{"id":112349,"date":"2017-11-19T06:30:54","date_gmt":"2017-11-18T22:30:54","guid":{"rendered":"\/\/m.iemloyee.com\/?p=112349"},"modified":"2017-11-16T23:10:44","modified_gmt":"2017-11-16T15:10:44","slug":"nano-energy%ef%bc%9a%e4%ba%8c%e6%b0%a7%e5%8c%96%e7%a2%b3%e5%82%ac%e5%8c%96%e5%8a%a0%e6%b0%a2%e4%b9%8b%e9%87%91%e5%b1%9e%e9%93%9c%e7%ba%b3%e7%b1%b3%e7%b2%92%e5%ad%90%e5%82%ac%e5%8c%96%e5%89%82%e7%9a%84","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=112349","title":{"rendered":"Nano Energy\uff1a\u4e8c\u6c27\u5316\u78b3\u50ac\u5316\u52a0\u6c22\u4e4b\u91d1\u5c5e\u94dc\u7eb3\u7c73\u7c92\u5b50\u50ac\u5316\u5242\u7684\u4f18\u5316"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n

\u5229\u7528\u94dc\u50ac\u5316\u7684\u6709\u673a\u5408\u6210\u53cd\u5e94\u6bd4\u8f83\u591a\uff0c\u5982\u50ac\u5316\u52a0\u6c22\u3001C-C\u952e\u7684\u5f62\u6210\u6216\u73af\u52a0\u6210\u53cd\u5e94\u7b49\u3002\u800c\u672c\u6587\u5c31\u662f\u5728CO2<\/sub>\u6761\u4ef6\u4e0b\uff0c\u4f7f\u7528Cu\u7eb3\u7c73\u7c92\u5b50\u50ac\u5316CO2<\/sub>\u52a0\u6c22\u5236\u7532\u9187\u3002\u4e3e\u4f8b\u800c\u8a00\uff0c\u5176\u4e2d\u6709\u4e00\u79cd\u65b9\u6cd5\u662f\u91c7\u7528\u4e0d\u540c\u5c3a\u5bf8\u5927\u5c0f\u7684\u94dc\u7eb3\u7c73\u7c92\u5b50\u50ac\u5316Ullmann\u53cd\u5e94\uff0c\u6b64\u65b9\u6cd5\u7814\u7a76\u4e86\u94dc\u7eb3\u7c73\u7c92\u5f84\u7684\u5927\u5c0f\u5bf9Ullmann\u5076\u8054\u53cd\u5e94\u7684\u5f71\u54cd\u3002\u7814\u7a76\u53d1\u73b0\u6b64\u5b9e\u9a8c\u4e2d\u94dc\u7eb3\u7c73\u7c92\u5b50\u8d8a\u5c0f\uff0c\u53cd\u5e94\u4ea7\u7387\u8d8a\u9ad8\uff1b\u8fd8\u6709\u4e00\u79cd\u65b9\u6cd5\u662f\u201cClick\u201d\u53cd\u5e94\uff0c\u6b64\u53cd\u5e94\u4e3b\u8981\u5206\u4e3a\u4ee5\u4e0b\u4e24\u79cd\u65b9\u5f0f\uff0c\u4e00\u79cd\u662f\u901a\u8fc7\u5408\u6210\u6709\u673a\u7684\u53e0\u6c2e\u5316\u5408\u7269\u4f7f\u5176\u6eb6\u89e3\u4e8e\u6709\u673a\u6eb6\u5242\u4e2d\u800c\u53d1\u751f\u3002\u53e6\u4e00\u79cd\u65b9\u5f0f\u662f\u4ee5\u6c34\u4e3a\u6eb6\u5242\uff0c\u901a\u8fc7\u53e0\u6c2e\u5316\u94a0\u7684\u7f6e\u6362\u5b9e\u73b0\u4e00\u9505\u6cd5\u5408\u6210\u4e09\u6c2e\u5511\u3002\u8fd8\u6709\u8bb8\u591a\u94dc\u7eb3\u7c73\u7c92\u5b50\u7684\u53cd\u5e94\u673a\u7406\uff0c\u6709\u5174\u8da3\u7684\u8bfb\u8005\u53ef\u81ea\u884c\u67e5\u9605\uff0c\u7531\u4e8e\u672c\u6587\u4ee5\u4e8c\u6c27\u5316\u78b3\u6c14\u6c1b\u4e3a\u4e3b\u4f53\uff0c\u5177\u6709\u4e00\u5b9a\u9650\u5236\u6027\uff0c\u6240\u4ee5\u672c\u5f15\u8a00\u4e0d\u518d\u8d58\u8ff0\u5176\u4ed6\u65b9\u6cd5\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u4e86\u89e3\u4e8c\u6c27\u5316\u78b3\u6c22\u5316\u4f5c\u7528\u800c\u5bf9\u7532\u9187\u7684\u673a\u7406\u7814\u7a76\u5728\u73af\u5883\u95ee\u9898\u4e2d\u662f\u5f88\u91cd\u8981\u7684\uff0c\u751a\u81f3\u4ece\u793e\u4f1a\u548c\u6280\u672f\u89d2\u5ea6\u770b