{"id":109695,"date":"2017-11-05T14:00:08","date_gmt":"2017-11-05T06:00:08","guid":{"rendered":"\/\/m.iemloyee.com\/?p=109695"},"modified":"2017-11-04T14:12:03","modified_gmt":"2017-11-04T06:12:03","slug":"adv-mater%ef%bc%9a%e7%94%a8%e4%ba%8e%e6%b0%b4%e5%88%86%e8%a7%a3%e5%82%ac%e5%8c%96%e7%9a%84%e9%93%b1%e5%9f%ba%e5%a4%9a%e5%ad%94%e7%ba%b3%e7%b1%b3%e6%9d%90%e6%96%99","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=109695","title":{"rendered":"Adv. Mater\uff1a\u7528\u4e8e\u6c34\u5206\u89e3\u50ac\u5316\u7684\u94f1\u57fa\u591a\u5b54\u7eb3\u7c73\u6750\u6599"},"content":{"rendered":"

\u3010\u5f15\u8a00<\/strong>\u3011<\/p>\n

\u7535\u5316\u5b66\u6c34\u5206\u89e3\u6280\u672f\u662f\u4e00\u79cd\u53ef\u6301\u7eed\u3001\u73af\u4fdd\u5e76\u4e14\u4f4e\u6210\u672c\u7684\u80fd\u6e90\u518d\u751f\u6280\u672f\uff0c\u800cPt\u548cIr\u7684\u7eb3\u7c73\u6676\u4f53\u6750\u6599\u5219\u662f\u4fc3\u8fdb\u6790\u6c22\u53cd\u5e94\uff08CO\uff09\u548c\u6790\u6c27\u53cd\u5e94\uff08OER\uff09\u7684\u6700\u4f73\u91d1\u5c5e\u50ac\u5316\u5242\u3002\u7136\u800c\uff0c\u7531\u4e8e\u6790\u6c22\u53cd\u5e94\u548c\u6790\u6c27\u53cd\u5e94\u52a8\u529b\u5b66\u4e0a\u4e0d\u7a33\u5b9a\uff0c\u4e25\u91cd\u5f71\u54cd\u4e86\u50ac\u5316\u5242\u5185\u5728\u7684\u7535\u50ac\u5316\u6d3b\u6027\u3002\u8fd1\u65e5\uff0c\u6709\u5b66\u8005\u8bbe\u8ba1\u51fa\u4e86\u9ad8\u50ac\u5316\u6027\u80fd\u7684\u8d35\u91d1\u5c5e\u7eb3\u7c73\u50ac\u5316\u5242\uff0c\u5176\u62e5\u6709\u4f18\u5f02\u7684\u50ac\u5316\u6548\u7387\u548c\u8010\u4e45\u6027\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb<\/strong>\u3011<\/p>\n

\u8fd1\u65e5\uff0c\u5317\u4eac\u5927\u5b66\u90ed\u5c11\u519b\u6559\u6388<\/strong>(\u901a\u8baf\u4f5c\u8005<\/strong>)\u56e2\u961f\u5728Adv. Mater<\/strong>\u4e0a\u53d1\u5e03\u4e86\u4e00\u7bc7\u5173\u4e8e\u7535\u50ac\u5316\u5242\u7684\u6587\u7ae0\uff0c\u9898\u4e3a\u201cIridium-Based Multimetallic Porous Hollow Nanocrystals for Efficient Overall-Water-Splitting Catalysis<\/strong>\u201d\u3002 \u4f5c\u8005\u901a\u8fc7Fe3+<\/sup>\u79bb\u5b50\u523b\u8680\u94f1(Ir)\u57fa\u591a\u91d1\u5c5e\u56fa\u4f53\u7eb3\u7c73\u6676\u4f53\u7684\u65b9\u6cd5\uff0c\u63a7\u5236IrM (M = Co, Ni, CoNi) \u591a\u91d1\u5c5e\u591a\u5b54\u4e2d\u7a7a\u7eb3\u7c73\u6676\u4f53\uff08PHNC\uff09\u7684\u5408\u6210\u3002\u6b64\u5916\uff0c\u4f5c\u8005\u8fd8\u901a\u8fc7\u7b2c\u4e00\u539f\u7406\u8ba1\u7b97\u63ed\u793a\u4e86\u5408\u91d1\u5316Ir\u4e0e3d\u8fc7\u6e21\u91d1\u5c5e\u8bf1\u5bfc\u7684\u914d\u4f53\u6548\u5e94\u3002<\/p>\n

