{"id":110538,"date":"2017-11-10T06:30:53","date_gmt":"2017-11-09T22:30:53","guid":{"rendered":"\/\/m.iemloyee.com\/?p=110538"},"modified":"2017-11-08T19:45:32","modified_gmt":"2017-11-08T11:45:32","slug":"nature-chemistry%ef%bc%9a%e5%9f%ba%e4%ba%8e%e5%a4%9a%e9%87%91%e5%b1%9e%e6%b0%a7%e9%85%b8%e7%9b%90%e7%9a%84%e6%9e%90%e6%b0%a7%e5%82%ac%e5%8c%96%e5%89%82-%e5%bc%ba%e9%85%b8%e6%80%a7%e6%9d%a1%e4%bb%b6","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=110538","title":{"rendered":"Nature Chemistry\uff1a\u57fa\u4e8e\u591a\u91d1\u5c5e\u6c27\u9178\u76d0\u7684\u6790\u6c27\u50ac\u5316\u5242-\u5f3a\u9178\u6027\u6761\u4ef6\u4e0b\u8d85\u8d8aIrO2\u7684\u7535\u50ac\u5316\u6790\u6c27\u6027\u80fd"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n

\u6790\u6c27\u53cd\u5e94\uff08OER\uff09\u4f5c\u4e3a\u6c34\u5206\u89e3\u5168\u53cd\u5e94\u4e2d\u7684\u4e00\u4e2a\u534a\u53cd\u5e94\uff0c\u5728\u6c27\u5316\u6c34\u4ea7\u751f\u6c27\u6c14\u7684\u540c\u65f6\u4e3a\u6790\u6c22\u53cd\u5e94\uff08HER\uff09\u63d0\u4f9b\u4e86\u6c22\u79bb\u5b50\u548c\u7535\u5b50\u3002\u4f5c\u4e3a\u4e00\u4e2a\u590d\u6742\u7684\u56db\u7535\u5b50\u6c27\u5316\u8fd8\u539f\u53cd\u5e94\uff0c\u6790\u6c27\u53cd\u5e94\u901a\u5e38\u9700\u8981\u5728\u9ad8\u7684\u8fc7\u7535\u4f4d\u4e0b\u8fdb\u884c\uff0c\u5176\u7f13\u6162\u7684\u52a8\u529b\u5b66\u7279\u5f81\u4e25\u91cd\u5236\u7ea6\u4e86\u91d1\u5c5e-\u7a7a\u6c14\u7535\u6c60\u3001\u71c3\u6599\u7535\u6c60\u7b49\u6e05\u6d01\u80fd\u6e90\u5668\u4ef6\u7684\u80fd\u91cf\u8f6c\u6362\u6548\u7387\u3002<\/p>\n

