{"id":113078,"date":"2017-11-21T06:30:20","date_gmt":"2017-11-20T22:30:20","guid":{"rendered":"\/\/m.iemloyee.com\/?p=113078"},"modified":"2017-11-20T22:09:08","modified_gmt":"2017-11-20T14:09:08","slug":"angew-chem-int-ed-%ef%bc%9a%e5%88%a9%e7%94%a8%e7%a2%b1%e9%87%91%e5%b1%9e%e5%88%b6%e5%a4%87%e9%bb%91%e7%a3%b7%e6%8f%92%e5%b1%82%e5%8c%96%e5%90%88%e7%89%a9","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=113078","title":{"rendered":"Angew. Chem. Int. Ed.\uff1a\u5229\u7528\u78b1\u91d1\u5c5e\u5236\u5907\u9ed1\u78f7\u63d2\u5c42\u5316\u5408\u7269"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n

\u4f5c\u4e3a\u4e00\u79cd\u65b0\u578b\u7684\u975e\u78b3\u4e8c\u7ef4\u6750\u6599\uff0c\u5355\u5c42\u6216\u5c11\u5c42\u7684\u9ed1\u78f7\uff08BP\uff09\u5177\u5907\u8f83\u9ad8\u7684p-\u578b\u8f7d\u6d41\u5b50\u8fc1\u79fb\u901f\u7387\u548c\u53ef\u8c03\u7684\u76f4\u63a5\u7981\u5e26\u5bbd\u5ea6\uff0c\u5728\u5149\u7535\u5b50\u548c\u80fd\u91cf\u50a8\u5b58\u9886\u57df\u663e\u793a\u51fa\u8bf1\u4eba\u7684\u5e94\u7528\u524d\u666f\u3002\u7814\u7a76\u53d1\u73b0\uff1a\u5728BP\u8868\u9762\u8fdb\u884c\u94be\uff08K\uff09\u539f\u5b50\u63ba\u6742\u53ef\u4ee5\u5b9e\u73b0\u5bf9\u5355\u6676\u6001BP\u7981\u5e26\u5bbd\u5ea6\u7684\u8c03\u8282\uff0c\u663e\u8457\u63d0\u9ad8\u5176\u7535\u5b66\u6027\u80fd\u3002\u56e0\u6b64\uff0c\u901a\u8fc7\u5728BP\u4e2d\u5d4c\u5165\u4f9b\u4f53\u578b\u78b1\u91d1\u5c5e\u5236\u5907\u63d2\u5c42\u5316\u5408\u7269\u6210\u4e3a\u4e8c\u7ef4\u6750\u6599\u7814\u7a76\u9886\u57df\u65b0\u7684\u70ed\u70b9\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u57c3\u5c14\u6717\u6839<\/strong>–<\/strong>\u7ebd\u4f26\u5821\u5927\u5b66<\/strong>\u7684Andreas Hirsch<\/strong>\u6559\u6388\uff08\u901a\u8baf\u4f5c\u8005\uff09<\/strong>\u7b49\u5728Angew. Chem. Int. Ed. <\/strong>\u4e0a\u53d1\u8868\u4e86\u9898\u4e3a\u201cExploring the Formation of Black Phosphorus Intercalation Compounds with Alkali Metals<\/strong>\u201d\u7684\u7814\u7a76\u8bba\u6587\uff0c\u62a5\u9053\u4e86\u78b1\u91d1\u5c5e\u5236\u5907\u9ed1\u78f7\u63d2\u5c42\u5316\u5408\u7269\uff08BPICs\uff09\u7684\u6700\u65b0\u7814\u7a76\u8fdb\u5c55\u3002\u7814\u7a76\u4eba\u5458\u5206\u522b\u91c7\u7528\u56fa\u76f8\u6cd5\u548c\u6c14\u76f8\u6cd5\u5b9e\u73b0\u4e86BPICs\u7684\u6279\u91cf\u5236\u5907\u3002\u7ed3\u5408\u539f\u4f4dXRD\uff0c\u539f\u4f4d\u62c9\u66fc\u5149\u8c31\u548c\u5bc6\u5ea6\u6cdb\u51fd\u7406\u8bba\uff08DFT\uff09\u8ba1\u7b97\uff0c\u7814\u7a76\u4eba\u5458\u9996\u6b21\u63ed\u793a\u4e86\u4e0d\u540c\u63d2\u5c42\u7a0b\u5ea6\u4e0bBPICs\u7684\u7ed3\u6784\u884c\u4e3a\u3002\u7814\u7a76\u53d1\u73b0\uff1aBPICs\u7684\u7ed3\u6784\u590d\u6742\u6027\u548c\u52a8\u529b\u5b66\u884c\u4e3a\u4e0e\u4f20\u7edf\u7684\u77f3\u58a8\u63d2\u5c42\u5316\u5408\u7269\uff08GICs\uff09\u5b58\u5728\u660e\u663e\u7684\u5dee\u5f02\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n