\u3010\u56fe\u7247\u5bfc\u8bfb<\/strong>\u3011<\/p>\n

\u56fe1 IrCoNi PHNC\u6750\u6599\u7684\u7ed3\u6784<\/strong><\/p>\n

\"\"
\n (a<\/strong>) IrCoNi PHNC\u6750\u6599\u7684\u5f62\u6210\u8fc7\u7a0b\u793a\u610f\u56fe\uff1b<\/p>\n

(b<\/strong>) \u6837\u54c1\u7684TEM\u7167\u7247;<\/p>\n

(c<\/strong>–d<\/strong>) \u6837\u54c1\u9ad8\u5206\u8fa8\u7387TEM\u7167\u7247\uff1b<\/p>\n

(e<\/strong>) \u6837\u54c1\u5927\u89d2\u5ea6\u73af\u5f62\u6697\u573a\uff08HAADF\uff09\u2014STEM\u56fe\u50cf\u548c\u5bf9\u5e94\u7684\u7ebf\u5256\u9762\uff1b<\/p>\n

(f<\/strong>) IrCoNi PHNC\u6750\u6599\u76f8\u5e94\u7684\u5143\u7d20\u6620\u5c04\u3002<\/p>\n

\u56fe2 IrCo\u548cIrNi PHNC\u6750\u6599\u7684\u7ed3\u6784\u7279\u5f81<\/strong><\/p>\n

\"\"<\/p>\n

(a<\/strong>–b<\/strong>) \u6837\u54c1\u7684TEM\u7167\u7247\uff1b<\/p>\n

(c<\/strong>–f<\/strong>) \u6837\u54c1\u9ad8\u5206\u8fa8\u7387TEM\u7167\u7247;<\/p>\n

(g<\/strong>–h<\/strong>) \u6837\u54c1\u7684HAADF\u2014STEM\u56fe\u50cf\u548c\u5bf9\u5e94\u7684\u7ebf\u5256\u9762\uff1b<\/p>\n

(i<\/strong>–j<\/strong>) IrCo\u548cIrNi\u76f8\u5e94\u7684\u5143\u7d20\u6620\u5c04\u3002<\/p>\n

\u56fe3 IrCo, IrCoNi\u548cIrNi PHNC\u6750\u6599\u7684\u6790\u6c22\u6790\u6c27\u6027\u80fd<\/strong><\/p>\n

\"\"<\/p>\n

(a<\/strong>) \u6781\u5316\u66f2\u7ebf\uff1b<\/p>\n

(b<\/strong>) \u6790\u6c22\u53cd\u5e94\u7684Tafel\u66f2\u7ebf;<\/p>\n

(c<\/strong>) \u6790\u6c22\u53cd\u5e94\u7684\u8d85\u7535\u52bf\uff1b<\/p>\n

(d<\/strong>–e<\/strong>) \u6781\u5316\u66f2\u7ebf\u548cTafel\u66f2\u7ebf\uff1b<\/p>\n

(f<\/strong>) \u6790\u6c27\u53cd\u5e94\u7684\u6807\u51c6\u5316\u7535\u6d41\u5bc6\u5ea6\u3002<\/p>\n

\u56fe4 \u6790\u6c27\u53cd\u5e94\u7684DFT\u6a21\u62df<\/strong><\/p>\n

\"\"
\n (a<\/strong>) IrCoNi\u6a21\u5f0f\u4e0bOH\uff0cO\u548cOOH\u4e2d\u95f4\u4f53\u7684\u7ed3\u6784\u51e0\u4f55\uff1b<\/p>\n