\u7531\u4e8e\u6790\u6c22\u53cd\u5e94\u66f4\u5bb9\u6613\u5728\u9178\u6027\u6761\u4ef6\u4e0b\u8fdb\u884c\uff0c\u800c\u5728\u78b1\u6027\u6761\u4ef6\u4e0b\u7535\u89e3\u6c34\u4ea7\u7269\u5f80\u5f80\u96be\u4ee5\u5206\u79bb\uff0c\u6240\u4ee5\u5728\u9178\u6027\u7535\u89e3\u8d28\u6eb6\u6db2\u4e2d\u8fdb\u884c\u7535\u89e3\u6c34\u5168\u53cd\u5e94\u662f\u4e00\u4e2a\u66f4\u597d\u7684\u9009\u62e9\u3002\u7136\u800c\uff0c\u7edd\u5927\u591a\u6570\u975e\u8d35\u91d1\u5c5e\u6790\u6c27\u50ac\u5316\u5242\u4ec5\u9002\u7528\u4e8e\u4e2d\u6027\u81f3\u78b1\u6027\u6761\u4ef6\u4e0b\u7684\u6c34\u5206\u89e3\uff0c\u800c\u5728\u5f3a\u9178\u6027\u6761\u4ef6\u4e0b\u80fd\u8fbe\u5230\u8f83\u9ad8\u6790\u6c27\u6d3b\u6027\u7684\u7535\u50ac\u5316\u5242\u4ec5\u6709\u4ee5IrO2<\/sub>\u548cRuO2<\/sub>\u4e3a\u4ee3\u8868\u7684\u8d35\u91d1\u5c5e\u57fa\u50ac\u5316\u5242\u3002\u56e0\u6b64\uff0c\u9700\u8981\u5bfb\u627e\u5728\u5f3a\u9178\u6027\u6761\u4ef6\u4e0b\u7535\u50ac\u5316\u6790\u6c27\u6d3b\u6027\u53ca\u7a33\u5b9a\u6027\u5747\u80fd\u4e0eIrO2<\/sub>\u76f8\u5ab2\u7f8e\u7684\u975e\u8d35\u91d1\u5c5e\u50ac\u5316\u5242\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u897f\u73ed\u7259\u5df4\u585e\u7f57\u90a3\u79d1\u5b66\u6280\u672f\u7814\u7a76\u6240\uff08BIST<\/strong>\uff09\u7684J. R. Galan-Mascaros<\/strong>\u7814\u7a76\u6559\u6388\uff08\u901a\u8baf\u4f5c\u8005\uff09<\/strong>\u7b49\u9996\u6b21\u5236\u5907\u51fa\u5728\u5f3a\u9178\u6027\u6761\u4ef6\u4e0b\u5177\u6709\u6781\u9ad8\u7535\u50ac\u5316\u6790\u6c27\u6d3b\u6027\u53ca\u7a33\u5b9a\u6027\u7684\u591a\u91d1\u5c5e\u6c27\u9178\u76d0\u56fa\u4f53\u50ac\u5316\u5242\u3002\u5728\u8fd9\u9879\u5de5\u4f5c\u4e2d\uff0c\u7814\u7a76\u4eba\u5458\u901a\u8fc7\u7b80\u5355\u7684\u6db2\u76f8\u590d\u5206\u89e3\u53cd\u5e94\u5e76\u5728\u52a0\u70ed\u6761\u4ef6\u4e0b\u7ecf\u9178\u6eb6\u6db2\u6d88\u5316\u5904\u7406\uff0c\u5236\u5907\u51faCs15<\/sub>K[Co9<\/sub>(H2<\/sub>O)6<\/sub>(OH)3<\/sub>(HPO4<\/sub>)2<\/sub>(PW9<\/sub>O34<\/sub>)3<\/sub>] \u00b728H2<\/sub>O\uff08\u8bb0\u4e3aCs[Co-POM]\uff09\u548cBa8<\/sub>[Co9<\/sub>(H2<\/sub>O)6<\/sub>(OH)3<\/sub>(HPO4<\/sub>)2<\/sub>(PW9<\/sub>O34<\/sub>)3<\/sub>] \u00b755H2<\/sub>O\uff08\u8bb0\u4e3aBa[Co-POM]\uff09\u7684\u56fa\u4f53\u7c89\u672b\uff0c\u5e76\u5c06\u8be5\u7c89\u672b\u4e0e\u78b3\u7cca\uff08CP\uff09\u590d\u5408\u5236\u5f97Cs[Co-POM]\/CP\u548cBa[Co-POM] \/CP\u7535\u6781\u3002\u8fd9\u4e9b\u7535\u6781\u57281 M