624b\u87ba\u65cb\u548c\u53f3\u624b\u87ba\u65cb\u60c5\u51b5\u53d8\u5f97\u4e00\u81f4\u3002<\/p>\n

\u7814\u7a76\u8005\u56e2\u961f\u8868\u660e\uff0c\u6298\u53e0\u548c\u73af\u5316\u4f5c\u7528\u5728\u81ea\u7136\u754c\u4e2d\u90fd\u5341\u5206\u666e\u53ca\uff0c\u6b63\u662f\u7531\u8fd9\u4e24\u4e2a\u57fa\u672c\u539f\u5219\u5e2e\u52a9\u751f\u7269\u5206\u5b50\u4ea7\u751f\u4e86\u7279\u5b9a\u7684\u529f\u80fd\u3002\u56e0\u6b64\uff0c\u6b64\u9879\u7814\u7a76\u7684\u610f\u4e49\u975e\u51e1\uff0c\u4f8b\u5982\u6539\u53d8\u5f15\u8d77\u764c\u75c7\u6216\u8005\u8001\u5e74\u75f4\u5446\u8fd9\u4e9b\u75be\u75c5\u7684\u67d0\u4e9b\u9176\u7684\u7ed3\u6784\uff0c\u80fd\u591f\u5e2e\u52a9\u6211\u4eec\u6cbb\u7597\u75be\u75c5\uff0c\u63a8\u52a8\u533b\u5b66\u7684\u53d1\u5c55\u3002\u5728\u4e4b\u540e\u7684\u7814\u7a76\u4e2d\uff0c\u6b64\u6210\u679c\u8fd8\u6709\u671b\u5e94\u7528\u5728\u751f\u7269\u4f53\u7684\u50ac\u5316\u4f5c\u7528\u548c\u80fd\u91cf\u8f6c\u6362\u65b9\u9762\u3002<\/p>\n

\u56fe\u6587\u5bfc\u8bfb\uff1a<\/strong><\/p>\n

\u65b9\u6848<\/strong>1 <\/strong>\u4e2d\u4f4e\u805a\u7269<\/strong>1<\/strong>\u548c<\/strong>2<\/strong>\u7684\u8bbe\u8ba1\u662f\u4e3a\u4e86\u9a8c\u8bc1\u53cc\u786b\u952e\u662f\u5426\u80fd\u591f\u7528\u6765\u7a33\u5b9a\u82b3\u9170\u80fa\u6298\u53e0\u4f53\u7684\u87ba\u65cb\u5f62\u6001\u5e76\u4e14\u5c06\u51e0\u4e2a\u87ba\u65cb\u4f53\u7ec4\u5408\u5728\u4e00\u8d77\u3002<\/strong><\/p>\n

\"1\"<\/p>\n

\u65b9\u68481. \u4f4e\u805a\u72691\u548c2\u5408\u6210\u4e3a\u5927\u73af\u7c7b\u5316\u5408\u72693\u548c4\u3002\u53cd\u5e94\u6761\u4ef6\uff1aa) 14\u6beb\u6469\u5c14\/\u5347\u7684THF\/H2<\/sub>O(\u56db\u6c22\u544b\u5583\/\u6c34\uff0c\u4f53\u79ef\u6bd4\u4e3a3:1)\u6eb6\u6db2\u4e2d\uff0c40\u5fae\u5347\u4e8c\u5f02\u4e19\u57fa\u4e59\u80fa\uff0c25\u2103\uff0c\u53cd\u5e9448\u5c0f\u65f6\u3002<\/p>\n

\u56fe<\/strong>1<\/strong>\u4e2d<\/strong>(a)<\/strong>\u662f\u7531\u53d4\u4e01\u916f\u7684\u524d\u4f53<\/strong>1<\/strong>\u5f62\u6210\u87ba\u65cb\u6676\u4f53\u7ed3\u6784\u7684\u793a\u610f\u56fe\uff0c\u4f4d\u4e8e\u4e2d\u5fc3\u7684\u4e24\u4e2a\u786b\u9187\u94fe\u8ddd\u79bb\u5f88\u8fd1\u5e76\u4e14\u4e0e\u87ba\u65cb\u7ed3\u6784\u7684\u4e00\u7aef\u504f\u79bb\uff0c\u8fd9\u9690\u793a\u4e86\u5728\u5206\u5b50\u5185\u90e8\u5f62\u6210\u53cc\u786b\u6865\u662f\u53ef\u80fd\u7684\u3002<\/strong>(b)<\/strong>\u662f\u4f4e\u805a\u7269<\/strong>1<\/strong>\u5728\u65b9\u6848<\/strong>1<\/strong>\u4e2d\u7684<\/strong>a<\/strong>\u53cd\u5e94\u6761\u4ef6\u4e0b\u5f62\u6210\u7684\u5316\u5408\u7269<\/strong>3<\/strong>\u7684\u87ba\u65cb\u793a\u610f\u56fe\uff0c\u5176\u4e2d\u952e\u5185\u5b58\u5728\u786b\u6865\u3002<\/strong>(c)<\/strong>\u662f\u7531\u4f4e\u805a\u7269<\/strong>2<\/strong>\u5f62\u6210\u87ba\u65cb\u6676\u4f53\u7ed3\u6784\u7684\u793a\u610f\u56fe\uff0c\u4f46\u662f\u5373\u4f7f\u8003\u8651\u4e0a\u4fa7\u94fe\u7684\u7075\u6d3b\u6027\uff0c\u4e24\u4e2a\u786b\u9187\u94fe\u7684\u8ddd\u79bb\u8fd8\u662f\u592a\u8fdc\uff0c\u4ee5\u81f3\u4e8e\u4e0d\u80fd\u5f62\u6210\u53cc\u786b\u6865\u3002<\/strong><\/p>\n