(b<\/strong>) OH\uff0cO\u548cOOH\u6d3b\u6027\u4e0e\u7ed3\u5408\u80fd\u7684\u5173\u7cfb;<\/p>\n

(c<\/strong>) Ir(\u9ed1\u8272)\u548cIrCoNi (\u7ea2\u8272)d\u6ce2\u6bb5\u7684DOS\uff1b<\/p>\n

(d<\/strong>) \u6790\u6c27\u53cd\u5e94\u53cd\u5e94\u8def\u5f84\u7684\u793a\u610f\u56fe\u3002<\/p>\n

\u56fe5 IrCoNi PHNC\u6750\u6599\u7684\u6574\u4f53\u6c34\u5206\u89e3\u6027\u80fd<\/strong><\/p>\n

\"\"
\n (a<\/strong>) IrCoNi \/ CFP\u6790\u6c22\u6790\u6c27\u53cd\u5e94\u7684\u6781\u5316\u66f2\u7ebf\uff1b<\/p>\n

(b<\/strong>) \u6837\u54c1\u4ee55mVs-1\u7684\u626b\u63cf\u901f\u7387\u8fdb\u884c\u603b\u4f53\u6c34\u5206\u89e3\u7684\u6781\u5316\u66f2\u7ebf;<\/p>\n

(c<\/strong>) \u6837\u54c110,500\u548c1000\u6b21\u5faa\u73af\u540e\u7684\u6574\u4f53\u6c34\u5206\u79bb\u6781\u5316\u66f2\u7ebf\uff1b<\/p>\n

(d<\/strong>) \u6837\u54c1\u7684\u7535\u6d41\u5bc6\u5ea6\u635f\u5931\u3002<\/p>\n

\u3010\u5c0f\u7ed3<\/strong>\u3011<\/p>\n

\u8fd9\u7bc7\u6587\u7ae0\u4ecb\u7ecd\u4e86\u4f7f\u7528Fe3+<\/sup>\u8680\u523bIrM\uff08M = Co\uff0cNi\uff09SNCs\u4f5c\u4e3a\u5408\u6210\u5177\u6709\u4e2d\u7a7a\u7ed3\u6784\u548c\u591a\u5b54\u7279\u5f81\u7684\u4e00\u7c7bIrCo\uff0cIrNi\u548cIrCoNi PHNC\u6750\u6599\u7684\u65b9\u6cd5\u3002DFT\u8ba1\u7b97\u8868\u660e\uff0c\u5408\u91d1Ir\u4e0e3d\u8fc7\u6e21\u91d1\u5c5e\u53ef\u4ee5\u901a\u8fc7\u5de5\u7a0b\u5316d\u5e26\u4e2d\u5fc3\u6765\u51cf\u5f31\u6c27\u57fa\u4e2d\u95f4\u4f53\u7684\u5438\u9644\uff0c\u4ece\u800c\u89e3\u91ca\u4e86\u8fc7\u6e21\u91d1\u5c5e\u7684\u6790\u6c27\u53cd\u5e94\uff08OER\uff09\u6d3b\u6027\u3002<\/p>\n

