{"id":110088,"date":"2017-11-07T14:00:50","date_gmt":"2017-11-07T06:00:50","guid":{"rendered":"\/\/m.iemloyee.com\/?p=110088"},"modified":"2017-11-08T13:25:08","modified_gmt":"2017-11-08T05:25:08","slug":"corros-sci-%e4%bd%8e%e7%a2%b3%e9%92%a2%e5%9c%a8%e6%b5%b7%e6%b0%b4%e5%92%8c%e6%b2%89%e6%b7%80%e7%89%a9%e7%95%8c%e9%9d%a2%e5%a4%84%e7%9a%84%e8%85%90%e8%9a%80%e6%9c%ba%e7%90%86%e5%92%8c%e5%8a%a8","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=110088","title":{"rendered":"Corros. Sci. \uff1a\u4f4e\u78b3\u94a2\u5728\u6d77\u6c34\u548c\u6c89\u6dc0\u7269\u754c\u9762\u5904\u7684\u8150\u8680\u673a\u7406\u548c\u52a8\u529b\u5b66"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n

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\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u6cd5\u56fd\u62c9\u7f57\u8c22\u5c14\u5927\u5b66Ph. Refait\uff08\u901a\u8baf\u4f5c\u8005\uff09\u56e2\u961f<\/strong>\u5728Corros. Sci.<\/strong>\u4e0a\u53d1\u8868\u4e86\u4e00\u7bc7\u9898\u4e3a\u201cCorrosion of mild steel at the seawater\/sediments interface: mechanisms and kinetics<\/strong>\u201d\u7684\u6587\u7ae0\u3002\u8be5\u7814\u7a76\u56e2\u961f\u4e3a\u7814\u7a76\u4f4e\u78b3\u94a2\u5728\u6d77\u6d0b\u6c89\u6dc0\u7269\u4e0e\u6d77\u6c34\u754c\u9762\u5904\u7684\u8150\u8680\u673a\u7406\u548c\u52a8\u529b\u5b66\uff0c\u5c06S355NL\u78b3\u94a2\u6302\u7247\u6d78\u6ca1\u5728\u6d45\u5c42\u5929\u7136\u6d77\u6d0b\u6c89\u6dc0\u7269\u4e2d\u8fbe6\u4e2a\u6708\u81f36\u5e74\uff0c\u4ee5\u62c9\u66fc\u5149\u8c31\u548cXRD\u5206\u6790\u8150\u8680\u4ea7\u7269\u6210\u5206\uff0c\u901a\u8fc7\u6d4b\u91cf\u5269\u4f59\u539a\u5ea6\u8ba1\u7b97\u8150\u8680\u901f\u7387\u3002\u7814\u7a76\u7ed3\u679c\u8868\u660e\u4f4e\u78b3\u94a2\u5728\u6d77\u6c34\u6c89\u6dc0\u7269\u4e2d\u8150\u8680\u751f\u6210\u4e86\u94c1\u7684\u786b\u5316\u7269\u548c4\u79cd\u4e0d\u540c\u7684\u7eff\u9508\u5316\u5408\u7269\uff0c\u7eff\u9508\u4ea7\u7269\u4e0d\u540c\u8868\u660e\u4ecb\u8d28\u6210\u5206\u5b58\u5728\u5c40\u90e8\u5dee\u5f02\uff1b\u4f4e\u78b3\u94a2\u5728\u6d77\u6c34\u6c89\u6dc0\u7269\u4e2d\u7684\u5c40\u90e8\u8150\u8680\u901f\u7387\u53ef\u9ad8\u8fbe140\u03bcm yr-1<\/sup>\u3002<\/p>\n

\u3010\u56fe\u6587\u89e3\u8bfb\u3011<\/strong><\/p>\n

\u56fe1 \u88c5\u6709\u4f4e\u78b3\u94a2\u6302\u7247\u7684\u73bb\u7483\u5bb9\u5668\u00a0<\/strong><\/p>\n

\"\"<\/p>\n

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\u62c9\u66fc\u5cf0211cm-1<\/sup>\u548c287-289cm-1<\/sup>\u662fFeS\u7eb3\u7c73\u6676\u7684\u7279\u5f81\u5cf0\uff1b\u4f4d\u4e8e256-258cm-1<\/sup>\u3001308-313cm-1<\/sup>\u3001318-322cm-1<\/sup>\u548c355cm-1<\/sup>\u5904\u7684\u62c9\u66fc\u5cf0\u7531\u542bFe\uff08III\uff09\u7684\u786b\u94c1\u77ff\u4ea7\u751f\uff1b\u7eff\u9508\u7684\u7279\u5f81\u5cf0\u4e3b\u8981\u96c6\u4e2d\u5728425-440m-1<\/sup>\u548c510-530cm-1<\/sup>\uff0c\u4f4d\u4e8e163 cm-1<\/sup>\u548c235-239 cm-1<\/sup>\u7684\u62c9\u66fc\u5cf0\u4e5f\u53ef\u5f52\u56e0\u4e8e\u7eff\u9508\u3002<\/p>\n