\"2\"<\/p>\n

\u56fe1. (a)(c)(d)\u5206\u522b\u8868\u793a\u4e86\u65b9\u68481\u4e2d\u7684\u4f4e\u805a\u72691\uff0c2\u548c\u5927\u73af\u7c7b\u5316\u5408\u72694\u7684\u6676\u4f53\u7ed3\u6784\u3002(b)\u56fe\u8868\u793a\u901a\u8fc7\u80fd\u91cf\u6700\u5c0f\u5316\u6a21\u578b\u5206\u6790\u51fa\u7684\u5f62\u6210\u5927\u73af\u7c7b\u5316\u5408\u72693\u8fc7\u7a0b\u4e2d\u7684\u6676\u4f53\u7ed3\u6784\u8f6c\u53d8\u3002\u6240\u6709\u7684\u56fe\u793a\u90fd\u5305\u62ec\u4e86\u4fa7\u89c6\u56fe\u548c\u9876\u90e8\u89c6\u56fe\uff0c\u4e3a\u4e86\u6e05\u6670\u8d77\u89c1\uff0c\u56fe\u4e2d\u7701\u7565\u4e86\u6c28\u4ee5\u5916\u7684\u6c22\u79bb\u5b50\uff0c\u6eb6\u5242\u5206\u5b50\u548c\u5f02\u4e01\u6c27\u57fa\u4fa7\u94fe\u3002\u5728(d)(c)\u56fe\u4e2d\u7684\u692d\u5706\u4ee3\u8868\u7c7b\u4f3c\u7684\u4fa7\u94fe\u6784\u8c61\u3002\u78b3\uff0c\u786b\uff0c\u6c2e\uff0c\u6c27\uff0c\u6c22\u5206\u522b\u5bf9\u5e94\u4e86\u56fe\u4e2d\u7684\u7070\u8272\uff0c\u9ec4\u8272\uff0c\u84dd\u8272\uff0c\u7ea2\u8272\u548c\u767d\u8272\uff0c\u7eff\u8272\u95f4\u65ad\u7ebf\u8868\u793a\u4e86\u5206\u5b50\u95f4\u7684\u8ddd\u79bb\u3002<\/p>\n

\"3\"<\/p>\n

\u56fe<\/strong>2. <\/strong>\u5404\u5316\u5408\u7269\u5728\u6709\u673a\u6eb6\u5242<\/strong>CDCl3<\/sub><\/strong>\u4e2d<\/strong>300<\/strong>\u5146\u8d6b\u5179\u7684<\/strong>1<\/sup><\/strong>H<\/strong>\u6838\u78c1\u5171\u632f\u8c31\uff1a<\/strong>a)1<\/strong>\uff1b<\/strong>b)3<\/strong>\uff1b<\/strong>c)2<\/strong>\uff1b<\/strong>d)4<\/strong>\u3002\u661f\u53f7\u8868\u793a\u6837\u54c1\u4e2d\u4e19\u916e\u7684\u6b8b\u7559\u3002<\/strong><\/p>\n