\u793a\u610f\u56fe<\/strong>-1. <\/strong>\u9ed1\u78f7\u63d2\u5c42\u5316\u5408\u7269\u7684\u5236\u5907\u53ca\u7ed3\u6784\u793a\u610f\u56fe<\/strong><\/p>\n

\"\"<\/p>\n

\uff08a\uff09\u78b1\u91d1\u5c5e\uff08AM\uff09\u5d4c\u5165\u9ed1\u78f7\uff08BP\uff09\u5f62\u6210AM-BPICs\u793a\u610f\u56fe\u3002<\/p>\n

\uff08b\uff09\u6839\u636eDFT\u8ba1\u7b97\u7ed3\u679c\uff0cAM-BPICs\u6cbf\u6276\u624b\u6905\uff08armchair\uff09\u65b9\u5411\u7684\u4fa7\u89c6\u56fe\u3002\u78b1\u6027\u91d1\u5c5e\uff08\u9ed1\u8272\uff09\u4f4d\u7f6e\u56fa\u5b9a\uff0cBP\u5c42\uff08\u91d1\u8272\uff09\u4eceAB<\/p>\n

\u5806\u79ef\u65b9\u5f0f\u5411AC\u5806\u79ef\u65b9\u5f0f\u6ed1\u79fb\u3002<\/p>\n

\uff08c\uff09\u6839\u636eDFT\u8ba1\u7b97\u7ed3\u679c\uff0cAM-BPICs\u6cbfZigzag\u65b9\u5411\u7684\u4fa7\u89c6\u56fe\u3002<\/p>\n

\uff08d\uff09\u78b1\u91d1\u5c5e\u63d2\u5c42\u9ed1\u78f7\u7684\u4fef\u89c6\u56fe\u3002<\/p>\n

\u56fe<\/strong>-1. <\/strong>\u6837\u54c1\u7684\u6676\u4f53\u7ed3\u6784\u8868\u5f81<\/strong><\/p>\n

\"\"<\/p>\n

\uff08a\uff09BP\u539f\u6599\uff08\u9ed1\u7ebf\uff09\u4ee5\u53caAM-BPICs\u7684X\u5c04\u7ebf\u5f3a\u5ea6\u3002\uff08\u5176\u4e2d\u7ea2\u7ebf\u8868\u793aNa:P\u4e3a1:4 \u7684BPICs\uff0c\u7eff\u7ebf\u8868\u793aK:P\u4e3a 1:4\u7684BPICs\uff0cNa3<\/sub>P\u548cK3<\/sub>P\u7684\u884d\u5c04\u5cf0\u4f4d\u7f6e\u5206\u522b\u7531\u9ed1\u8272\u865a\u7ebf\uff0c\u7ea2\u8272\u865a\u7ebf\u548c\u7eff\u8272\u865a\u7ebf\u8868\u793a\u3002\u4e3a\u4e86\u63d0\u9ad8\u5bf9\u6bd4\u5ea6\uff0cX\u5c04\u7ebf\u5f3a\u5ea6\u8fdb\u884c\u4e86\u5782\u76f4\u504f\u79fb\u3002)<\/p>\n

\uff08b\uff09\uff08c\uff09\u56fe-1\uff08a\uff09\u4e2d\u65b0\u51fa\u73b0\u7684\u884d\u5c04\u5cf0\u4ee5\u53ca\u5206\u5316\u7684\u884d\u5c04\u5cf0\u7684\u5c40\u90e8\u653e\u5927\u56fe\u6837\u3002<\/p>\n

\uff08d\uff09\u4ece\u7ed3\u6676\u76f8\uff08\u76f8\u5e72\u6563\u5c04\uff09\u5230\u975e\u6676\u4f53\u6563\u5c04\u5f3a\u5ea6\uff08\u6f2b\u5c04\uff09\u6563\u5c04\u5f3a\u5ea6\u964d\u4f4e\uff1a\u901a\u8fc7\u5d4c\u5165\u8f83\u5927\u7684\u94be\u539f\u5b50\u53ef\u4ee5\u589e\u5927\u975e\u6676\u5316\u5ea6\u3002<\/p>\n

\uff08e\uff09\u4e0d\u540c\u7ed3\u6676\u76f8\u5411\u975e\u6676\u76f8\u8f6c\u53d8\u7684\u793a\u610f\u56fe\u3002 X\u5c04\u7ebf\u6ce2\u957f\u4e3a0.1542 nm\u3002<\/p>\n