\u4f5c\u662f\u53ef\u518d\u751f\u80fd\u6e90\u5faa\u73af\u4f7f\u7528\u3002\u8377\u5170\u79d1\u6280\u5927\u5b66<\/strong>Eindhoven<\/strong>\u6559\u6388\u548c\u53a6\u95e8\u5927\u5b66\u5b59\u4e16\u521a\u6559\u6388<\/strong>\u7528\u5bc6\u5ea6\u6cdb\u51fd\u7406\u8bba\u8ba1\u7b97\u7cfb\u7edf\u5730\u7814\u7a76\u4e86\u94dc\u56e2\u7c07\u7684\u5927\u5c0f\uff0c\u5176\u5bf9\u53cd\u5e94\u7269\u548c\u53cd\u5e94\u4e2d\u95f4\u4ee5\u53ca\u4e0d\u540c\u53cd\u5e94\u6b65\u9aa4\u5728\u6f5c\u5728\u7684\u4e8c\u6c27\u5316\u78b3\u6709\u65e0\u52a0\u6c22\u7684\u6fc0\u6d3b\u4e0b\u5bf9\u7ed3\u5408\u5f3a\u5ea6\u7684\u5f71\u54cd\u3002\u5728CO\u548cO\u5438\u9644\u80fd\u4e0b\uff0c\u51e0\u4e4e\u6240\u6709\u7684\u57fa\u672c\u53cd\u5e94\u91cf\u5ea6\u90fd\u8868\u73b0\u51fa\u7ebf\u6027\u6269\u5c55\u5173\u7cfb\u3002\u5728\u5fae\u52a8\u529b\u5b66\u6a21\u62df\u4e2d\uff0c\u6211\u4eec\u9884\u6d4b\u4e2d\u7b49\u5927\u5c0fCu19<\/sub>\u56e2\u7c07\u4f1a\u663e\u793a\u51fa\u4e8c\u6c27\u5316\u78b3\u7684\u6700\u9ad8\u6c34\u5e73\u7684\u6c22\u5316\u53cd\u5e94\uff0c\u5e76\u4e14\u53ef\u4ee5\u5c06\u5176\u89c6\u4e3a\u4e2d\u7b49\u7684\u4e8c\u6c27\u5316\u78b3\u8986\u76d6\u548c\u4f4e\u7b49\u7684\u4e8c\u6c27\u5316\u78b3\u5206\u89e3\u754c\u9650\u3002\u4e0e55\u4e2a\u6216\u66f4\u5c11\u7684\u94dc\u539f\u5b50\u7684\u56e2\u7c07\u7684\u5438\u9644\u80fd\u76f8\u6bd4\uff0c\u53ef\u4ee5\u4ece\u7eb3\u7c73\u5c3a\u5ea6\u6548\u5e94\u5f3a\u70c8\u7684\u6ce2\u52a8\u4e2d\u89c2\u5bdf\u5230\u5176\u533a\u522b\u3002\u636e\u9884\u6d4b\uff0c\u66f4\u5927\u7684\u56e2\u7c07\u548c\u7eb3\u7c73\u7c92\u5b50\u5c06\u4f9d\u8d56\u4e8e\u8868\u9762\u539f\u5b50\u7684\u4f4e\u914d\u4f4d\u7684\u53cd\u5e94\u6027\u8d28\u3002\u4f18\u5316\u4e0e\u5728\u94dc\u56e2\u7c07\u548c\u5ef6\u4f38\u7684\u8868\u9762\u4e0a\u7684d-\u6ce2\u6bb5\u4e2d\u5fc3\u4f4d\u7f6e\u6240\u51b3\u5b9a\u7684\u53cd\u5e94\u9636\u6bb5\u7684\u952e\u5f3a\u5ea6\u6709\u5173\u3002d\u6ce2\u6bb5\u4e2d\u5fc3\u7684\u4e0a\u5347\u901a\u5e38\u4f1a\u52a0\u5f3a\u91d1\u5c5e\u4e4b\u95f4\u7684\u952e\u5408\u4f5c\u7528\uff0c\u4ece\u800c\u5f71\u54cd\u4e86\u4e8c\u6c27\u5316\u78b3\u7684\u51cf\u5c11\u6d3b\u52a8\u3002\u63d0\u4f9b\u7684\u5927\u5c0f\u6d3b\u52a8\u5173\u7cfb\u63d0\u4f9b\u4e86\u6761\u4ef6\uff0c\u5373\u6700\u5927\u9650\u5ea6\u5730\u5229\u7528\u4e8c\u6c27\u5316\u78b3\u6c22\u5316\u53cd\u5e94\u7684\u6027\u80fd\uff0c\u80fd\u5bf9\u94dc\u50ac\u5316\u5242\u7684\u8bbe\u8ba1\u6709\u66f4\u597d\u7684\u89c1\u89e3\uff0c\u5bf9\u4e8c\u6c27\u5316\u78b3\u7684\u6700\u5927\u8d28\u91cf\u53cd\u5e94\u6027\u53cd\u5e94\u52a0\u6c22\u6027\u80fd\u6709\u5386\u53f2\u6027\u8fdb\u5c55\u3002\u4e3a\u63d0\u4f9b\u7684\u5927\u5c0f\u6d3b\u52a8\u5173\u7cfb\u63d0\u4f9b\u4e86\u6709\u7528\u7684\u89c1\u89e3\uff0c\u53ef\u4ee5\u8fdb\u884c\u66f4\u597d\u7684\u94dc\u50ac\u5316\u5242\u7684\u8bbe\u8ba1\u3002<\/p>\n