\u5728\u5b9e\u9a8c\u4e2d\uff0c\u4e3a\u4e86\u8861\u91cf\u87ba\u65cb\u5f62\u7684\u70ed\u7a33\u5b9a\u6027\u3002\u7814\u7a76\u4eba\u5458\u6d4b\u5b9a\u4e86P\u548cM\u87ba\u65cb\u95f4\u7684\u76f8\u4e92\u8f6c\u6362\u7387\u3002\u56fe3a-c\u4e2d\u4f7f\u7528\u4e86\u624b\u6027\u9ad8\u6548\u6db2\u76f8\u8272\u8c31\u6cd5\u6765\u533a\u5206P\u548cM\u578b\u87ba\u65cb\u6784\u8c61\u3002\u56fe3d\u8bb0\u5f55\u7684CD\u8c31\u8868\u660e\u4e86\u6837\u54c1\u65e0\u8bba\u662f\u5728CHCl3<\/sub>\u8fd8\u662fTHF\u4e2d\u6eb6\u89e3\uff0c\u7279\u6b8a\u7684\u8c31\u5e26\u90fd\u4f1a\u8870\u51cf\u5e76\u4e14\u7b26\u5408\u4e00\u7ea7\u52a8\u529b\u5b66\u539f\u7406(\u56fe3e)\u3002<\/strong><\/p>\n

\"4\"<\/p>\n

\u56fe3. \u624b\u6027\u6d88\u65cb\u52a8\u529b\u5b66\u3002P\u548cM\u578b\u87ba\u65cb\u6784\u8c61\u7684\u8272\u8c31\u5206\u79bb\uff1aa)\u4f4e\u805a\u72691(\u56db\u6c22\u544b\u5583\u4e0e\u6b63\u5df1\u70f7\u4f53\u79ef\u6bd440:60)\uff1bb)\u5927\u73af\u7c7b\u5316\u5408\u72693(\u56db\u6c22\u544b\u5583\u4e0e\u6b63\u5df1\u70f7\u4f53\u79ef\u6bd450:50)\uff1b c)\u5927\u73af\u7c7b\u5316\u5408\u72694(\u4e09\u6c2f\u7532\u70f7\u548c\u4e59\u9178\u4e59\u916f\u4f53\u79ef\u6bd430:70)\u3002UV\u68c0\u6d4b\u8ddf\u8e2a(300\u7eb3\u7c73)\u5728\u9876\u90e8\u663e\u793a\uff0cCD\u68c0\u6d4b\u8ddf\u8e2a(360\u7eb3\u7c73)\u5728\u5e95\u90e8\u663e\u793a\u3002d)\u5316\u5408\u72694\u572830\u2103\u7684\u4e09\u6c2f\u7532\u70f7\u4e2dCD\u5f3a\u5ea6\u8870\u51cf\u7684\u793a\u610f\u56fe\uff1be)CD\u5f3a\u5ea6\u4e00\u9636\u8870\u51cf\u7ebf\u6027\u56fe\uff1a\u25c6\u8868\u793a3\uff0c\u25a0\u8868\u793a4\uff0c\u25cf\u8868\u793a1\u3002<\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u7f16\u8f91\u90e8\u5c09\u8c37\u96e8\u63d0\u4f9b\u7d20\u6750\uff0c\u590f\u6dfb\u7f16\u8f91\u6574\u7406\u3002<\/p>\n

\u8fd9\u9879\u7814\u7a76\u53d1\u8868\u5728\u8fd1\u671f\u7684Angew.Chem<\/a>\u4e0a\u3002<\/p>\n

\u539f\u6587\u53c2\u8003\u94fe\u63a5\uff1aFolding molecules into screw-shaped structures<\/a><\/p>\n

\u6587\u732e\u94fe\u63a5\uff1aSelective Dynamic Assembly of Disulfide Macrocyclic Helical Foldamers with Remote Communication of Handedness<\/a><\/p>\n","protected":false},"excerpt":{"rendered":"

\u65b0\u95fb\u7b80\u4ecb\uff1a\u8fd1\u671f\uff0c\u7531\u6cd5\u56fd\u6ce2\u5c14\u591a\u5927\u5b66\u7684\u7814\u7a76\u8005\u4eec\u5e26\u9886\u7684\u56fd\u9645\u56e2\u961f\u7814\u7a76\u51fa\u4e86\u4e00\u79cd\u5c06\u4eba\u5de5\u5206\u5b50\u7684\u6563\u4e71\u6392\u5217\u8f6c\u53d8\u4e3a\u5de6\u624b\u87ba\u65cb\u548c\u53f3\u624b\u87ba\u65cb\u7ed3\u6784\u7684\u65b9\u6cd5\u3002\u76f8\u5173\u8bba\u6587\u53d1\u8868\u5728Angewandte …<\/p>\n","protected":false},"author":35,"featured_media":11409,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[2],"tags":[42],"class_list":["post-11346","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-keji","tag-gaofenzi"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/11346"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/35"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=11346"}],"version-history":[{"count":6,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/11346\/revisions"}],"predecessor-version":[{"id":11421,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/11346\/revisions\/11421"}],"wp:featuredmedia":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/media\/11409"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=11346"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=11346"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=11346"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}