\u56fe4 \u6302\u7247\u8868\u9762\u8150\u8680\u4ea7\u7269XRD<\/strong><\/p>\n

\"\"<\/p>\n

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A=\u6587\u77f3\uff1bC=\u65b9\u89e3\u77f3\uff1bGC=\u78b3\u9178\u76d0\u7eff\u9508\uff1bGR=\u786b\u9178\u76d0\u7eff\u9508\uff1bGRy=\u201cy\u201d\u7eff\u9508\uff08\u89c1\u6587\u672c\uff09\uff1bI=\u4f0a\u5229\u77f3\uff1bK=\u9ad8\u5cad\u77f3\uff1bQ=\u77f3\u82f1\u3002\u884d\u5c04\u7ebf\u7531\u76f8\u5e94\u7684\u5bc6\u52d2\u6307\u6570\u8868\u793a\u3002<\/p>\n

\u56fe5 C6\u6302\u7247\u8868\u9762\u8150\u8680\u4ea7\u7269\u62c9\u66fc\u5149\u8c31<\/strong><\/p>\n

\"\"<\/p>\n

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(a) B\u9762\u4e0a\u90e8\u6837\u54c1XRD\u56fe\u6837\uff1b<\/p>\n

(b) B\u9762\u4e0b\u90e8\u6837\u54c1XRD\u56fe\u6837\u3002<\/p>\n

C=\u65b9\u89e3\u77f3\uff1bGC=\u78b3\u9178\u76d0\u7eff\u9508\uff1bGR=\u786b\u9178\u76d0\u7eff\u9508\uff1bGRx=\u201cx\u201d\u7eff\u9508\uff08\u89c1\u6587\u672c\uff09\uff1bGRy=\u201cy\u201d\u7eff\u9508\uff08\u89c1\u6587\u672c\uff09\uff1bI=\u4f0a\u5229\u77f3\uff1bK=\u9ad8\u5cad\u77f3\uff1bMcK=\u786b\u94c1\u77ff\uff1bQ=\u77f3\u82f1\uff1bS=\u83f1\u94c1\u77ff\u3002\u884d\u5c04\u7ebf\u7531\u76f8\u5e94\u7684\u5bc6\u52d2\u6307\u6570\u8868\u793a\u3002<\/p>\n

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\"\"<\/p>\n

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(a) \u53d6\u81eaA\u9762\u4e0b\u90e8\u6837\u54c1\u7684\u6574\u4f53XRD\u56fe\u6837\uff1b<\/p>\n

(b)-(c) \u5206\u522b\u4e3aGRxy003\u548cGRxy006\u884d\u5c04\u7ebf\u7279\u5b9a\u89d2\u5ea6\u533a\u57df\uff1b\u5176\u4e2d\u70b9\u4e3a\u5b9e\u9a8c\u6570\u636e\uff0c\u9ed1\u7ebf\u4e3a\u8ba1\u7b97\u66f2\u7ebf\uff0c\u7070\u7ebf\u4e3a\u5404\u884d\u5c04\u5cf0\u3002<\/p>\n

C=\u65b9\u89e3\u77f3\uff1bGRx=\u201cx\u201d\u7eff\u9508\uff08\u89c1\u6587\u672c\uff09\uff1bGRy=\u201cy\u201d\u7eff\u9508\uff08\u89c1\u6587\u672c\uff09\uff1bI=\u4f0a\u5229\u77f3\uff1bQ=\u77f3\u82f1\uff1bS=\u83f1\u94c1\u77ff\u3002\u884d\u5c04\u7ebf\u7531\u76f8\u5e94\u7684\u5bc6\u52d2\u6307\u6570\u8868\u793a\u3002<\/p>\n

\u88688 d<\/em>003<\/sub>\u8ba1\u7b97\u5e73\u5747\u503c\u4e0e\u53c2\u8003\u503c\u6bd4\u8f83<\/strong><\/p>\n\n\n\n\n\n\n
GR compound<\/td>\n\n

