{"id":110650,"date":"2017-11-08T14:30:40","date_gmt":"2017-11-08T06:30:40","guid":{"rendered":"\/\/m.iemloyee.com\/?p=110650"},"modified":"2017-11-08T17:30:34","modified_gmt":"2017-11-08T09:30:34","slug":"%e6%b1%aa%e4%b9%90%e4%bd%99sci-bull-%ef%bc%9a%e4%b8%89%e7%bb%b4ni-co-se%e7%ba%b3%e7%b1%b3%e7%bd%91%e7%8a%b6%e9%98%b5%e5%88%97%e7%bb%93%e6%9e%84%e4%bd%9c%e4%b8%ba%e9%ab%98%e6%95%88%e7%9a%84oer","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=110650","title":{"rendered":"\u6c6a\u4e50\u4f59Sci. Bull.\uff1a\u4e09\u7ef4Ni-Co-Se\u7eb3\u7c73\u7f51\u72b6\u9635\u5217\u7ed3\u6784\u4f5c\u4e3a\u9ad8\u6548\u7684OER\u50ac\u5316\u5242"},"content":{"rendered":"

\u3010\u5f15\u8a00<\/strong>\u3011<\/p>\n

\u7535\u89e3\u6c34\u6280\u672f\u4ea7\u51fa\u6e05\u6d01\u3001\u53ef\u518d\u751f\u7684\u6c22\u80fd\uff0c\u6709\u5229\u4e8e\u6539\u5584\u80fd\u6e90\u7ed3\u6784\uff0c\u7f13\u89e3\u73af\u5883\u6c61\u67d3\u3002\u7535\u89e3\u6c34\u7684\u9633\u6781\u534a\u53cd\u5e94\u2014\u2014\u6790\u6c27\u53cd\u5e94\uff08OER\uff09\u7684\u53cd\u5e94\u52a8\u529b\u5b66\u8fc7\u7a0b\u7f13\u6162\uff0c\u80fd\u8017\u5927\u3001\u6548\u7387\u4f4e\uff0c\u6210\u4e3a\u4e86\u7535\u89e3\u6c34\u6280\u672f\u53d1\u5c55\u7684\u74f6\u9888\u3002RuO2<\/sub>\u3001IrO2<\/sub>\u7b49\u8d35\u91d1\u5c5e\u6c27\u5316\u7269\u5bf9OER\u5177\u6709\u9ad8\u7684\u7535\u50ac\u5316\u6d3b\u6027\uff0c\u4f46\u5176\u4ef7\u683c\u6602\u8d35\uff0c\u50a8\u91cf\u6709\u9650\uff0c\u9650\u5236\u4e86\u5176\u89c4\u6a21\u5316\u5b9e\u9645\u5e94\u7528\u3002\u5bfb\u627e\u548c\u5f00\u53d1\u4e00\u79cd\u5ec9\u4ef7\u3001\u9ad8\u6548\u3001\u7a33\u5b9a\u7684\u6790\u6c27\u50ac\u5316\u5242\u6210\u4e3a\u4e86\u76ee\u524d\u8be5\u9886\u57df\u7814\u7a76\u7684\u70ed\u70b9\u4e0e\u96be\u70b9\u3002\u8fc7\u6e21\u91d1\u5c5e\u7852\u5316\u7269\u5177\u6709\u6210\u672c\u4f4e\u3001\u4e30\u5bcc\u7684\u4ef7\u6001\u3001\u72ec\u7279\u7684\u7535\u5b50\u7ed3\u6784\u4ee5\u53ca\u4f4e\u7535\u963b\u7b49\u7279\u6027\uff0c\u5728\u50ac\u5316\u7535\u89e3\u6c34\u9886\u57df\u6709\u6781\u5927\u7684\u6f5c\u529b\uff0c\u6709\u671b\u66ff\u4ee3\u8d35\u91d1\u5c5e\u3002\u8fd1\u65e5\uff0c\u6709\u5b66\u8005\u7814\u7a76\u4e86\u4e00\u79cd\u5728\u6ce1\u6cab\u954d\uff08NF\uff09\u8868\u9762\u539f\u4f4d\u751f\u957fNiCoSe2<\/sub>\u7eb3\u7c73\u5237\u9635\u5217\u7684\u9ad8\u6548\u6790\u6c27\u50ac\u5316\u5242\uff0c\u5177\u6709\u9ad8\u6bd4\u8868\u9762\u79ef\u3001\u4e30\u5bcc\u6d3b\u6027\u4f4d\u70b9\u3001\u826f\u597d\u5bfc\u7535\u6027\u4ee5\u53ca\u9ad8\u7a33\u5b9a\u6027\uff0c\u5bf9\u964d\u4f4eOER\u50ac\u5316\u80fd\u8017\u3001\u63a8\u52a8\u65b0\u80fd\u6e90\u53d1\u5c55\uff0c\u6709\u7740\u91cd\u8981\u7684\u79d1\u5b66\u610f\u4e49\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb<\/strong>\u3011<\/p>\n