\u8be5\u6210\u679c\u4ee5\u201cOptimum Cu Nanoparticle Catalysts for CO2 <\/sub>Hydrogenation Towards Methanol<\/strong>\u201d\u4e3a\u9898\u4e8e2017\u5e7411\u67089\u65e5\u53d1\u8868\u5728Nano Energy<\/strong>\u4e0a\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n

\u56fe<\/strong>1.Cun<\/sub>(n=13<\/strong>\u3001<\/strong>15<\/strong>\u3001<\/strong>19<\/strong>\u3001<\/strong>55<\/strong>\u548c<\/strong>79)<\/strong>\u56e2\u7c07\u4e0a\u7684\u5173\u952e\u4e2d\u95f4\u4ea7\u7269\u548c\u6269\u5c55\u8868\u9762\u4e0a\u7684\u51e0\u4f55\u56fe\u5f62\u4f18\u5316\u3002<\/strong><\/p>\n

\"\"<\/p>\n

\u56fe1\u4e2d\u6570\u636e\u8868\u660e\uff0c\u952e\u4e0e\u952e\u4e4b\u95f4\u7684\u4e2d\u95f4\u4ea7\u7269\u7684\u5438\u9644\u4f5c\u7528\uff0c\u5982CO\uff0cOH\u548cO\uff0c\u90fd\u662f\u4e0e\u7c92\u5b50\u7684\u7ed3\u6784\u5c3a\u5bf8\u5927\u5c0f\u76f8\u5173\u7684\u3002<\/p>\n

\u56fe<\/strong>2.<\/strong>\u8868\u793a\u6240\u6d89\u53ca\u7684\u7269\u79cd\u7684\u5438\u9644\u80fd\u91cf\u4e4b\u95f4\u7684\u7ebf\u6027\u6bd4\u4f8b\u5173\u7cfb<\/strong><\/p>\n

\"\"<\/p>\n

A:CO2\uff0cB:CHO\uff0cC:CH2O\uff0cD:CH3O\uff0cE:CH3OH\uff0cF:H\uff0cG:O\uff0cH:H2O\u548c\u5438\u9644\u80fd(CO+O)\u6216O\uff0c\u7528\u7ebf\u6027\u62df\u5408\u65b9\u7a0b\u662f\u8868\u793a\u3002<\/p>\n

\u56fe<\/strong>3. <\/strong>\u5229\u7528<\/strong>Cu<\/strong>\u805a\u96c6\u56e2\u548c\u6269\u5c55\u9762\u5bf9\u7532\u9187\u8fdb\u884c<\/strong>CO2<\/sub><\/strong>\u52a0\u6c22\u673a\u7406\u53cd\u5e94\u673a\u5236<\/strong><\/p>\n

\"\"<\/p>\n

\u56fe<\/strong>4.<\/strong>\u5bf9\u94dc\u7c07\u548c\u6269\u5c55\u8868\u9762\u7684\u4e8c\u6c27\u5316\u78b3\u51cf\u5c11\u7684\u6f5c\u5728\u80fd\u91cf\u8868\u9762\uff08\u6240\u6709\u7684\u57fa\u672c\u53cd\u5e94\u754c\u9650\u4ee5<\/strong>eV<\/strong>\u4e3a\u5355\u4f4d\u8868\u8fbe\uff09<\/strong><\/p>\n