H2<\/sub>SO4<\/sub>\u6eb6\u6db2\uff08pH\u7ea6\u4e3a0.1~0.2\uff09\u4e2d\u8868\u73b0\u51fa\u6781\u9ad8\u7684\u7535\u50ac\u5316\u6790\u6c27\u6d3b\u6027\u53ca\u7a33\u5b9a\u6027\uff0c\u5176\u4e2dBa[Co-POM] \/CP\u7535\u6781\u7684\u8d77\u59cb\u8fc7\u7535\u4f4d\u4ec5\u4e3a88 mV\uff0c\u6bd4\u76f8\u540c\u6761\u4ef6\u4e0bIrO2<\/sub> \/CP\u7535\u6781\u7684\u8d77\u59cb\u8fc7\u7535\u4f4d\u4f4e246 mV\u3002Ba[Co-POM] \/CP\u7535\u6781\u8fbe\u52301 mA\/cm2<\/sup>\u548c10 mA\/cm2<\/sup>\u7684\u7535\u6d41\u5bc6\u5ea6\u5206\u522b\u9700\u8981189 mV\u548c361 mV\u7684\u8fc7\u7535\u4f4d\uff0c\u6bd4\u76f8\u540c\u6761\u4ef6\u4e0bIrO2<\/sub> \/CP\u7535\u6781\u6240\u9700\u8981\u7684\u8fc7\u7535\u4f4d\u5206\u522b\u4f4e190 mV\u548c97 mV\u3002Cs[Co-POM] \/CP\u548cBa[Co-POM] \/CP\u57281 M H2<\/sub>SO4<\/sub>\u6eb6\u6db2\u4e2d\u7684Tafel\u659c\u7387\u76f8\u8fd1\uff0c\u5206\u522b\u4e3a98 mV\/dec\u548c97 mV\/dec\uff0c\u9ad8\u4e8eIrO2<\/sub> \/CP\u5728\u540c\u7b49\u6761\u4ef6\u4e0b\u7684Tafel\u659c\u7387\uff0866 mV\/dec\uff09\u3002\u7814\u7a76\u4eba\u5458\u901a\u8fc7\u7535\u5316\u5b66\u6027\u80fd\u5bf9\u6bd4\u53caXRD\u3001XPS\u7b49\u7ed3\u6784\u8868\u5f81\u624b\u6bb5\u6392\u9664\u4e86\u7535\u50ac\u5316\u6790\u6c27\u8fc7\u7a0b\u4e2d\u539f\u4f4d\u751f\u6210\u9ad8\u6d3b\u6027CoOx<\/sub>\u7269\u79cd\u7684\u5f71\u54cd\u3002ICP-OES\u6d4b\u8bd5\u8868\u660e\uff0c\u5f53\u7535\u6d41\u5bc6\u5ea6\u4e3a1 mA\/cm2<\/sup>\u65f6\uff0cCs[Co-POM] \/CP\u548cBa[Co-POM] \/CP\u57281 M H2<\/sub>SO4<\/sub>\u6eb6\u6db2\u4e2d\u7535\u89e32 h\u540e\u7684\u91d1\u5c5e\u79bb\u5b50\u6eb6\u51fa\u91cf\u4ec5\u57281~10 ppm\u6570\u91cf\u7ea7\uff0c\u6545\u6eb6\u6db2\u4e2d\u91d1\u5c5e\u79bb\u5b50\u7684\u5747\u76f8\u50ac\u5316\u5bf9\u6790\u6c27\u53cd\u5e94\u7684\u8d21\u732e\u53ef\u4ee5\u5ffd\u7565\u4e0d\u8ba1\u3002\u6b64\u5916\uff0c\u8be5\u7814\u7a76\u8fd8\u53d1\u73b0\u78b3\u7cca\u5bfc\u7535\u57fa\u5e95\u4e0e\u6709\u673a\u7c98\u5408\u5242\u7684\u4ecb\u5165\u80fd\u589e\u5f3a\u7535\u6781\u8868\u9762\u7684\u758f\u6c34\u6027\uff0c\u4ece\u800c\u63d0\u9ad8\u591a\u91d1\u5c5e\u6c27\u9178\u76d0\u751a\u81f3\u8fc7\u6e21\u91d1\u5c5e\u6c27\u5316\u7269\uff08\u5982CoOx<\/sub>\uff09\u7b49\u6790\u6c27\u50ac\u5316\u5242\u5728\u9178\u6027\u6eb6\u6db2\u4e2d\u7684\u7a33\u5b9a\u6027\u3002\u8be5\u7814\u7a76\u6210\u679c\u4ee5\u201cPolyoxometalate electrocatalysts based on earth-abundant metals for efficient water oxidation in acidic media<\/strong>\u201d\u4e3a\u9898\uff0c\u53d1\u8868\u5728Nat.Chem.<\/strong>\u4e0a\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n