\u8fd1\u65e5\uff0c\u5317\u4eac\u5316\u5de5\u5927\u5b66\u6c6a\u4e50\u4f59<\/strong>(\u901a\u8baf\u4f5c\u8005<\/strong>)\u56e2\u961f\u5728Sci. Bull.<\/strong>\u4e0a\u53d1\u5e03\u4e86\u4e00\u7bc7\u5173\u4e8e\u6790\u6c27\u50ac\u5316\u5242\u7684\u6587\u7ae0\uff0c\u9898\u4e3a\u201c3D nickel-cobalt diselenide nanonetwork for highly efficient oxygen evolution<\/strong>\u201d\u3002<\/p>\n

\u4f5c\u8005\u91c7\u7528\u6c34\u70ed\u5408\u6210\u6cd5\uff0c\u901a\u8fc7\u8c03\u63a7\u6c1f\u5316\u94f5\u7684\u7528\u91cf\uff0c\u5206\u522b\u5f97\u5230\u5177\u6709\u7eb3\u7c73\u68d2\u3001\u7eb3\u7c73\u5237\u548c\u7eb3\u7c73\u7247\u5f62\u8c8c\u7684NiCo-LDH\u9635\u5217\u7ed3\u6784\u3002\u968f\u540e\u5c06NiCo-LDH\u9635\u5217\u4f5c\u4e3a\u524d\u9a71\u4f53\uff0c\u5229\u7528\u7ba1\u5f0f\u7089\u70ed\u5904\u7406\u4fdd\u5f62\u7852\u5316\u7684\u7b56\u7565\uff0c\u5236\u5907\u4e86\u76f8\u5e94\u4e09\u7ef4\u7ed3\u6784\u7684NiCoSe2<\/sub>\u9635\u5217\u7eb3\u7c73\u7f51\u3002<\/p>\n

\u7814\u7a76\u7ed3\u679c\u8868\u660e\uff0cNiCoSe2<\/sub>\u7eb3\u7c73\u5237\u9635\u5217\u76f8\u6bd4\u4e8e\u7eb3\u7c73\u68d2\u548c\u7eb3\u7c73\u7247\u6709\u7740\u6700\u5927\u7684\u7535\u5316\u5b66\u6d3b\u6027\u9762\u79ef\uff0c\u5728\u78b1\u6027\u73af\u5883\u6761\u4ef6\u4e0bOER\u6027\u80fd\u6d4b\u8bd5\u4e2d\u4e5f\u8868\u73b0\u51fa\u6700\u597d\u7684\u6d3b\u6027\u3002<\/p>\n

\u3010\u56fe\u7247\u5bfc\u8bfb<\/strong>\u3011<\/p>\n

\u56fe1 \u6837\u54c1\u7684TEM\u56fe\u50cf<\/strong><\/p>\n

\"\"
\n (a-b<\/strong>) NiCoSe2<\/sub> \u7eb3\u7c73\u7247TEM\u56fe\u50cf\u548c\u76f8\u5e94\u7684HRTEM\u56fe\u50cf\uff1b<\/p>\n

(c-d<\/strong>) NiCoSe2<\/sub>\u7eb3\u7c73\u68d2\u4eceNiCoSe2<\/sub>\u7eb3\u7c73\u5237\/ NF\u7f51\u7edc\u4e2d\u5206\u79bb;<\/p>\n