\"\"<\/p>\n

\u56fe<\/strong>5.<\/strong>\u4e8c\u6c27\u5316\u78b3\u8fd8\u539f\u53cd\u5e94\u901f\u7387<\/strong>(log r<\/strong>\uff0c\u4ee5\u6469\u5c14<\/strong>-1<\/sup><\/strong>\u4f4d\u79fb<\/strong>-1<\/sup><\/strong>\u79d2<\/strong>-1<\/sup><\/strong>\u4e3a\u5355\u4f4d<\/strong>)<\/strong>\u4f5c\u4e3a<\/strong>CO<\/strong>\u548c<\/strong>O<\/strong>\u5438\u9644\u80fd\u4f5c\u7528\u5728\u94dc\u7c07\u548c\u8868\u9762<\/strong>(T = 500 K; p = 0.05 bar; CO\/O2 = 1:5)<\/strong>\u7684\u51fd\u6570\u3002\u4e0d\u540c<\/strong>Cu<\/strong>\u9884\u6d4b\u7684\u4e8c\u6c27\u5316\u78b3\u964d\u4f4e\u7387\u7c92\u5b50\u548c\u8868\u9762\u88ab\u6307\u793a\u3002<\/strong><\/p>\n

\"\"<\/p>\n

\u3010\u5c55\u671b\u3011<\/strong><\/p>\n

\u6709\u673a\u7269\u50ac\u5316\u662f\u4e2a\u201c\u53f2\u5b66\u201d\u95ee\u9898\uff0c\u5ef6\u4f38\u81f3\u4eca\uff0c\u5176\u5185\u5bb9\u53cd\u54cd\u535a\u5927\u7cbe\u6df1\u3002\u6700\u8fd1\uff0c\u5b59\u4e16\u521a\u6559\u6388\u5bf9\u91d1\u5c5e\u94dc\u7eb3\u7c73\u7c92\u5b50\u50ac\u5316\u4e8c\u6c27\u5316\u78b3\u4e0b\u5bf9\u7532\u9187\u52a0\u6c22\u4f5c\u7528\u673a\u7406\u8fdb\u884c\u4e86\u9610\u8ff0\uff0c\u76f8\u4fe1\u5728\u672a\u6765\u7684\u6709\u673a\u7269\u50ac\u5316\u9053\u8def\u4e0a\uff0c\u56fd\u4eba\u7684\u6210\u5c31\u5c06\u8d8a\u8d70\u8d8a\u52c7\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/strong>Optimum Cu Nanoparticle Catalysts for CO2<\/sub> Hydrogenation Towards Methanol<\/a>\uff08Nano Energy\uff0c2017, DOI:10.1016\/j.nanoen.2017.11.021\uff09<\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u7f16\u8f91\u90e8\u4ed8\u94b0\u7f16\u8f91\uff0c\u8d75\u98de\u9f99\u5ba1\u6838\uff0c\u70b9\u6211\u52a0\u5165\u6750\u6599\u4eba\u7f16\u8f91\u90e8<\/a>\u3002\u00a0<\/p>\n

\u6750\u6599\u6d4b\u8bd5\uff0c\u6570\u636e\u5206\u6790\uff0c\u4e0a<\/strong>\u6d4b\u8bd5\u8c37<\/strong><\/a>!<\/strong><\/p>\n","protected":false},"excerpt":{"rendered":"

\u3010\u5f15\u8a00\u3011 \u5229\u7528\u94dc\u50ac\u5316\u7684\u6709\u673a\u5408\u6210\u53cd\u5e94\u6bd4\u8f83\u591a\uff0c\u5982\u50ac\u5316\u52a0\u6c22\u3001C-C\u952e\u7684\u5f62\u6210\u6216\u73af\u52a0\u6210\u53cd\u5e94\u7b49\u3002\u800c\u672c\u6587\u5c31\u662f\u5728CO2\u6761\u4ef6\u4e0b\uff0c\u4f7f\u7528Cu\u7eb3\u7c73\u7c92\u5b50\u50ac\u5316CO2\u52a0\u6c22\u5236\u7532\u9187\u3002\u4e3e\u4f8b\u800c\u8a00\uff0c\u5176…<\/p>\n","protected":false},"author":230,"featured_media":112350,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215,2],"tags":[2559],"class_list":["post-112349","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-jiedu","category-keji","tag-co2"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/112349"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/230"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=112349"}],"version-history":[{"count":1,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/112349\/revisions"}],"predecessor-version":[{"id":112355,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/112349\/revisions\/112355"}],"wp:featuredmedia":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/media\/112350"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=112349"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=112349"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=112349"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}