{"id":110668,"date":"2017-11-13T06:30:07","date_gmt":"2017-11-12T22:30:07","guid":{"rendered":"\/\/m.iemloyee.com\/?p=110668"},"modified":"2017-11-09T20:59:45","modified_gmt":"2017-11-09T12:59:45","slug":"j-am-chem-soc-%e6%9f%93%e6%96%99%e6%95%8f%e5%8c%96%e5%88%86%e8%a7%a3hbr%e5%88%b6%e5%a4%87%e5%a4%aa%e9%98%b3%e8%83%bd%e7%87%83%e6%96%99","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=110668","title":{"rendered":"J. Am. Chem. Soc. : \u67d3\u6599\u654f\u5316\u5206\u89e3HBr\u5236\u5907\u592a\u9633\u80fd\u71c3\u6599"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n

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\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u5317\u5361\u7f57\u6765\u7eb3\u5927\u5b66\u6559\u5802\u5c71\u5206\u6821Gerald J. Meyer \u6559\u6388(\u901a\u8baf\u4f5c\u8005)\u7b49<\/strong>\u5236\u5907\u4e86\u4e00\u79cd\u65b0\u578b\u948c(II)\u591a\u5421\u5576\u914d\u5408\u7269\u654f\u5316\u9510\u949b\u77ffTiO2<\/sub>\u6216SnO2<\/sub>\/TiO2<\/sub>\u6838-\u58f3\u7eb3\u7c73\u9897\u7c92(CS)\u7684\u4ecb\u5b54\u8584\u819c\u4f5c\u4e3a\u5149\u50ac\u5316\u5242\u7528\u4e8e\u6eb4\u6c27\u5316\uff0c\u5e76\u5728J. Am. Chem. Soc.<\/strong>\u4e0a\u53d1\u8868\u4e86\u9898\u4e3a\u201cDye-Sensitized Hydrobromic Acid Splitting for Hydrogen Solar Fuel Production<\/strong>\u201d\u7684\u7814\u7a76\u8bba\u6587\u3002\u5728\u67d3\u6599\u654f\u5316\u5149\u7535\u6c60\u4e2d\u5bf9\u4e0a\u8ff0\u8584\u819c\u5149\u7535\u6781\u8fdb\u884c\u6d4b\u8bd5\u3002\u57281 N HBr(\u6eb6\u6db2)\u4e2d\uff0c\u6fc0\u53d1\u6001\u7535\u5b50\u6ce8\u5165\u5149\u50ac\u5316\u5242\u5e76\u53d1\u751f\u5149\u9a71\u52a8Br–<\/sup>\u6c27\u5316\u3002\u6ce8\u5165\u7684\u7535\u5b50\u5728\u94c2\u7535\u6781\u4e0a\u8bf1\u5bfc\u8d28\u5b50\u8fd8\u539f\u3002100 mW\u00b7cm-2<\/sup> \u767d\u5149\u7167\u5c04\u4e0b\uff0c\u5728\u76f8\u5e94\u7684\u504f\u538b\u4e0b\u53ef\u6d4b\u91cf\u52301.5 mA\u00b7cm-2<\/sup>\u7684\u6301\u7eed\u5149\u7535\u6d41\u3002Br-\u6c27\u5316\u7684\u6cd5\u62c9\u7b2c\u6548\u7387\u4e3a71\u00b15%\uff0c\u5236\u6c22\u7684\u6cd5\u62c9\u7b2c\u6548\u7387\u4e3a94\u00b12%\u3002\u5149\u7167\u671f\u95f4\u53ef\u4fdd\u630112 \u03bcmol\u00b7h-1<\/sup>\u7684\u5236\u6c22\u901f\u7387\u3002<\/p>\n

\u3010\u56fe\u6587\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u56fe1 \u50ac\u5316\u5242\u7684\u5206\u5b50\u4e0e\u80fd\u5e26\u7ed3\u6784<\/strong><\/p>\n

