{"id":110403,"date":"2017-11-08T06:30:41","date_gmt":"2017-11-07T22:30:41","guid":{"rendered":"\/\/m.iemloyee.com\/?p=110403"},"modified":"2017-11-06T19:09:04","modified_gmt":"2017-11-06T11:09:04","slug":"%e4%b8%ad%e5%9b%bd%e7%9f%b3%e6%b2%b9%e5%a4%a7%e5%ad%a6%e5%8d%8e%e4%b8%9c%e4%b8%87%e6%96%87%e6%98%8e%e5%8d%9a%e5%a3%abnat-commun-%ef%bc%9a%e5%b0%86%e5%b7%b4%e6%af%94%e8%80%b6%e5%8f%8d%e5%ba%94","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=110403","title":{"rendered":"\u4e2d\u56fd\u77f3\u6cb9\u5927\u5b66(\u534e\u4e1c)\u4e07\u6587\u660e\u535a\u58ebNat. Commun.\uff1a\u5c06\u5df4\u6bd4\u8036\u53cd\u5e94\uff08Barbier Reaction\uff09\u5f15\u5165\u9ad8\u5206\u5b50\u5316\u5b66\u9886\u57df"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n

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\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

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\u8fd1\u65e5\uff0c\u4e2d\u56fd\u77f3\u6cb9\u5927\u5b66\uff08\u534e\u4e1c\uff09<\/strong>\u7684\u4e07\u6587\u660e<\/strong>\u535a\u58eb\u5728Nat.Commun<\/strong>\u4e0a\u53d1\u8868\u4e86\u4e00\u7bc7\u5173\u4e8e\u5c06Barbier Reaction<\/strong>\u5f15\u5165\u9ad8\u5206\u5b50\u5408\u6210\u9886\u57df\u7684\u6587\u7ae0\uff0c\u9898\u4e3a\u201cThe introduction of the Barbier reaction into polymer chemistry<\/strong>\u201d\u3002\u8be5\u6587\u7ae0\u4ecb\u7ecd\u4e86\u5df4\u6bd4\u8036\u9ad8\u5206\u5b50\u5316\u5b66\u53cd\u5e94\u3002\u901a\u8fc7\u540c\u65f6\u5305\u542b\u6709\u673a\u5364\u5316\u7269\u548c\u82ef\u7532\u9170\u57fa\u7684\u5355\u4f53\u7684Barbier\u52a0\u805a\uff08A2<\/sub> + B2<\/sub>\u578b\u548cAB\u578b\uff09\uff0c\u5df2\u7ecf\u6210\u529f\u5236\u5907\u4e86\u4e00\u7cfb\u5217\u82ef\u7532\u9187\u805a\u5408\u7269\uff0c\u8fd9\u4e9b\u805a\u5408\u7269\u663e\u793a\u51fa\u7279\u6b8a\u7684\u523a\u6fc0\u54cd\u5e94\u6027\uff0c\u53ef\u5e94\u7528\u4e8e\u53cc\u91cd\u70ed\u54cd\u5e94\uff08\u53d1\u5149\u548c\u6d4a\u5ea6\uff09\u805a\u5408\u7269\u6750\u6599\u9886\u57df\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n

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\u56fe<\/strong>3<\/strong> PTPM-1<\/strong>\u7684\u805a\u96c6\u8bf1\u5bfc\u53d1\u5149\uff08<\/strong>AIE<\/strong>\uff09\u7279\u6027<\/strong>
\n <\/strong><\/p>\n

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a\uff09\u53d1\u5c04\u5149\u8c31\u3002<\/p>\n

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\u56fe<\/strong>4 \u00a0PTPM-1<\/strong>\u7684\u53cc\u91cd\uff08\u8367\u5149\u548c\u6d51\u6d4a\u5ea6\uff09\u70ed\u654f\u54cd\u5e94\u7279\u6027<\/strong><\/p>\n

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b\uff09\u53d1\u5c04\u5149\u8c31\uff08346nm\uff09\u3002<\/p>\n

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\u56fe<\/strong>5\u00a0 PTPM-1<\/strong>\u7684\u5e94\u7528<\/strong>
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c\uff09RB\u8584\u819c\u3001PTPM-1\u8584\u819c\u548c1 wt\uff05\u7684RB\/PTPM-1\u8584\u819c\u7684\u53d1\u5c04\u5149\u8c31\u3002<\/p>\n

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\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n