\u56fe1. Co-POM\u7684\u5206\u5b50\u7ed3\u6784\u793a\u610f\u56fe\u53caCs[Co-POM]\/CP\u548cBa[Co-POM] \/CP\u7684\u7535\u5316\u5b66\u6027\u80fd\u8868\u5f81<\/strong><\/p>\n

\"\"<\/p>\n

(a) [Co9<\/sub>(H2<\/sub>O)6<\/sub>(OH)3<\/sub>(HPO4<\/sub>)2<\/sub>(PW9<\/sub>O34<\/sub>)3<\/sub>]16-<\/sup>\u7684\u5206\u5b50\u7ed3\u6784\u793a\u610f\u56fe\uff0c\u5176\u4e2d\u7c89\u7ea2\u8272\u5c0f\u7403\u4ee3\u8868Co\u539f\u5b50\uff0c\u7ea2\u8272\u5c0f\u7403\u4ee3\u8868O\u539f\u5b50\uff0c\u7070\u8272\u516b\u9762\u4f53\u8868\u793aWO6<\/sub>\u7ed3\u6784\u5355\u5143\uff0c\u9ed1\u8272\u56db\u9762\u4f53\u8868\u793aPO4<\/sub>\u7ed3\u6784\u5355\u5143\u3002<\/p>\n

(b,c) \u4e0d\u540c\u50ac\u5316\u5242\u542b\u91cf\u4e0b (b) Cs[Co-POM]\/CP \u548c (c) Ba[Co-POM] \/CP\u57281 M H2<\/sub>SO4<\/sub>\u6eb6\u6db2\u4e2d\u7684\u6781\u5316\u66f2\u7ebf\u3002<\/p>\n

\u56fe2. \u7535\u5316\u5b66\u6027\u80fd\u8868\u5f81\u53ca\u5bf9\u6bd4<\/strong><\/p>\n

\"\"<\/p>\n

(a) 40% Cs[Co-POM]\u300140% Ba[Co-POM]\u548c\u4e0d\u540c\u50ac\u5316\u5242\u542b\u91cf\u4e0bIrO2<\/sub> \/CP\u57281 M H2<\/sub>SO4<\/sub>\u6eb6\u6db2\u4e2d\u7684\u6781\u5316\u66f2\u7ebf\u5bf9\u6bd4\u56fe\u3002<\/p>\n

(b) \u50ac\u5316\u5242\u542b\u91cf\u4e3a30%\u65f6\u4e0d\u540c\u50ac\u5316\u5242\/CP\u4f53\u7cfb\u57281 M H2<\/sub>SO4<\/sub>\u6eb6\u6db2\u4e2d\u7684Tafel\u659c\u7387\u6bd4\u8f83\u3002<\/p>\n

(c) 40% Cs[Co-POM]\u300140% Ba[Co-POM]\u548c\u4e0d\u540c\u50ac\u5316\u5242\u542b\u91cf\u4e0bCo3<\/sub>O4<\/sub>\/CP\u57281 M H2<\/sub>SO4<\/sub>\u6eb6\u6db2\u4e2d\u7684\u6781\u5316\u66f2\u7ebf\u5bf9\u6bd4\u56fe\u3002<\/p>\n

