{"id":110424,"date":"2017-11-13T06:30:55","date_gmt":"2017-11-12T22:30:55","guid":{"rendered":"\/\/m.iemloyee.com\/?p=110424"},"modified":"2017-11-09T21:03:01","modified_gmt":"2017-11-09T13:03:01","slug":"nat-commun-%ef%bc%9a%e6%b0%a2%e4%bb%a3%e7%9f%b3%e5%a2%a8%e7%82%94%e4%bd%9c%e4%b8%ba%e4%ba%8c%e7%bb%b4%e7%a2%b3%e5%9f%ba%e6%9f%94%e6%80%a7%e7%94%b5%e6%9e%81%e5%9c%a8%e9%94%82%e7%94%b5%e5%92%8c","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=110424","title":{"rendered":"Nat. Commun.\uff1a\u6c22\u4ee3\u77f3\u58a8\u7094\u4f5c\u4e3a\u4e8c\u7ef4\u78b3\u57fa\u67d4\u6027\u7535\u6781\u5728\u9502\u7535\u548c\u94a0\u7535\u4e2d\u7684\u5e94\u7528"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n

\u81eaWilliams\u7b491969\u5e74\u9996\u6b21\u62a5\u9053\u540e\uff0c\u67d4\u6027\u7535\u6781\u6750\u6599\u7531\u4e8e\u5176\u8bbe\u8ba1\u7684\u591a\u6837\u6027\u3001\u7075\u6d3b\u6027\u3001\u4f4e\u6210\u672c\u548c\u73af\u4fdd\u7684\u7279\u6027\u5438\u5f15\u4e86\u8bf8\u591a\u79d1\u5b66\u5bb6\u7684\u7814\u7a76\u5174\u8da3\u3002\u7136\u800c\u5bfc\u7535\u805a\u5408\u7269\u57fa\u6709\u673a\u6750\u6599\u6240\u9762\u4e34\u7684\u4e3b\u8981\u95ee\u9898\u662f\u8f83\u4f4e\u7684\u80fd\u91cf\u5bc6\u5ea6\u548c\u7a33\u5b9a\u6027\u3002\u6b64\u5916\uff0c\u5728\u4f20\u7edf\u7684\u975e\u6c34\u7535\u89e3\u8d28\u4e2d\uff0c\u5176\u4ed6\u6750\u6599(\u5982\u6709\u673a\u4e8c\u786b\u5316\u7269\u3001\u6709\u673a\u81ea\u7531\u57fa\u548c\u7fb0\u57fa)\u672c\u8eab\u5bfc\u7535\u6027\u4f4e\u4e14\u6eb6\u89e3\u5ea6\u9ad8\u3002\u5bcc\u78b3\u6750\u6599\u6216\u8005\u5168\u78b3\u6846\u67b6\u4e8c\u7ef4\u6750\u6599\u5177\u6709\u7279\u6b8a\u7684\u70ed\/\u5316\u5b66\u7a33\u5b9a\u6027\u3001\u826f\u597d\u7684\u5bfc\u7535\u7387\u3001\u9ad8\u5f3a\u5ea6\u4ee5\u53ca\u975e\u6bd4\u5bfb\u5e38\u7684\u673a\u68b0\u6027\u80fd(\u5982\u5f3a\u70c8\u7684\u526a\u5207\u53d8\u5f62)\u3002\u4e0a\u8ff0\u4f18\u8d8a\u7279\u6027\u4f7f\u5176\u6709\u671b\u6210\u4e3a\u9502\u79bb\u5b50\u7535\u6c60(LIBs)\u548c\u94a0\u79bb\u5b50\u7535\u6c60(SIBs)\u7535\u6781\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u5728\u4e2d\u79d1\u9662\u674e\u7389\u826f\u9662\u58eb<\/strong>\u7684\u5e26\u9886\u4e0b\uff0c\u4e2d\u79d1\u9662\u9752\u5c9b\u751f\u7269\u80fd\u6e90\u4e0e\u8fc7\u7a0b\u7814\u7a76\u6240\u9ec4\u957f\u6c34\u7814\u7a76\u5458<\/strong>(\u5171\u540c\u901a\u8baf\u4f5c\u8005<\/strong>)\u548c\u4e2d\u79d1\u9662\u5316\u5b66\u7814\u7a76\u6240<\/strong>\u5408\u4f5c\uff0c\u4e13\u6ce8\u4e8e\u63d0\u9ad8\u7535\u5bfc\u7387\u3001\u5bb9\u91cf\u548c\u826f\u597d\u7684\u4f53\u76f8\u79bb\u5b50\u8fd0\u8f93\u7684\u78b3\u6750\u6599\u5206\u5b50\u8bbe\u8ba1\uff0c\u901a\u8fc7\u5728\u94dc\u7b94\u4e0a\u8fdb\u884c\u539f\u4f4d\u7684\u4e09\u4e59\u7094\u57fa\u82ef\u4ea4\u53c9\u5076\u8054\u53cd\u5e94\u5236\u5907\u4e86\u78b3\u6846\u67b6\u6c22\u53d6\u4ee3\u77f3\u58a8\u7094(HsGDY)\u8584\u819c\uff0c\u5e76\u5728Nat. Commun.<\/strong>\u4e0a\u53d1\u8868\u4e86\u9898\u4e3a\u201cHydrogen substituted graphdiyne as carbon-rich flexible electrode for lithium and sodium ion batteries<\/strong>\u201d\u7684\u7814\u7a76\u8bba\u6587\u3002\u4e0a\u8ff0\u78b3\u6750\u6599\u8584\u819c\u53ef\u4ee5\u4f5c\u4e3a\u9502\u79bb\u5b50\u548c\u94a0\u79bb\u5b50\u7535\u6c60\u72ec\u7acb\u7684\u67d4\u6027\u7535\u6781\uff0c\u9502\u79bb\u5b50\u7535\u6c60\u4e2d\u53ef\u9006\u5bb9\u91cf\u53ef\u8fbe\u52301050 mAh\u00b7g-1<\/sup>\uff0c\u94a0\u79bb\u5b50\u7535\u6c60\u4e2d\u4e3a650 mAh\u00b7g-1<\/sup>\u3002\u7535\u6781\u8fd8\u663e\u793a\u51fa\u4f18\u8d8a\u7684\u500d\u7387\u548c\u5faa\u73af\u6027\u80fd\uff0c\u5e94\u5f52\u56e0\u4e8e\u5176\u6269\u5c55\u7684\u03c0-\u5171\u8f6d\u4f53\u7cfb\u4ee5\u53ca\u9ad8\u8868\u9762\u79ef\u7684\u5206\u5c42\u5b54\u9699\u3002<\/p>\n