\u56fe<\/strong>-2. BP<\/strong>\u539f\u6599\u548c\u6700\u7a33\u5b9a\uff08\u7ed3\u6676\uff09<\/strong>K<\/strong>\u63d2\u5c42\u5316\u5408\u7269\uff08<\/strong>K:P = 1:8,1:4<\/strong>\u548c<\/strong>1:2<\/strong>\uff09<\/strong>\u7684\u7406\u8bba\u8ba1\u7b97<\/strong><\/p>\n

\"\"<\/p>\n

\uff08a\uff09\u7406\u8bba\u4e0a\u9884\u6d4bBP\u539f\u6599\u548cK\u63d2\u5c42\u5316\u5408\u7269\u7684\u62c9\u66fc\u4f4d\u79fb\u3002<\/p>\n

\uff08b\uff09\u5728\u6276\u624b\u6905\u65b9\u5411\u8ba1\u7b97BP\u539f\u6599\u7684\u7ed3\u6784\u548c\u6700\u7a33\u5b9a\u7684K\u63d2\u5c42\u5316\u5408\u7269\u3002<\/p>\n

\uff08c\uff09\u7247\u72b6BP\u548cK\u63d2\u5c42\u5316\u5408\u7269\u7684\u9876\u89c6\u56fe\u3002\u5728K:P = 1:4\u548c1:2\u7684\u60c5\u51b5\u4e0b\uff0c\u7ea2\u70b9\u8868\u793a\u5206\u5f00\u7684P\u5e26\u3002<\/p>\n

\uff08d\uff09BP\u7684\u62c9\u66fc\u4e3b\u52a8\u632f\u52a8\u7684\u53ef\u89c6\u5316\u56fe\u7247\u3002<\/p>\n

\u56fe<\/strong>-3. <\/strong>\u62c9\u66fc\u5149\u8c31\u89c2\u6d4b<\/strong>BP<\/strong>\u7684\u6c14\u76f8\u63d2\u5c42\u8fc7\u7a0b<\/strong><\/p>\n

\"\"<\/p>\n

\uff08a\uff09\u5728\u4e0d\u540c\u63ba\u6742\u65f6\u95f4\u6d4b\u91cf\u7684K\u63d2\u5c42\u9ed1\u8272\u78f7\uff08BP\uff09\u7684\u539f\u4f4d\u62c9\u66fc\u5149\u8c31\u3002<\/p>\n

\uff08b\uff09\u5728\u4e0d\u540c\u63ba\u6742\u65f6\u95f4\u6d4b\u91cf\u7684Na\u63d2\u5c42\u9ed1\u8272\u78f7\uff08BP\uff09\u7684\u539f\u4f4d\u62c9\u66fc\u5149\u8c31\u3002\uff08c\uff09\u6d1b\u4f26\u5179\u5bbd\u5316\uff08\u534a\u9ad8\u5bbd\u4e3a5.0 cm-1<\/sup>\uff09\u5904\u7406\u540e\u901a\u8fc7\u8ba1\u7b97\u5f97\u5230\u7684\u534a\u5bfc\u4f53K-P\u76f8\u7684\u62c9\u66fc\u5149\u8c31\u3002\uff08\u4e3a\u4e86\u6bd4\u8f83\uff0c\u7406\u8bba\u9884\u6d4b\u7684\u539f\u59cbBP\u7684\u62c9\u66fc\u4f4d\u79fb\u7531\u865a\u7ebf\u8868\u793a\u3002\u5bf9\u5e94\u7684\u91d1\u5c5e\u95f4\u76f8\u548cKP2<\/sub>\u7684\u533a\u57df\u4ee5\u7eff\u8272\u7a81\u51fa\u663e\u793a\uff0c\u4f4d\u4e8e250-350 cm-1<\/sup>\u4e4b\u95f4\u7684\u63d2\u5c42\u5316\u5408\u7269\u7684\u7279\u5f81\u53cc\u5cf0\u76f8\u5173\u7684\u533a\u57df\u4ee5\u7c89\u7ea2\u8272\u7a81\u51fa\u663e\u793a\u3002\uff09<\/p>\n

\uff08d\uff09\u4e0d\u540c\u63ba\u6742\u65f6\u95f4K-BPICs.\u4e09\u79cd\u4e3b\u8981\u632f\u52a8\u6a21\u5f0f\uff1aA1g<\/sub>\uff0cB2g<\/sub>\u548cA2g<\/sub>\u3002<\/p>\n