\u7814\u7a76\u7ed3\u679c\u8868\u660e\uff0cIrCoNi PHNC\u6750\u6599\u57282mA\u2022cm-2<\/sup>\u7684\u7535\u6d41\u5bc6\u5ea6\u4e0b\u663e\u793a\u4ec51.56V\u7684\u4f4e\u7535\u6c60\u7535\u538b\uff0c\u5e76\u4e14\u57281000\u6b21\u5faa\u73af\u8010\u4e45\u6027\u8bd5\u9a8c\u540e\u4ec5\u663e\u793a8mV\u7684\u504f\u632f\u66f2\u7ebf\u504f\u79fb\uff0c\u4ece\u800c\u57280.5m \u7684H2<\/sub>SO4<\/sub>\u6eb6\u6db2\u4e2d\u8868\u73b0\u51fa\u9ad8\u6548\u7684\u50ac\u5316\u6027\u80fd\u3002\u65b0\u578b\u591a\u91d1\u5c5ePHNC\u6750\u6599\u4f5c\u4e3a\u9ad8\u6d3b\u6027\u548c\u8010\u7528\u7684\u53cc\u529f\u80fd\u7535\u50ac\u5316\u5242\u5177\u6709\u826f\u597d\u7684\u524d\u666f\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5<\/strong>\uff1a Iridium-Based Multimetallic Porous Hollow Nanocrystals for Efficient Overall-Water-Splitting Catalysis <\/a>(Adv. Mater, 30 October, 2017 , DOI: 10.1002\/adma.201703798\uff09<\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u7f16\u8f91\u90e8\u91d1\u5c5e\u5b66\u672f\u7ec4jcfxs01\u4f9b\u7a3f\uff0c\u6750\u6599\u725b\u7f16\u8f91\u6574\u7406\u3002<\/p>\n

\u6750\u6599\u725b\u7f51\u4e13\u6ce8\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u53ca\u884c\u4e1a\u8fdb\u5c55\uff0c\u8fd9\u91cc\u6c47\u96c6\u4e86\u5404\u5927\u9ad8\u6821\u7855\u535a\u751f\u3001\u4e00\u7ebf\u79d1\u7814\u4eba\u5458\u4ee5\u53ca\u884c\u4e1a\u4ece\u4e1a\u8005\uff0c\u5982\u679c\u60a8\u5bf9\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u8fdb\u5c55\uff0c\u89e3\u8bfb\u9ad8\u6c34\u5e73\u6587\u7ae0\u6216\u662f\u8bc4\u8ff0\u884c\u4e1a\u6709\u5174\u8da3\uff0c\u70b9\u6211\u52a0\u5165\u7f16\u8f91\u90e8\u5927\u5bb6\u5ead<\/a>\u3002<\/p>\n

\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1tougao@cailiaoren.com<\/a>\u3002<\/p>\n

\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1aRDD-2011-CHERISH\uff0c\u4efb\u4e39\u4e39\uff0c\u6211\u4eec\u4f1a\u9080\u8bf7\u5404\u4f4d\u8001\u5e08\u52a0\u5165\u4e13\u5bb6\u7fa4\u3002<\/strong><\/p>\n

\u6750\u6599\u6d4b\u8bd5\u3001\u6570\u636e\u5206\u6790\uff0c\u4e0a\u6d4b\u8bd5\u8c37<\/a>\uff01<\/strong><\/p>\n","protected":false},"excerpt":{"rendered":"

\u3010\u5f15\u8a00\u3011 \u7535\u5316\u5b66\u6c34\u5206\u89e3\u6280\u672f\u662f\u4e00\u79cd\u53ef\u6301\u7eed\u3001\u73af\u4fdd\u5e76\u4e14\u4f4e\u6210\u672c\u7684\u80fd\u6e90\u518d\u751f\u6280\u672f\uff0c\u800cPt\u548cIr\u7684\u7eb3\u7c73\u6676\u4f53\u6750\u6599\u5219\u662f\u4fc3\u8fdb\u6790\u6c22\u53cd\u5e94\uff08CO\uff09\u548c\u6790\u6c27\u53cd\u5e94\uff08OER\uff09\u7684\u6700\u4f73\u91d1\u5c5e\u50ac\u5316\u5242\u3002\u7136…<\/p>\n","protected":false},"author":4915,"featured_media":109702,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[116,18,33],"class_list":["post-109695","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-jiedu","tag-catalyst","tag-xinnengyuan","tag-nano"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/109695"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/4915"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=109695"}],"version-history":[{"count":6,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/109695\/revisions"}],"predecessor-version":[{"id":110130,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/109695\/revisions\/110130"}],"wp:featuredmedia":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/media\/109702"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=109695"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=109695"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=109695"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}