\u3010\u56fe\u6587\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u56fe1 HsGDY\u7684\u7ed3\u6784\u548c\u5916\u89c2<\/strong><\/p>\n

\"\"<\/p>\n

a) HsGDY \u7684\u5408\u6210\u793a\u610f\u56fe\uff1b \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0b) HsGDY\u8584\u819c\u7684\u6570\u7801\u7167\u7247\uff1b<\/p>\n

c) HsGDY\u4e2d\u78b3\u548c\u5b98\u80fd\u56e2\u7684\u79cd\u7c7b\uff1b \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0d) HsGDY \u768413<\/sup>C \u56fa\u6001NMR\u5149\u8c31\uff1b<\/p>\n

e) HsGDY\u7684XRD\u8c31\u7ebf\uff1b \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0f) HsGDY \u7684XPS\u5149\u8c31\uff1b<\/p>\n

g) HsGDY\u7684Raman\u5149\u8c31\uff1b \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 h) HsGDY\u7684FT-IR\u5149\u8c31\u3002<\/p>\n

\u56fe2 HsGDY\u7684\u5f62\u8c8c<\/strong><\/p>\n

\"\"<\/p>\n

a,b) HsGDY\u7684TEM\u56fe\u50cf\uff1b<\/p>\n

c) HsGDY\u7684\u6a2a\u65ad\u9762TEM\u56fe\u50cf\uff1b<\/p>\n

d,e) HsGDY\u7684SEM\u56fe\u50cf\uff1b<\/p>\n

f) HsGDY\u7684\u6a2a\u65ad\u9762SEM\u56fe\u50cf\uff1b<\/p>\n

g) HsGDY\u7684\u6c2e\u6c14\u5438\u9644-\u8131\u9644\u7b49\u6e29\u7ebf\uff1b<\/p>\n

h,i) HsGDY\u7684DFT\u589e\u91cf\u5f0f\u5b54\u5f84\u5206\u5e03\u3002<\/p>\n

\u56fe3 HsGDY\u7535\u6781\u5728LIB\u4e2d\u7684\u7535\u5316\u5b66\u6027\u80fd<\/strong><\/p>\n

