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BTC\u662f1,3,5-\u82ef\u4e09\u7fa7\u9178\u76d0\uff09\u4e2d[MIV<\/sup>6<\/sub>\uff08\u03bc3<\/sub>-O\uff094<\/sub>\uff08\u03bc3<\/sub>-ONa\uff094<\/sub>H6<\/sub>] 6-<\/sup>\u8282\u70b9\u7684\u5b9a\u91cf\u8f6c\u5316\u3002MIII<\/sup>H-BTC\u4e2d\u7684\u914d\u4f4d\u4e0d\u9971\u548cMIII<\/sup>H\u4e2d\u5fc3\u5bf9\u5421\u5576\u548c\u55b9\u5549\u76841,4-\u8131\u6eb4\u6c22\u5316\u548c\u6c22\u5316\u7845\u70f7\u5316\u5177\u6709\u9ad8\u6d3b\u6027\u548c\u9009\u62e9\u6027\u3002\u76f8\u5173\u6210\u679c\u4ee5\u9898\u4e3a\u201cTrivalent Zirconium and Hafnium Metal\u2013Organic Frameworks for Catalytic 1,4-Dearomative Additions of Pyridines and Quinolines<\/strong>\u201d\u53d1\u8868\u5728\u4e86Journal of the American Chemical Society<\/strong>\u4e0a\u3002<\/p>\n \u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n \u56fe1 \u5c06MIVCl2<\/sub>-BTC\u8fd8\u539f\u6210MIIIH-BTC<\/strong><\/p>\n \u8fd9\u79cd\u65b9\u6cd5\u63d0\u4f9b\u4e86\u7814\u7a76\u4ee5\u524d\u96be\u4ee5\u6349\u6478\u7684ZrIII<\/sup>\u7269\u8d28\u7684\u7535\u5b50\u6027\u8d28\u548c\u50ac\u5316\u6d3b\u6027\u7684\u72ec\u7279\u673a\u4f1a\u3002<\/p>\n \u56fe2 ZrIII<\/sup>H-BTC\u5408\u6210\u53ca\u6a21\u62df<\/strong><\/p>\n \uff08a\uff09\u901a\u8fc7ZrIVCl2<\/sub>-BTC\u7684\u6c2f\u5316\u7269\/\u6c22\u5316\u7269\u5206\u89e3\uff0c\u4ee5\u53ca\u968f\u540eH2<\/sub>\u7684\u53cc\u91d1\u5c5e\u8fd8\u539f\u6d88\u9664\u5408\u6210ZrIII<\/sup>H-BTC<\/p>\n \uff08b\uff09\u6a21\u62dfZr-BTC\uff08\u9ed1\u8272\uff09\uff0cZrIII<\/sup>H-BTC\uff08\u7ea2\u8272\uff09\u7684PXRD\u56fe\uff0cZrIII<\/sup>H-BTC\u7ecf\u8fc7\u5421\u5576\u787c\u6c22\u5316\uff08\u84dd\u8272\uff09\u548c\u6c22\u5316\u7845\u70f7\u5316\uff08\u7c89\u7ea2\u8272\uff09\u548cZrIVH-BTC\uff08\u7eff\u8272\uff09\u5904\u7406<\/p>\n \uff08c\uff09ZrVCl2<\/sub>-BTC\uff08\u5e95\u90e8\uff09\u548cZrIII<\/sup>H-BTC\uff08\u9876\u90e8\uff09\u7684Zr 3d XPS\u5149\u8c31<\/p>\n \uff08d\uff09\u5bf9ZrIVCl2<\/sub>-BTC\uff08\u9ed1\u8272\uff09\uff0cZrIII<\/sup>H-BTC\uff08\u7ea2\u8272\uff09\u548cZrIV<\/sup>H-BTC\uff08\u84dd\u8272\uff09\u7684XANES\u5206\u6790<\/p>\n \uff08e\uff09ZrIII<\/sup>H-BTC\u7684EXAFS\u62df\u5408<\/p>\n \u56fe3 EPR\u8c31\u5206\u6790<\/strong><\/p>\n \uff08a\uff09\u4eceZrIII<\/sup>H-BTC\u5411FcPF6<\/sub>\uff0cO2<\/sub>\u548c\u7532\u8418\u918c\u7684\u7535\u5b50\u8f6c\u79fb<\/p>\n \uff08b\uff09Zr\uff08O2<\/sub>\u00b7\uff09-BTC\u7684EPR\u8c31<\/p>\n \uff08c\uff09ZrIV<\/sup>H-BTC\u7ed3\u5408\u534a\u918c\u7684EPR\u8c31<\/p>\n \u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n \u6865\u8054\u6c27\u4ee3\/\u7fa7\u9178\u76d0\u914d\u4f53\u548cMOF\u6846\u67b6\u7684\u4f4d\u70b9\u5206\u79bb\u4f5c\u7528\u7a33\u5b9a\u4e86\u914d\u4f4d\u4e0d\u9971\u548cMIIIH\u4e2d\u5fc3\uff0c\u4e3a\u5421\u5576\u548c\u55b9\u5549\u76841,4-\u52a0\u6c22\u8131\u6c22\u548c1,4-\u6c22\u5316\u7845\u70f7\u5316\u63d0\u4f9b\u4e86\u9ad8\u6d3b\u6027\u548c\u9009\u62e9\u6027\u7684\u50ac\u5316\u5242\uff0c\u8fd9\u9879\u5de5\u4f5c\u8868\u660eSBU\u8f6c\u5316\u662f\u4e00\u79cd\u901a\u7528\u548c\u5f3a\u5927\u7684\u7b56\u7565\u3002<\/p>\n \u6587\u732e\u94fe\u63a5<\/strong>\uff1aTrivalent Zirconium and Hafnium Metal\u2013Organic Frameworks for Catalytic 1,4-Dearomative Additions of Pyridines and Quinolines<\/a>\uff08JACS,2017,DOI:10.1021\/ jacs.7b09093\uff09<\/p>\n \u672c\u6587\u7531\u6750\u6599\u4eba\u751f\u7269\u6750\u6599\u7ec4Allen\u4f9b\u7a3f\uff0c\u6750\u6599\u725b\u6574\u7406\u7f16\u8f91\u3002<\/p>\n \u6750\u6599\u725b\u7f51\u4e13\u6ce8\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u53ca\u884c\u4e1a\u8fdb\u5c55\uff0c\u8fd9\u91cc\u6c47\u96c6\u4e86\u5404\u5927\u9ad8\u6821\u7855\u535a\u751f\u3001\u4e00\u7ebf\u79d1\u7814\u4eba\u5458\u4ee5\u53ca\u884c\u4e1a\u4ece\u4e1a\u8005\uff0c\u5982\u679c\u60a8\u5bf9\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u8fdb\u5c55\uff0c\u89e3\u8bfb\u9ad8\u6c34\u5e73\u6587\u7ae0\u6216\u662f\u8bc4\u8ff0\u884c\u4e1a\u6709\u5174\u8da3\uff0c\u70b9\u6211\u52a0\u5165\u7f16\u8f91\u90e8\u5927\u5bb6\u5ead<\/a>\u3002<\/p>\n \u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1tougao@cailiaoren.com\u3002<\/p>\n \u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1aRDD-2011-CHERISH\uff0c\u4efb\u4e39\u4e39\uff0c\u6211\u4eec\u4f1a\u9080\u8bf7\u5404\u4f4d\u8001\u5e08\u52a0\u5165\u4e13\u5bb6\u7fa4\u3002<\/b><\/strong><\/p>\n<\/p>\n
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