(e<\/strong>) EDX\u5143\u7d20\u6620\u5c04\u56fe\u50cf\u3002<\/p>\n

\u56fe2 \u4e0d\u540c\u6c1f\u5316\u94f5\u7528\u91cf\u5236\u5907\u7684NiCo-LDH\/NF\u6837\u54c1\u7684SEM\u56fe<\/strong><\/p>\n

\"\"
\n (a<\/strong>) 0 mmol\uff1b<\/p>\n

(b<\/strong>) 6 mmol;<\/p>\n

(c<\/strong>) 12 mmol\uff1b<\/p>\n

(d-f<\/strong>) \u7ecf\u8fc7\u7852\u5316\u70ed\u5904\u7406\u540e\u76f8\u5e94\u7684NiCoSe2<\/sub>\/NF\u7684SEM\u56fe\u3002<\/p>\n

\u56fe3 \u6837\u54c1\u7684\u7535\u5316\u5b66\u6d4b\u91cf<\/strong><\/p>\n

\"\"<\/p>\n

(a<\/strong>) \u57281M KOH\u6eb6\u6db2\u4e2d\u626b\u901f\u4e3a1mV\/s\u4e0b\u2460 NiCoSe2<\/sub> \u7eb3\u7c73\u5237\/NF, \u2461 NiCoSe2<\/sub> \u7eb3\u7c73\u68d2\/NF \u2462 NiCoSe2<\/sub> \u7eb3\u7c73\u7247\/NF, \u2463 RuO2<\/sub>\/NF, \u2464 NiCo-LDH\/NF and \u2465 NF \u7684\u6781\u5316\u66f2\u7ebf\uff1b<\/p>\n

(b<\/strong>) \u6781\u5316\u66f2\u7ebf\u5bf9\u5e94\u7684\u5854\u83f2\u5c14\u659c\u7387;<\/p>\n

(c<\/strong>) NiCoSe2<\/sub> \u7eb3\u7c73\u5237\u57281.53 V\u7535\u4f4d\u4e0b\u7684\u8ba1\u65f6\u7535\u6d41\u66f2\u7ebf;<\/p>\n

(d<\/strong>) NiCoSe2<\/sub> \u7eb3\u7c73\u5237\u57285000CV\u5faa\u73af\u524d\u540e\u7684\u6781\u5316\u66f2\u7ebf\u3002<\/p>\n

\u3010\u5c0f\u7ed3<\/strong>\u3011<\/p>\n

\u8fd9\u7bc7\u6587\u7ae0\u4ecb\u7ecd\u4e86\u901a\u8fc7\u6c34\u70ed\u5408\u6210\u4e0e\u7852\u5316\u70ed\u5904\u7406\u76f8\u7ed3\u5408\u7684\u65b9\u6cd5\uff0c\u5236\u5907\u5177\u6709\u7eb3\u7c73\u68d2\u3001\u7eb3\u7c73\u5237\u548c\u7eb3\u7c73\u7247\u5f62\u8c8c\u7684NiCoSe2<\/sub>\u9635\u5217\u7ed3\u6784\u3002\u7814\u7a76\u7ed3\u679c\u663e\u793a\uff0c\u4e09\u7ef4\u7ed3\u6784\u7684NiCoSe2<\/sub>\u9635\u5217\u7eb3\u7c73\u7f51\u662f\u6027\u80fd\u4f18\u5f02\u7684OER\u50ac\u5316\u5242\uff0c\u5176\u591a\u7ea7\u7eb3\u7c73\u5237\u7ed3\u6784\u6bd4\u8868\u9762\u79ef\u9ad8\uff0c\u5145\u5206\u66b4\u9732\u4e30\u5bcc\u7684\u50ac\u5316\u6d3b\u6027\u4f4d\u70b9\uff0c\u4f20\u8d28\u901f\u7387\u5feb\uff0c\u4ea7\u7269O2<\/sub>\u9038\u51fa\u8fc5\u901f\u3002\u672c\u5de5\u4f5c\u4ece\u8fc7\u6e21\u91d1\u5c5e\u50ac\u5316\u5242\u7684\u7ed3\u6784\u8bbe\u8ba1\u548c\u5fae\u7ed3\u6784\u8c03\u63a7\u5165\u624b\uff0c\u5229\u7528\u6784-\u6548\u5173\u7cfb\u5168\u9762\u63d0\u5347OER\u6027\u80fd\uff0c\u4e3a\u975e\u8d35\u91d1\u5c5e\u50ac\u5316\u5242\u7684\u8bbe\u8ba1\u548c\u5236\u5907\u63d0\u4f9b\u4e86\u4e00\u4e2a\u65b0\u6750\u6599\u548c\u65b0\u601d\u8def\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5<\/strong>\uff1a 3D nickel-cobalt diselenide nanonetwork for highly efficient oxygen evolution\u00a0\u00a0<\/a>(Sci. Bull., 2017, 62(20): 1373-1379\uff0cDOI:10.1016\/j.scib.2017.09.012)<\/p>\n