\uff08e\uff09\u4e0d\u540c\u63ba\u6742\u65f6\u95f4Na-BPICs.\u4e09\u79cd\u4e3b\u8981\u632f\u52a8\u6a21\u5f0f\uff1aA1g<\/sub>\uff0cB2g<\/sub>\u548cA2g<\/sub>\u3002<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n

\u00a0\u00a0 <\/strong>\u00a0\u672c\u6587\u5229\u7528\u78b1\u91d1\u5c5e\u63d2\u5c42\u5236\u5907\u5f97\u5230\u4e86\u9ed1\u78f7\u63d2\u5c42\u5316\u5408\u7269\uff0c\u5e76\u7ed3\u5408\u539f\u4f4dXRD\uff0c\u539f\u4f4d\u62c9\u66fc\u548cDFT\u8ba1\u7b97\u5bf9BPICs\u7684\u7ed3\u6784\u6f14\u53d8\u8fdb\u884c\u4e86\u6df1\u5165\u7814\u7a76\u3002\u7814\u7a76\u53d1\u73b0\uff1a\u63d2\u5c42\u8fc7\u7a0b\u4e2d\u4f1a\u5f62\u6210\u65b0\u7684\u63d2\u5c42\u76f8\u5e76\u4e14\u4f34\u968f\u7740BP\u5c42\u7684\u6ed1\u79fb\uff0cAB\u5806\u79ef\u65b9\u5f0f\u7684BP\u5728\u63d2\u5c42\u5904\u7406\u540e\u8f6c\u53d8\u4e3aAC\u5806\u79ef\u65b9\u5f0f\uff1b\u4fdd\u6301\u5c42\u7ed3\u6784\u7684\u6700\u5927\u5316\u5b66\u8ba1\u91cf\u4e3aM:P = 1:4\uff0c\u8d85\u8fc7\u8be5\u4e34\u754c\u503c\u540e\u5c42\u72b6\u7ed3\u6784\u4f1a\u7834\u574f\u5f62\u6210\u94fe\u72b6\u7ed3\u6784\u3002\u672c\u6587\u4e3aBP\u4e0e\u78b1\u91d1\u5c5e\u7684\u63d2\u5c42\u8fc7\u7a0b\u63d0\u4f9b\u4e86\u66f4\u52a0\u6df1\u5165\u7684\u7406\u89e3\uff0c\u4e3a\u5c06\u6765BPICs\u7684\u5236\u5907\u548c\u7814\u7a76\u63d0\u4f9b\u4e86\u65b0\u7684\u601d\u8def\u53c2\u8003\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/strong> Exploring the Formation of Black Phosphorus Intercalation Compounds with Alkali Metals<\/a>(Angew. Chem., 2017, DOI:\u00a010.1002\/anie.201707462)<\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u7f16\u8f91\u90e8\u5f20\u6770\u7f16\u8bd1\uff0c\u8d75\u98de\u9f99\u5ba1\u6838\uff0c\u70b9\u6211\u52a0\u5165\u6750\u6599\u4eba\u7f16\u8f91\u90e8\u3002<\/a><\/p>\n

\u6750\u6599\u6d4b\u8bd5\uff0c\u6570\u636e\u5206\u6790\uff0c\u4e0a\u6d4b\u8bd5\u8c37<\/a>\uff01<\/p>\n","protected":false},"excerpt":{"rendered":"

\u3010\u5f15\u8a00\u3011 \u4f5c\u4e3a\u4e00\u79cd\u65b0\u578b\u7684\u975e\u78b3\u4e8c\u7ef4\u6750\u6599\uff0c\u5355\u5c42\u6216\u5c11\u5c42\u7684\u9ed1\u78f7\uff08BP\uff09\u5177\u5907\u8f83\u9ad8\u7684p-\u578b\u8f7d\u6d41\u5b50\u8fc1\u79fb\u901f\u7387\u548c\u53ef\u8c03\u7684\u76f4\u63a5\u7981\u5e26\u5bbd\u5ea6\uff0c\u5728\u5149\u7535\u5b50\u548c\u80fd\u91cf\u50a8\u5b58\u9886\u57df\u663e\u793a\u51fa\u8bf1\u4eba\u7684\u5e94\u7528\u524d\u666f\u3002\u7814…<\/p>\n","protected":false},"author":230,"featured_media":113079,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215,2],"tags":[1544],"class_list":["post-113078","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-jiedu","category-keji","tag-1544"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/113078"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/230"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=113078"}],"version-history":[{"count":3,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/113078\/revisions"}],"predecessor-version":[{"id":113207,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/113078\/revisions\/113207"}],"wp:featuredmedia":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/media\/113079"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=113078"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=113078"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=113078"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}