(d) \u50ac\u5316\u5242\u542b\u91cf\u4e3a30%\u65f6\u4e0d\u540c\u50ac\u5316\u5242\/CP\u4f53\u7cfb\u5bf9\u91d1\u5c5e\u539f\u5b50\u6d3b\u6027\u4e2d\u5fc3\u542b\u91cf\u5f52\u4e00\u5316\u540e\u5f97\u5230\u7684\u6781\u5316\u66f2\u7ebf\u5bf9\u6bd4\u56fe\u3002<\/p>\n

\u56fe3. \u4e0d\u540c\u50ac\u5316\u5242\/CP\u7535\u6781\u7684\u7535\u5316\u5b66\u7a33\u5b9a\u6027\u5bf9\u6bd4<\/strong><\/p>\n

\"\"<\/p>\n

(a) \u8fc7\u7535\u4f4d\u4e3a250 mV\u65f6\uff0c\u50ac\u5316\u5242\u542b\u91cf\u4e3a30%\u7684\u4e0d\u540c\u50ac\u5316\u5242\/CP\u4f53\u7cfb\u57281 M H2<\/sub>SO4<\/sub>\u6eb6\u6db2\u4e2d\u7684\u7535\u6d41\u5bc6\u5ea6-\u65f6\u95f4\u66f2\u7ebf\u3002\u7a7a\u5fc3\u539f\u70b9\u8868\u793a\u6bcf\u7535\u89e31 h\u540e\u6682\u505c20 min\u518d\u91cd\u65b0\u5f00\u59cb\u7535\u89e3\u5bfc\u81f4\u7684\u7535\u6d41\u5bc6\u5ea6\u53d8\u5316\u3002<\/p>\n

(b) \u5c06\u56fe(a)\u653e\u5927\u5f97\u5230\u7684\u7535\u6d41\u5bc6\u5ea6-\u65f6\u95f4\u66f2\u7ebf\u3002<\/p>\n

(c) \u5c06\u56fe(a)\u5bf9\u91d1\u5c5e\u539f\u5b50\u542b\u91cf\u5f52\u4e00\u5316\u540e\u5f97\u5230\u7684\u6781\u5316\u66f2\u7ebf\u3002<\/p>\n

\u5206\u6790\uff1a\u56fe(a)\u4e2d\u7a7a\u5fc3\u539f\u70b9\u8868\u793a\u7684\u7535\u6d41\u5bc6\u5ea6\u53d8\u5316\u8d8b\u52bf\u8868\u660e\uff0c\u7535\u89e3\u521a\u5f00\u59cb\u65f6\u7684\u524d\u51e0\u4e2a\u5c0f\u65f6\u4ee5\u5185\uff0c\u7535\u6d41\u5bc6\u5ea6\u4e0b\u964d\u7684\u4e3b\u8981\u539f\u56e0\u662f\u7535\u5bb9\u7535\u6d41\u7684\u8d21\u732e\u3002\u8fd9\u53ef\u80fd\u662f\u7531\u4e8e\u7535\u50ac\u5316\u8fc7\u7a0b\u4e2d\u53d1\u751f\u7684\u7535\u8377\u5c40\u57df\u5316\u5f15\u8d77\u7535\u6781\u4f53\u7cfb\u7684\u7535\u963b\u5347\u9ad8\uff0c\u4ece\u800c\u4f7f\u7535\u6d41\u5bc6\u5ea6\u4e0b\u964d\u3002<\/p>\n

\u88681. \u7535\u50ac\u5316\u6790\u6c27\u6027\u80fd\u5bf9\u6bd4<\/strong><\/p>\n

\"\"<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n

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\u6587\u732e\u94fe\u63a5\uff1a<\/strong>Polyoxometalate electrocatalysts based on earth-abundant metals for efficient water oxidation in acidic media<\/a> (Nat.Chem., 2017, DOI: 10.1038\/nchem.2874)<\/p>\n

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