\"\"<\/p>\n

a) HsGDY\u57fa\u7535\u67810.1 A\u00b7g-1<\/sup>\u4e0b\u7684\u5145\u653e\u7535\u66f2\u7ebf\uff1b<\/p>\n

b) LIBs\u67d4\u6027\u7535\u6781\u7684\u500d\u7387\u6027\u80fd\uff1b<\/p>\n

c,d) \u67d4\u6027\u7535\u6781\u57280.1 A\u00b7g-1<\/sup>\u548c1 A\u00b7g-1<\/sup>\u4e0b\u7684\u5faa\u73af\u6027\u80fd\uff1b<\/p>\n

e) HsGDY\u50a8\u9502\u673a\u7406\uff1b<\/p>\n

f) \u7531HsGDY\u7ec4\u6210\u7684\u900f\u660e\u53ef\u5f2f\u66f2LIB\u3002<\/p>\n

\u56fe4 HsGDY\u7535\u6781\u5728SIB\u4e2d\u7684\u7535\u5316\u5b66\u6027\u80fd<\/strong><\/p>\n

\"\"<\/p>\n

a) HsGDY\u57fa\u7535\u67810.1 A\u00b7g-1<\/sup>\u4e0b\u7684\u5145\u653e\u7535\u66f2\u7ebf\uff1b<\/p>\n

b) LIBs\u67d4\u6027\u7535\u6781\u7684\u500d\u7387\u6027\u80fd\uff1b<\/p>\n

c-e) \u67d4\u6027\u7535\u6781\u57280.1 A\u00b7g-1<\/sup>\u30010.5 A\u00b7g-1<\/sup>\u548c1 A\u00b7g-1<\/sup>\u4e0b\u7684\u5faa\u73af\u6027\u80fd\u3002<\/p>\n

f) \u9502\u79bb\u5b50\u548c\u94a0\u79bb\u5b50\u5728\u5bcc\u78b3\u6846\u67b6\u4e2d\u7684\u6269\u6563\u9014\u5f84\u3002<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n

\u8be5\u7814\u7a76\u901a\u8fc7\u4ea4\u53c9\u5076\u8054\u53cd\u5e94\u5236\u5907\u4e86HsGDY\u8584\u819c\u3002\u4e0a\u8ff0\u5177\u6709\u591a\u5b54\u7ed3\u6784\u548c\u82b3\u57fa\u6c22(Ar-H)\u7684\u6269\u5c55\u03c0-\u5171\u8f6d\u78b3\u9aa8\u67b6\u5177\u6709\u9ad8\u7684\u6bd4\u8868\u9762\u79ef\u3001\u826f\u597d\u7684\u7535\u5316\u5b66\u6027\u80fd\u4ee5\u53ca\u5927\u91cf\u7684\u6d3b\u6027\u79bb\u5b50\u7ed3\u5408\u4f4d\u70b9\u3002\u6b64\u5916\uff0c\u5bfc\u7535\u826f\u597d\u7684\u4e09\u7ef4\u5206\u7ea7\u591a\u5b54\u7ed3\u6784\u4e3a\u7535\u5b50\u7684\u8df3\u8dc3\u548c\u8fd0\u8f93\u63d0\u4f9b\u4e86\u57fa\u8d28\uff0c\u4ee5\u786e\u4fdd\u7535\u8377\u9ad8\u6548\u6536\u96c6\u548c\u6269\u6563\u3002\u53d7\u76ca\u4e8e\u6b64\uff0c\u8be5\u72ec\u7acb\u7684\u67d4\u6027\u7535\u6781\u53ef\u9006\u548c\u7a33\u5b9a\u5bb9\u91cf\u5f97\u5230\u4e86\u6781\u5927\u6539\u5584\uff0c\u5728LIBs\u4e2d\u9ad8\u4e8e\u56fa\u6709\u78b3\u540c\u7d20\u5f02\u5f62\u4f53\u548c\u5bfc\u7535\u6709\u673a\u5206\u5b50\u3002100\u5708\u5faa\u73af\u540eSIB\u4e2d\u53ef\u9006\u5bb9\u91cf\u9ad8\u8fbe650 mAh\u00b7g-1<\/sup>\uff0c\u5728\u73b0\u6709\u62a5\u9053\u7684\u67d4\u6027\u7535\u6781\u4e2d\u662f\u8f83\u9ad8\u7684\u3002\u4f18\u8d8a\u7684\u5faa\u73af\u6027\u80fd\u3001\u9ad8\u53ef\u9006\u5bb9\u91cf\u548c\u8f83\u9ad8\u7684\u500d\u7387\u5bb9\u91cf\u4f7f\u5f97HsGDY\u5728LIBs\u548cSIBs\u4e2d\u5e94\u7528\u524d\u666f\u826f\u597d\u3002\u8be5\u65b0\u578b\u9633\u6781\u6750\u6599\u4e3a\u9ad8\u6027\u80fd\u67d4\u6027\u7535\u6781\u63d0\u4f9b\u4e86\u4e00\u79cd\u65b0\u7684\u8bbe\u8ba1\u7406\u5ff5\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1aHydrogen substituted graphdiyne as carbon-rich flexible electrode for lithium and sodium ion batteries<\/a><\/strong>\u00a0(Nat. Commun., 2017, DOI: 10.1038\/s41467-017-01202-2)<\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u7f16\u8f91\u90e8\u65b0\u80fd\u6e90\u5c0f\u7ec4abc940504\u7f16\u8bd1\u6574\u7406\uff0c\u53c2\u4e0e\u65b0\u80fd\u6e90\u8bdd\u9898\u8ba8\u8bba\u8bf7\u52a0\u5165\u201c\u6750\u6599\u4eba\u65b0\u80fd\u6e90\u6750\u6599\u4ea4\u6d41\u7fa4 422065953\u201d\u3002<\/p>\n