Computed d<\/em>003<\/sub>(nm)<\/p>\n<\/td>\n

Reference value of d<\/em>003<\/sub>(nm) and corresponding literature data<\/td>\n<\/tr>\n
GR(CO3<\/sub>2-<\/sup>)<\/td>\n0.755\u00b10.002<\/td>\n0.750\u00b10.005[34, 40]<\/td>\n<\/tr>\n
GRx<\/td>\n0.792\u00b10.003<\/td>\n0.795\u00b10.002 for GR(Cl–<\/sup>)[15]<\/td>\n<\/tr>\n
GRy<\/td>\n0.781\u00b10.002<\/td>\n0.784\u00b10.002 for GR(C2<\/sub>O4<\/sub>2-<\/sup>)[31]<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n

\u56fe9 C6\u6302\u7247B\u9762\u4e0d\u540c\u533a\u57df\u793a\u610f\u56fe\u53ca\u76f8\u5e94\u8150\u8680\u901f\u7387\u5e73\u5747\u503c\u00a0<\/strong><\/p>\n

\"\"<\/p>\n

\u989c\u8272\u8d8a\u6df1\u8868\u660e\u8150\u8680\u901f\u7387\u8d8a\u9ad8\u3002<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n

\u7814\u7a76\u7ed3\u679c\u8868\u660e\uff0c\u8150\u8680\u4ea7\u7269\u4e2d\u5b58\u5728\u591a\u79cd\u7eff\u9508\u4e0eFeS\u4f34\u751f\uff0c\u5e76\u9996\u6b21\u53d1\u73b0\u94a2\u7684\u81ea\u7136\u73af\u5883\u4e2d\u9664\u53ef\u4ee5\u751f\u6210\u8150\u8680\u4ea7\u7269GR\uff08CO3<\/sub>2-<\/sup>\uff09\u3001GR\uff08SO4<\/sub>2-<\/sup>\uff09\u548cGR\uff08Cl–<\/sup>\uff09\u4e4b\u5916\uff0c\u8fd8\u53ef\u4ee5\u751f\u6210GR\uff08C2<\/sub>O4<\/sub>2-<\/sup>\uff09\uff1b\u4f4e\u78b3\u94a2\u8868\u9762\u8150\u8680\u901f\u7387\u5b58\u5728\u4e0d\u540c\uff0c\u6302\u7247\u4e0b\u90e8\u7684\u8150\u8680\u901f\u7387\u66f4\u5927\uff0c\u8bf4\u660e\u867d\u7136\u6d77\u6d0b\u6c89\u79ef\u7269\u4e2d\u4f4e\u78b3\u94a2\u8150\u8680\u901f\u7387\u8f83\u4f4e\uff0c\u4f46\u5c40\u90e8\u8150\u8680\u660e\u663e\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/strong>Corrosion of mild steel at the seawater\/sediments interface: mechanisms and kinetics<\/a>\u00a0 (Corros. Sci., 7-4-2017, DOI:10.1016\/j.corsci.2017.10.016)<\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u91d1\u5c5e\u7ec4\u8a79\u82f1\u6770\u7f16\u8bd1\uff0c\u70b9\u6211\u52a0\u5165\u6750\u6599\u4eba\u7f16\u8f91\u90e8<\/a>\u3002<\/p>\n

\u6750\u6599\u6d4b\u8bd5\uff0c\u6570\u636e\u5206\u6790\uff0c<\/strong>\u4e0a\u6d4b\u8bd5\u8c37<\/a>\uff01<\/p>\n","protected":false},"excerpt":{"rendered":"

\u3010\u5f15\u8a00\u3011 \u7531\u4e8e\u666e\u904d\u8ba4\u4e3a\u6d77\u6d0b\u6c89\u6dc0\u533a\u7684\u8150\u8680\u901f\u7387\u8f83\u4f4e(\u6bd4\u6d78\u6ca1\u533a\u3001\u6f6e\u6c50\u533a\u7b49\u4f4e1-2\u4e2a\u6570\u91cf\u7ea7)\uff0c\u56e0\u6b64\u8fd1\u5e74\u6765\u8f83\u5c11\u5f00\u5c55\u4f4e\u78b3\u94a2\u5728\u6d77\u6d0b\u6c89\u6dc0\u7269\u4e2d\u8150\u8680\u884c\u4e3a\u65b9\u9762\u7684\u7814\u7a76\u3002 \u3010\u6210\u679c\u7b80\u4ecb\u3011 …<\/p>\n","protected":false},"author":5240,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[],"class_list":["post-110088","post","type-post","status-publish","format-standard","hentry","category-jiedu"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/110088"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/5240"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=110088"}],"version-history":[{"count":7,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/110088\/revisions"}],"predecessor-version":[{"id":110149,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/110088\/revisions\/110149"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=110088"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=110088"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=110088"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}