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\u6587\u732e\u94fe\u63a5<\/strong>\uff1aThe introduction of the Barbier reaction into polymer chemistry<\/a>\uff08Nat. Commun.\uff0c2017\uff0cDOI: 10.1038\/s41467-017-01472-w\uff09<\/p>\n

\u4e07\u6587\u660e<\/strong>\u535a\u58eb\u4ecb\u7ecd\uff1a<\/p>\n

\u4e07\u6587\u660e\u535a\u58eb\u957f\u671f\u4ece\u4e8b\u9ad8\u5206\u5b50\u5408\u6210\u65b9\u6cd5\u5b66\u7684\u5f00\u53d1\u548c\u5bf9\u9ad8\u5206\u5b50\u6750\u6599\u7ed3\u6784\u3001\u7ec4\u88c5\u4f53\u4ee5\u53ca\u529f\u80fd\u8c03\u8282\u65b9\u9762\u7684\u7814\u7a76\u3002\u4e07\u6587\u660e\u535a\u58eb\u53d1\u660e\u4e86\u805a\u5408\u8bf1\u5bfc\u81ea\u7ec4\u88c5\uff08Polymerization-Induced Self-Assembly\uff0c\u5373PISA\uff09\u805a\u5408\u65b9\u6cd5<\/strong>\u3002\u8be5\u65b9\u6cd5\u662f\u5f53\u524d\u5236\u5907\u9ad8\u6d53\u5ea6\u4e30\u5bcc\u5f62\u8c8c\u7ed3\u6784\u9ad8\u5206\u5b50\u7eb3\u7c73\u6750\u6599\u7684\u5148\u8fdb\u6280\u672f\uff0c\u662f\u9ad8\u5206\u5b50\u5408\u6210\u9886\u57df\u7684\u91cd\u8981\u7814\u7a76\u70ed\u70b9\uff0c\u73b0\u5df2\u5165\u9009\u56fd\u5bb6\u81ea\u7136\u79d1\u5b66\u57fa\u91d1\u5316\u5b66\u79d1\u5b66\u90e8\u9ad8\u5206\u5b50\u79d1\u5b66\u7533\u62a5\u5173\u952e\u8bcd\u3002\u5728\u7f8e\u56fd\u5316\u5b66\u4f1a\u300a\u5927\u5206\u5b50\u300b\uff08Macromolecules\uff09\u6742\u5fd7\u521b\u520a50\u5468\u5e74\u7279\u522b\u5c55\u671b\u4e2d\uff0c\u8bfa\u8d1d\u5c14\u5316\u5b66\u5956\u5f97\u4e3b\u7f57\u4f2f\u7279\u00b7\u683c\u62c9\u5e03\uff08Robert H. Grubbs\uff09\u6559\u6388\u7279\u522b\u5355\u72ec\u6307\u51fa\u4e86\u8be5\u65b9\u6cd5\u7684\u91cd\u8981\u6027\u548c\u524d\u77bb\u6027\uff0c\u5e76\u5c06\u5176\u5217\u4e3a\u9ad8\u5206\u5b50\u6d3b\u6027\u805a\u5408\u9886\u57df6\u5927\u672a\u6765\u65b9\u5411\u4e4b\u4e00\u3002\u4e07\u6587\u660e\u535a\u58eb\u4ee5\u7b2c\u4e00\u4f5c\u8005\/\u901a\u8baf\u4f5c\u8005\u5728Nature Communications\u3001Angewandte Chemie International Edition\u3001ACS Macro Letters\u3001Macromolecules\u3001Chemical Communications\u3001Polymer Chemistry\u3001Macromolecular Rapid Communications\u7b49\u56fd\u9645\u8457\u540d\u6742\u5fd7\u4e0a\u53d1\u8868\u6587\u7ae022\u7bc7\uff08\u5176\u4e2dSCI\u4e00\u533a17\u7bc7\uff09\u3002\u6587\u7ae0\u88ab\u603b \u5f15900\u4f59\u6b21\uff0c\u5176\u4e2d3\u7bc7\u6587\u7ae0\u5355\u7bc7\u88ab\u5f15\u8d85\u8fc7\u767e\u6b21\u3002\u73b0\u4e3a\u591a\u5bb6\u77e5\u540d\u6742\u5fd7\u7684\u7279\u9080\u5ba1\u7a3f\u4eba\uff0c\u5982Advanced Functional Materials\u3001Chemical Communications\u7b49\u3002<\/p>\n

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