\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1aRDD-2011-CHERISH\uff0c\u4efb\u4e39\u4e39\uff0c\u6211\u4eec\u4f1a\u9080\u8bf7\u5404\u4f4d\u8001\u5e08\u52a0\u5165\u4e13\u5bb6\u7fa4\u3002<\/strong><\/p>\n

\u6750\u6599\u725b\u7f51\u4e13\u6ce8\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u53ca\u884c\u4e1a\u8fdb\u5c55\uff0c\u5982\u679c\u60a8\u5bf9\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u8fdb\u5c55\uff0c\u89e3\u8bfb\u9ad8\u6c34\u5e73\u6587\u7ae0\u6216\u662f\u8bc4\u8ff0\u884c\u4e1a\u6709\u5174\u8da3\uff0c\u70b9\u6211\u52a0\u5165\u7f16\u8f91\u90e8<\/a><\/strong>\u3002\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1tougao@cailiaoren.com\u3002<\/p>\n

\u4eea\u5668\u8bbe\u5907\u3001\u8bd5\u5242\u8017\u6750\u3001\u6750\u6599\u6d4b\u8bd5\u3001\u6570\u636e\u5206\u6790\uff0c\u627e\u6750\u6599\u4eba<\/a><\/strong>\u3001\u4e0a\u6d4b\u8bd5\u8c37<\/a><\/strong>\uff01<\/p>\n","protected":false},"excerpt":{"rendered":"

\u3010\u5f15\u8a00\u3011 \u81eaWilliams\u7b491969\u5e74\u9996\u6b21\u62a5\u9053\u540e\uff0c\u67d4\u6027\u7535\u6781\u6750\u6599\u7531\u4e8e\u5176\u8bbe\u8ba1\u7684\u591a\u6837\u6027\u3001\u7075\u6d3b\u6027\u3001\u4f4e\u6210\u672c\u548c\u73af\u4fdd\u7684\u7279\u6027\u5438\u5f15\u4e86\u8bf8\u591a\u79d1\u5b66\u5bb6\u7684\u7814\u7a76\u5174\u8da3\u3002\u7136\u800c\u5bfc\u7535\u805a\u5408\u7269\u57fa\u6709\u673a\u6750…<\/p>\n","protected":false},"author":4931,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[],"class_list":["post-110424","post","type-post","status-publish","format-standard","hentry","category-jiedu"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/110424"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/4931"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=110424"}],"version-history":[{"count":7,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/110424\/revisions"}],"predecessor-version":[{"id":111128,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/110424\/revisions\/111128"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=110424"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=110424"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=110424"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}