\u672c\u6587\u7531Science Bulletin\u7f16\u8f91\u90e8<\/strong>\u4f9b\u7a3f\uff0c\u6750\u6599\u725b\u7f16\u8f91\u6574\u7406\u3002<\/p>\n

\u6750\u6599\u725b\u7f51\u4e13\u6ce8\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u53ca\u884c\u4e1a\u8fdb\u5c55\uff0c\u8fd9\u91cc\u6c47\u96c6\u4e86\u5404\u5927\u9ad8\u6821\u7855\u535a\u751f\u3001\u4e00\u7ebf\u79d1\u7814\u4eba\u5458\u4ee5\u53ca\u884c\u4e1a\u4ece\u4e1a\u8005\uff0c\u5982\u679c\u60a8\u5bf9\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u8fdb\u5c55\uff0c\u89e3\u8bfb\u9ad8\u6c34\u5e73\u6587\u7ae0\u6216\u662f\u8bc4\u8ff0\u884c\u4e1a\u6709\u5174\u8da3\uff0c\u70b9\u6211\u52a0\u5165\u7f16\u8f91\u90e8\u5927\u5bb6\u5ead<\/a>\u3002<\/p>\n

\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1tougao@cailiaoren.com\u3002<\/p>\n

\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1aRDD-2011-CHERISH\uff0c\u4efb\u4e39\u4e39\uff0c\u6211\u4eec\u4f1a\u9080\u8bf7\u5404\u4f4d\u8001\u5e08\u52a0\u5165\u4e13\u5bb6\u7fa4\u3002
\n<\/strong>
\n \u6750\u6599\u6d4b\u8bd5\u3001\u6570\u636e\u5206\u6790\uff0c\u4e0a\u6d4b\u8bd5\u8c37<\/a>\uff01<\/strong><\/p>\n","protected":false},"excerpt":{"rendered":"

\u3010\u5f15\u8a00\u3011 \u7535\u89e3\u6c34\u6280\u672f\u4ea7\u51fa\u6e05\u6d01\u3001\u53ef\u518d\u751f\u7684\u6c22\u80fd\uff0c\u6709\u5229\u4e8e\u6539\u5584\u80fd\u6e90\u7ed3\u6784\uff0c\u7f13\u89e3\u73af\u5883\u6c61\u67d3\u3002\u7535\u89e3\u6c34\u7684\u9633\u6781\u534a\u53cd\u5e94\u2014\u2014\u6790\u6c27\u53cd\u5e94\uff08OER\uff09\u7684\u53cd\u5e94\u52a8\u529b\u5b66\u8fc7\u7a0b\u7f13\u6162\uff0c\u80fd\u8017\u5927\u3001\u6548\u7387\u4f4e\uff0c\u6210\u4e3a…<\/p>\n","protected":false},"author":4915,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[116,33],"class_list":["post-110650","post","type-post","status-publish","format-standard","hentry","category-jiedu","tag-catalyst","tag-nano"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/110650"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/4915"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=110650"}],"version-history":[{"count":7,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/110650\/revisions"}],"predecessor-version":[{"id":110843,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/110650\/revisions\/110843"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=110650"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=110650"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=110650"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}