\"\"<\/p>\n

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b) \u8868\u9762\u952e\u5408Ru(btfmb)2<\/sub>P\u5149\u50ac\u5316\u5242\u7684\u57fa\u6001\/\u6fc0\u53d1\u6001(\u84dd\u8272)\u3001\u5355\u7535\u5b50Br-\u6c27\u5316\u8fd8\u539f\u7535\u5bf9(\u68d5\u8272)\u4ee5\u53caTiO2<\/sub> and SnO2<\/sub>\/TiO2<\/sub> CS\u4ecb\u5b54\u8584\u819c\u53d7\u4f53\u80fd\u7ea7\u7684\u6001\u5bc6\u5ea6(\u7070\u8272)\u3002<\/p>\n

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\"\"<\/p>\n

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\"\"<\/p>\n

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\u67d3\u6599\u654f\u5316Br–<\/sup>\u6c27\u5316\u53d1\u751f\u5668(600 mV)\u548c\u96c6\u7535\u6781(50 mV)\u7684\u7535\u6d41\u968f\u65f6\u95f4\u53d8\u5316\u66f2\u7ebf<\/p>\n

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\"\"<\/p>\n

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\u6587\u732e\u94fe\u63a5\uff1aDye-Sensitized Hydrobromic Acid Splitting for Hydrogen Solar Fuel Production<\/a><\/strong>\u00a0(J. Am. Chem. Soc., 2017, DOI: 10.1021\/jacs.7b09367)<\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u7f16\u8f91\u90e8\u65b0\u80fd\u6e90\u5c0f\u7ec4abc940504\u7f16\u8bd1\u6574\u7406\uff0c\u53c2\u4e0e\u65b0\u80fd\u6e90\u8bdd\u9898\u8ba8\u8bba\u8bf7\u52a0\u5165\u201c\u6750\u6599\u4eba\u65b0\u80fd\u6e90\u6750\u6599\u4ea4\u6d41\u7fa4 422065953\u201d\u3002<\/p>\n

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\u6750\u6599\u725b\u7f51\u4e13\u6ce8\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u53ca\u884c\u4e1a\u8fdb\u5c55\uff0c\u5982\u679c\u60a8\u5bf9\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u8fdb\u5c55\uff0c\u89e3\u8bfb\u9ad8\u6c34\u5e73\u6587\u7ae0\u6216\u662f\u8bc4\u8ff0\u884c\u4e1a\u6709\u5174\u8da3\uff0c\u70b9\u6211\u52a0\u5165\u7f16\u8f91\u90e8<\/a><\/strong>\u3002\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1tougao@cailiaoren.com\u3002<\/p>\n

\u4eea\u5668\u8bbe\u5907\u3001\u8bd5\u5242\u8017\u6750\u3001\u6750\u6599\u6d4b\u8bd5\u3001\u6570\u636e\u5206\u6790\uff0c\u627e\u6750\u6599\u4eba<\/a><\/strong>\u3001\u4e0a\u6d4b\u8bd5\u8c37<\/a><\/strong>\uff01<\/p>\n","protected":false},"excerpt":{"rendered":"

\u3010\u5f15\u8a00\u3011 \u5c06\u592a\u9633\u80fd\u8f6c\u5316\u4e3a\u53ef\u6301\u7eed\u7684\u592a\u9633\u80fd\u71c3\u6599\u663e\u793a\u51fa\u5de8\u5927\u7684\u6f5c\u529b\uff0c\u4e0e\u6b64\u540c\u65f6\u53ef\u51cf\u5c11\u6e29\u5ba4\u6c14\u4f53\u6392\u653e\u4ee5\u53ca\u5316\u77f3\u71c3\u6599\u7684\u4f7f\u7528\u3002\u9664\u5149\u50ac\u5316\u5206\u89e3\u6c34\u5236\u6c22\u5916\uff0c\u5206\u89e3\u6c22\u5364\u9178(HX)\u4e5f\u662f\u751f\u6210\u592a\u9633\u80fd…<\/p>\n","protected":false},"author":4931,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[],"class_list":["post-110668","post","type-post","status-publish","format-standard","hentry","category-jiedu"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/110668"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/4931"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=110668"}],"version-history":[{"count":6,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/110668\/revisions"}],"predecessor-version":[{"id":111125,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/110668\/revisions\/111125"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=110668"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=110668"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=110668"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}